Electrical and Computer Engineering Commons^™

The Electrochemical Reduction Of 2-Ethylanthraquinone (2eaq), Yaobin Zhu

Journal of Electrochemistry

The process of electrochemical reduction of 2EAQ in DMSO is studied using CVand ESR methods in this work, Pt, Pd and some implanted materials are used as electrodes. The quasi-rever-sible property of two electron transfer steps and their following homogeneous chemical reactions are illustrated. The mechanism of the electrochemical red uction of 2EAQ and the kinetic parameters of the related steps are obtained. Having measured the influence of water content in the system, the effect of the proton donor is discussed. After comparising the experimental results with each other these experiments gives us the idea that the replacement of metal …

Horseradish Peroxidase/Poly-O-Phen Ylenediamine Mem Brane Electrode: Preparation And Properties, Dong Wei, Huihuang Wu

Journal of Electrochemistry

A horseradish peroxidase (HRP)/poly-o-phenylenediamine (PPD) membrane electrode was prepared by electropolymerization of o-phenylenediamine on glassy carbon in pH 7.0 phosphate buffer, the process of the enzyme immobilization was studied. The enzyme electrode obtained exhibits the activity to catalyze the electroreduction of hydrogen peroxide in the absence of any electron transfer mediator. The red uction reaction occurs in the potential range of PPD redoxprocess, it was believed that the polymer participates in electron transfer of the enzyme. The enzyme reaction kinetics at rotating HRP/PPD electrode was analysed, and the factors influencing kinetic parameters were discussed.

Laser Scanning In-Situ Photoelectrochemical Microscopictechnique And Its Applications, Zugeng Lin, Jinkua You, Xiangdong Zhuo, Chun Zhang, Yong Yang

Journal of Electrochemistry

The main factors of the laser scanning in-situ photoelectrochemical microscopic measurement system which is set up in our lab have been discusaed in this paper. Some applications of this technique for in-situ study of modification and processing of semiconductor electrodes, monitoring of electro deposition process of semiconducting material and redox reaction occurring at metal oxide electrodes have also been presented. The results have shown that the technique is very powerful that for studing local photoelectrochemical properties of semiconductors and metal oxide electrodes. These provide important information on the micro structural and electronic properties in the solid/electrolyte interface.

Studies On Low Temperature Performance Of Rechargeable Mh-Ni Batteries, Wenkuan Zhang, Jingxian Shi, Yuwan Lou, Qiusheng Duan

Journal of Electrochemistry

The Dependence of low temperature performance on the alloy composition and electrolyte component for rechargeable MH-Ni batteries is studied, the suitable composition of alloy and electrofyte are founds.

An Indirect Electrochemical Oxidation Of Toluene──Anodic Oxidation Of Mn(Ⅱ) On The Lead Electrode, Zhonghua Wang, Qingmin Hua, Guacai Chen, Zhongquan Wang, Yunan Qiu, Xingguo Yan

Journal of Electrochemistry

The electrochemical oxidation of Mn(Ⅱ) to Mn(Ⅱ) in concentrated H₂SO₄ (2 ~ 8 mol⋅L^-1) at lead electrode has been studied. It is found that the electrode surface is oxidized to PbO₂ in a direct electrochemical reaction, then PbO₂ formed reacts with Mn(Ⅱ) in a chemical reaction. Some effects involves current density, concentration of H₂SO₄, temperature and conversionwere evaluated. The rule of electrogenerated Mn(Ⅲ) in flow electrolysis cell were determined at several conditions. The current efficiency at greater than 90% is obtained in general.

Electrochemically Modified Glassy Carbon Electrode And Determination Of Copper By Anodic Stripping Voltammetry, Jinrui Xu, Yie Liu, Xiurun Zhuang, Tomoo Miwa, Toyohide Takeuchi

Journal of Electrochemistry

This paper reported the glassy carbon electrode modified by cyclic voltammetrybetween -0.1 and +1.5 V (vs. SCE) in an aqueous solution containing catechol, for maldehyde and talium hydroxide. The modified electrode can be applied to the determination of copper(Ⅱ) in water, and its sensitivity is about 35 times higher than that of unmedified glassy carbon electrode, The quantitative limit with this modified electrode is 0.1 ng/ml.

