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Articles 2131 - 2160 of 3176

Full-Text Articles in Engineering Science and Materials

Corrosion Behaviors Of 316 Stainless Steel Weldment Studied By Array Reference Electrodes, Wang-Huo Yang, Rong-Gang Hu, Chen-Qing Ye, Wei Hang, Ning Li, Chang-Jian Lin Nov 2011

Corrosion Behaviors Of 316 Stainless Steel Weldment Studied By Array Reference Electrodes, Wang-Huo Yang, Rong-Gang Hu, Chen-Qing Ye, Wei Hang, Ning Li, Chang-Jian Lin

Journal of Electrochemistry

The array reference electrodes were developed to in situ measure the potential distributions of the welded 316 stainless steel in 12% FeCl3 solution, combined with metallographic analysis, polarization curve, EIS measurement and Kelvin volta potential imaging. It was indicated that the weld zone of metal suffered a serious preferential corrosion when immersed in the environment due to the distinct changes of structure and composition during the welding process. With time prolonging, the corrosion potential of the welding zone was negatively shifted to a maximum value, and then declined gradually. At 45 min immersion, the corrosion development from welding zone to …

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Electrocatalytic Determination Of 15 Kinds Of Phenolic Compounds By Novel Gold Nanoparticles-Modified Glassy Carbon Electrode, Yan-Ping Cui, Wei-Xing Wang, Chang-Zhu Yang, Wen-Hong Pu Nov 2011

Electrocatalytic Determination Of 15 Kinds Of Phenolic Compounds By Novel Gold Nanoparticles-Modified Glassy Carbon Electrode, Yan-Ping Cui, Wei-Xing Wang, Chang-Zhu Yang, Wen-Hong Pu

Journal of Electrochemistry

A gold nanoparticles modified glassy carbon electrode (Au/GCE) was used to detect 15 kinds of phenolic compounds. In the cyclic voltammetry measurements, the peak currents of phenolic compounds at Au/GCE were all increased as compared with GCE and planar gold electrodes, and the oxidation potentials were determined by the activity of analytes. Besides, electrocatalysis of salicylic acid was studied at Au/GCE. The results showed that, there was a good linear relationship between the oxidation current and the concentration of salicylic acid, and the current sensitivity was 1.8 fold higher than that obtained on GCE. Trace phenolic compounds determination could be …

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Preparation And Characterization Of Casno3 Anode Material For Lithium Ion Batteries, Ran Sun, Zi-Geng Liu, Ya-Qi Jiang Nov 2011

Preparation And Characterization Of Casno3 Anode Material For Lithium Ion Batteries, Ran Sun, Zi-Geng Liu, Ya-Qi Jiang

Journal of Electrochemistry

In this study the precursor CaSn(OH)6 was prepared via a hydrothermal process, and its composition, surface feature and phase-transition were characterized by XRD, SEM and DSC-TGA. The shapes of CaSn(OH)6 crystals were effectively controlled by adjusting the volumn ratio of H2O and CH3CH2OH solvents. Perovskite CaSnO3 could be obtained by calcination of CaSn(OH)6 at 800 ℃. The reversible capacity of 334.4 mAh/g with good cycling stability could be achieved with the CaSnO3 electrode.

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Preparation And Characterization Of The Lani0.6Fe0.4O3-δ Cathode For Intermediate Temperature Solid Oxide Fuel Cell, Hang Liu, Bo Huang, Xin-Jian Zhu Nov 2011

Preparation And Characterization Of The Lani0.6Fe0.4O3-δ Cathode For Intermediate Temperature Solid Oxide Fuel Cell, Hang Liu, Bo Huang, Xin-Jian Zhu

