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2018

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Articles 721 - 750 of 1644

Full-Text Articles in Electrical and Computer Engineering

A Novel Design For A Silicon And Cadmium Telluride Tandem Solar Cell., Jacob A Vittitow May 2018

A Novel Design For A Silicon And Cadmium Telluride Tandem Solar Cell., Jacob A Vittitow

Electronic Theses and Dissertations

No abstract provided.


Software Defined Radio For Cubesat Communication, Sarah Watkins May 2018

Software Defined Radio For Cubesat Communication, Sarah Watkins

Undergraduate Honors Capstone Projects

Cube satellites, more commonly referred to as CubeSats, are small satellites that have become increasingly popular for academic, amateur, commercial, and scientific applications over the past five to ten years. These satellites provide a fairly inexpensive and compact platform for deploying many different types of equipment. While CubeSats do not allow for housing large, complex instruments, some organizations have begun to explore the possibility of deploying networks, or clusters, of CubeSats. Satellites in these clusters could theoretically be tied together via radio frequency communications to accomplish more than a single CubeSat could alone.

This report summarizes the preliminary design and …


Hscr: High Speed Cubesat Radio, Colton Lindstrom May 2018

Hscr: High Speed Cubesat Radio, Colton Lindstrom

Undergraduate Honors Capstone Projects

Software Defined Radios (SOR) are limited by their usable bandwidth, which restricts how quickly they can transmit or receive data. The High Speed Cubesat Radio (HSCR) is capable of transmitting and receiving higher bandwidth signals by combining the bandwidths of several individual SOR transceivers. The HSCR performs phase correction to seamlessly stitch the bandwidths of each individual SOR into a single larger bandwidth.

By increasing the number of SDRs inside the HSCR, the bandwidth of the overall system will increase. This increase in bandwidth is limited only by the speed of the processing unit in working with received or transmitting …


Assisted Switched Reluctance Machines, Amy Robinson May 2018

Assisted Switched Reluctance Machines, Amy Robinson

Honors Scholar Theses

Switched reluctance machine (SRM) modifications in both control schemes and physical design have been steadily increasing in academia to improve machine performance. Assisted switched reluctance machines (ASRMs) are a type of design modification for SRMs. Permanent magnets (PMs) and electromagnetic DC coils (DCC) are being added to the SRM to improve its torque output and overall efficiency. The choice for the design modification has been evolving throughout the decades. The focus has shifted from adding DCC to ASRM to adding PMs to ASRMs. This paper reviews the research trends of ASRMs and includes an analysis of the modified stator yoke …


Buffer Controlled Cache For Low Power Multicore Processors, Marven Calagos May 2018

Buffer Controlled Cache For Low Power Multicore Processors, Marven Calagos

Theses and Dissertations

This thesis proposes a buffered dual access mode cache to reduce power consumption in multicore caches for embedded systems. This cache is called Buffer Controlled Cache (BCC cache). The proposed scheme introduces a pre-cache buffer to determine how to access the cache. The proposed cache shows better prediction rates and lower power consumption than conventional caches, such as Phased cache and Way-prediction cache. For single core implementation, Simplescalar and Cacti simulators have been used for these simulations using SPEC2000 benchmark programs. The experimental results show that the proposed cache improves the power consumption by 37%-42% over the conventional caches. Multi2Sim …


Critical-Point Model Dielectric Function Analysis Of Wo3 Thin Films Deposited By Atomic Layer Deposition Techniques, Ufuk Kılıç, Derek Sekora, Alyssa Mock, Rafał Korlacki, Elena M. Echeverría, Natale J. Ianno, Eva Schubert, Mathias Schubert May 2018

Critical-Point Model Dielectric Function Analysis Of Wo3 Thin Films Deposited By Atomic Layer Deposition Techniques, Ufuk Kılıç, Derek Sekora, Alyssa Mock, Rafał Korlacki, Elena M. Echeverría, Natale J. Ianno, Eva Schubert, Mathias Schubert

Department of Electrical and Computer Engineering: Faculty Publications

WO3 thin films were grown by atomic layer deposition and spectroscopic ellipsometry data gathered in the photon energy range of 0.72-8.5 eV and from multiple samples was utilized to determine the frequency dependent complex-valued isotropic dielectric function for WO3. We employ a critical-point model dielectric function analysis and determine a parameterized set of oscillators and compare the observed critical-point contributions with the vertical transition energy distribution found within the band structure of WO3 calculated by density functional theory. We investigate surface roughness with atomic force microscopy and compare to ellipsometric determined effective roughness layer thickness.


