Engineering Science and Materials Commons^™

Development Of Self-Healing Mechanisms For Asphalt Pavements, Max Abelardo Aguirre Deras

LSU Doctoral Dissertations

Self-healing mechanisms, such as microcapsules or hollow-fibers, filled with an asphalt rejuvenator present an emerging technology that would enhance an asphalt mixture’s resistance to cracking damage caused by vehicular and environmental loading. The objectives of this study were to: (a) Evaluate the effects of asphalt rejuvenators on hot-mix asphalt mixtures in order to test its effects on the fundamental engineering properties of the mixtures at high and intermediate temperatures; (b) Develop a synthesis procedure for production of microcapsules and hollow-fibers containing an asphalt rejuvenator; (c) Evaluate the self-healing efficiency of double-walled microcapsules and hollow-fibers filled with an asphalt rejuvenator, through …

A Coupled Thermo-Mechanical Theory Of Strain Gradient Plasticity For Small And Finite Deformations, Yooseob Song

LSU Doctoral Dissertations

In this work, a thermodynamically consistent coupled thermo-mechanical gradient enhanced continuum plasticity theory is developed for small and finite deformations. The proposed model is conceptually based on the dislocations interaction mechanisms and thermal activation energy. The thermodynamic conjugate microstresses are decomposed into energetic and dissipative components. This work incorporates the thermal and mechanical responses of microsystems. It addresses phenomena such as size and boundary effects and in particular microscale heat transfer in fast-transient processes. Not only the partial heat dissipation caused by the fast transient time, but also the distribution of temperature caused by the transition from the plastic work …

Rice Hull Bioreactor For Recirculating Aquaculture, Marlon A. Greensword

LSU Doctoral Dissertations

The engineering of floating media biofilters has been optimized over the years. The backwashing process has made them more energy and water efficient. Likewise, moving bed bioreactors (MBBR) are gaining interest and popularity because they are relatively affordable to build. Yet, developing countries’ aquaculture production remains largely excluded from the advances made in recirculating aquaculture systems (RAS). This discrepancy is partially driven by the high costs of media such plastic beads and Kaldnes (KMT) media, commonly used in MBBR.

This dissertation evaluates the usability and profitability of rice hulls (RH), an abundant by-product in many developing nations, as a sinking …

Performance Evaluation And Characterization Of Encapsulated Calcium Nitrate For Self-Healing Concrete Applications, Jose Eduardo Milla

LSU Doctoral Dissertations

Self-healing concrete through microencapsulated calcium nitrate is a novel approach to enhance durability and decrease the costs associated with maintenance and repairs. However, to fully assess the potential of this technology, there are many questions to be answered, ranging from identifying the microcapsule properties that are successfully carry the healing agent, to the effect of the microcapsule size, concentration (by weight of cement), and morphology have on the intrinsic concrete material properties and self-healing potential. Hence, the objectives of this study were to: (a) Develop a microencapsulation procedure for calcium nitrate as the healing agent; (b) Measure the short-term healing …

Reuse And Recycling Drill Cuttings In Concrete Applications, Maziar Foroutan

LSU Master's Theses

Drill cutting (DC) is a major waste produced during petroleum extraction, which could present a major source of contamination to soil and groundwater, if not disposed of properly. The objective of this study aims to test the hypothesis that drill cuttings can be incorporated as an aggregate in the production of concrete, and is suitable for use in controlled, low-strength material (CLSM) for non-structural applications. To achieve this objective, the physical and consensus properties of drill cuttings were characterized. Concrete mixtures were designed for CLSM applications with and without drill cuttings sampled from two sources. Prepared concrete mixes were then …

Tribological And Dynamical Study Of An Automotive Transmission System, Meng Li

LSU Doctoral Dissertations

The transmission system is critical for automotive and heavy duty equipment due to its prominent role in the powertrain system, which is often challenged with degraded torque capacity and harsh dynamic response. Simulation-guided design can provide appropriate guidelines to resolve these problems with virtual analyses. In current study, the tribological and dynamical study of an automatic transmission is performed at two levels: a wet clutch and powertrain. In this dissertation, tribological study is performed for a wet clutch based on the thermohydrodynamic (THD) analysis that takes the following factors into account. • The groove effect (depth, area, and pattern) is …