Journal of Electrochemistry

The LaNi0.6Fe0.4O3-δ as cathode material for intermediate temperature solid oxide fuel cell was prepared using a combustion synthesis technique. The X-ray diffraction (XRD) pattern showed that the single-phase LaNi0.6Fe0.4O3-δ perovskite could be obtained after heat treatment at 600°C. The TEM and SEM images of the synthesized powders revealed that the grains were 50-100nm. According to the electrochemical impedance spectra (EIS), the polarization resistance of the symmetric cell LaNi0.6Fe0.4O3-δ/ScSZ/LaNi0.6Fe0.4O3-δ sintered at 1050°C was the smallest (0.70Ω·cm2, 0.27Ω·cm2 …

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Preparation And Application Of Macroporous Ato/Sio2 Electrode In Electrochemical Degradation Of 4-Chlorophenol, Zhang-Lin Chai, Rui-Feng Zhang, Tong-Hu Xiao, Yun-Xiao Liang Nov 2011

Preparation And Application Of Macroporous Ato/Sio2 Electrode In Electrochemical Degradation Of 4-Chlorophenol, Zhang-Lin Chai, Rui-Feng Zhang, Tong-Hu Xiao, Yun-Xiao Liang

Journal of Electrochemistry

The macroporous ATO/SiO2 materials were prepared through multiple steps of hydrolysis deposition in ethylene glycol and acetonitrile mixed solutions of SnCl2/SbCl3 and subsequent calcination at high temperature. The structures of the obtained materials were characterized by means of SEM and XRD. The results showed that the nano-ATO chemically deposited on the SiO2 support underwent well-controlled aggregation and recrystallization to form a sandwich structure (ATO-SiO2-ATO). Through four times loading of ATO the volume resistivity and the specific surface area reached 10·cm and 77 m2·g-1, respectively. The oxygen evolution potential on …

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Dynamic Modeling And Characteristic Analysis Of Proton Exchange Membrane Fuel Cell, Qiu-Hong Jia, Ming Han, Bin Deng, Cai-Zhi Zhang Nov 2011

Dynamic Modeling And Characteristic Analysis Of Proton Exchange Membrane Fuel Cell, Qiu-Hong Jia, Ming Han, Bin Deng, Cai-Zhi Zhang

Journal of Electrochemistry

In this paper, a dynamic model of PEMFC is developed to estimate the dynamic performance of PEMFC by analyzing in detail the influence factors of voltage of PEMFC including various losses. The partial pressure of hydrogen and oxygen is obtained using the differential form of the ideal-gas equation in this model. The steady-state model is obtained by setting reasonable parameter values. The simulation results and experimental results have good consistency, which shows that the simulation model is correct, reasonable and effective. It analyzed the dynamic response characteristics of the output voltage and the partial pressure of hydrogen in condition of …

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Indirect Electrochemical Reduction And Cotton Dyeing Process In Fe(Ⅲ)-Oxalate-Calcium Gluconate System, Qing-Zhi Wang, Wei Wang Nov 2011

Indirect Electrochemical Reduction And Cotton Dyeing Process In Fe(Ⅲ)-Oxalate-Calcium Gluconate System, Qing-Zhi Wang, Wei Wang

Journal of Electrochemistry

The electrochemical behavior and possible reaction mechanism in Fe(Ⅲ)-oxalate-calcium gluconate system were studied by cyclic voltammetry. The results showed that Fe(Ⅱ)-gluconate was the final reductant. The reduction time, the working voltage and the cathode area influenced the current efficiency. The high current efficiency of 89% for the indirect electrochemical reduction of Vat Scarlet R could be achieved with reduction time of 10 min, working voltage of 4 V and cathode area of 40 cm2 in Fe(Ⅲ)-oxalate-calcium gluconate system.

