Environmental Engineering Commons^™

Denitrification And Biological Phosphorus Removal Using Focused, Pulse-Treated, Thickened Waste Activated Sludge As An Internal Carbon Source, Holly Anne Hillard

Civil & Environmental Engineering Theses & Dissertations

Recent research shows that an internal carbon source, derived from the treatment of waste activated sludge (WAS), could be used as an alternative to external carbon sources for denitrification in biological wastewater treatment processes. In this study, a thickened waste activated sludge (TWAS) treatment technology, developed by the company OpenCEL, was used to treat TWAS with pulsed electric fields (PEF) to transform it into an organic substrate for heterotrophic denitrification in a biological nutrient removal (BNR) system. If effective, this technique could significantly reduce the external carbon source demand.

To determine the utility of OpenCEL-treated TWAS as an internal carbon …

Ion Exchange Nutrient Recovery From Municipal Wastewater, Allen Williams

Master's Theses (2009 -)

Nitrogen and phosphorus discharge is regulated due to eutrophication. Typically ammonium-nitrogen is removed through nitrification which requires energy and phosphorus (P) is removed by metal salt addition to precipitate P. A more sustainable approach may be to implement nutrient recovery to form fertilizers. Most nitrogen fertilizer is formed through the energy intensive Haber-Bosch process. Phosphate rock, a limited resource, is mined for P fertilizer. Discharge regulations and the fertilizer production costs provide an economic driver for recovery. The current project used anionic and cationic ion exchange (IX) to concentrate the nutrients with recovery by struvite precipitation. Previous work lacks direct …

Anaerobic Co-Digestion Planning And Research For Green Bay, Wi, Jonathan Kusowski

Master's Theses (2009 -)

The aspiration to find an alternative sustainable fuel source is an ever growing concern. Anaerobic digestion might hold the answer to finding an alternative sustainable energy source. Anaerobic digestion does not only provide a renewable resource in the form of biogas, but also stabilizes wastes, preventing large amounts from being landfilled or incinerated. Anaerobic digestion of municipal wastewater sludges can often be improved by the addition of high strength industrial wastes, in a process called co-digestion. High strength industrial wastes provide an additional carbon source for the microbes to utilize and convert into usable biogas. Co-digestion also offers the opportunity …

Optimization Of Demon® Sidestream Treatment And Potential For Anammox Mainstream Bioaugmentation, Andrea Lauren Nifong

Civil & Environmental Engineering Theses & Dissertations

Anaerobically digested sludge dewatering liquors (e.g. centrate) can represent 15-25% of the total kjeldahl nitrogen (TKN) load on a typical municipal waste water treatment plant (WWTP). Sidestream nitrogen removal has been demonstrated to be an effective tool for improving nitrogen removal performance and reliability with a savings in aeration energy, chemicals (supplemental alkalinity and carbon), and sludge production.

Deammonification, partial nitritation by ammonia oxidizing bacteria (AOB) combined with anaerobic ammonium oxidation (AMX or anammox), provides near complete nitrogen removal with a 65% reduction in energy and 100% reduction in supplemental carbon and alkalinity requirements as compared to traditional nitrification-denitrification. The …

Evidence Supporting Treatment Practice Based Delineation Of Stormwater Runoff Zones, Jacob J. Gorski

Dissertations and Theses

Particles mobilized by stormwater negatively affect receiving surface waters. Stormwater best management practices (BMPs) can reduce solids along with associated pollutants in runoff but engineers and environmental managers have been long vexed by the problem of choosing the optimal BMP for a given situation. A common BMP process for solids removal is sedimentation. This thesis addresses the question of whether the effectiveness (and thus choice) of a sedimentation device can be estimated (and thus optimized) from the particle size properties of runoff, which, in turn, could be associated with specific runoff zones or land uses. Presented here is a series …

Characterization Of Secondary Organic Aerosol Precursors Using Two-Dimensional Gas Chromatography With Time Of Flight Mass Spectrometry (Gc×Gc/Tofms), Melissa Jordan Roskamp

Dissertations and Theses

The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality through the formation of secondary organic aerosols (SOA). More than 1000TgC/yr of non-methane VOCs are emitted from biogenic sources (significantly greater than from anthropogenic sources). Despite this magnitude and potential importance for air quality, the body of knowledge around the identities, quantities and oxidation processes of these compounds is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). Two-dimensional gas chromatography paired with time-of-flight mass spectrometry (GC×GC/TOFMS) is a powerful analytical technique which is explored here for its role in better …

