Power and Energy Commons^™

A Study On The Lifepo4/Mwcnts Cathode Materials For Li-Ion Batteries, You-Yi Peng, Hai-Yan Zhang, Chun-Hua He, Wei Xie, Zhi-Feng Zeng

Journal of Electrochemistry

The LiFePO₄/MWCNTs composite was synthesized by ball milling,then the composite electrode was assembled into button lithium-ion batteries.The structure and morphology of the samples,the electrochemical performance of the electrodes were investigated by ways of X-ray diffraction,scanning electron microscopy,cyclic voltammetry and charge-discharge capacity tests. The electrochemical performance of the composite electrodes with different MWNTs contents were studied. The results indicated that the composite electrode containing 10% MWCNTs(by mass)exhibited the most excellent electrochemical performance with the initial charge-discharge capacities of 139 mAh·g^-1,128.5 mAh·g^-1,respectively,and a Kulun efficiency of 92.4% at 0.1C rate under room temperature.Compared to the electrodes …

A Direct Borohydride Fuel Cell With Fecopc2-Catalysed Cathode, Jin-Fu Ma, Yan Liu, Jun-Hua Lai, Yong-Ning Liu

Journal of Electrochemistry

In this paper,a membraneless direct borohydride fuel cell was investigated. Cyclic voltammograms of FeCoPc₂-modified glassy carbon electrode in the alkaline solution show that FeCoPc₂ was active for oxygen reduction reaction. In addition, the steady-state polarization curve tests indicate that FeCoPc₂ had better activity than FePc,CoPc or FePc+CoPc, which is due to its conjugated effect and synergistic effect of Fe and Co. Finally, a maximum power density of 110 mW/cm² was attained, and the 25-day life test shows that the direct borohydride fuel cell had a good stability.

Electrochemical Reduction Of Nitrobenzene In Different Ionic Liquids, Jun-Li Fan, Wei-Lin Ye, Rong Wang, Li-Qun Xu, Xia-Qin Wu

Journal of Electrochemistry

Electrochemical reduction of nitrobenzene at glassy carbon electrode in different ionic liquids,such as N-methylimidazolium-p-toluene sulfonic acid ([Mim][PhSO₃]) and ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF₆]) have been investigated by cyclic voltammetry. Experimental results showed that only a cathodic current peak was observed in [Mim][PhSO₃],which is a diffusional controlled irreversible reaction. And two pairs of current peaks were obtained in [Bmim][PF₆] in the same potential range,indicating showed that the reduction products of nitrobenzene were different in different ionic liquids.

Electrochemical Studies On The Ionic Charge Transfer Properties Of The Oxygen Vacancy Defects In The Oxide Films Formed On Titanium, De-Sheng Kong, Hai-Yan Liu, Wen-Juan Fan, Wen-Hua Lv, Zhang-Yu Yu, Yuan-Yuan Feng

Journal of Electrochemistry

The ionic charge transfer properties of the oxygen vacancy point defects in TiO₂ films formed on titanium were studied in 1.0 mol·L^-1 HClO₄ solution with cyclic voltammetry,potentiostatic polarization,galvanostatic reduction and capacitance measurements. The measured capacitance data were analyzed based on the Mott-Schottky equation and Einstein equation. Based on the different response times to the changes of the applied electric field between the ionic and the electronic charge transfers,the diffusion coefficient of the point defects in the anodic oxide film on titanium was estimated. It was shown that the passive potential region for titanium in 1.0 mol·L^{-1 …}

Synthesis And Characterization Of Sulfur-Carbonnanotubes As Cathode Of Lithium/Sulfur Rechargeable Battery, Rui Du, Zhong-Zhi Yuan

Journal of Electrochemistry

A carbon-containing composite was synthesized by heating element sulfur and carbon nanotubes. The sulfur-carbonnanotube composites were characterized by X-ray diffraction, SEM, Brunauer-Emmett-Teller. The electrochemical property was characterized by cyclic voltammetry,constant current charge and discharge. It was revealed that the sulfur-carbonnanotube cathode 2016-type coin cells exhibited a good electrochemical property with the initial dicharge specific capacity up to 680 mAh/g and a stable capacity approximately 500 mAh/g after 30 cycle numbers.

