Power and Energy Commons^™

Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer

Electrical & Computer Engineering Theses & Dissertations

Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.

When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …

Correlations Of Capacitance-Voltage Hysteresis With Thin-Film Cdte Solar Cell Performance During Accelerated Lifetime Testing, David S. Albin, Joseph A. Del Cueto

Publications (E)

In this paper we present the correlation of CdTe solar cell performance with capacitance-voltage hysteresis, defined presently as the difference in capacitance measured at zero-volt bias when collecting such data with different pre-measurement bias conditions. These correlations were obtained on CdTe cells stressed under conditions of 1-sun illumination, open-circuit bias, and an acceleration temperature of approximately 100 ºC.

Use Of 2nd And 3rd Level Correlation Analysis For Studying Degradation In Polycrystalline Thin-Film Solar Cells, David S. Albin, Joseph A. Del Cueto, S. H. Demtsu, S. Bansal

Publications (E)

The correlation of stress-induced changes in the performance of laboratory-made CdTe solar cells with various 2^nd and 3^rd level metrics is discussed. The overall behavior of aggregated data showing how cell efficiency changes as a function of open-circuit voltage (V_oc), shortcircuit current density (J_sc), and fill factor (FF) is explained using a two-diode, PSpice model in which degradation is simulated by systematically changing model parameters. FF shows the highest correlation with performance during stress, and is subsequently shown to be most affected by shunt resistance, recombination and in some cases voltage-dependent collection. Large decreases …

Effect Of Hysteresis On Measurements Of Thin-Film Cell Performance, David S. Albin, Joseph A. Del Cueto

Publications (E)

Transient or hysteresis effects in polycrystalline thin film CdS/CdTe cells are a function of pre-measurement voltage bias and whether Cu is introduced as an intentional dopant during back contact fabrication. When Cu is added, the current-density (J) vs. voltage (V) measurements performed in a reverse-to-forward voltage direction will yield higher open-circuit voltage (V_oc), up to 10 mV, and smaller short-circuit current density (J_sc), by up to 2 mA/cm², relative to scanning voltage in a forward-to-reverse direction. The variation at the maximum power point, Pmax, is however small. The resulting variation in FF can be …

High Efficiency, Low Cost Solar Cells Manufactured Using ‘Silicon Ink’ On Thin Crystalline Silicon Wafers October 2009 - November 2010, Homer Antoniadis

Publications (E)

The objectives of Phase I (Feb – Oct 2009) include the development and demonstration of a 17% efficient 25mm x 25mm crystalline Silicon solar cell and a 16% efficient 125mm x 125mm crystalline Silicon solar cell, both produced by Ink-jet printing Silicon Ink on a thin crystalline Sil-icon wafer. To achieve these objectives, processing approaches were developed to print the Silicon Ink in a predetermined pattern to form a high efficiency selective emitter, remove the solvents in the Silicon Ink and fuse the deposited particle Silicon films. Additionally, standard solar cell manufacturing equipment with slightly modified processes were used to …

Hybrid Cooling Systems For Low-Temperature Geothermal Power Production, Andrea Ashwood, Desikan Bharathan

Publications (E)

The overall objective of this investigation is to identify and evaluate methods by which the net power output of an air-cooled geothermal power plant can be enhanced during hot ambient conditions using minimal amounts of water.

Geothermal power plants that use air-cooled heat rejection systems experience a decrease in power production during hot periods of the day. This decrease in power output typically coincides with the time when utilities need power to address high air conditioning loads. Hybrid cooling options, which use both air and water, have been studied for this report to assess how they might mitigate the net …

"Buried-Anode" Technology Leads To Advanced Lithium Batteries, National Renewable Energy Laboratory

Publications (E)

A technology developed at the National Renewable Energy Laboratory has sparked a start-up company that has attracted funding from the Advanced Projects Research Agency-Energy (ARPA-E). Planar Energy, Inc. has licensed NREL's "buried-anode" technology and put it to work in solid-state lithium batteries. The company claims its large-format batteries can achieve triple the performance of today's lithium-ion batteries at half the cost, and if so, they could provide a significant boost to the emerging market for electric and plug-in hybrid vehicles.