Rooftop Pv Impacts On Fossil Fuel Electricity Generation And Co2 Emissions In The Pacific Northwest, Daniel Albert Weiland

Dissertations and Theses

This thesis estimates the impacts of rooftop photovoltaic (PV) capacity on electricity generation and CO2 emissions in America's Pacific Northwest. The region's demand for electricity is increasing at the same time that it is attempting to reduce its greenhouse gas emissions. The electricity generated by rooftop PV capacity is expected to displace electricity from fossil fueled electricity generators and reduce CO2 emissions, but when and how much? And how can this region maximize and focus the impacts of additional rooftop PV capacity on CO2 emissions? To answer these questions, an hourly urban rooftop PV generation profile for 2009 was created …

Gloria Slope Approach - Monitoring Plant Community Changes In Mountain Ecosystems, Jarle I. Holten, Sverre Lundemo, Ph.D.

Guest Lectures

The research described in this presentation is part of the Global Observation Research Initiative in Alpine Environments (GLORIA) whose purpose is to establish and maintain a global, long-term observation network in alpine environments.

Despite changes in mountaintop-vegetation due to recent climate change being observed throughout the world, trends are not consistent. Moreover, as plant communities can be impacted by several different factors, it is important to be able to separate what is due to climate change and what is due to e.g. changes in grazing pressure (see additional file below).

A Novel Approach To Flow Estimation In Tidal Rivers, Hamed Moftakhari Rostamkhani, David A. Jay, Stefan A. Talke, Tobias Kukulka, Peter D. Bromirski

Civil and Environmental Engineering Faculty Publications and Presentations

Reliable estimation of river discharge to the ocean from large tidal rivers is vital for water resources management and climate analyses. Due to the difficulties inherent in measuring tidal-river discharge, flow records are often limited in length and/or quality and tidal records often predate discharge records. Tidal theory indicates that tides and river discharge interact through quadratic bed friction, which diminishes and distorts the tidal wave as discharge increases. We use this phenomenon to develop a method of estimating river discharge for time periods with tidal data but no flow record. Employing sequential 32 day harmonic analyses of tidal properties, …

Passive Stormwater Samplers For Sampling Highway Runoff From Bmps: Feasibility Studies, Mitchell R. Klein

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Pollution from highway stormwater runoff has been an increasing area of concern within the environmental field. To respond to the need for reduced contamination within runoff many Best Management Practices (BMPs) have been implemented. One difficult aspect of BMPs is monitoring their effectiveness along with determining effluent concentrations. The current methods for stormwater sampling include sending technicians or installing an auto-sampler to collect either grab or composite samples. These methods become costly, cumbersome and infeasible due to the potentially large amount of BMPs across a region and the irregularity and difficulty of predicting storms. Passive samplers have proven themselves as …

Renovation Of Ammonia Contaminated Produced Water Using Constructed Wetlands, Donald Beebe

All Dissertations

Pilot-scale wetland treatment systems were designed and constructed to evaluate renovation of simulated oilfield produced water contaminated with ammonia (20 mg/L ammonia-N). A process-based pilot-scale constructed wetland was designed to meet specific biogeochemical conditions for conversion of ammonia to nitrogen gas through microbial nitrification and denitrification. The process-based constructed wetland treated the simulated produced water to meet stringent discharge requirements (less than 1.2 mg/L ammonia-N). Clinoptilolite, a zeolite mineral, was evaluated for use in constructed wetlands to increase ammonia sorption and nitrification activity. Clinoptilolite increased wetland ammonia sorption capacity and served as a microbial carrier for nitrifying bacteria when ranges …

Improvement Of Onsite Wastewater Treatment By Use Of Electrically Conductive Carbon Cloth, Christopher Weber

All Theses

The purpose of this research is primarily focused on carbon oxidation in domestic septic systems. Small-scale septic waste reactors utilizing electrically conductive carbon cloth were assessed for improving carbon oxidation and therefore the overall efficiency of on-site wastewater treatment systems.
A bioelectrochemical system was developed to enhance carbon oxidation in septic systems using electrically conductive carbon cloth as an anode/cathode bridge to transfer electrons from strictly anoxic septic wastewater to an oxic system outside of the septic reactor. This 'septic snorkel' (so named since the system 'breathes' via the carbon cloth extends into an aerobic zone) was designed to lower …

