Engineering Science and Materials Commons^™

Development Of Software Tools And Experimental In Situ Electron Spin Resonance For Characterizing The Magnetic And Electrocatalytic Properties Of Transition Metal Chalcogenide Crystals, Jose Armando Delgado

Open Access Theses & Dissertations

Studying the magnetic properties and crystal defects of transition metal chalcogenide crystals is of paramount importance for utilizing them for next generation spintronics devices and hydrogen evolution reaction catalysts. Hydrothermally grown transition metal chalcogenide nanocrystals (MoS2, Ru2S3, Rh2S3, Co2S8) were chosen as catalysts for the hydrogen evolution reaction due to their low dimensionality and previous utilization as catalysts for hydrodesulfurization. The relationship between crystal defect sites and catalytic activity must be discerned to maximize the efficiency of hydrogen production during the hydrogen evolution reaction. ESR spectroscopy was utilized as a spin sensitive technique to study the defects and local changes …

Jominy Hardenability Tester With In-Situ Heating, Luke Allen

Williams Honors College, Honors Research Projects

This project centers on building a Jominy Hardenability tester with In-Situ heating for the manufacturing lab at the University of Akron. A new process and setup will be designed using engineering concepts in order to make the testing more efficient and safer for the teaching and testing of metal hardness. The current Jominy testing setup has efficiency issues within the transfer of specimen from induction heater to testing rig. Our design will simplify the design by creating a test rig that removes the traveling aspect of the specimen which will limit the amount of premature cooling done and will be …

Investigation Of Iron Doped Gallium Oxide (Ga-Fe-O) System: Structure Property Relationship And Performance Evaluation For Optical And Catalytic Applications, Swadipta Roy

Open Access Theses & Dissertations

From September 2012 to May 2015, a phenocam monitored the seaward edge of a protected mangrove forest. Calculated GCC revealed seasonal greening patterns of a mangrove species, Rhizophoa apiculata, and an overall increase in the GCC, suggesting mangrove expansion. In comparing temperature and precipitation effects, it was found that this particular mangrove species had a greening optima at temperatures between 28°C and 28.5°C, and greening and canopy development response lag time of 10 weeks in response to precipitation. Tree saplings were monitored and showed to grow by 50%, mostly during a three month period during the rainy season. The establishment …

Additive Manufacturing Of Engineered Material Systems For Energy Applications, Luis Angel Chavez

Open Access Theses & Dissertations

Despite increasing efforts to use renewable electricity generation techniques in the last couple of decades, the world is still heavily reliant on traditional power generation techniques. This creates the need to make such systems cheaper and less pollutant through improvements to their efficiency. Increasing the efficiency and reliability of energy conversion systems, specially those based on combustion processes has been of interest for many years. However, material limitations have brought these systems to a stagnant condition.

A novel approach to help increase the efficiency of such systems is to closely monitor their operating conditions and therefore be able to increase …

Evaluation Of Cyclo Olefin Polymer As Sabot Material For High-Density Projectiles, Estebanne Tarango

Open Access Theses & Dissertations

Assuring the integrity of spacecraft and its occupants are a priority in the field of space exploration. Micrometeoroids and orbital debris are one of the primary threats that affect spacecraft materials due to the high kinetic energies involved with hypervelocity impacts. Improvement of projectile launching capabilities prompts the investigation of adequate materials for the manufacturing of sabots able to carry high-density projectiles without catastrophic failure. Polycarbonate (PC) has been the chosen material by the Hypervelocity Team at White Sands Test Facility for sabots on the 0.50 caliber launcher; however, there is a material constraint when the projectile becomes significantly dense …

The Study Of Non-Permanent Tattoo Ink Using Nano Silver Compounds And Untact 3d Printing Technology, Jisu Lee

Open Access Theses & Dissertations

Due to a recent epidemic of COVID 19, the possibility of 3D tattoo printing technology using the Internet of Things (IoT) control system developed in a non-face-to-face contact process was identified. A non-surgical tattoo process and hygiene safety differentiated with silver tattoo ink was used to solve the health problems arising from the surgical tattoo process and to identify 3D tattoo printing techniques through a non-personal contact concept. During the tattoo processing, the image selected by the customer is sent to a designated printer via an IoT control system in a separate location. A piston-type extruder (PTE) printing technique was …

Tabletop Mechanical Tester, Jamie Dombroski, Brian English, Richard Leffler, Andrew Shirk

Williams Honors College, Honors Research Projects

The need for hands-on and face-to-face experiences in the engineering classroom is very great. The equations, principles, and concepts can all be learned, but without the visual and tactile application, these don’t always sink in or become concrete. A small-scale tensile test machine was designed, sourced, manufactured, and tested for the purpose of being applied in classroom settings to provide this experience to engineering students. Extensive research was performed concerning tensile machines on the market, the essential elements of which are the load cell, grips, crosshead, extensometer, motor, and frame. The raw materials for the frame were purchased and drawings …

Designing Composites For Graceful Failure, Amany G. Micheal Prof., Yehia Ahmed Bahei El Din Prof.