Commercial Program Development For A Ground Loop Geothermal System: Energy Loads, Gui, Turbulent Flow, Heat Pump Model And Grid Study, Paul A. Gross Ii

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The use of the earth's thermal energy to heat and cool building space is nothing new; however, the heat transfer approximations used in modeling geothermal systems, leave uncertainty and lead to over sizing. The present work is part of a Wright State effort to improve the computer modeling tools used to simulate ground loop geothermal heating and cooling systems. The modern computer processor has equipped us with the computation speed to use a finite volume technique to solve the unsteady heat equation with hourly time steps for multi-year analyses in multiple spatial dimensions. Thus we feel there is more need …

Commercial Program Development For A Ground Loop Geothermal System: G-Functions, Commercial Codes And 3d Grid, Boundary And Property Extension, Kyle L. Hughes

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The rise in fossil fuel consumption and green house gas emissions has driven the need for alternative energy and energy efficiency. At the same time, ground loop heat exchangers (GLHE) have proven capable of producing large reductions in energy use while meeting peak demands. However, the initial cost of GLHEs sometimes makes this alternative energy source unattractive to the costumer. GLHE installers use commercial programs to determine the length of pipe needed for the system, which is a large fraction of the initial cost. These commercial programs use approximate methods to determine the length of pipe mainly due to their …

Ab Initio Simulations Of Graphene-Based Nanosensor For Detecting No2 And Li, Ahmed Jama Hassan

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Nanosensors, i.e., sensors based on nanomaterials, have the potential of superior performance owing to their size effect, and can have significant effects on detection of pollutants in the environment. Various nanowires have been used in this context. Here we investigate the possibility of NO2 and Li detection using the quantum conductance change in graphene nanoribbon. Quantum conductance modification in graphene nanoribbon upon NO2/Li adsorption was calculated using ab initio methods. The optimized structures of the adsorbed NO2 indicated two different geometries where either nitrogen or oxygen was closer to the graphene lattice. The former resulted in charge transfer from NO2 …

Model-Based Analysis Of Electric Drive Options For Medium-Duty Parcel Delivery Vehicles, Robb A. Barnitt, Aaron D. Brooker, Laurie Ramroth

Publications (T)

Medium-duty vehicles are used in a broad array of fleet applications, including parcel delivery. These vehicles are excellent candidates for electric drive applications due to their transient-intensive duty cycles, operation in densely populated areas, and relatively high fuel consumption and emissions. The National Renewable Energy Laboratory (NREL) conducted a robust assessment of parcel delivery routes and completed a model-based techno-economic analysis of hybrid electric vehicle (HEV) and plug-in hybrid electric vehicle (PHEV) configurations. First, NREL characterized parcel delivery vehicle usage patterns, most notably daily distance driven and drive-cycle intensity. Second, drive-cycle analysis results framed the selection of drive cycles used …

Economic Analysis Of A Brackish Water Photovoltaic-Operated (Bwro-Pv) Desalination System, Ali Al-Karaghouli, Lawrence L. Kazmerski

Publications (E)

The photovoltaic (PV)-powered reverse-osmosis (RO) desalination system is considered one of the most promising technologies in producing fresh water from both brackish and sea water, especially for small systems located in remote areas. We analyze the economic viability of a small PV-operated RO system with a capacity of 5 m³/day used to desalinate brackish water of 4000 ppm total dissolve solids, which is proposed to be installed in a remote area of the Babylon governorate in the middle of Iraq; this area possesses excellent insolation throughout the year. Our analysis predicts very good economic and environmental benefits of …

User's Guide To Mbc3: Multi-Blade Coordinate Transformation Code For 3-Bladed Wind Turbine, G. S. Bir

Publications (E)

The dynamics of wind turbine rotor blades are conventionally expressed in rotating frames attached to the individual blades. The tower-nacelle subsystem though, sees the combined effect of all rotor blades, not the individual blades. Also, the rotor responds as a whole to excitations such as aerodynamic gusts, control inputs, and tower-nacelle motion—all of which occur in a nonrotating frame. Multi-blade coordinate transformation (MBC) helps integrate the dynamics of individual blades and express them in a fixed (nonrotating) frame. MBC involves two steps: transforming the rotating degrees of freedom and transforming the equations of motion. Reference 1 details the MBC operation. …

Green Power Marketing In The United States: A Status Report (2009 Data), Lori Bird, Jenny Sumner

Publications (E)

This report documents green power marketing activities and trends in the United States. Aggregate green power sales data for all voluntary purchase markets across the United States are presented for 2009. The data presented in this report are based primarily on figures provided to NREL by utilities and independent renewable energy marketers. Because data cannot be obtained from all market participants, the estimates presented here likely represent an underestimate of the market size. Key trends identified in this year’s report include:
• In 2009, total retail sales of renewable energy in voluntary markets exceeded 30 million MWh, an increase of …

Further Developments On The Geothermal System Scoping Model, Mark Antkowiak, Rosemary Sargent, Jesse W. Geiger

Publications (E)

The fields of well construction and engineering, power plant construction and engineering, and reservoir engineering often proceed independently of one another. Yet the subsystems of a geothermal plant with which each of these fields is concerned need to be integrated in order to create a viable geothermal power system and make enhanced (or engineered) geothermal systems (EGS) a technical and an economic reality. Furthermore, each of these subsystems need to be examined in the context of the overall power system to aid with plant construction, and–more salient to the U.S. Department of Energy–to help determine best investment of research dollars. …