Removal Of N-Nitrosodimethylamine And Trihalomethane Precursors With Powdered Activated Carbon, Wilson Beita Sandi

All Theses

N-nitrosodimethylamine (NDMA) has been used commercially in several applications, including the production of liquid rocket fuel, and a variety of foods, but gained more relevance when it was discovered as a drinking water disinfection by-product (DBP) in 1989. NDMA is a probable human carcinogen with 10-6 lifetime cancer risk associated with a drinking water concentration of 0.7 ng/L, and is listed as a priority pollutant in the Code of Federal Regulations; no federal maximum contaminant level has been established for drinking water yet. However, the United States Environmental Protection Agency is planning to make a preliminary regulatory determination in 2013 …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

Evaluation Of Anaerobic Biodegradation Of High Concentrations Of Halogenated Methanes, Priya Rachel Jacob

All Theses

Removal of the chlorinated methanes, carbon tetrachloride (CT), chloroform (CF) and dichloromethane (DCM), and the halogenated methane, trichlorofluoromethane (commonly known as CFC-11 or Freon-11) from contaminated soil and groundwater remains challenging. Releases to the environment resulted from historically poor disposal practices, as well as spills and leaks from underground storage tanks. Among these three compounds, CF is considered the benchmark for evaluating the feasibility of bioremediation, due to its typically high level of toxicity towards most anaerobic prokaryotes. However, inhibitory effects of low concentrations of CFC-11 on anaerobes have been reported as well. Bioremediation is an attractive option for clean-up, …

Phosphorus Removal From Ebpr Sludge Dewatering Liquors Using Lanthanum Chloride, Aluminum Sulfate And Ferric Chloride, Michael Strileski

UNLV Theses, Dissertations, Professional Papers, and Capstones

In wastewater treatment, enhanced biological phosphorus removal (EBPR) is becoming an increasingly popular alternative to chemical precipitation (CP) because of its lower costs and reduced sludge production. However, downstream solids handling processes such as digestion, sludge storage and dewatering promote an undesirable release (i.e. secondary release) of polyphosphate that was stored within EBPR sludge. Released phosphate is recycled to the head of the plant with the liquors of sludge dewatering processes. The concentration of phosphate in recycle streams from EBPR systems can be one to two orders of magnitude higher than the influent phosphorus concentration entering the EBPR system. Plants …

Removal Of Arsenic From Simulated Groundwater Using A Pilot-Scale Constructed Wetland Treatment System, Jeffrey Schwindaman

All Theses

A pilot-scale constructed wetland treatment system (CWTS) was designed and built to produce biogeochemical conditions that promoted targeted processes for removal of arsenic from simulated groundwater. Two series were designed to promote co-precipitation and sorption of arsenic with iron oxyhydroxides under oxidizing conditions, and two series were designed to promote precipitation of arsenic sulfide and co-precipitation of arsenic with iron sulfide under reducing conditions. The two major objectives were to (1) assess arsenic removal performance and (2) determine the fate and distribution of arsenic in each series. Results indicate that arsenic removal performance was greater in series designed to promote …

Air Pressure Energy Storage For Reverse Osmosis: Bench-Scale Proof Of Concept, Ying Sun

All Theses

Society faces diminishing access to clean drinking water because of increasing global population and the development of modern industries. At the same time, climate change and other environmental problems caused by the increase in fossil fuel consumption the emphasis on reducing dependency on traditional energy resources in the process of potable water production. To address both problems, a small-scale wind powered reverse osmosis (RO) desalination system with a unique energy storage mechanism was envisioned to provide an energy buffer such that fluctuating and intermittent wind can be utilized. Energy is stored in the form of compressed air in a pressure …

The Extraction Of Acetic Acid From Thermotoga Neapolitana Fermentation Spent Medium Using Fresh/Recovered Aliquat 336 And Produce Cma, Yifan Du