Helping College Students To Manage Stress: A Human Centered Smartphone Application For Stress Relief, Saad R. Almesalm May 2018

Helping College Students To Manage Stress: A Human Centered Smartphone Application For Stress Relief, Saad R. Almesalm

Theses and Dissertations

This dissertation represents a Human Centered Design research to evaluate the perception and handling of stress. To successfully evaluate this research, an iOS smartphone application was developed. This research includes five HCD stages: identify needs, research/analysis, design, evaluation and delivery. The importance of this topic was revealed when we realized that stress can affect students internally and externally. We started with understanding the topic and gathering information about stressed students specifically in college. We created an ontology representing the causes of stress based on previous studies. The ontology includes three main factors: Academic, Social, and Personal/Family stress. In addition, the …


Design, Fabrication, And Characterization Of Novel Optoelectronic Devices For Near-Infrared Detection, Ahmad Nusir May 2018

Design, Fabrication, And Characterization Of Novel Optoelectronic Devices For Near-Infrared Detection, Ahmad Nusir

Graduate Theses and Dissertations

Investigating semiconductor materials and devices at the nanoscale has become crucial in order to maintain the exponential development in today’s technology. There is a critical need for making devices lower in power consumption and smaller in size. Nanoscale semiconductor materials provide a powerful platform for optoelectronic device engineers. They own interesting properties which include enhanced photoconductivity and size-tunable interband transitions.

In this research, different types of nanostructures were investigated for optoelectronic devices: nanocrystals, nanowires, and thin-films. First, lead selenide nanocrystals with narrow bandgap were synthesized, size-tailored, and functionalized with molecular ligands for the application of uncooled near-infrared photodetectors. The devices …


Experimental And Model-Based Terahertz Imaging And Spectroscopy For Mice, Human, And Phantom Breast Cancer Tissues, Tyler Bowman May 2018

Experimental And Model-Based Terahertz Imaging And Spectroscopy For Mice, Human, And Phantom Breast Cancer Tissues, Tyler Bowman

Graduate Theses and Dissertations

The goal of this work is to investigate terahertz technology for assessing the surgical margins of breast tumors through electromagnetic modeling and terahertz experiments. The measurements were conducted using a pulsed terahertz system that provides time and frequency domain signals. Three types of breast tissues were investigated in this work. The first was formalin-fixed, paraffin-embedded tissues from human infiltrating ductal and lobular carcinomas. The second was human tumors excised within 24-hours of lumpectomy or mastectomy surgeries. The third was xenograft and transgenic mice breast cancer tumors grown in a controlled laboratory environment to achieve more data for statistical analysis.

Experimental …


Developing A Hil-Based Software Platform For Testing Electric And Hybrid Vehicle Powertrains, Daniel Schwartz May 2018

Developing A Hil-Based Software Platform For Testing Electric And Hybrid Vehicle Powertrains, Daniel Schwartz

Graduate Theses and Dissertations

The objective of this thesis is to present a dynamometer test stand with hardware in the loop (HIL) testing capabilities for the evaluation of electric and hybrid vehicle powertrains under realistic driving conditions. The traction inverter and dc/dc converter are two crucial subsystems of the powertrain and new prototypes require significant validation before implementing into production vehicles. As fundamental technologies such as power modules, thermal management systems, and passive components improve; the performance improvements to the overall system must be demonstrated. The plug and play nature of the testbed makes it ideal for making direct comparisons of design iterations under …


Design, Fabrication, And Characterization Of All-Inorganic Quantum Dot Light Emitting Diodes, Ramesh Vasan May 2018

Design, Fabrication, And Characterization Of All-Inorganic Quantum Dot Light Emitting Diodes, Ramesh Vasan

Graduate Theses and Dissertations

Quantum dot light emitting diodes are investigated as a replacement to the existing organic light emitting diodes that are commonly used for thin film lighting and display applications. In this, all-inorganic quantum dot light emitting diodes with inorganic quantum dot emissive layer and inorganic charge transport layers are designed, fabricated, and characterized. Inorganic materials are more environmentally stable and can handle higher current densities than organic materials. The device consists of CdSe/ZnS alloyed core/shell quantum dots as the emissive layer and metal oxide charge transport layer. The charge transport in these devices is found to occur through resonant energy transfer …