The Reduction Of Oxygen To Hydrogen Peroxide At The Poly(O-Phenylenediamine)-Filmed Electrode, Zhaoe Lu, Tiangeng Zhong, Guanyong Zhang

Journal of Electrochemistry

The poly(o-phenylenediamine) (PPD) filmed graphite electrode was formed by electro-polymerization of o-phenylenediamine in acidified (pH=1) 0.2 mol·L^-1 Na₂SO₄ solution using the cyclic voltammetric methed. The catalytic effect of the electrcareduction of oxygen in acid olution was demonstrated by the voltammogram of the electrode in the oxygen saturated acid solutionof Na₂SO₄. The current efficiency of the reduction of oxygen to hydrogen peroxide was determined by the electrolysis in a divided cell under the condition of constant current. The various effectsinfluencing the accmulation of H₂O₂ in the catholyte were discussed.

Studies On Coordination Behavior Of Dimethyl Sulfoxide In Complex Of Rare Earth With Cryptand, Shichang Liu, Tianpei Zhu

Journal of Electrochemistry

Electrochemical reduction reaction in the course of the titration of Eu(2.2.2) and Eu(2.2) using strong bonding solvent, DMSO, in C₂H₄Cl₂ has been investigated by cyclic voltammetry. The greater the concentration of strong bonding solvent, the more negative the half-wave potentials for the reduction reaction are. The coordination number of Eu(2.2.2) and Eu(2.2) which are 2 and 3 respectively, with DMSO can be calculated, according to the relations between half-wave potentials and the variety of concentration of DMSO.

The Study Of The Growth Processes Of The Oxides On Lead Electrodes In Sulfuric Acid Solution, Hesheng Zhai, Xuguang Chen, Jinkua You, Yong Yang, Zugeng Lin

Journal of Electrochemistry

The growth processes of PbO and PbO₂ on lead electrodes have been investigatedby using in-situ methods that are combined with temporary AC resistance measurment technique and in-situ laser scanning photoelectrochemical microscopy. It is found that a linear relationship existsbetween the electrode resistance(R) and^1/2 after the electrode is oxidized at +0.6 V(vs.Hg/H₂SO₄/35% H₂SO₄) for more than 5 min. This result suggests that the growth of PbO is well distributed during the early stage of oxidation. The study by using laser scanning photoelectrochemical microscopy has further proved this point. The results also …

The Catalytic Behavior For Ni-W Electrode Modified By Carbon Ion Beam Implantion, Jishuang Zhang, Yaojiao Lv, Qinglian Li, Baoen Shen

Journal of Electrochemistry

The hydrogen evolution activity in acidic and basic mediums for Ni-W electrodemodified by carbon ion bean implantation was investigated. The experimental results show thiselectrode has superior catalytic activity for the hydrogen evolution reaction than that of the unmodified Ni-electrode. Long period testing of electrolysis under high current density show that this electrode hasalonger useful life hence it is a practical electrode material. The temperature effect of electrocatalytic property was also inverstigated. The experimental regularities are explained on the basis of the formation of surface multialloys of Ni-W-WC.

A Photoelectrochemical Investigation Of Zirconium Oxide Film, Maizhi Yang, Ping Wei, Di Quarto F., Piazza S., Sunseri C.

Journal of Electrochemistry

A photoelectrochemical investigation has been carried out on zirconium initialoxide film and its oxide film grownanodically at constant rate up to different thickness. Both anodicand cathedic photocurrents on the photocurrent spectrum depended on the potential, but had littlerelation with the forming anedic films or measuring solutions. Photocurrent spectrum and photocurrenttransients suggested that the oxide films on zirconium were duplex layers structure. The internal layerwas ZrO₂ and the external layer ZrO₂·(H₂O)_n. The photocurrent included photogenerated carrier ininternal and external oxide films, as well as internal photoinjection process for electrons from thesubstrate metal into the …

Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang

Journal of Electrochemistry

The titanium substrates were bombarded with 1×10¹⁷～5×10¹⁷ ions·cm^-2 ofpalladium at the room temperature. The surface composition of implanted electrode and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene (NB) in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry. The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion, which is the product of one-electronelectroreduction of NB, was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of …

Electroreduction Of Holmium Ion On Iron Electrde In Molten Cholorides, Qiqin Yang, Guankun Liu, Yuzhi Su

Journal of Electrochemistry

The cyclic voltammetry, open circuit potential-time curve after poteritiostatic electrolysis, current-time curve at potential step, X-ray diffraction and electron probe microanalysiswere used to investigate the electrode process of Ho(Ⅲ) reduced on iron electrode in molten chloridesand the phases of surface alloy layer. The Ho-Fe alloys are formed at first, and then the metallic holmium is deposited when Ho(Ⅲ) is reduced on iron electrode. The charge transfer is reversible. The free energies of formation for the four inter metallic compounds of Ho-Fe system, the diffusion coefficients and diffusion activation energy of Ho in alloyed cathode are determined.

Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/SbAd Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_ad) was investigated. Results showed that the Pt/Sb_ad electrode was electrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid. In the case of formaldehyde, an oxidation peak appeared at a potential of ca. 0.7V. During the oxidation of formic acid, a 4-fold increase in the 1st peak current was observed. The Sb-modified platinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05. The electrocatalytic activity of the Pt/Sb_ad electrode can be best …

Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO₂ during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the Li_xCoO₂ crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co₃O₄ when deeply charge.The variation of lattice parameter C₀ value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …

Using Matlab To Illustrate The 'Phenomenon Of Aliasing', Sol Neeman, Ph.D.

Engineering Studies Faculty Publications and Creative Works

The phenomenon of aliasing is important when sampling analog signals. In cases where the signal is bandlimited, one can avoid aliasing by ensuring that the sampling rate is higher than the Nyquist rate . But in cases where the signal is not bandlimited , aliasing is unavoidable if the signal is not filtered before it is sampled. It is then crucial to understand the phenomenon in order to estimate the distortion generated when the signal is reconstructed from its samples. Using the software package MATLAB by MathWorks, Inc ., two examples are presented. The first is a pure sinusoid which …

Model For Complete Drawdown Of Floating Solids In Stirred Tank Reactors, J Mmbaga

Tanzania Journal of Engineering and Technology (TJET)

A Semi-empirical model has been developed on the basis of Kolmogoroff's theory of isotropic turbulence to determine the minimum drawdown speed for floating solids in a mechanically agitated vessel. An adjustable pa- rameter in the model is found to be afunction of impeller type and position in a vessel. A simplified representation of macroscopicflow pattern, rep- resenting the circulation flow in a vessel depending on impeller pumping characteristic is developed to account for recirculation pattern.

Application Of Improved Pressure Transducers For Pressure Measurements, P Mtui

Tanzania Journal of Engineering and Technology (TJET)

Substantial improvement of low sensitivity pressure transducers aiming at obtaining a more realistic output signal is discussed. The output signal direct from these transducers has deficiencies of amplitude attenuation and phase lag, thus the measured values are not necessarily the true in- stantaneous values. In order to correct for such shortcomings the unit step response of these transducers is also studied experimentally. A math- ematical model is established based on the experimental results to build up a compensation circuit which is then included in the instrumentation setup to eliminate these deficiencies. The effectiveness of the compensated transducer is demonstrated by …

An Alternative Method Of Interfacing A Dc Motor To A Microprocessor For Mo- Tion Control, M Selekwa

Tanzania Journal of Engineering and Technology (TJET)

A Simple and cheap alternative method Of interfacing a permanent mag- net dc motor to a motion control using switch- ing transistor motor drivers is presented. This method involves the use Of very few transistor-transistor logic (TTL) devices and a 555 timer to pro- duce a pulse width modulated (P WM) signal which is required by the mo- ror driver. The motor driver in this case should be of an H-bridge type. Like other methods currently in use, it relieves the MPU of all timing func- tions which are necessary in the generation of P WM signals. The present method, …

Practical Aspects In Sensing Vrm Magneti- Sation Characteristics For Rotor Position Detection, N Mvungi

Tanzania Journal of Engineering and Technology (TJET)

The detection of rotor position (stator/roror poles overlap) in a variable reluc- tance motor using the dependence of permeance on rotor position is the core of the effort to eliminate the need of a physical position sensor in the rotor shaft in the positional feedback operation of the motor. The reliability of the whole proc- ess Of eliminating the need of a physical sensor rests squarely On the ability to measure the instantaneous permeance ofa phase when the motor is in operation and at stand still. This paper presents an experimental investigation on the in- triguing problems of obtaining repeatable …

Simultaneous Design Of Active Vibration Control And Passive Damping, Michele Lynn Devereaux Gaudreault

Theses and Dissertations

A modified form of the standard linear quadratic regulator LQR cost functional is used to optimally blend active vibration control and passive structural damping, whether viscous or viscoelastic. Viscoelastic damping is first modelled by a standard linear model, and then by a fractional derivative model. For the viscous damping case and the classically modelled viscoelastic damping case, a sub-optimal closed form solution is derived that is independent of the initial conditions. An iterative technique that minimizes the average value of the cost functional and one that minimizes the maximum value are developed. Both techniques are applicable to viscous and viscoelastic …

Robot Force Velocity Control Using Expert System For Control Mode Changes, William R. Doggett

Electrical & Computer Engineering Theses & Dissertations

The most important property of an automated mechanical system is reliable execution of a specified task. Automated mechanical systems work best in precisely structured environments where all operations are repeatable. Typically, these systems are difficult to modify and expensive to install. Sensors can be used to detect disturbances, thus reducing hardware cost by offsetting the need for precise rigid construction components. Sensors, however, increase the complexity and cost of the control software. Efficient methods of reacting to sensor information during automated system operation are required to reduce software complexity and expense.