Input-Output Analysis Of Irish Construction Sector Greenhouse Gas Emissions, Adolf Acquaye, Aidan Duffy

Articles

Ireland is committed to limiting its greenhouse gas (GHG) emissions to 113% of 1990 levels over the period 2008-12 and to 84% of 2005 levels by 2020 under the Kyoto Agreement and the EU’s ’20 20’ by 2020 respectively. National policies have targeted many industry sectors but have failed to directly tackle GHG emissions associated with construction activity. This paper estimates energy and GHG emissions intensities of the Irish construction sector and subsectors and estimates its contribution to Irish national emissions. This information is used to identify and assess the impacts of policy measures which would result in a reduction …

Barrier Coatings For Thin Film Solar Cells: Final Subcontract Report, L. C. Olsen

Publications (E)

This program has involved investigations of the stability of CdTe and copper-indium-gallium-diselenide (CIGS) solar cells under damp heat conditions and effects of barrier coatings. CdTe and CIGS cells were subjected to environmental conditions characterized by 60ºC and 90% relative humidity (60/90), and to some extent 85ºC and 85 % relative humidity (85/85). Barrier coating technology developed at PNNL for OLEDs was used to investigate approaches to encapsulation of the two types of thin film solar cells. Moisture barriers consisting of multi-layer coatings involving alternating layers of polymer and aluminum oxide were deposited directly onto the front surface of CIGS cells …

Solar Power And The Electric Grid, Energy Analysis, Nrel Energy Analysis

Publications (E)

In today’s electricity generation system, different resources make different contributions to the electricity grid. This fact sheet illustrates the roles of distributed and centralized renewable energy technologies, particularly solar power, and how they will contribute to the future electricity system. The advantages of a diversified mix of power generation systems are highlighted.

Consortia Focused On Photovoltaic R&D, Manufacturing, And Testing: A Review Of Existing Models And Structures, Charlie Coggeshall, Robert M. Margolis

Publications (E)

As the U.S. Department of Energy's (DOE's) Solar Energy Technologies Program prepares to initiate a new cost-shared research and development (R&D) effort on photovoltaic (PV) manufacturing, it is useful to review the experience to date with consortia focused on PV R&D, manufacturing, and testing. Information was gathered for this report by conducting interviews and accessing Web sites of 14 U.S. consortia and four European consortia, each with either a primary focus on or an emerging interest in PV technology R&D, manufacturing, or testing. Additional input was collected from several workshops held by the DOE and National Academy of Sciences (NAS) …

The Value Of Concentrating Solar Power And Thermal Energy Storage, Ramteen Sioshansi, Paul Denholm

Publications (E)

This paper examines the value of concentrating solar power (CSP) and thermal energy storage (TES) in four regions in the southwestern United States. Our analysis shows that TES can increase the value of CSP by allowing more thermal energy from a CSP plant’s solar field to be used, by allowing a CSP plant to accommodate a larger solar field, and by allowing CSP generation to be shifted to hours with higher energy prices. We analyze the sensitivity of CSP value to a number of factors, including the optimization period, price and solar forecasting, ancillary service sales, capacity value and dry …

Doe Request For Information (Rfi) De-Foa-0000153 Pv Manufacturing Initiative: Summary Report, National Renewable Energy Laboratory

Publications (E)

Clean Cities hosts a collection of tools on the exploring concepts for a “PV Manufacturing Initiative” to facilitate the development of a strong photovoltaic (PV) manufacturing industry in the United States. As an integral part this effort, and to inform the creation of a new funding opportunity in this area, DOE sought feedback from the PV industry.

This document summarizes the results of the PV Manufacturing Request for Information (RFI), DE-FOA-0000153. (See Attachment 1.) The RFI was posted on http://www.grants.gov on 4 September 2009 and the NREL Web site on 9 September 2009. Respondents were asked to submit RFI inputs …

Ab Initio Simulations Of Hydrogen And Lithium Adsorption On Silicene, Tim H. Osborn

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The energies and temperature-dependent dynamics of hydrogen and lithium chemisorption on a silicon nanosheet, called silicene, were studied using density functional theory and molecular-dynamics (MD) simulations. Silicene has a buckled honeycomb structure, and has been fabricated as suspended monolayer sheets and nanoribbons in recent experiments. We calculated the adsorption energies of hydrogen and lithium on silicene for different adsorption ratios between 3.1% and 100%. The studies will clarify the characteristics of these novel and promising nanomaterials, and pave the way for their applications.