Automated Control System Design Manual For Plant Growth And Support, Brooke Benham May 2018

Automated Control System Design Manual For Plant Growth And Support, Brooke Benham

Biological and Agricultural Engineering Undergraduate Honors Theses

The “Automated Control System Design Manual for Plant Growth and Support” project contains a teaching manual for high school students and teachers to use to aid in teaching STEM subjects. Building confidence in students and encouraging the pursuit of STEM related fields is one of the primary functions. This project utilizes low cost instruments and freely available software to teach the construction, installation, programming, and application for an automated control system with emphasis on plant growth and regulation. The end result is a fully automated system that can be controlled wirelessly via an android application to monitor temperature, humidity, and …


Real-Time Streaming Video And Image Processing On Inexpensive Hardware With Low Latency, Richard L. Gregg May 2018

Real-Time Streaming Video And Image Processing On Inexpensive Hardware With Low Latency, Richard L. Gregg

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

The use of resource constrained inexpensive hardware places restrictions on the design of streaming video and image processing system performance. In order to achieve acceptable frame-per-second (fps) performance with low latency, it is important to understand the response time requirements that the system needs to meet. For humans to be able to process and react to an image there should not be more than a 100ms delay between the time a camera captures an image and subsequently displays that image to the user.

In order to accomplish this goal, several design considerations need to be taken into account that limit …


Characterization And Analysis Of Ultrathin Cigs Films And Solar Cells Deposited By 3-Stage Process, Grace Rajan, Krishna Aryal, Shankar Karki, Puruswottam Aryal, Robert W. Collins, Sylvain Marsillac May 2018

Characterization And Analysis Of Ultrathin Cigs Films And Solar Cells Deposited By 3-Stage Process, Grace Rajan, Krishna Aryal, Shankar Karki, Puruswottam Aryal, Robert W. Collins, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

In view of the large-scale utilization of Cu(In,Ga)Se2 (CIGS) solar cells for photovoltaic application, it is of interest not only to enhance the conversion efficiency but also to reduce the thickness of the CIGS absorber layer in order to reduce the cost and improve the solar cell manufacturing throughput. In situ and real-time spectroscopic ellipsometry (RTSE) has been used conjointly with ex situ characterizations to understand the properties of ultrathin CIGS films. This enables monitoring the growth process, analyzing the optical properties of the CIGS films during deposition, and extracting composition, film thickness, grain size, and surface roughness which …


Low Latency Intrusion Detection In Smart Grids, Israel Zairi Akingeneye May 2018

Low Latency Intrusion Detection In Smart Grids, Israel Zairi Akingeneye

Graduate Theses and Dissertations

The transformation of traditional power grids into smart grids has seen more new technologies such as communication networks and smart meters (sensors) being integrated into the physical infrastructure of the power grids. However, these technologies pose new vulnerabilities to the cybersecurity of power grids as malicious attacks can be launched by adversaries to attack the smart meters and modify the measurement data collected by these meters. If not timely detected and removed, these attacks may lead to inaccurate system state estimation, which is critical to the system operators for control decisions such as economic dispatch and other related functions.

This …


Application Of Modular Multilevel Converters (Mmc) Using Phase-Shifted Pwm And Selective Harmonic Elimination In Distribution Systems, Thouhidul Islam May 2018

Application Of Modular Multilevel Converters (Mmc) Using Phase-Shifted Pwm And Selective Harmonic Elimination In Distribution Systems, Thouhidul Islam

Graduate Theses and Dissertations

Reducing the size and weight of a power electric system is a prodigious challenge to researchers as the development of the latest technologies emerge in the field of electrical engineering. A similar urge is there to develop a light-weight mobile power substation (MPS) to use in the electric power distribution systems during emergency conditions. This thesis proposes a power electronics based solution using the modular multilevel converter (MMC) topology to design the MPS system. The market-available power semiconductor devices are analyzed and suitable devices are selected to design the system. The phase-shifted pulse width modulation (PS-PWM) and selective harmonic elimination …


Fabrication And Characterization Of Graphene Based 2d Materials For Supercapacitors, Anishkumar Manoharan May 2018

Fabrication And Characterization Of Graphene Based 2d Materials For Supercapacitors, Anishkumar Manoharan

