Power and Energy Commons^™

Which Factor Dominates Battery Performance: Metal Ion Solvation Structure-Derived Interfacial Behavior Or Solid Electrolyte Interphase Layer?, Hao-Ran Cheng, Zheng Ma, Ying-Jun Guo, Chun-Sheng Sun, Qian Li, Jun Ming

Journal of Electrochemistry

Solid-electrolyte interphase (SEI) layer formed on the electrode by electrolyte decomposition has been considered to be one of the most important factors affecting the battery performance. We discover that the metal ion solvation structure can also influence the performance, particularly, it can elucidate many phenomena that the SEI cannot. In this review, we summarize the importance of the metal ion solvation structure and the derived metal ion de-solvation behaviors, by which we can build an interfacial model to show the relationship between the interfacial behavior and electrode performance, and then apply to different electrode and battery systems. We emphasize the …

New Solid Polymer Electrolytes For Lithium, Sodium, And Calcium-Based Batteries, Francielli Silva Genier

Dissertations - ALL

The establishment of sustainable energy sources highly depends on efficient storage devices to guarantee a consistent power supply. The growing demand for lithium-ion batteries (LIBs) for this purpose, combined with concerns about lithium availability, has motivated the search for viable storage alternatives, such as sodium and calcium. While several studies have investigated different lithium-free liquid electrolytes, the transport of these alternative ions in their polymer counterparts remains understudied. The advantages of solid polymer electrolytes include the possibility of higher energy density in solid-state devices and the elimination of safety concerns associated with liquid electrolytes, such as flammability, leakage, and dendrite …

Parameter Estimation And Charge Control In Standalone And Grid-Tied Batteries, Asadullah Khalid

FIU Electronic Theses and Dissertations

Energy storage systems are the critical components enabling an electrified future ranging from electric vehicles (EVs) to microgrid (MG) applications. With the advancements in these applications, the operational dynamics of electrochemical energy storage such as Lithium-ion batteries need to be analyzed from the lifecycle impact, cybersecurity, balancing requirements, and prognostics perspectives. These operations enable the interconnected systems to be secure, efficient, and self-adaptive while reducing greenhouse emissions.

This research aims to develop threefold solutions. The first objective of this dissertation is to analyze lifecycle impact, quantify the interconnection requirements of battery energy storage systems, and evaluate cybersecurity frameworks for battery …