Healing Mechanism Investigation Of Self-Healing Concrete By Microencapsulated Calcium Nitrate, Gabriel Andres Arce Amador

LSU Doctoral Dissertations

Durability of reinforced concrete structures depends highly on the integrity of the concrete which protects the structure from the environment. However, concrete is a brittle material and as such it is prone to cracking which allows for detrimental agents to penetrate the structure and produce early deterioration. Embedding microcapsules with chemical healing agents in concrete materials for self-healing applications as well as implementing SMAs as reinforcement of concrete structures for self-closing of cracks are both state-of-the-art techniques with enormous potential for enhancement of concrete infrastructure durability. In this work, both techniques are combined as an alternative for superior self-healing of …

Integration Of Shape-Memory Alloys And Self-Healing Microcapsules To Enhance Concrete Durability, Luis Adolfo Bonilla

LSU Doctoral Dissertations

Self-healing is a term that has not been used for building material until a few decades ago. The concept of developing a material that mimics what living organisms do, such as identify and repair damage, rather than interesting, constitutes a necessity in today’s deteriorated infrastructure. Concrete is one of the main building blocks that support our society’s roads, buildings, and dams. Increasing the service life of such structures will have an important socio-economic benefit in our society. Self-healing methods in concrete have been studied in order to minimize human intervention in maintenance procedures. Previous research in this area has provided …

Computational Studies On Fluid And Particle Dynamics, Chenguang Zhang

LSU Doctoral Dissertations

This dissertation is divided into two parts. The first part includes chapter 2 to 4, which focus on development and application of numerical algorithm on particle and fluid simulation. Starting with a pure granular system in a driven cavity setup (Chapter 2), we move on to the immersed boundary simulation of fluid solid interaction (Chapter 3). This part ends with a coupled immersed boundary-discrete particle implementation. The second part includes Chapter 5 and Appendix A, each deals with an independent problem and focuses more on the theoretical aspects. Chapter 5 deals with a classic fluid dynamics problem of thermal wave …

Internal Cooling Using Novel Swirl Enhancement Strategies In A Slot Shaped Single Pass Channel, Del Alan Segura

LSU Doctoral Dissertations

A series of heat transfer tests using a single pass slot shaped channel utilizing varying configurations of trapezoid shaped turbulence enhancement strip or varying configurations of high velocity jets issuing from side channels are studied. Thermochromatic Liquid Crystal techniques are used to determine local heat transfer coefficients, which are converted to normalized Nusselt values. The results show a marked improvement over traditional heat transfer enhancements used in the mid-span region of first stage turbine blades.

Analysis Of Disruptions In The Gulf Of Mexico Oil And Gas Industry Supply Chain And Related Economic Impacts, Negar Dahitaleghani

LSU Doctoral Dissertations

Catastrophic events are human and economic tragedies in collaboration. Oil spills have enormous impacts on the local economy of the area and for the local labor markets. The Deepwater Horizon oil spill was caused by an explosion on semisubmersible drilling rig (Macondo) on April 20, 2010. Another regional disaster, Hurricane Katrina as it ripped over the core of the Gulf of Mexico producing zone, one of the most important oil and gas production region. With Geological complexities, continued of drilling and production in GoM increases the risk of having leak/spill. Therefore, the Econometrics methods, and Modeling to forecast impacts of …

Analysis And Management Of The Price Volatility In The Construction Industry, Alireza Joukar

LSU Doctoral Dissertations

The problem of price volatility as it pertains to material and labor is a major source of risk and financial distress for all the participants in the construction industry. The overarching goal of this dissertation is to address this problem from both viewpoints of risk analysis and risk management. This dissertation offers three independent papers addressing this goal. In the first paper using the Engineering News Record Construction Cost Index (ENR CCI), a predictive model is developed. The model uses General Autoregressive Conditional Heteroscedastic (GARCH) approach which facilitates both forecasting of the future values of the CCI, and capturing and …

Numerical Simulations Of Wind Effects On Wave Nonlinearity And Hurricane-Induced Sediment Transport On Louisiana Coast, Ke Liu