All Theses

To offer an alternative pathway to produce calcium magnesium acetate (CMA) as an environmental friendly deicer to relieve the pressure on fossil fuels demand, a liquid-liquid extraction process was studied. This process includes using Aliquat 336 (tri-n-octylmethylammonium chloride) diluted in kerosene as an organic extractant to extract acetic acid from Thermotoga neapolitana fermentation spent medium, which contained 34 g/L of acetic acid and 10 g/L of NaCl.
The extraction efficiency of Aliquat 336 was studied under several different extraction conditions. The initial pH of the spent medium was adjusted to a pH range of 2.25 to 5.75 with a 0.5 …

Describing Plutonium Contamination Issues In Hanford Soils: Development Of A Thermodynamic Surface Complexation Model, Sarah Herr

All Theses

The development of remediation strategies for long-term site management requires knowledge of an actinide's geochemical behavior. Understanding this behavior can lead to the formation of a subsurface transport model. For example, plutonium mobility in the subsurface environment is significantly influenced by oxidation-reduction and complexation reactions. This work considered the surface-mediated reduction of plutonium, as well as the hydrolysis and carbonate complexation of the actinide.
Evaluating the significance of these reactions required several variable pH batch sorption studies. Experiments incorporated plutonium and neptunium sorption to sediments from the Hanford Nuclear Reservation in Washington State. Two different sediments were examined: coarse-grained and …

Modeling Benefits Of Implementing Low Impact Development Practices Within Forecasted Growth Scenarios Of The Reedy River Watershed, Stephen Taylor

All Theses

For this research, a previously developed comprehensive watershed water quality model for the Reedy River as developed for South Carolina Department of Health and Environmental Control (SCDHEC) and the US Environmental Protection Agency (EPA) as a total maximum daily load (TMDL) assessment tool was used to assess the benefits of using low impact development (LID) designs in future growth of Greenville County, within the Reedy River watershed. The original intent of this model was to provide SCDHEC with a defensible model that could be used to prepare nutrient TMDLs for an area located at Boyd Millpond and the Reedy River …

Navigating The Academic Job Search For Environmental Engineers: Guidance For Job Seekers And Mentors, David A. Ladner, Stephanie C. Bolyard, Defne Apul, Andrew J. Whelton

Publications

Students and postdoctoral associates interested in tenure-track environmental engineering positions have limited resources to aid them. The Student Services Committee (SSC) of the Association of Environmental Engineering and Science Professors (AEESP) organized a workshop to fill some of the need. Newly hired faculty and experienced search committee and department chairs shared information on how to create competitive applications. Students and postdoctoral associates were also provided with individualized feedback on their faculty application packages. Survey data were collected for all participants, and these data are presented in this paper along with tips shared during the workshop and information collected from the …

Triclosan Enriches For Dehalococcoides-Like Chloroflexi In Anaerobic Soil At Environmentally Relevant Concentrations, Patrick J. Mcnamara, Mark J. Krzmarzick

Civil and Environmental Engineering Faculty Research and Publications

Triclosan is an antimicrobial agent that is discharged to soils with land-applied wastewater biosolids, is persistent under anaerobic conditions, and yet its impact on anaerobic microbial communities in soils is largely unknown. We hypothesized that triclosan enriches for Dehalococcoides-like Chloroflexi because these bacteria respire organochlorides and are likely less sensitive, relative to other bacteria, to the antimicrobial effects of triclosan. Triplicate anaerobic soil microcosms were seeded with agricultural soil, which was not previously exposed to triclosan, and were amended with 1 mg kg⁻¹ of triclosan. Triplicate control microcosms did not receive triclosan, and the experiment was run for …

Cereal Grain Combustion In Domestic Boilers, Andrew Keppel, John Finnan, Bernard Rice, Philip Owende, Kevin Macdonnell

Articles

This study compared the combustion characteristics and the combustion behaviour of oats, barley, triticale and wheat to that of wood pellets. Sustained grain combustion in domestic boilers was feasible but problematic, the main impediment being clinker formation with ash agglomeration. Clinker formation was lowest for oats which burned easily with fewer operational problems. Triticale displayed reasonably good combustion characteristics and also ignited easily. In contrast, barley and wheat proved difficult to ignite while barley combustion was prone to self-extinguish. Thermal and combustion efficiency and heat output were considerably higher at a grain moisture content of 15% compared to a moisture …

Environmental Consequences Of A Power Plant Shut-Down: A Three-Dimensional Water Quality Model Of Dublin Bay, Zeinab Bedri, Michael Bruen, Aodh Dowley, Barthelomew Masterson