Architectural Engineering

When inevitable, failure in composite laminates is preferred to occur gracefully to avoid loss of property and possibly life. While the inherent inhomogeneity leads to slow dissipation of damage-related energy, overall failure is fiber-dominated and occurs in a rather brittle manner. Multidirectional plies usually give a more ductile response. Additionally, stiffness and strength as well as cost are important factors to consider in designing composite laminates. It is hence desirable to optimize for high mechanical properties and low cost while keeping graceful failure. Designing composite laminates with hybrid systems and layups, which permit gradual damage energy dissipation, are two ways …

Generation Of Warm Dense Plasma On Solar Panel Infrastructure In Exo-Atmospheric Conditions, Harrison C. Wenzel

Theses and Dissertations

The use of a weaponized thermo-nuclear device in exo-atmospheric conditions would be of great impact on the material integrity of orbiting satellite infrastructure. Particular damage would occur to the multi-layered, solar cell components of such satellites. The rapid absorption of X-ray radiation originating from a nuclear blast into these layers occurs over a picosecond time scale and leads to the generation of Warm Dense Plasma (WDP). While incredibly difficult and costly to replicate in a laboratory setting, a collection of computational techniques and software libraries may be utilized to simulate the intricate atomic and subatomic physics characteristics of such an …

Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves

Graduate Theses, Dissertations, and Problem Reports (ETD)

Having been theorized in 1947, it was not until 2004 that graphene was first isolated. In the years since its isolation, graphene has been the subject of intense, world-wide study due to its incredibly diverse array of useful properties. Even though many billions of dollars have been spent on its development, graphene has yet to break out of the laboratory and penetrate mainstream industrial applications markets. This is because graphene faces a ‘grand challenge.’ Simply put, there is currently no method of manufacturing high-quality graphene on the industrial scale. This grand challenge looms particularly large for electronic applications where the …

Morphology Controlled Preparations And Electrochemical Properties Of Znco2O4 Electrode Materials For Supercapacitors, Yue-Shen Zhou, Meng Li, Shuang Wu, Zhao-Lei Li, Yan-Min Gao

Journal of Electrochemistry

In this work, hydrothermal reaction and high temperature were used to grow ZnCo₂O₄ active materials on Ni foam. The crystal stuctures and surface morphlogies of four samples were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The electrochemical performances were characterized by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) testing and electrochemical impedance spectroscopy (EIS) on an electrochemical station. It can be seen that active materials tended to form denser stuctures with an increasing amount of NH₄F in the solution system and four different morphologies of ZnCo_{2 …}

Electrochemical Behaviors Of Azopurine On Gold Electrodes, Ming-Xue Li, Hang Shi, Jia Liu, Meng Zhang, Jian-Zhang Zhou, De-Yin Wu, Zhong-Qun Tian

Journal of Electrochemistry

In this paper, we studied the electrochemical behaviors of azopurine on polished gold electrodes with cyclic voltammetry (CV). On the basis of analyzing scan rate and peak current, it was supposed that the redox process belonged to a reversible process controlled by adsorption in 0.2 mol·L^-1 PBS (pH = 4.0 ~ 10.0) solutions. The potentials of redox peaks moved more negatively with increasing pH value. This proved that the H⁺ proton has participcted in the electrochemical reaction. The further data analysis and the calculation of surface adsorption excess demonstrated that the reaction was a two-proton and two-electron process. …

Polyaniline Coated Hollow Sulfur Prepared Using Sublimate 2,4,6-Tri(Propan-2-Yl)-1,3,5-Trioxane As Template For Sulfur Electrode, Zhang-Feng Li, Xiao-Rui Wang, Wen-Sheng Tian, Jin-Ze Yang, Ping Zhang, Li-Ping Ma, Yang Chen, Xiao-Li Cui, Zhi-Yu Jiang

Journal of Electrochemistry

An advance method for preparing polyaniline-coated hollow sulfur material using sublimate material ADD(2,4,6-tri(propan-2-yl)-1,3,5-trioxane) as a template was developed for lithium-sulfur battery. At first, the smashed ADD particles were coated by a sulfur layer through the reaction of Na₂S₂O₃ with diluted HCl. Then polyaniline layer was coated again on the surface of sulfur layer through the reaction of aniline with (NH₄)₂S₂O₈. After being dried at 60 ^oC for 12 h, the ADD in such a composite evaporated totally, and resulted in the formation of polyaniline-coated hollow sulfur …