Graduate Theses and Dissertations

Supercapacitors have attracted a lot attention due to their efficient energy storage. In comparison to batteries, supercapacitors have high capacitance, energy, and power densities per unit mass than conventional capacitors. Carbon based materials are most promising in supercapacitor application due to their outstanding physical and electrochemical behavior. In this work, a facile method to synthesize a nanocomposite electrode consisting of annealed carbon from carbon ink and MoS2 was demonstrated. Effects of various aqueous and solid electrolytes were studied. It was found that the nanocomposite electrode with 10% MoS2 and 1M Na2SO4 as the aqueous electrolyte tested using the three electrode …


Gating Methods For High-Voltage Silicon Carbide Power Mosfets, Audrey Dearien May 2018

Gating Methods For High-Voltage Silicon Carbide Power Mosfets, Audrey Dearien

Graduate Theses and Dissertations

The objective of this thesis is to assess the challenges associated with driving Silicon Carbide (SiC) power devices, and to compare the potential gate drive methods for these devices which address those challenges. SiC power devices present many benefits that make them suitable for next generation automotive, power utility grid, and energy management applications. High efficiency, increased power density, and reliability at high-temperatures are some of the main benefits of SiC technology. However, the many challenges associated with these devices have prevented their adoption into industry applications. The argument is made in this thesis that the gate driver is a …


Protection Against Ungrounded Single Phase Open Circuit Faults In 3-Phase Distribution Transformers, Higinio Ariel Montoya May 2018

Protection Against Ungrounded Single Phase Open Circuit Faults In 3-Phase Distribution Transformers, Higinio Ariel Montoya

Master's Theses

This thesis explores the impacts and behavior of 3-phase distribution transformers when subject to ungrounded single phase open circuit faults. A simple 3-phase system is modeled using MATLAB Simulink and operation under fault conditions are simulated and studied. Simulation results are confirmed via lab experimentation. Finally, a robust detection and protection method using neutral current injection (as proposed in industry literature) is built and demonstrated.

Electric utility operating experience has demonstrated that all too often, loads on 3-phase distribution transformers are not adequately protected against an ungrounded single phase open circuit fault (commonly called “single phasing”). This type of fault …


Improving Operator Situation Awareness By Phasor Measurement Unit (Pmu) Data Visualization, Esa M. Rantanen, Ernest Fokoue, Jacob Haut, Chandini Ramesh, Kathleen Gegner, Thomas Overbye, Komal Shetye May 2018

Improving Operator Situation Awareness By Phasor Measurement Unit (Pmu) Data Visualization, Esa M. Rantanen, Ernest Fokoue, Jacob Haut, Chandini Ramesh, Kathleen Gegner, Thomas Overbye, Komal Shetye

Articles

The application of phasor measurement unit (PMU) data in the power industry is currently an area of intense interest. The key driver for PMU technology is to use the precise time sources provided by Global Positioning System (GPS) satellites to accurately measure the relative voltage and current phase angles at buses across an interconnect at a very high sampling rate. Presenting PMU data to power system operators in a format that is truly useful for them and that affords improved situation awareness (SA) and fast and accurate decision making is a particular challenge to display design. This report describes development …


Remote Vibration Estimation Using Displaced-Phase-Center Antenna Sar For Strong Clutter Environments, Justin B. Campbell, Francisco Pérez, Qi Wang, Balasubramaniam Santhanam, Ralf Dunkel, Armin W. Doerry, Thomas Atwood, Majeed M. Hayat May 2018

Remote Vibration Estimation Using Displaced-Phase-Center Antenna Sar For Strong Clutter Environments, Justin B. Campbell, Francisco Pérez, Qi Wang, Balasubramaniam Santhanam, Ralf Dunkel, Armin W. Doerry, Thomas Atwood, Majeed M. Hayat

Electrical and Computer Engineering Faculty Research and Publications

It has been previously demonstrated that it is possible to perform remote vibrometry using synthetic aperture radar (SAR) in conjunction with the discrete fractional Fourier transform (DFrFT). Specifically, the DFrFT estimates the chirp parameters (related to the instantaneous acceleration of a vibrating object) of a slow-time signal associated with the SAR image. However, ground clutter surrounding a vibrating object introduces uncertainties in the estimate of the chirp parameter retrieved via the DFrFT method. To overcome this shortcoming, various techniques based on subspace decomposition of the SAR slow-time signal have been developed. Nonetheless, the effectiveness of these techniques is limited to …


Association Learning Via Deep Neural Networks, Trevor J. Landeen May 2018

Association Learning Via Deep Neural Networks, Trevor J. Landeen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Deep learning has been making headlines in recent years and is often portrayed as an emerging technology on a meteoric rise towards fully sentient artificial intelligence. In reality, deep learning is the most recent renaissance of a 70 year old technology and is far from possessing true intelligence. The renewed interest is motivated by recent successes in challenging problems, the accessibility made possible by hardware developments, and dataset availability.