LSU Doctoral Dissertations

The objective of this study is to model wind effects on wave nonlinearity and the sediment suspension, transport and redistribution caused by hurricanes. The following questions are addressed through numerical simulations: (1) How do winds affect wave triad interactions and wave shape in the shallow water? (2) What is the role of hurricanes in coastal landscape evolution? Do they create more erosion or deposition? (3) Where does the observed post-hurricane deposition on coastal wetlands come from? First, wind effects were incorporated into a Boussinesq-type wave model, and evolution equations were derived for triad interactions with winds. Second, a coupled modeling …

Production Of Fermentable Sugars From Energy Cane Bagasse, Saeed Oladi

LSU Doctoral Dissertations

Lignocellulosic biomass contains cellulose and hemicellulose which are composed of hexose and pentose sugars. These sugars can be used in the sustainable production of fuels and chemicals. However, the recalcitrant nature of lignocellulosic biomass makes this conversion a challenging process. An effective pretreatment can remove lignin, solubilize the hemicellulose, decrease cellulose crystallinity, and prepare the biomass for enzymatic hydrolysis and conversion into green renewable chemicals. The research study presented in this dissertation addressed some of the challenges associated with the conversion of lignocellulosic biomass into green fuels and chemicals. This study was divided into three main goals. The first goal …

Automated Generation And Visualization Of Initial Construction Schedules From Building Information Models, Yibrah Weldemihret Weldu

LSU Doctoral Dissertations

Recent advances in digital technology have had a significant influence on the quality and speed of sharing and communicating project information in the architecture, engineering, and construction (AEC) industry. The process of acquiring the design intent in order to develop and communicate project schedules, as critical components of project delivery, have similarly been benefitting from such progress. With the relatively recent techniques of Building Information Modeling (BIM) and its capability to integrate the facility design with its construction schedule, meaningul strides have been made in improving the information flow and eventually visualizing the final schedule in 4D. However, the need …

Thermo-Catalytic Upgrading Of Pyrolysis Vapors Using Electromagnetic Heating, Pranjali Devidas Muley

LSU Doctoral Dissertations

Electromagnetic heating offers several advantages such as rapid heating rates, accurate temperature control and energy efficiency over conventional reactors. The goal of this study was to design an effective and energy efficient catalytic reactor for pyrolysis vapor upgrading. An induction based catalytic reactor was designed for upgrading of pyrolysis vapors. The effect of catalyst bed temperatures (290°, 330° and 370°C) and biomass to catalyst ratios of 1, 1.5 and 2 was studied. The results were compared to conventional heating reactor. Induction heating reactor performance exceeded that of conventional heater. The biomass to catalyst ratio of 2 in combination with the …

Time-Resolved Investigations Of Continuous Flow Synthesis Of Nanomaterials And Catalysis Using Millifluidic Reactors For Biomass Conversion Reactors, Chelliah V Navin

LSU Doctoral Dissertations

Millifluidics can be used as a simple tool and convenient platform to perform in-situ investigations on nanoparticles synthesis to generate real-time information in a continuous flow fashion. These investigations can be used to observe the relationship between the structure and performance of nanoparticles for catalytic applications as a function of space and time. These improvements in nanoparticles research offer unique advantages to develop catalysts with molecular strategies. In order to showcase these advantages of the millifluidic reactors, here we: A. Extensively covered a complete literature review on Lab-on-a-chip devices for gold nanoparticle synthesis and as a catalyst support for continuous …

Constitutive Modeling And Experiments For The Micro And Nano Behaviors In Metals, Cheng Zhang

LSU Doctoral Dissertations

This work addresses the micro- and nano-behaviors in metals through constitutive modeling and experiments. The size effect encountered during nanoindentation experiments, which is known as indentation size effect (ISE), is investigated for metal materials. The ISE is believed to be related with the strain gradient at small indentation depths. Geometrically necessary dislocations (GNDs) are formed in order to accommodate the strain gradient, which results in the increase in the material hardness. The grain boundaries in polycrystalline materials play an important role on the material hardness during nanoindentation experiments as there is a soften-hardening segment in the curve of hardness as …

Integrated Sustainability And Resiliency Assessment Methodology For The Design Of Single-Family Residential Structures Subject To Wind And Flood Hazards, Elizabeth Chisolm Matthews