Study On Electro-Sorption Of Heavy Metals And Sulfamethoxazole On Activated Carbon Fibers, Wen-Jun Zhao, Bing-Xin Jia, Ya-Nan Zhang, Jiu-Nian Guan, Jiao Qu, Ying Lu

Journal of Electrochemistry

To study the optimal removal condition, adsorption mechanism and comparative analysis of the three typical cationic pollutants, i.e., Zn(II), anionic pollutant Cr(VI) and molecular pollutant sulfamethoxazole (SMX), using self-made upflowed electro-sorption device for adsorptions of above three pollutants by modified activated carbon fiber were researched. The activated carbon fiber (ACF) was modified by hydrochloric acid. The ACF morphology and structure before and after modification were characterized by SEM, BET and FTIR. The characterization results show that the modified ACF had fewer surface impurities than the modified surface and the gully is more obvious, the specific surface area was increased by …

Transient Electrochemical Surface-Enhanced Raman Spectroscopic Study In Electrochemical Reduction Of P-Nitrothiophenol, Yun Ling, Jing Tang, Guo-Kun Liu, Cheng Zong

Journal of Electrochemistry

P-nitrothiophenol (PNTP) is one of the most common probe molecules studied by surface-enhanced Raman spectroscopy (SERS). The research in electrochemical reduction behavior of PNTP will help understanding the mechanism for the nitrobenzene reduction. In this paper, we used transient electrochemical surface-enhanced Raman spectroscopy (TEC-SERS) to study the SERS of PNTP with cyclic voltammetry and chronoamperometry on gold electrodes. The results show that the TEC-SERS provide a time resolution that equals the transient electrochemical methods, and we concluded that the reaction was so quick that we did not observe the spectral information of intermediate species described in the literatures with a …

Electrochemical Properties Of Sulfur In Different Carbon Support Materials, Bo Zhang, Jia Liu, Xiao-Chen Liu, De-Jun Li

Journal of Electrochemistry

In order to investigate the effect of carbon structure on electrochemical performance of sulfur/carbon composite in lithium-sulfur battery, in this paper, sublimation sulfur was incorporated into three types of carbon materials, namely, graphene, carbon black and porous carbon. The three sulfur/carbon composites were characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) techniques, and their electrochemical performances were also studied. The results showed that the sulfur/porous carbon composite offered an initial discharge capacity of 1623.2 mA·h·g^-1 and remained 845 mA·h·g^-1 after 100 cycles. Compared with graphene and carbon black, the mesopores and micropores in porous …

Electrochemical Sensor Based On Magnetic Electrode Modified With Magnetic Molecularly Imprinted Nanoparticles Immobilized Hemoglobin For Determination Of Hydrogen Peroxide, Yang Yuan, Jia-Xin Wang, Yu-Hua Cao

Journal of Electrochemistry

In this work, the surface-imprinted technique was used to prepare magnetic hemoglobin (Hb) imprinted nanoparticles, using Fe₃O₄@SiO₂ NPs as the carrier, Hb as the template molecule, and tetraethyl orthosilicate (TEOS) as the imprinted polymer monomer. The nanoparticles had a core-shell structure, with magnetic Fe₃O₄ NPs as the core and Hb imprinted polymers as the shell. Therefore, Hb could be concentrated and fixed on the surface of the magnetic imprinted nanoparticles (MMIPs NPs). Furthermore, MMIPs NPs were immobilized with chitosan (CS) on the surface of a magnetic electrode to constitute Hb enzyme-like biosensor …

Zif-67-Derived Ag/Co-Embedded N-Enriched Mesoporous Carbon For Oxygen Reduction Reaction, Zheng-Ling Di, Jing Zhu, Lei Dai, Wei Meng, Yue-Hua Li, Zhang-Xing He, Ling Wang

Journal of Electrochemistry

Nitrogen-doped porous carbon materials are considered as one of the most promising catalysts for oxygen reduction reaction (ORR). Herein, in order to further improve the activity of the nitrogen-doped porous carbon, Ag/Co bimetal is embedded into nitrogendoped porous carbon to form Ag/Co-embedded nitrogen-doped porous carbon material (AgCo@NC). The AgCo@NC was derived by the wet impregnation of Ag+ into ZIF-67 precursor, followed by chemical reduction and a subsequent pyrolysis process under Ar atmosphere at different temperatures (500 ℃, 600 ℃, 700 ℃). The morphologic characterization shows that the Ag/Co nanoparticles were successfully embedded in the mesoporous carbon framework with abundant nitrogen …