Tungstate/Pertungstate System Cathodic Indirect Oxidation To Synthesis Hydrophobic Monascus Yellow Colorant, Wen-Jian Chen, Xue-Hong Huang, Zhen Chen, Sheng-Bo Ke, You-Zhen Lin

Journal of Electrochemistry

Using SBS-g-(AA/StSO₃Na)/SBS-g-DMAEMA Bipolar Membrane as a separator between the cathode and anode chambers in the electrolysis cell,the optimum conditions of deoxidization of oxygen in cathode were obtained through orthogonal experiment. Then using tungstate/pertungstate as media to indirect electrooxidate hydrophobic monascus red colorant to prepare hydrophobic monascus yellow colorant in cathode. The experiment results show the average current efficiency of cathode was up to 72.39% under the following conditions:that graphite as electrode,10% sulfuric acid as anode electrolyte,0.5 g·L^-1 hydrophobic monascus red colorant solution as cathode electrolyte,tungstate concentration:15 mmol/L,pH=3,flow rate of oxygen:65 cm³/min,electrolyze 2 h under the …

Electrocatalytic Oxidation Of Glucose On Cnt/Nanocrystlline Tio2-Pt Complex Film Electrode In Ionic Liquids, Dao-Bao Chu, Long-Wu Zha, Shu-Xi Wang, Jian Wang, Ying Xiao, Yuan-Yuan Hou, Jian-Guo He, Xue-Jiao Zhang

Journal of Electrochemistry

Using ionic liquid [EMI]BF₄ as the electrolyte,the electrocatalytic oxidation of glucose on carbon nanotubes/nanocrystlline TiO₂ film loaded on Pt (CNT/nanoTiO₂-Pt) complex film electrode was investigated by cyclic voltammetry. The results found that the CNT/nanoTiO₂-Pt complex electrode had high catalytic activity to the electrochemical oxidation of glucose in ionic liquids and the oxidation potential was -0.46 V. The best effect of glucose oxidation was obtained with the volume ratio of ionic liquid to water being 3:1. The process of electrodic reaction process was concentration polarization controlled.

Ellipsometric Study On Colored Electroplating Of Cuprous Oxide On Ni Substrate, Xue-Song Feng, Jing-Lei Lei, Ai-Xiang Chen, Wan-Shan Yin, Ling-Jie Li, Sha Zheng, Hui Zhao, Shao-Yan Pan

Journal of Electrochemistry

The colored Cu₂O coating was electroplated on Ni substrate to meet the decorative requirements. Results of X-ray photoelectron spectroscopy (XPS) indicate the coating consisting of Cu₂O. Images of scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) show that the Cu₂O coating is smooth and uniform,and covers the Ni substrate wholly. Ellipsomtric measurements for Cu₂O coatings with various electroplating time were carried out. Using a 4-layer model of "Air-Cu₂O layer-interphase-Ni" ,the interphase was modeled with the graded effective medium approximation (EMA),the ellipsomtric data were deconvoluted and the Cu₂O …

Networks - I: An Instantiation Of Way Point Routing For Mobile Ad Hoc Networks, Waseem M. Arain, Sayeed Ghani

International Conference on Information and Communication Technologies

Mobile ad hoc networks are increasingly finding their existence in the marketplace heading to a new paradigm of pervasive computing. However there are many areas open to research in the field. Due to node mobility resulting in an ever-changing network topology, conventional routing methods cannot be applied in MANETS. Therefore, this is one of the core areas of research. Researchers are challenged to design protocols that can potentially scale to anything from thousand to tens of thousands of nodes and to reduce the route discovery latency. In this paper a different instantiation of way point routing (WPR) model is proposed, …

The Very Basics Of Sustainability - An Alternative Viewpoint (Slides With Audio) (Large File! To Speed Up Download, Right-Click On "Download" Link To Save To Own Pc.), Jim Mcgovern

Other resources

This presentation sets out the very basics of ‘sustainability’, although a definition of sustainability is not attempted. Some of the very basics are the context in which the Earth and humankind exist in space and time, the Earth’s climate, the Earth’s population and humankind’s options and choices. The author advocates keeping an open mind on all available options, including the use of oil, gas, coal, tar sands, carbon capture and sequestration, nuclear power etc., as well as the technologies that are more widely considered ‘green’. The author also argues that, in addressing the challenges that humankind faces, globally concerted effort …

Randomcast: An Energy-Efficient Communication Scheme For Mobile Ad Hoc Networks, Sunho Lim, Chansu Yu, Chita R. Das