The predecessor to deep learning, commonly known as the artificial neural network, is a computational network setup to mimic the biological neural structure found in brains. However, unlike human brains, artificial …


Radio-Frequency Transmitter Geolocation Using Non-Ideal Received Signal Strength Indicators, Samuel Whiting May 2018

Radio-Frequency Transmitter Geolocation Using Non-Ideal Received Signal Strength Indicators, Samuel Whiting

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Locating a radio transmitter is important in a number of problems such as finding radio tags, people with radios, and devices that are collecting information in an unauthorized manner. Locating a radio transmitter is inherently difficult because the radio waves of concern are not in the visible spectrum, they reflect and distort easily, and they propagate at the speed of light.

A number of methods for locating transmitters are currently used, the majority of which require expensive hardware and extensive processing. This thesis presents a method of using simpler measurements to produce similar location estimates in order to augment or …


Infrared Resonant-Coupled Metamaterial Sensing And Phonon-Polariton-Enhanced Infrared Interconnects, Michael Francis Finch May 2018

Infrared Resonant-Coupled Metamaterial Sensing And Phonon-Polariton-Enhanced Infrared Interconnects, Michael Francis Finch

Theses and Dissertations

Coupled-mode theory has been applied to various fields of endeavor from waveguide splitters/combiners and molecular sensing to light-matter interactions. Metamaterials, engineered periodic or aperiodic structures, are employed to sense molecular vibrational fingerprints in the mid to long infrared wavelengths. A metasurface, a 2D metamaterial, can be designed such that it has a resonance at a molecular vibrational frequency. Mode splitting results from the coupling of two electromagnetic field distributions, or modes, spatially and/or temporally. Metamaterial and molecular resonance coupling is a result of near field interaction. Fano resonances have an asymmetric line-shape that results from the coupling of a continuum …


Modular, Scalable Battery Systems With Integrated Cell Balancing And Dc Bus Power Processing, Muhammad Muneeb Ur Rehman May 2018

Modular, Scalable Battery Systems With Integrated Cell Balancing And Dc Bus Power Processing, Muhammad Muneeb Ur Rehman

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Traditional electric vehicle and stationary battery systems use series-connected battery packs that employ centralized battery management and power processing architecture. Though, these systems meet the basic safety and power requirements with a simple hard- ware structure, the approach results in a battery pack that is energy and power limited by weak cells throughout life and most importantly at end-of-life. The applications of battery systems can benefit significantly from modular, scalable battery systems capable of advanced cell balancing, efficient power processing, and cost gains via reuse beyond first-use application. The design of modular battery systems has unique requirements for the power …


Advancing The Understanding Of Environmental Transformations, Bioavailability And Effects Of Nanomaterials, An International Us Environmental Protection Agency—Uk Environmental Nanoscience Initiative Joint Program, Mitch M. Lasat, Kian Fan Chung, Jamie Lead, Steve Mcgrath, Richard J. Owen, Sophie Rocks, Jason M. Unrine, Junfeng Zhang Apr 2018

Advancing The Understanding Of Environmental Transformations, Bioavailability And Effects Of Nanomaterials, An International Us Environmental Protection Agency—Uk Environmental Nanoscience Initiative Joint Program, Mitch M. Lasat, Kian Fan Chung, Jamie Lead, Steve Mcgrath, Richard J. Owen, Sophie Rocks, Jason M. Unrine, Junfeng Zhang

Plant and Soil Sciences Faculty Publications

Nanotechnology has significant economic, health, and environmental benefits, including renewable energy and innovative environmental solutions. Manufactured nanoparticles have been incorporated into new materials and products because of their novel or enhanced properties. These very same properties also have prompted concerns about the potential environmental and human health hazard and risk posed by the manufactured nanomaterials. Appropriate risk management responses require the development of models capable of predicting the environmental and human health effects of the nanomaterials. Development of predictive models has been hampered by a lack of information concerning the environmental fate, behavior and effects of manufactured nanoparticles. The United …