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Electrochemical Behaviors Of Hydroquinone On Polypyrrole/Stab-Nammt/Gc Electrode, Rong Li, Jian Xiong, Wei-Qiong Zhu, Yuan-Yuan Han, Jin Xu, Xiao-Ying He Nov 2011

Electrochemical Behaviors Of Hydroquinone On Polypyrrole/Stab-Nammt/Gc Electrode, Rong Li, Jian Xiong, Wei-Qiong Zhu, Yuan-Yuan Han, Jin Xu, Xiao-Ying He

Journal of Electrochemistry

The PPy/STAB-MMT/GC electrode was made using montmorillonite modified by STAB and polypyrrole (PPy). The electrochemical behaviors of hydroquinone on the PPy/STAB-MMT/GC electrode were researched by cyclic voltammetry and square wave stripping voltammetry (SWSV). The results showed that the electrode reaction occurred on the hydroquinone electrode was controlled by diffusion in PBS (pH=6.0). The number of electron transfer was equal to the number of protons (n=m=1) with the effective area of PPy/STAB-MMT/GC electrode Aeff=0.031 cm2. Under the optimized conditions, the linear response of peak current in SWSV with the concentration of hydroquinone in a range of 8.0×10-6~8.0×10 …

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Study On Residual Powders Of Lithium-Ion Batteries With Different Voltages After Explosion, He Li, Zhi-Kui Chen, Ji-Na Cao, Guang-Chuan Liang Aug 2011

Study On Residual Powders Of Lithium-Ion Batteries With Different Voltages After Explosion, He Li, Zhi-Kui Chen, Ji-Na Cao, Guang-Chuan Liang

Journal of Electrochemistry

The residual powders of lithium-ion batteries at different voltages after explosion were obtained by using the battery impact testing machine. And these powders have been investigated by weighing, water solution and X-ray diffraction (XRD). The results showed that the integrity status of copper current collector and weight of residual powders decreased gradually with increasing of battery voltage, rising of burning temperature and releasing of burning duration time. The residual powders could be separated to insoluble powders and soluble powders by the water solution. The proportion of the insoluble powders is more (about 90%) including C, Co and CoO, while the …

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Electrochemical Performance Of Tin Dioxide/Carbon Xerogel Composites As Anode Materials For Lithium-Ion Batteries, Xiao-Jing Liu, Lin-Lin Qin, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong Aug 2011

Electrochemical Performance Of Tin Dioxide/Carbon Xerogel Composites As Anode Materials For Lithium-Ion Batteries, Xiao-Jing Liu, Lin-Lin Qin, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

The tin dioxide/carbon xerogel composites were synthesized by using vacuum infiltration method. Structural characterization and morphology of the composites were investigated by using XRD, TEM and SEM techniques. BET test was performed to determine the pore size distributions of carbon xerogels and the composites. The results showed that the nano-sized SnO2 particles (5~10 nm) were encapsulated in the pores of carbon xerogels. During the electrochemical tests the SnO2 in the composites exhibited capacity retention of 61.9% after 100 cycles of charge-discharge tests at 100 mA/g.

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Study On The Fluorescent Carbon Nanodots With Electrochemical Methods, Bao-Ping Qi, Yan-Min Long, Lei Bao, Cui Liu, Zhi-Ling Zhang, Dai-Wen Pang Aug 2011

Study On The Fluorescent Carbon Nanodots With Electrochemical Methods, Bao-Ping Qi, Yan-Min Long, Lei Bao, Cui Liu, Zhi-Ling Zhang, Dai-Wen Pang

Journal of Electrochemistry

Carbon nanodots are a new class of fluorescent nanoparticles with a carbon-based core, which possess wavelength-tunable luminescence, high photostability, resistance to photobleaching, water-solubility, and ease of bioconjugation. Owing to their attractive merits, carbon nanodots like other carbon nanomaterials such as fullerene, carbon nanotubes and graphene, have attracted much attention. In addition, carbon nanodots can be inexpensively produced by electrochemical methods with simple post-processing under mild conditions. Electrochemical approaches have unique advantages in the analysis of surface structures and luminescence mechanism of materials. In this review, recent advances in electrochemical methods used for the synthesis and luminescence mechanism of fluorescent carbon …