Quantitative Detection Of Levofloxacin Hydrochloride By Differential Pulse Stripping Voltammetry With Electrodeposited Bismuth Film Electrodes, Zi-Ying Guo, Zuo-Peng Li, Jiang Li, Jian-Guo Zhao, Feng Feng

Journal of Electrochemistry

In this study, differential pulse stripping voltammetry was developed for the quantitative detection of levofloxacin hydrochloride indirectly. Levofloxacin hydrochloride contains organic amine, which can be precipitated upon interaction with Zn(SCN)₄^2-. By means of differential pulse stripping voltammetry, the concentration of Zn²⁺ can be determined using an in-situ formed bismuth film electrode, which allows determining indirectly the amount of levofloxacine hydrochloride. The linearity equation, I = 1.1401c - 0.5309 with the correlative coefficient R = 0.9979, was presented in the experiment. The results showed that this approach is very sensitive, having a limitation of detection of 3.18 …

Ionic Liquid Assisted Synthesis Of Porous Carbons From Rice Husk For Supercapacitors, Han-Fang Zhang, Feng Wei, Jian Sun, Meng-Ying Jing, Xiao-Jun He

Journal of Electrochemistry

It is still a challenge to prepare carbon materials with high specific surface area at low cost from renewable resources. Herein, the authors report an efficient approach to synthesize porous carbons (PCs) from rice husk with ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF₆)) as a template and an activation agent. The as-made PCs featured the high specific surface area up to 1438 m²·g^-1. As electrodes for supercapacitors, PCs showed a high specific capacitance of 256 F·g^-1 at 0.05 A·g^-1 in 6 mol·L^-1 KOH aqueous electrolyte and a good rate performance of 211 F·g …

Bipolar-Membrane Electrodialysis Method To Treat Industrial High Saline Perfume Wastewater, Jian Zhang, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang

Journal of Electrochemistry

Large amount of organic saline wastewater is generated from various chemical industries. The contents of organic saline wastewater are more and more complicated as they are created from different types of industries. Directly discharging the organic saline wastewater without pre-treatment can generate severe environmental problem and waste useful resources. It is necessary to use an economical method to treat the organic saline wastewater and recover the salt into useful materials to achieve resource reuse. Bipolar-membrane electrodialysis (BMED) is one of the methods that can remove salt from the wastewater and convert it into certain acid and base with higher value …

Design Of Efficient Carbon-Based Adsorbents For The Removal Of Organic And Inorganic Water Contaminants, Sayedeh Soroosh Mortazavian Dehkordi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Granular activated carbon (AC) and biochar (BC) are two carbon-based adsorbents commonly used for water and wastewater treatment. However, these adsorbents have drawbacks that suppress their aqueous contaminants removal efficiency. Their major disadvantages are that AC has low selectivity and reusability potential, and BC has a hydrophobic nature.

The scope of this dissertation is to enhance the performance of commonly-used carbon-based adsorbents for the removal of organic and inorganic water contaminants and to understand the interactive mechanism of contaminants’ ions/molecules with adsorbents. Hexavalent chromium (Cr(VI)) and trichloroethylene (TCE) are two types of inorganic and organic water contaminants, respectively, which are …

Pressure Driven Electronic Band Gap Engineering In Tin(Iv)-O,N Compounds, Daniel Thomas Sneed

UNLV Theses, Dissertations, Professional Papers, and Capstones

The intrinsic link between long-range order, coordination geometry, and the electronic properties of a system must be understood in order to tailor function-specific materials. Although material properties are typically tailored using chemical dopants, such methods can cause irreversible changes to the structure, limiting the range of functionality. The application of high pressure may provide an alternative “clean” method to tune the electronic properties of semiconducting materials by tailoring their defect density and structure.

We have explored a number of optoelectronic relevant materials with promising characteristics, specifically Sn-(O,N) compounds which have been predicted to undergo pressure-mediated opening of their optical band …

The Flame Characteristics Of Diesel Fuel Blend With Kepuh (Sterculia Foetida) Biodiesel, Dani Hari Tunggal Prasetiyo, Nasrul Ilminnafik, Salahuddin Junus

Journal of Mechanical Engineering Science and Technology (JMEST)

Kepuh biodiesel fuel (sterculia foetida) is an alternative fuel that can be used to replace fossil fuel. Diesel fuel is performed to determine the laminar burning velocity and high flame by adding biodiesel kepuh volume of 10%, 20%, 30%. The purpose of this study was to study the effect of biodiesel and the effect of bunsen burners on the laminar burning velocity and flame height. Bunsen burner is made of copper and stainless steel. Testing of flame characteristics was carried out by heating the mixture of fuel and air at a temperature of 200°C. The purpose of heating the air …