LSU Doctoral Dissertations

Sustainability and resiliency have become important in shaping the criteria in performance-based design objectives in the recent past and will continue to shape future design as climate change impacts and disasters become more prevalent. While much work has been carried out in developing tools to aid in sustainable and resilient performance-based design there is still much work to be done. It is evident that while sustainability and resiliency have mutual advantages there are also inherent conflicts between the two design approaches. Some of the conflict relates to the robustness required of resilient design, which may have higher environmental impacts than …

Automated Conversion Of Text Instructions To Human Motion Animation, Ravikumar Vishwanath Chimmalgi

LSU Master's Theses

Text to animation is the conversion of textual instructions to animations following and depicting those instructions. Text to animation is important to fields such as crime scene investigation, military special operations and storytelling where text is utilized. It is also useful for physical therapy where a doctor can factor in disability parameters in the 3D models and determine the safest therapy exercises for patients. It can be used in robotics, where robot assistants can be instructed to perform tasks through text instructions. In this research, a system was created to generate 3D animation of workouts from their textual instructions. An …

Interorganizational Collaboration And Systemic Change Framework For Building Information Modeling (Bim) Adoption, Rehema Joseph Monko

LSU Doctoral Dissertations

It was found that an integrated framework needs to be developed for the construction industry that allows optimized interorganizational collaboration and systemic change while using Building Information Modeling (BIM) technologies. The framework needs to be effective so the industry can adopt BIM through a set of interdependent activities beyond their organizational boundaries. The adoption has been proven difficult because of industry competitiveness and a fragmented work environment. Meanwhile, existing frameworks vary between studies. This research developed an integrated framework, identified critical factors, and provided an evaluation guide for interorganizational collaboration and set of coordinated changes necessary to adopt BIM. This …

Product Parameters Optimization For Double Purge Of C-Magma Integrated With Conventional Three-Boiling Crystallization Scheme To Improve Raw Sugar Whole Color, Luz Stella Polanco

LSU Doctoral Dissertations

Efficient crystallization in raw sugar production is the result of a combination of factors and responses that meet specific criteria. Matching a sugar quality standard, maximizing sugar yield, maximizing crystallization equipment capacity and minimizing heat requirement are all necessary optimization criteria. A double centrifugation or purge of C-magma is intended to improve raw sugar whole color by the reduction of color recirculation with the sugar crystal. Combining a three boiling crystallization scheme with a second centrifugation after the last crystallization stage required optimizing the input/output product parameters (purities) and the location of the liquid recycle component (double purge molasses) for …

Thiol-Ene Scaffolds As Synthetic Augments And Silicate Ceramics As Osteogenic Components For Bone Tissue Engineering Applications, Cong Chen

LSU Doctoral Dissertations

Bone tissue engineering approaches using polymer/ceramic composites show promise as effective biocompatible, absorbable, and osteoinductive materials. A novel class of in situ polymerizing thiol-acrylate based copolymers synthesized via an amine-catalyzed Michael addition was studied for its potential to be used in bone defect repair. Both pentaerythritol triacrylate-co-trimethylolpropane tris(3-mercaptopropionate) (PETA-co-TMPTMP) and PETA-co-TMPTMP with hydroxyapatite composites were fabricated in solid cast and foamed forms. These materials were characterized chemically and mechanically followed by an in vitro evaluation of the biocompatibility and chemical stability in conjunction with human adipose-derived mesenchymal pluripotent stem cells (hASC). The solid PETA-co-TMPTMP with and without hydroxyapatite (HA) exhibited …

Context Aware Textual Entailment, Soha Arab-Khazaeli

LSU Doctoral Dissertations

In conversations, stories, news reporting, and other forms of natural language, understanding requires participants to make assumptions (hypothesis) based on background knowledge, a process called entailment. These assumptions may then be supported, contradicted, or refined as a conversation or story progresses and additional facts become known and context changes. It is often the case that we do not know an aspect of the story with certainty but rather believe it to be the case; i.e., what we know is associated with uncertainty or ambiguity. In this research a method has been developed to identify different contexts of the input raw …

Risk-Based Wind Loss And Mitigation For Residential Wood Framed Construction, Fatemeh Orooji