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Effects Of Graphene On Electrochemical Behaviors Of Ni(Oh)2 As Supercapacitor Material, Zhen-Zhen Zhao, Wen-Bin Ni, Neng-Yue Gao, Hong-Bo Wang, Jian-Wei Zhao Aug 2011

Effects Of Graphene On Electrochemical Behaviors Of Ni(Oh)2 As Supercapacitor Material, Zhen-Zhen Zhao, Wen-Bin Ni, Neng-Yue Gao, Hong-Bo Wang, Jian-Wei Zhao

Journal of Electrochemistry

The enhanced electrochemical properties of Ni(OH)2 by the oxidation defected graphene were studied by both experimental method and theoretical calculation. The composite material of nano-Ni(OH)2/graphene was prepared by potentiostatic deposition on the graphene substrate. Observed by TEM, the Ni(OH)2 nanoparticles were well dispersed on the graphene substrate with the diameter of 5.0±0.5 nm. The capacitance of the system measured by the electrochemical test was 1928 F·g-1. As indicated by the theoretical calculations, the composite material becomes conductive since Ni(OH)2 is combined with surface functional groups of the graphene through the strong chemical interaction. …

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Simultaneous Determination Of Dopamine(Da)And Epinephrine (Ep) At Ca/Gc Electrode, Wang Ren, Ying Zhang, Min-Jiao Li Aug 2011

Simultaneous Determination Of Dopamine(Da)And Epinephrine (Ep) At Ca/Gc Electrode, Wang Ren, Ying Zhang, Min-Jiao Li

Journal of Electrochemistry

The citric acid modified glassy carbon electrode (CA/GC) was prepared by potentiostatic technique and was used for detections of dopamine (DA), epinephrine (EP), and their mixtures by differential pulse voltammetry (DPV). The modified electrode shows the enhanced sensitivity and excellent electrochemical discrimination to DA and EP. The cathodic potential difference between DA and EP was about 380 mV, while no cathodic reduction of ascorbic acid (AA) was observed because the oxidation of AA is an irreversible reaction at the sensor. As a result, DA and EP could be determined simultaneously with the interferences of high concentrations of AA being eliminated. …

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Study On The Electrochemical Behaviors Of Gc Electrode Modified With Carbon Nanotube-Polyelectrolytes And Its Application For Rutin Detection, Liang Hua, Xia-Qin Wu, Rong Wang Aug 2011

Study On The Electrochemical Behaviors Of Gc Electrode Modified With Carbon Nanotube-Polyelectrolytes And Its Application For Rutin Detection, Liang Hua, Xia-Qin Wu, Rong Wang

Journal of Electrochemistry

The electrochemical behaviors of rutin and ascorbic acid at single-wall carbon nanotube and polyelectrolytes (dimethyl-diallylammonium chloride, PDDA) film modified glassy carbon electrode was investigated. The cyclic voltammetric results showed that electron transfer of rutin at PDDA/SWCNTs/GC modified electrode is an adsorption-controlled process. The separation of oxidation peak potentials of rutin and ascorbic acid was more than 200 mV. The rutin concentration in the presence of AA were detected by differential pulse voltammetry (DPV). The experimental results indicated that the PDDA/SWCNTs/GC modified electrode can be used for the detection of rutin in the presence of high concentration of AA. The DPV …

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Brief Introduction To Metal Corrosion And Protection, Hou-Yi Ma, Cong-Ying Cui, Ting Chen Aug 2011

Brief Introduction To Metal Corrosion And Protection, Hou-Yi Ma, Cong-Ying Cui, Ting Chen

Journal of Electrochemistry

This paper explains why corrosion processes are usually electrochemical in nature, describes the significance of electrochemical kinetic parameters of corrosion process, and briefly introduces the principles of corrosion protection, the most common corrosion protection methods and some special application of corrosion processes.