Electrochemical Oxidation Of P-Chlorophenol On Porous Ti/Bdd Electrode Cooperated With Cathode Dechlorination, Rong-Ling Chen, Wei-Min Huang, Ya-Peng He, Jun Shi, Hai-Bo Lin Apr 2018

Electrochemical Oxidation Of P-Chlorophenol On Porous Ti/Bdd Electrode Cooperated With Cathode Dechlorination, Rong-Ling Chen, Wei-Min Huang, Ya-Peng He, Jun Shi, Hai-Bo Lin

Journal of Electrochemistry

The electrochemical oxidation of p-chlorophenol on porous Ti/BDD electrode cooperated with synergistic effect of cathode dechlorination was studied. Electrochemical degradation tests of p-chlorophenol were conducted in single and double compartment electrolytic cells separately, and the results showed that the mineralization happened mainly in the anode region. The product of chloride ions produced from the cathodic reduction of 4-chlorophenol in the single cell migrated to the anode region and further generated active chlorine toward electro-catalytic oxidation. At the same time, the chloride ion produced from the cathode of the double cell was difficult to be migrated to the anode region, which …


Preparation Of Ni(Dpim)2Cl2 Complex For The Electrocatalytic Reduction Of Co2, Li-Pu Zhang, Dong-Fang Niu, Xin-Sheng Zhang Apr 2018

Preparation Of Ni(Dpim)2Cl2 Complex For The Electrocatalytic Reduction Of Co2, Li-Pu Zhang, Dong-Fang Niu, Xin-Sheng Zhang

Journal of Electrochemistry

A new Ni(dpim)2Cl2complex using 2-(diphenylphosphino)-1-methylimidazole (dpim) as ligand was prepared and served as a catalyst for the electrochemical reduction of CO2. The electrochemical redox behavior of Ni(dpim)2Cl2 in CH3CN/TPABF4 solution under nitrogen atmosphere showed the two-electron irreversible reduction at -0.7 V and one-electron quasi-reversible reduction at -1.3 V. After bubbling CO2 into the electrolyte, the reduction peak appeared at -1.3 V became irreversible and the peak current increased from 0.48 mA·cm-2 to 0.55 mA·cm-2. Moreover, the peak current at -1.3 V could further increase …


Preparation And Properties Of Manganese Oxide And Polyaniline-Carbon Composite Electrode, Tian-Tian Zhou, Bing Wu, Chao Deng, Ying Gao Apr 2018

Preparation And Properties Of Manganese Oxide And Polyaniline-Carbon Composite Electrode, Tian-Tian Zhou, Bing Wu, Chao Deng, Ying Gao

Journal of Electrochemistry

The polyaniline-carbon (PAnC) electrode was prepared by the polymerization of aniline monomer and activated carbon in ice water bath, and followed by chemical deposition of manganese dioxide MnO2-PAnC composite material. The specific capacitance of MnO2-PAnC reached 459 F•g-1. The cyclic voltammetric results showed a small deformation in the voltammogram curve obtained with the MnO2-PAnC electrode at high scan rate, indicating good reversibility and capacitive properties. The AC impedance results revealed that the MnO2-PAnC electrode displayed the smallest charge transfer resistance and the fastest diffusion
rate of surface ions than other …


Preparation Of Co3O4/Ti Electrocatalytic Membrane Electrode For Catalytic Oxidation Of Benzyl Alcohol, Yu-Mei Zheng, Zhen Yin, Hong Wang, Jian-Xin Li Apr 2018

Preparation Of Co3O4/Ti Electrocatalytic Membrane Electrode For Catalytic Oxidation Of Benzyl Alcohol, Yu-Mei Zheng, Zhen Yin, Hong Wang, Jian-Xin Li

Journal of Electrochemistry

The cobalt oxide(Co3O4) nanoparticles were loaded on microporous Ti membrane to prepare Co3O4/Ti electrocatalytic membrane electrode by dip-coating method. The microstructures and electrochemical properties of Co3O4/Ti electrocatalytic membrane were investigated. The Co3O4/Ti electrocatalytic membrane reactor (ECMR) assembled by using the Co3O4/Ti electrocatalytic membrane as an anode was adopted for catalytic oxidation of benzyl alcohol to produce benzaldehyde and benzoic acid.The effects of different operation parameters on benzyl alcohol conversion, and selectivity to benzaldehyde and benzoic acid of ECMR were studied. …