Electrical and Computer Engineering Faculty Publications

In mobile ad hoc networks (MANETs), every node overhears every data transmission occurring in its vicinity and thus, consumes energy unnecessarily. However, since some MANET routing protocols such as dynamic source routing (DSR) collect route information via overhearing, they would suffer if they are used in combination with 802.11 PSM. Allowing no overhearing may critically deteriorate the performance of the underlying routing protocol, while unconditional overhearing may offset the advantage of using PSM. This paper proposes a new communication mechanism, called RandomCast, via which a sender can specify the desired level of overhearing, making a prudent balance between energy and …

Design And Development Of Rapid Battery Exchange Systems For Electric Vehicles To Be Used As Efficient Student Transportation, Jonathan A. Bevier

Master's Theses

Rapid battery exchange systems were built for an electric van and pedal assist electric bike as a method of eliminating the need to recharge the vehicles batteries in order to increase the feasibility of using electric propulsion as a method of efficient student transportation. After selecting proper materials it was found that the systems would need a protective coating to ensure consistent operation. 1020 cold rolled steel samples coated with multiple thicknesses of vinyl resin paint, epoxy resin paint, and powder coating were subjected to environmental wear tests in order to determine if the type and thickness of common protective …

An Efficient And Effective Implementation Of The Trust System For Power Grid Compartmentalization, Juan M. Carlos Gonzalez

Theses and Dissertations

As utility companies develop and incorporate new technologies, such as moving to utility Internet technology based architecture and standard; it is crucial that we do so with history in mind. We know that traditional utility protection and control systems were not designed with security in their top priorities. This presents a danger in an environment where near real-time responses are required to ensure safe operations. As a consequence, system security becomes a burden to the system rather than necessary protection. Unfortunately, technology implementation is not the only concern. The number of utility privately-owned companies has multiplied as the market has …

Multidisciplinary Design Optimization Of An Extreme Aspect Ratio Hale Uav, Bryan J. Morrisey

Master's Theses

ABSTRACT

Multidisciplinary Design Optimization of an Extreme Aspect Ratio HALE UAV

Bryan J. Morrisey

Development of High Altitude Long Endurance (HALE) aircraft systems is part of a vision for a low cost communications/surveillance capability. Applications of a multi payload aircraft operating for extended periods at stratospheric altitudes span military and civil genres and support battlefield operations, communications, atmospheric or agricultural monitoring, surveillance, and other disciplines that may currently require satellite-based infrastructure. Presently, several development efforts are underway in this field, including a project sponsored by DARPA that aims at producing an aircraft that can sustain flight for multiple years and …

1.5 Kw Pwm Bipolar Inverter, Michael Newbry, Percy Vigo

Electrical Engineering

This report focuses on the design, construction, and testing of a PWM inverter capable of converting 1.5 kW. The purpose for the inverter is to convert DC solar energy to power an air conditioner. The inverter uses a bipolar control scheme which comes from a PIC microcontroller. This report contains the advantages and disadvantages of all the PWM control schemes. Furthermore, the testing shows bipolar inverter characteristics and a sample use of filters to obtain sinusoidal waveforms. The design of the circuit makes the inverter easy and safe to use and test.

Novel Current-Fed Boundary-Mode Parallel-Resonant Push-Pull Converter, Jonathan David Paolucci

Master's Theses

The inherent difficulty in designing high voltage power supplies is often compounded by demands of high reliability, high performance, and safe functionality. A proposed high step-up ratio DC-DC converter meets the exacting requirements of applications such as uninterruptible power systems, radar, and pulsed power systems. The proposed DC-DC converter topology combines a multi-phase buck input stage with a novel self-tracking zero-voltage-switching (ZVS) resonant output stage. Traditionally, the inclusion of multiple power processing stages within a power supply topology severely degrades the overall converter efficiency. Due to the inherent high efficiency per stage, however, this effect is minimized. The self-tracking switching …

Electrode Of Metallic Oxides Coated Titanium With Interlayer, Yi Tang, Li-Kun Xu, Yong-Lei Xin, Jun-Tao Wang, Ping Long

Journal of Electrochemistry

Various Ti/IrRuSn,Ti/IrTa/IrRuSn and Ti/IrTaSn/IrRuSn oxide electrodes were prepared by sol-gel method.The surface morphology and microstructure were analysed with FESEM and XRD.The electrochemical activity and stability were investigated using electrochemical technologies including chlorine and oxygen evolving potential measurements,cyclic voltammetry,accelerated life test,and alternative electrolysis.The results indicate that the electrodes with interlayers present more cracks on the surface and a little bigger average grain size,with particles of different shapes precipitated in the cracks.The electroactive sites are increased and the selectivity for the chlorine evolving reaction is enhanced,but the current efficiency for the chlorine production is somewhat lowered by the addition of different interlayers.The …