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Surface Diffusion Of Adsorptive Species On Gold Nanoelectrodes, Bao-Fa Su, Wei Wang, Dong-Ping Zhan, Bin Ren, Zhong-Qun Tian Aug 2011

Surface Diffusion Of Adsorptive Species On Gold Nanoelectrodes, Bao-Fa Su, Wei Wang, Dong-Ping Zhan, Bin Ren, Zhong-Qun Tian

Journal of Electrochemistry

Gold nanoelectrodes were prepared successfully by a programmed laser puller. The Faraday adsorptions of oxygen and iodine, and the underpotential deposition of lead on the gold nanoelectrodes were investigated. The results showed that the active areas of nanoelectrodes were dramatically higher than their appearant geometry areas, which is caused by the surface diffusion of adsorptive species from the nanoscale gold/electrolyte interface to the adjacent gold surface.

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Synthesis Of Limnpo4/C Used As Cathode Material For Lithium Ion Batteries, Xin Yang, Xue-Wu Liu, Gui-Chang Liu, Zhi-Cong Shi, Xin Li, Guo-Hua Chen Aug 2011

Synthesis Of Limnpo4/C Used As Cathode Material For Lithium Ion Batteries, Xin Yang, Xue-Wu Liu, Gui-Chang Liu, Zhi-Cong Shi, Xin Li, Guo-Hua Chen

Journal of Electrochemistry

The LiMnPO4/C composites were prepared using a solid-state reaction with addition of the resorcinol formaldehyde resin as the carbon source. The effects of reaction temperature and time on the crystal structure, morphology and electrochemical properties of the LiMnPO4/C composites were investigated. The results show that the best performance was achieved with the LiMnPO4/C composites synthesized at 600 oC for 12 h which had the particle sizes about 100~200 nm. The initial discharge capacities were 121.6 mAh·g-1 at 0.02C, 110 mAh·g-1 at 0.1C and more than 60 mAh·g-1 at 1C. An …

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Synthesis And Electrochemical Behaviors Of Li2Coxmn1-XSio4 As A Cathode Material For Lithium-Ion Batteries, Lin Wang, Dong-Ping Lv, Yong Yang Aug 2011

Synthesis And Electrochemical Behaviors Of Li2Coxmn1-XSio4 As A Cathode Material For Lithium-Ion Batteries, Lin Wang, Dong-Ping Lv, Yong Yang

Journal of Electrochemistry

We have successfully synthesized Li2CoxMn1-xSiO4/C (x=0, 0.1, 0.3, 0.5, 1)/C composites using hydrothermal assisted sol-gel process and ball-milling method. The results of X-ray diffraction show that the solid solutions of Li2CoxMn1-xSiO4 can be achieved when x≤0.3. The initial capacities increase from 70 mAh·g-1 of Li2MnSiO4/C to 105 mAh·g-1 of Li2Co0.3Mn0.7SiO4/C. Cyclic Voltammetry (CV) curves show that the replacement of Mn with Co can reduce the electrochemical polarization, making the insertion-extraction reaction …

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Corrosion Characteristics Of Galvanized Flat Steel For Power Grounding In Nacl Solution Medium, Yong Li, Gao-Lin Wu, Bang-Fei Deng, Ping Yang, Xue-Ming Li, Qing-Bin Zong Aug 2011

Corrosion Characteristics Of Galvanized Flat Steel For Power Grounding In Nacl Solution Medium, Yong Li, Gao-Lin Wu, Bang-Fei Deng, Ping Yang, Xue-Ming Li, Qing-Bin Zong

Journal of Electrochemistry

The corrosion behavior of power grounding galvanized flat steel was studied by polarization measurement, electrochemical impedance spectroscopy and neutral salt spray test in 5% NaCl solutions. The surface morphologies of galvanized coating and structural properties of corrosion products were observed with scanning electron microscope and X-ray diffraction spectrometer, respectively. Results showed that under the temperatures of 20~60℃, the corrosion currents of galvanized flat steel increased with the temperature rising. The corrosion rate at 60℃ was 0.8408 mA·cm-2, which is 2.9 times larger than that at 20℃. The corrosion rate dropped after reaching the maximal value of 1.95 mg·cm …