LSU Doctoral Dissertations

As a result of increasing windstorm losses in the United States over the past 50 years, a variety of residential wind hazard mitigation methods have been suggested. Mitigation undoubtedly reduces windstorm losses; however, the expected economic risk reduction of mitigation practices over the life of the building depends on the building characteristics (i.e., capacity) and the intensity and occurrence of wind speeds (i.e., demand). Effective decision making requires estimation of potential future losses based on many variables. Many models, primarily mechanics-based simulation models, have been developed to predict building damage from wind events; however; fewer models of economic loss have …

Image-Based Modeling Of Porous Media Using Fem And Lagrangian Particle Tracking, Paula Cysneiros Sanematsu

LSU Doctoral Dissertations

The study of fundamental flow and transport processes at the pore scale is essential to understanding how the mechanisms affect larger, field-scale, processes that occur in oil and gas recovery, groundwater flow, contaminant transport, and CO2 sequestration. Pore-scale imaging and modeling is one of the techniques used to investigate these fundamental mechanisms. Although extensive development of pore-scale imaging and modeling has occurred recently, some areas still need further advances. In this work, we address two areas: (1) imaging of bulk proppants and proppant-filled fractures under varying loading stress and flow simulation in these systems and (2) nanoparticle (NP) transport modeling …

Developing Co-Current And Counter-Current Spray Drying Computational Fluid Dynamics (Cfd) Simulation Studies To Predict The Quality Of Microencapsulated Fish Oil With Egg White Hydrolysates Powders, Kevin Estuardo Mis Solval

LSU Doctoral Dissertations

Eggs are an excellent source of high quality protein containing all essential amino acids (EAA) including leucine. Food-grade protein hydrolysates can enhance the growth of lactic acid bacteria (LAB). Thermal degradation of bioactives normally occurs during microencapsulation by spray drying. Spray drying modeling using computational tools is essential to engineer new food powders and to minimize and thermal degradation of bioactives. The first chapter of this work discusses the optimization of an enzymatic process in terms of reaction temperature, pH, enzyme:substrate ratio, and reaction time using a response surface methodology (RSM) to produce food-grade protein hydrolysates from egg whites (EWH). …

Release, Stability And Functionality Of Nanodelivered Hydrophobic (Lutein And Beta-Carotene) And Hydrophilic (Folic Acid) Antioxidants Using Zein Nanoparticles, Thanida Chuacharoen

LSU Doctoral Dissertations

Nanodelivery systems enable innovations that can benefit foods and human health on a large scale in the coming years. The instabilities of antioxidants during food processing and during digestion are drawbacks that can be successfully addressed by nanoentrapment. This research provided technical strategies to synthesize zein nanoparticles loaded with hydrophobic/hydrophilic antioxidants, and to study the release profiles and physical stability of nanocarriers and chemical stability of entrapped bioactives under on-shelf and GI conditions. The results supported the potential of zein nanoparticles stabilized by surfactants to improve chemical stability of entrapped lutein, and to slowly release lutein under PBS conditions. Same …

Optimal Location Of Biomethane Gas Manufacturing Plants And Allocation Of Feedstock And Liquified Carbon Product, Bingqing Wu

LSU Doctoral Dissertations

Biomethane gas (BMG), known for its sustainability, low environmental impact, and high profitability, has received wide attention in recent years. To facilitate the process of making strategic plans for building a BMG production system, this dissertation leverages the mathematical modeling and optimization techniques to minimize the supply chain cost for such a system. Typical elements in a BMG production system consist of the local farms that produce the feedstock, the hubs that collect and store the feedstock produced by farms, the reactors that generate BMG from the feedstock transported from the hubs, the condensers that liquefy the BMG from the …

Synthesis And Characterization Of Novel Polyester Scaffolds From Sugarcane Industry By-Products For Use In Skin And Bone Tissue Engineering, Akanksha Kanitkar

LSU Doctoral Dissertations

The aim of this work was to synthesize non-toxic, biodegradable polyesters of aconitic acid, cinnamic acid and glycerol from by-products of the sugarcane industry as scaffolds for skin and bone tissue engineering. Utilizing the by-products, molasses and sugarcane bagasse, not only add value to the cane industry, but also paves path for synthesizing novel bio-based materials from the isolated specialty chemicals. Molasses contain an economically recoverable quantity of aconitic acid and its extraction was studied in detail as a part of this work. The yields of recovered aconitic acid varied from 25–69% depending on the extraction conditions. Under all the …