Critical Solid Fraction Point Analysis: Case Study On Cement Mill Machine Diaphragm, Mochamad Achyarsyah, Poppy Puspitasari

Journal of Mechanical Engineering Science and Technology (JMEST)

During the solidification process, metal liquids turn into solid geometry units including the riser and gating system. The disruption in the liquid flow often causes shrinkage in the object. Critical Solid Fraction Point is a critical point where the continuous liquid supply turned solid and unable to pour to some sections. Simulation software can predict the critical solid fraction time of an object and the liquid supply behavior. The simulation helps the designer in the casting design. The application of low steel alloys in the cement industry, e.g., the Diaphragm, needs development to minimize the shrinkage. This research aimed to …

Characteristic Analysis Of Horizontal Axis Wind Turbine Using Airfoil Naca 4712, Bili Darnanto Susilo, Gaguk Jatisukamto, Nurkoyim Kustanto

Journal of Mechanical Engineering Science and Technology (JMEST)

Wind energy has been developed and used as a source of electrical energy by converting wind energy into electrical energy using a generator. There are some wind turbine parameters that important for wind turbines design and model, includes the size of the rotor radius, airfoil selection, chord length, and pitch angle. The study aims to characterize the performance of a horizontal axis wind turbine using computational methods. The methods used a design and simulation of NACA 4412 and NACA 4712 airfoil using QBlade software using wind conditions in the region of Pancer, Jember. Results show that the maximum Cl value …

Synthesis And Applications Of Hematite Α-Fe2o3 : A Review, Muhamad Muhajir, Poppy Puspitasari, Jeefferie Abdul Razak

Journal of Mechanical Engineering Science and Technology (JMEST)

This article reviewed the hematite α-Fe2O3. It focuses on its material properties, nanostructures, synthesis techniques, and its numerous applications. Researchers prepared the hematite nanostructure using the synthesis methods such as hydrothermal, and, further, enhanced it by improving the techniques to accommodate the best performance for specific applications and to explore new applications of hematite in humidity sensing.

Failure Analysis On Titen Proto-Xx Car Chassis, Gaguk Jatisukamto, Rika Dwi Hidayatul Qoryah, Santoso Mulyadi

Journal of Mechanical Engineering Science and Technology (JMEST)

The car chassis as a skeleton supports all loads and is the most important component. Car chassis requirements must be rigid, twisting resistant, vibration resistant and resistant to fatigue. This study aims to find the cause of the failure of the Titen Proto-XX car chassis connection. The research methodology was conducted by testing the composition of materials and structural analysis using Ansys Workbench Release 15.0 software. The conclusion of the research is that the skeletal structure material uses Aluminum AA series 1XXX with Al content greater than 99.5%, the welding ability is low, causing a failure in the welded joint. …

The Effect Of Chlorophyll Concentration From Papaya Leaves On The Performance Of Dye-Sensitized Solar Cell, Dede Rizali, Heru Suryanto, Sukarni Sukarni

Journal of Mechanical Engineering Science and Technology (JMEST)

Dye-Sensitized Solar Cell (DSSC) is the third generation solar cell that has sandwich structure consisted of organic dye material and other components such as titanium dioxide (TiO2) semiconductor, electrolyte, and substrates (counter electrode and working electrode). The dye in the device was made from green plant chlorophyll such as papaya. This research aimed to find the influence of dye concentration from papaya leaves chlorophyll on the performance of DSCC. The discussion covered the output power (Pout), Fill Factor (FF), and efficiency (ɳ). The method in this research was explorative experimental with independent variables such as direct and indirect sunlight. The …

Development Of Engineered Cementitious Composites With Conductive Inclusions For Use In Self-Sensing Applications, Benny Suryanto Dr, Danah Saraireh Ms, Steven Walls Mr, Jaehwan Kim Dr, W John Mccarter Prof

International Conference on Durability of Concrete Structures

The mechanical and a.c. electrical properties of a new varietal of engineered cementitious composite (ECC) incorporating conductive inclusions are presented. Electrical measurements were undertaken over a wide frequency range while curing and when under uniaxial tensile loading to study the influence of ongoing hydration and multiple microcrack formation on the composite electrical impedance. When presented in Nyquist format, the work shows that conductive inclusions reduce the bulk resistance of the composite while enhancing its polarizability, transforming the classic, single-arc bulk response of typical cement-based materials to a two-arc response. The bulk resistance was shown to increase with time and damage, …