This thesis analyzes a robotic construction task and describes …

Theoretical And Experimental Study Of Inlet Manifold Pressure Profiles Using Compensated Transducers, P Mtui

Tanzania Journal of Engineering and Technology (TJET)

Computer simulation and experimental findings on single cylinder four-stroke cycle engine were done with a view of getting more realistic inlet manifold pressures. Since there is a direct relationship between the inlet pressure profiles and the volumetric efficiency of the engine, then there is a possibility of utilizing the knowledge of these profiles to enhance better engine air flow characteristics and hence improvement of engine performance.

The simulation program is based on hometropic process with constant specific heats where the results were validated using experimental findings of the engine with varying engine speeds.

Experimental results are obtained by measuring manifold …

Electrical Equivalent Method For The Calculation Of Vibrations In Transformers, D Chambega

Tanzania Journal of Engineering and Technology (TJET)

Noiselevel calculations may be done using an electrical equivalent method. So far a single mass and a double mass vibrating system may easily be represented by equivalent electrical circuits which are in turn useful for analysis. Multimass vibrating systems like transformers do not have straightforward methods which can enable analysis of noiselevels. This paper attempts to develop such a method by extending the method applicable to a double mass vibrating system. Then the validity of the method is tested using a transforme

Comparison Of Digital Controllers Used In Magnetic Suspension And Balance Systems, William A. Kilgore

Mechanical & Aerospace Engineering Faculty Publications

Dynamic systems that were once controlled by analog circuits are now controlled by digital computers. Presented is a comparison of the digital controllers presently used with magnetic suspension and balance systems. The overall responses of the systems are compared using a computer simulation of the magnetic suspension and balance system and the digital controllers. The comparisons include responses to both simulated force and position inputs. A preferred digital controller is determined from the simulated responses.

Hydrogenation Effects On Trap Related Conduction In Diamond, Linwood Cleveland Watkins Iii

Electrical & Computer Engineering Theses & Dissertations

In this research work, the results of an experimental investigation on the electrical conduction mechanism in type Ιa and Ilb diamonds are presented. These results are compared with those of previous theoretical studies. The basic physical properties of diamond are discussed. Details of ohmic contact formation on diamond are presented.

The current-voltage characteristics revealed the presence of traps located below the Fermi level. The unfilled trap density was determined. The deep traps were further studied using spectroscopic photoconductivity measurements and the trap energy levels were determined.

The effects of hydrogenation on trap related conduction were studied subsequently. Hydrogenation was carried …

An Electro Hydrodynamic Study Of The Negative Corona Electric Wind, Henry Thadei Kadete

Tanzania Journal of Engineering and Technology (TJET)

The velocity of corona generated electric wind is measured. From the velocity profile mass movement and electrokinetic conversion efficiencies are deduced. High speed schlieren photographs illustrate the form of the velocity distribution function as well as its high degree of turbulence.

Negative Corona Current Characteristics Of An Electric Wind System, Aviti Kadete

Tanzania Journal of Engineering and Technology (TJET)

The corona current characteristics of an electric wind system are investigated. First a brief summary of the negative point to plate corona mechanism and characteristics are presented. Then empirical equations for corona currents of an electric wind system are derived. Current waveform characteristics are also discussed. The effects of placing parallel rods in between a point-plate electrode gap to the corona currents are highlighted.

Ua64/3 Readout, Wku Industrial Education & Technology

WKU Administration Documents

Newsletter includes articles:

• New Departmental Programs
• Crisp, Jeff. Vocational-Industrial & Technical Teacher Education CBTE Project
• Lyons, Jerry. Not a Dirty Word, re productivity
• Conley, Frank. Comment, re: scholarships
• Dye, Wandel. Airbrush Rendering
• Student Chapter of SME Formed
• New Equipment Inventory
• Nalbach Demonstration Highlights Semester
• Environmental Science & Technology Building
• Industrial Technology Lecture Series

Ua64/3 Readout, Wku Industrial Education & Technology

WKU Administration Documents

Newsletter includes the following articles:

• Environmental Science & Technology Building
• Redrup, Donald. A Philosophy of Industrial Arts - ?
• Conley, Franklin. A Comment, re: energy crisis
• Bywaters, Gary. Student vs Faculty Sports
• Redrup, Donald. Department Possesses EDM Capability
• Craftsman and Guitar Genuis Speaks, re: Hascal haile
• Bochan, John. Computer Controlled Machinery at WKU
• Bywaters, Gary. Western Wins at KIEA
• Mr. Walter Nalbach Honored.