Articles

A hydro-environmental model is used to investigate the effect of cessation of thermal discharges from a power plant on the bathing water quality of Dublin Bay. Before closing down, cooling water from the plant was mixed with sewage effluent prior to its discharge, creating a warmer, less-saline buoyant pollutant plume that adversely affects the water quality of Dublin Bay. The model, calibrated to data from the period prior to the power-plant shut-down (Scenario 1), assessed the water quality following its shut-down under two scenarios; (i) Scenario 2: continued abstraction of water to dilute sewage effluents before discharge, and (ii) Scenario …

Bathing Water Quality Prediction Using An Integrated Catchment And 3-D Coastal Hydrodynamic Model, John O'Sullivan, Zeinab Bedri, Aisling Corkery, Louise Deering, Katalin Demeter, Wim Meijer, Barthelomew Masterson, Gregory O'Hare

Conference papers

Under the new European Union Bathing Water Directive (2006/7/EC) which comes into force in 2014, more stringent bathing water quality standards, defined in terms of Escherichia coli (E.coli) and Intestinal Enterococci (I.E.), will apply in Irish bathing waters. Compliance with these standards is ensured through a structured water quality monitoring programme that is published by Authorities with responsibility for bathing water areas in advance of each bathing season. The directive recognises that elevated levels of faecal coliform bacteria in bathing areas can derive from the overland transport of waste from livestock in the rural fraction of river catchments. On days …

Gis-Based Flood Analysis For Adequate Flood Mitigation In An Unplanned Urban Area; The Case Of Pikine Dagoudane In Dakar County, Senegal, Sokhna Helene Diop

Masters Theses

Since 1989, Pikine Dagoudane, in the suburbs of Dakar City has faced several flooding events, resulting in economic loss, environmental degradation and severe disturbance of the social life of the residents. The mitigation programs implemented have not appeared to provide any relief since 2000. Review of the existing literature on the crisis has revealed that the general scale of the studies, and the insufficient attention to some of the major factors could be accounted for such little efficiency. This thesis applies a different approach, based on a small area and focusing mainly on topographic characteristics, to provide a better understanding …

Dairy Manure Flushwater Treatment By Packed-Bed Anaerobic Digesters, Neal Cary Adler

Master's Theses

Wastewater treatment performance of three pilot-scale packed-bed anaerobic digesters with walnut shell medium was researched for treating dairy freestall barn flushwater. Reciprocation mixing was evaluated as a means to lessen channelization in the media bed and to improve biogas production and organic matter removal at ambient temperatures. Reciprocation has been used in biological nitrogen removal systems to introduce air into the system to repeatedly oxygenate nitrifying biofilm along with mixing (Behrends et al. 2003), but the anaerobic systems benefit from mixing. Two tanks were used in each system, where one was full and one was empty at any given time. …

Laboratory Evaluation Of A Turn Compensation Control System For A Ground Sprayer, Wesley M. Porter, Jorge A. Rascon, Yeyin Shi, Randal K. Taylor, Paul A. Weckler

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The ability to compensate sprayer nozzle flow across a horizontal boom has the potential to mitigate the problem of inaccurate chemical application rate due to lateral speed differences when sprayers are turning. A laboratory testing platform and procedure were developed and tested with a commercial turn compensation control system for a ground sprayer. Virtual paths consisting of simulated GPS signals representing right and left turns separated by straight segments were simulated with four turning radii (75%, 125%, 250%, and 500%) based on boom width. Actual application rates from 11 nozzles spread across the boom were measured using load cells in …

Comparison Of Biofilm Media In Reciprocating Biofilters Treating Dairy Flushwater, Kyle Keoki Tatsuo Fooks

Master's Theses

Reciprocating biofilters known as ReCip is a viable technology to manage nutrients, mainly nitrogen, problems at livestock operations such as swine farms and dairies. Past studies have demonstrated that ReCip is more adept at total nitrogen (TN) removal than traditional subsurface flow wetland systems. The traditional substrate used to attach biomass was rock aggregate; this media may be hard to obtain for some agricultural projects, so alternate substrates are tested and compared with the rock aggregate. The purpose of the study was twofold: first, different biofilm media were tested and compared in terms of treatment performance and, second, the long-term …