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The Effects Of Damage Arrestment Devices In Composite Plate Sandwiches With Fastener Holes, Mark Anderson, Nancy Hung Choy, Lacey Jones, Rita Kourskaya Jun 2011

The Effects Of Damage Arrestment Devices In Composite Plate Sandwiches With Fastener Holes, Mark Anderson, Nancy Hung Choy, Lacey Jones, Rita Kourskaya

Aerospace Engineering

Composite materials such as a carbon fiber are used in a variety of new technologies including aircraft, spacecraft, and motor vehicles. Carbon fiber has a high strength to weight ratio, a key advantage over other material options. This report discusses the use of composite damage arrestment devices (DADs) in composite sandwich panels with a foam core. There are three different curing cycles tested for the DADs: pressure only, vacuum only, and vacuum with 1000 lbs of pressure. Using a Tetrahedron Heat Press to cure the composite specimen and an Instron Machine to perform tensile testing, data was collected for each …

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Characterisation, Modelling And Simulation Of Flexible Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams Jun 2011

Characterisation, Modelling And Simulation Of Flexible Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams

Conference Papers

Flexible polyurethane foam is an open-celled polymeric material that exhibits strain rate and temperature effects. It has found various applications in areas including the packaging, medical, sports, aerospace and aeronautical industries. Polyurethane foam is ubiquitous in seating applications and finds particular use in specialised wheelchair seating where customised seating solutions are required which can provide proper comfort and support without the risk of developing pressure ulcers. Proper seating design is critical for users if this problem is to be avoided, but a lack of quantitative knowledge of this material’s behaviour has limited its effectiveness. The objectives of the work presented …

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Synthesis And Catalytic Property Of Flaked Spindle-Like Cuo Nanocrystals, Jian-Feng Fan, Li-Qing Li, Yu-Feng Huang, Lou-Zhen Fan May 2011

Synthesis And Catalytic Property Of Flaked Spindle-Like Cuo Nanocrystals, Jian-Feng Fan, Li-Qing Li, Yu-Feng Huang, Lou-Zhen Fan

Journal of Electrochemistry

A simple and efficient electrochemical route was developed for the synthesis of flaked spindle-like CuO nanocrystals using aqueous electrolyte and Cu sacrificial anode (graphite as the cathode) in an undivided cell at a constant potential mode under room temperature. The morphologies, structure and component of CuO nanocrystals obtained were characterized by SEM, XRD, respectively. Flaked spindle-like CuO nanocrystals were successfully used to modify a GC electrode to detect H2O2 with cyclic voltammetry (CV) and amperometric (AC).The results showed that products were pure monoclinic CuO nanocrystals. The linear range for the determination of hydrogen peroxide is from 1.0 …

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Detection Of Acute Promyelocytic Leukemia Pml/Rarî± Fusion Gene Using Graphene Modified Glassy Carbon Electrode, Zhi-Xian Lian, Guang-Xian Zhong, Kun Wang, Ai-Lin Liu, Xin-Hua Lin, Yuan-Zhong Chen May 2011

Detection Of Acute Promyelocytic Leukemia Pml/Rarî± Fusion Gene Using Graphene Modified Glassy Carbon Electrode, Zhi-Xian Lian, Guang-Xian Zhong, Kun Wang, Ai-Lin Liu, Xin-Hua Lin, Yuan-Zhong Chen