The Accelerated Test Of Simulated Atmospheric Corrosion And The Rust Evolution Of Low Carbon Steel, Jun-Hua Dong, Wei Ke

Journal of Electrochemistry

It has been set up an accelerated method of simulating to atmospheric corrosion by using wet/dry alternate test.The rust evolution rule of mass change vs time(in logarithmic coordinate) of low carbon steel under this test shows two linear sections with different slopes,in which the rust evolution transition in weight change corresponds to the compactness transition and crystallization transition during the rust layer growth.It has found that the rust evolution rule of low carbon steel in Wanning exposure site correlates to the rust evolution rule obtained by simulating the coastal atmospheric corrosion test,and the rust evolution rule of low carbon steel …

Investigation Of Electrochemical Noise In The Crevice Corrosion Of Q235 Carbon Cteel, Qian Hu, Yu-Bing Qiu, Xing-Peng Guo

Journal of Electrochemistry

The crevice corrosion behavior of Q235 carbon steels in a NaHCO₃+NaCl solution was investigated by electrochemical noise(EN) and electrochemical impedance spectroscopy(EIS).Three stages of crevice corrosion including the induction,the rapid transform and the stable development could be clearly distinguished.The characteristics of the electrochemical noise and the noise resistance Rn showed remarkable differences at each stage.The electrode area ratio(r) of outside to inside the crevice had a significant influence in the development of crevice corrosion.The time of the induction stage increased with increasing r.However,under the stable development stage of the crevice corrosion,the surface outside the crevice was at an active …

Preparation And Electrochemical Properties Of Layered Manganese Oxide(Li-Birnessite Type), Xing-Kang Huang, Hai-Tao Chang, Jian-Long Gan, Qing-Shun Zhang, Hong-Jun Yue, Dong-Ping Lv, Yong Yang

Journal of Electrochemistry

Layered Li-birnessite was prepared by means of oxidizing Mn²⁺ with O₂ gas in alkaline media.The as-prepared sample was characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), BET and thermogravimetric/diffenential thermal analysis(TG/DTA) techniques. The electrochemical properties of the material were also investigated. The results show that such a Li-birnessite consists of well-crystallized spherical particles with an interlayer distance of 0.70 nm. The Li-birnessite delivered a high discharge capacity of 203 mAh/g at a rate of 0.2 C(40 mA/g), and had good rate capability as well.

Electrochemical Performance Of The Exfoliated Graphite Containing Sulfur Cathode Material For Lithium Sulfur Battery, Ke-Guo Yuan, Wei-Kun Wang, Zhong-Bao Yu, An-Bang Wang

Journal of Electrochemistry

The exfoliated graphite containing sulfur cathode material was prepared by the high temperature sulfur gas diffusion adsorption method.This cathode material could obtain an initial discharge specific capacity 972 mAh·g^-1,capacity retention ratio 78% and cycling efficiency above 80%,respectively.The exfoliated graphite containing sulfur cathode could decrease the reaction interphase charge transfer impedance,and restrain the sulfur or polysulfide shuttle phenomenon during the charge-discharge process through improving the diffusion impedance.

Effects Of Kscn On Kinetic Characters Of The Positive Couple And Performance For Vanadium Redox Flow Battery, Jian-Guo Liu, Dong Shi, Yue Men, Chuan-Wei Yan

Journal of Electrochemistry

In order to improve the reaction activity of VO²⁺/VO²⁺ and the battery performance of Vanadium redox flow battery,different concentration of potassium sulfocyanates KSCN were added into 0.1mol/L VOSO₄/ H₂SO₄ solution,and the kinetic characters of electrochemical reaction of VO²⁺/VO²⁺ was studied by CV and EIS.The results showed that the addition of KSCN could improve the oxidative peak current value of positive couple VO²⁺/VO²⁺ reaction,but had little influence in the reductive peak.The addition of KSCN decreased the impedance at 1.0 V.And the value of standard rate constant k0 …

Electro-Oxidation Of Methanol On Fe-Doped Pt-Zro2/C Catalyst, Mao-Cai Lin, Dong-Dong Liu, Qing-Chun Yu, Ming-Ruo Hu, Heng-Yong Tu