For Hydrogen, the adsorption energy had a maximum of 3.01 eV/H for complete hydrogenation, and decreased by …

Fabrication Of Zinc Oxide Thin Films For Renewable Energy And Sensor Applications, Theresa Y. Hill

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Progress in commercializing renewable energy technologies is being advanced by developments in Zinc Oxide material science. The photovoltaic cell, for example, generates electricity by receiving solar energy into the cell, generating electrons, and simultaneously transporting electrical charge out of the cell. Metals are capable of removing electrical charge but block transmission of sunshine. Glass and plastics are capable of transmitting sunshine but block the removal of electrical charge. Therefore an exterior layer that is both optically transparent and electrically conductive is desirable. Transparent conductive oxides (TCOs) are the ideal material for such applications since they are capable of both functions. …

Sulfur-Tolerant Catalyst For The Solid Oxide Fuel Cell, Bozeman Joe Frank Iii

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JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which results in a poisonous hydrogen sulfide that degrades electrochemical activity and causes complete SOFC failure in some cases. The goal is to synthesize and verify a cost-effective, catalyst supported on cerium oxide that either stabilizes ionic conductivity in the presence of hydrogen sulfide and/or is highly sulfur-resistant. After thorough computational analysis, it was concluded that the platinum-copper skin catalyst was the most cost-effective, sulfur-resistant catalyst. Experimental synthesis of copper, platinum, and platinum-copper skin catalysts supported …

The Role Of Energy Storage With Renewable Electricity Generation, Paul Denholm, Erik Ela, Brendan Kirby, Michael Milligan

Publications (E)

Renewable energy sources, such as wind and solar, have vast potential to reduce dependence on fossil fuels and greenhouse gas emissions in the electric sector. Climate change concerns, state initiatives including renewable portfolio standards, and consumer efforts are resulting in increased deployments of both technologies. Both solar photovoltaics (PV) and wind energy have variable and uncertain (sometimes referred to as “intermittent”) output, which are unlike the dispatchable sources used for the majority of electricity generation in the United States. The variability of these sources has led to concerns regarding the reliability of an electric grid that derives a large fraction …

2008 Solar Technologies Market Report, U.S. Department Of Energy

Publications (E)

This report focuses on the U.S. solar electricity market, including photovoltaic (PV) and concentrating solar power (CSP) technologies. The report provides an overview of global and U.S. installation trends. It also presents production and shipment data, material and supply chain issues, and solar industry employment trends. It also presents cost, price, and performance trends; and discusses policy and market drivers such as recently passed federal legislation, state and local policies, and developments in project financing. The final chapter provides data on private investment trends and near-term market forecasts.

Analysis Of Hybrid Hydrogen Systems: Final Report, J. Dean, R. Braun, D. Munoz, M. Penev, C. Kinchin

Publications (E)

This project examined biomass pathways for hydrogen production and how they can be hybridized to support renewable electricity generation. The project considered many potential hybrid systems before narrowing the focus to two. The systems were studied in detail for process feasibility and economic performance. The best-performing system was estimated to produce hydrogen at a cost ($1.67/kg) within range of the Department of Energy target for central biomass-derived hydrogen production, while also providing value-added energy services to the electric grid.

Nrel: A Year In Clean Energy Innovations: A Review Of Nrel's Feature Stories, National Renewable Energy Laboratory

Publications (E)

The National Renewable Energy Laboratory (NREL) is the nation’s primary laboratory for renewable energy and energy efficiency research and development.

NREL’s mission and strategy are focused on advancing the U.S. Department of Energy’s and our nation’s energy goals. The laboratory’s scientists and researchers support critical market objectives to accelerate research from scientific innovations to market-viable alternative energy solutions. At the core of this strategic direction are NREL’s research and technology development competencies. These areas span from understanding renewable resources for energy, to the conversion of these resources to renewable electricity and fuels, and ultimately to the use of renewable electricity …

Wind Powering America: Fy09 Activities Summary, National Renewable Energy Laboratory

Publications (E)

The Wind Powering America FY09 Activities Summary reflects the accomplishments of state Wind Working Groups, WPA programs at the National Renewable Energy Laboratory, and partner organizations.

Reflective Optics Cpv Panels Enabling Large Scale, Reliable Generation Of Solar Energy Cost Competitive With Fossil Fuels, S. Horne, M. Mcdonald, N. Hartsoch, K. Desy

Publications (E)

The objective of this 18 month subcontract was the improvement of reflective optics CPV panels to enable the large-scale, reliable production of solar electricity to meet SAI-established LCOE targets, and ultimately provide a path to solar power at parity with or better than the cost of energy generated utilizing fossil fuels. To this end, SolFocus has completed this subcontract with great success as evidenced by the end results of a CPV panel with conversion efficiencies greater than the targeted 22% and manufacturing capabilities with a run rate capacity far exceeding the milestone benchmark >3MW.