Journal of Electrochemistry

A graphene modified glassy carbon electrode (GCE) was prepared by electrochemical reduction of graphite oxide fixed on the surface of GCE. Then, the amino-group modified probe of acute promyelocytic leukemia (APL) PML/RARα fusion gene fragment was immobilized onto surface of the graphene modified GCE by coupling activating agent. With methylene blue (MB) as a novel electrochemical indicator, artificial APL PML/RARα fusion gene fragment was measured by differential pulse voltammetry (DPV). The result indicated graphene nanomaterial showed good sensitization on the signal of MB. The relationship between the reduction peak current of MB and the concentration of complementary strand was linear …

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Influence Of Tert-Butylpyridine On The Band Energetics Of Nanostructured Tio2 Electrodes And The Photoelectrochemical Properties Of Dye-Seneitized Electrodes, Shu-Ming Yang, Ji-Chao Wang, Hui-Zhi Kou, Hong-Bin Xue, Hong-Jun Wang, Yu-Ling Guo May 2011

Influence Of Tert-Butylpyridine On The Band Energetics Of Nanostructured Tio2 Electrodes And The Photoelectrochemical Properties Of Dye-Seneitized Electrodes, Shu-Ming Yang, Ji-Chao Wang, Hui-Zhi Kou, Hong-Bin Xue, Hong-Jun Wang, Yu-Ling Guo

Journal of Electrochemistry

The flat band edges (Efb) of nanostructured TiO2 electrodes in electrolyte solutions with tert-butylpyridine (TBP) of different concentrations have been determined with spectroelectrochemical technique. TBP played a role in band energetics of nanostructured TiO2 electrodes. The Efb values of -2.25, -2.46 and -2.62 V were determined in three 0.2 mol•L-1 tetrabutylammonium perchlorate (TBAP) acetonitrile electrolytes which contain 0, 0.2 and 0.4 mol•L-1 TBP respectively. The addition of Li+ ions shifted Efb positively. The Efb values of -1.12, -1.22 and -1.30 V were determined in three 0.2 mol•L-1 LiClO4 acetonitrile electrolytes which contain 0, 0.2 …

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Effects Of Additives On The Electrochemical Behaviors Of Zn Electrode In Alkaline Solutions, Shu-Na Hong, Hai-Bin Lin, Zuo-Jian Su, He-Bing Zhou, Man Liang, Wei-Shan Li May 2011

Effects Of Additives On The Electrochemical Behaviors Of Zn Electrode In Alkaline Solutions, Shu-Na Hong, Hai-Bin Lin, Zuo-Jian Su, He-Bing Zhou, Man Liang, Wei-Shan Li

Journal of Electrochemistry

Electrochemical behaviors of Zn in 3mol⋅L-1 KOH solution containing the single additive(Pb(NO3)2, SDBS) the mixed additives(Pb(NO3)2+SDBS) were investigated. The results showed that all the additives can supress the corrosion of zinc in 3mol•L-1 KOH solution. And the inhibition effeciency of the mixed additives is higher than that of any single additive.

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Preparation And Electrocatalytic Activity Of The Pt/Wc/Tio2 Composites, Chun-An Ma, Bin Yu, Mei-Qin Shi, Xiao-Ling Lang May 2011

Preparation And Electrocatalytic Activity Of The Pt/Wc/Tio2 Composites, Chun-An Ma, Bin Yu, Mei-Qin Shi, Xiao-Ling Lang

Journal of Electrochemistry

TiO2 was used as the support for preparation of Pt/WC/TiO2 composite catalyst. The composites were characterized by XRD, SEM and TEM methods. The electrocatalytical activity of Pt/WC/TiO2 composite for oxidation of methanol was investigated by cyclic voltammetry. Pt/WC/TiO2 exhibited higher activity compared with that of Pt/TiO2 and Pt/WC composite catalysts. Based on this we discussed the effects of crystal phases of TiO2 on the electrocatalytical activity of Pt/WC/TiO2 composite catalyst.