Journal of Electrochemistry

The Fe-doped ZrO₂ powders were prepared by so-gel method.After that,Pt-Zr_1-xFe_xO₂/C catalysts were made by reducing platinum salts with ethylene glycol.The physical property of the catalyst was characterized by XRD and TEM.It was found that the distribution of the catalyst was narrow,the particle sizes of Pt and ZrO₂ particles were 2~4 nm and 3~7 nm,respectively.The Cyclic Voltammetry and Chronoamperometry testing indicated that the electro-catalytic activity for methanol electro-oxidation on Pt-ZrO₂/C catalyst increased when ZrO₂ was doped with Fe.And Pt-Zr_0.95Fe_0.05O₂/C catalyst showed the highest activity …

Dc-Ac Cascaded H-Bridge Multilevel Boost Inverter With No Inductors For Electric/Hybrid Electric Vehicle Applications, Zhong Du, Burak Ozpineci, Leon M. Tolbert, John N. Chiasson

Electrical and Computer Engineering Faculty Publications and Presentations

This paper presents a cascaded H-bridge multilevel boost inverter for electric vehicle (EV) and hybrid EV (HEV) applications implemented without the use of inductors. Currently available power inverter systems for HEVs use a dc–dc boost converter to boost the battery voltage for a traditional three-phase inverter. The present HEV traction drive inverters have low power density, are expensive, and have low efficiency because they need a bulky inductor. A cascaded H-bridge multilevel boost inverter design for EV and HEV applications implemented without the use of inductors is proposed in this paper. Traditionally, each H-bridge needs a dc power supply. The …

College Of Engineering Senior Design Competition Spring 2009, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge.

The senior design competition helps to focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects …

Harmonic Analysis Of A Static Var Compensated Mixed Load System, James David Ruckdaschel

Master's Theses

As power electronic based controllers and loads become more prevalent in power systems, there is a growing concern about how the harmonics generated by these controllers and loads affect the power quality of the system. One widely used power electronic based load is the Variable Frequency Drive (VFDs) used to vary the speed of an induction motor; whereas a common example of a power electronic based controller used in power systems is the Static VAR Compensator (SVC) for improving a system’s power factor. In this thesis, the harmonic content and overall performance of a system including both a VFD and …

Low Power Fft Processor Design Considerations For Ofdm Communications, David Layne Rushforth

UNLV Theses, Dissertations, Professional Papers, and Capstones

Today's emerging communication technologies require fast processing as well as efficient use of resources. This project specifically addresses the power-efficient design of an FFT processor as it relates to OFDM communications such as cognitive radio. The Fast Fourier Transform (FFT) processor is what enables the efficient modulation in OFDM. As the FFT processor is the most computationally intensive component in OFDM communication, the power efficiency improvement of this component can have great impacts on the overall system. These impacts are significant considering the number of mobile and remote communication devices that rely on limited battery-powered operation. This project explores current …

Anti-Islanding Schemes For Machine-Based Distributed Generation, Temesgen Tadegegn

UNLV Theses, Dissertations, Professional Papers, and Capstones

The most common method of detecting the islanding in a machine-based distributed generator (DG) is to establish an under/over frequency and under/over voltage window within which a synchronous DG is allowed to operate. When such a DG is islanded from the utility system, the frequency or voltage will quickly move outside the operating window if there is a sufficient difference between the local load and DG power generation level. However, there is a possibility that the system voltage and frequency will be maintained within the specified limits following loss of the grid in cases where the load and generator are …

A Compact Lidar For Aircraft Ozone Atmospheric Measurements, Joel A. Marcia

Electrical & Computer Engineering Theses & Dissertations

Researchers and the general public have expressed great concern over how human activities exacerbate pollution's deteriorating impact upon the environment. Effects such as global warming, air quality and ozone layer depletion are but a few examples that can have a dramatic effect on the quality of life worldwide.

A compact lidar system for the purpose of aircraft ozone atmospheric measurements was tested and evaluated. This system will eventually be deployed for aircraft-based, and possibly unpiloted atmospheric vehicle (UAV), ozone and aerosol measurements to improve our understanding of ozone production and transport. Each of the major subsystems was characterized and from …

Where Does Your Institution Stand?, Wendell Brase, Mark Askren

Information Technology Services: Publications

Media coverage of sustainability and "green" issues is hard to ignore these days. But less clear is a specific understanding of what this agenda means within higher ed IT organizations. For starters, it's useful to self-assess whether your campus is a leading innovator on all things "green" or satisfied to remain inconspicuous in the middle of the pack. If your institution is trailing but wants to assert a leadership role in environmental stewardship, you need to get engaged to understand what it will take to catch up and how IT can be a leader, not just a contributor, to such …