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Dft Study Of Co2 Reduction To Hydrocarbons On Cu Surfaces, Li-Hui Ou, Sheng-Li Chen May 2011

Dft Study Of Co2 Reduction To Hydrocarbons On Cu Surfaces, Li-Hui Ou, Sheng-Li Chen

Journal of Electrochemistry

CO2 reduction on Cu(111) single crystal surfaces was studied using DFT calculations on the reaction energies and the minimum energy paths. The results indicated that the possible reaction paths for CO2 reduction on Cu(111) surface are CO2(g) + H* → COOH* → (CO +OH)*, (CO + H)* → CHO*, CHO + H → CH2O* → (CH2+O)*, CH2* + 2H* → CH4 or 2CH2* → C2H4. On Cu(111) surface, the reaction rate is controlled by steps of CH2O* → (CH2 …

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Capacitance Behaviors Of Ti/Ru0.1Ti0.1Sn0.8O2 Electrodes, Hai-Yan Chen, Yan-Qun Shao, Dian Tang May 2011

Capacitance Behaviors Of Ti/Ru0.1Ti0.1Sn0.8O2 Electrodes, Hai-Yan Chen, Yan-Qun Shao, Dian Tang

Journal of Electrochemistry

Ti/Ru0.1Ti0.1Sn0.8O2 electrodes were prepared by low temperature thermal decomposition. The structural characteristics were analyzed by X-ray diffraction(XRD).The performances were tested by cyclic voltammetry and constant current charge-discharge measurements. The results show that, the structure of Ti/Ru0.1Ti0.1Sn0.8O2 belongs to small rutile phase. A high specific capacitance of 933F/g is obtained at scan rate of 20 mV/s. The cycle life test shows a 23.6% specific capacitance lost after 1000 cycles. The electrode has a good cycle stability and reversibility.

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Preparation And Performance Of Carbon-Coated Si/C Composites, Li-Li Du, Quan-Chao Zhuang, Tao Wei, Yong-Li Cui, Zhi Sun, Shi-Gang Sun May 2011

Preparation And Performance Of Carbon-Coated Si/C Composites, Li-Li Du, Quan-Chao Zhuang, Tao Wei, Yong-Li Cui, Zhi Sun, Shi-Gang Sun

Journal of Electrochemistry

Si/C composite for lithium ion batteries was obtained by pyrolyzing and ball-milling. The microstructure and component of the composite was characterized by SEM and XRD, the electrochemical performance was investigated by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and galvano static charge-discharge tests. The results illustrate that the particle of Si/C composite prepared by pyrolysis exhibits inerratic morphology, uniform carbon-coating layer, good electrical conductivity, low resistance. The first intercalated-lithium capacity of the composite material is 4495 mAh/g; the first coulomb efficiency is 65.3%. From the second week the coulomb efficiency maintains 97%, and the capacity at the 100th cycle can …

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The Flip-Flop Behavior Of Acetonitrile At Au Electrode Surface Investigated By Sum Frequency Generation Vibrational Spectroscopy, Zhi Huang, Xin Tang, Gang-Hua Deng, En-Cai Zhou, Hong-Fei Wang, Yuan Guo May 2011

The Flip-Flop Behavior Of Acetonitrile At Au Electrode Surface Investigated By Sum Frequency Generation Vibrational Spectroscopy, Zhi Huang, Xin Tang, Gang-Hua Deng, En-Cai Zhou, Hong-Fei Wang, Yuan Guo

Journal of Electrochemistry

The electrochemical interface between liquid acetonitrile and polycrystal gold electrode is investigated by in situ infrared visible sum frequency generation spectroscopy (SFG-VS). The structure of acetonitrile adsorbed at polycrystal gold electrode surface is studied as a function of electrode potential. The SFG spectra of CH3 group indicate acetonitrile orients in response to the electrode potential. The SFG signal of CH3 group turns lower as the electrode potential changes from -700mV to 300mV, and vanishes around the 300mV(pzc), then becomes a negative signal above 500mV, which indicates that the orientation is predominately with the CH3 group toward the …

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