Environmental Engineering Commons^™

Mineralogical Transformations In Coal Feedstocks During Carbon Conversion, Based On Packed-Bed Combustor Tests: Part 2. Behavior Of Individual Particles, Ratale H. Matjie, Colin R. Ward, Zhongsheng Li

Coal Combustion and Gasification Products Journal Archive

Handpicked carbon-rich particles (coal or char), mineral-rich particles (heated stones), and bonded stone aggregates (clinkers) from the upper and lower parts of a pilot-scale packed-bed combustor bed, designed to simulate conversion or combustion processes, were subjected to mineralogical and inorganic geochemical studies, in order to evaluate the reactions that may occur during carbon conversion at a particle-by-particle scale. The mineral matter of the carbon-rich particles was found to have higher proportions of carbonate minerals and kaolinite than the mineral-rich (stone) particles in the coal feedstocks used in the study, and to form phases such as anorthite, gehlenite, pyrrhotite, troilite, and …

Mineralogical Transformations In Coal Feedstocks During Carbon Conversion, Based On Packed-Bed Combustor Tests: Part 1. Bulk Coal And Ash Studies, Ratale H. Matjie, Colin R. Ward, Zhongsheng Li

Coal Combustion and Gasification Products Journal Archive

Mineralogical and inorganic geochemical studies have been carried out on composite samples of six different coarse-crushed (,120 mm) feed coals tested in a pilot-scale packed-bed combustor designed to simulate conversion and some fixed-bed combustion processes, and also on composite samples of the ashes produced. The mineral matter of the coals consisted mainly of quartz, kaolinite, and Ca-bearing carbonate minerals (calcite, dolomite, aragonite), with minor proportions of illite, pyrite, and several other phases, along with some Ca in an organically associated form. The base to acid ratio of the coal ashes ranged from 0.1 to 0.3, due mainly to variations in …

Potential Indoor Air Exposures And Health Risks From Mercury Off-Gassing Of Coal Combustion Products Used In Building Materials, Christopher M. Long, Sonja N. Sax, Ari S. Lewis

Coal Combustion and Gasification Products Journal Archive

Coal combustion products (CCPs), including coal fly ash (CFA) and flue gas desulfurization (FGD) gypsum, have gained accepted use as substitutes for traditional substances in building materials. Because of the presence of mercury (Hg) in CCP materials, some concerns have been raised regarding the potential for Hg to off-gas from building materials into indoor air. Risk assessment offers a well-accepted, objective framework in which to determine whether such off-gassing could result in humanexposures of health concern. We thus conducted a screening-level human health risk assessment to estimate worst-case inhalation risks from indoor air exposures to Hg for multiple CCP utilization …

Quantifying The Benefits Of Using Flue Gas Desulfurization Gypsum In Sustainable Wallboard Production, Jin Cheol Lee, Sabrina L. Bradshaw, Tuncer B. Edil, Craig H. Benson

Coal Combustion and Gasification Products Journal Archive

Electric utilities produce more than 11.2 Mt of flue gas desulfurization (FGD) gypsum annually. Approximately 7.5 Mt is used in wallboard production. This article examines the environmental and cost benefits associated with replacement of natural gypsum in wallboard with FGD gypsum. A life-cycle analysis program was used to quantify the benefits of using FGD gypsum from electric power production in wallboard construction. Comparisons were made between energy consumption, water use, and greenhouse gas (GHG) emissions associated with obtaining and processing virgin gypsum material and those with FGD gypsum. The added impact of disposing of the unused FGD gypsum in landfills …

Waste Classification Of Slag Generated In A Pilot-Scale Entrained-Flow Gasifier, Ashleigh Cousins, Robin W. Hughes, David J. Mccalden, Dennis Y. Lu, Edward J. Anthony

Coal Combustion and Gasification Products Journal Archive

Series of gasification tests have been completed in the pilot-scale entrained-flow slagging gasifier at CanmetENERGY using Canadian coals, oil-sand coke, and blends of these fuels to determine if the produced slags are nonhazardous in nature. Solid wastes generated during these tests were analyzed for their trace metals, crystallinity, and toxic constituent leaching tendency in an attempt to provide more insight into the possibility of disposal or by-product use of gasifier-produced solid waste. The gasification tests were performed at conditions representative of commercial gasifiers using a dry-fuel-feed configuration. The lower-volatility elements were found to partition between the slag and process-water solids …

Evaluating Corrosion Control Alternatives For A Reverse Osmosis, Nanofiltration And Anion-Exchange Blended Water Supply, Rebecca J. Wilder

Electronic Theses and Dissertations

The research reported herein describes the study activities performed by University of Central Florida (UCF) on behalf of the Town of Jupiter Water Utilities (Town). The Town recently changed its water treatment operations from a combination of reverse osmosis (RO), lime softening (LS) and anion-exchange (IX) to a combination of RO, IX and nanofiltration (NF). Although this treatment change provided enhanced water to the surrounding community in terms of better contaminant removal and reduced DBP formation potential, integration of the NF process altered finished water quality parameters including pH, alkalinity and hardness. There was concern that these changes could result …

A Review Of National Msw Generation Assessments In The United States, David J. Tonjes, Krista L. Greene

Technology & Society Faculty Publications

Municipal solid waste (MSW) is generated in very large quantities (probably, between 200 and 400 million tonnes per year) in the United States (US). MSW is generated at millions of places and there is no one precise, general definition for MSW that is generally applied, despite US Environmental Protection Agency efforts. As an element of both commerce and politics, reporting may be framed towards particular ends. Therefore, the two best known assessments of the quantity of US MSW production differ by approximately 50%. The assessors understand some of the reasons for the differences, but our analysis suggests that there are …

Trapping Phosphorus In Runoff With A Phosphorus Removal Structure, Chad J. Penn, Joshua M. Mcgrath, Elliott Rounds, Garey A. Fox, Derek M. Heeren

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Reduction of phosphorus (P) inputs to surface waters may decrease eutrophication. Some researchers have proposed fi ltering dissolved P in runoff with P-sorptive byproducts in structures placed in hydrologically active areas with high soil P concentrations. Th e objectives of this study were to construct and monitor a P removal structure in a suburban watershed and test the ability of empirically developed fl ow-through equations to predict structure performance. Steel slag was used as the P sorption material in the P removal structure. Water samples were collected before and after the structure using automatic samples and analyzed for total dissolved …

Timing Of Residential Electric Loads To Reduce Air Emissions From Power Generation, Michelle Marinich Rogers

Wayne State University Theses

Over the course of a day, power utilities must respond to changing demand by dispatching or shedding output from different generators. Each generator is associated with a unique profile of air emissions, based on the type of fuel consumed, installed pollution controls, and the generator's efficiency. The aim of this study is to determine whether shifting electric demand to times when cleaner generation sources are available would result in overall emissions reduction.

Dynamic wholesale pricing in the electric power market, specifically the Locational Marginal Price (LMP), provides a means to estimate the marginal generator fuel type. This knowledge was used …

An Improved Flood Forecasting Model Of The Blue Nile River In Sudan, Gamal Abdo, Ahmed Nasr

Articles

Reliable flood predictions with a reasonable lead time in the Blue Nile River in Sudan are vitally important to avoid catastrophic damages due to flooding of this river and the main River Nile. A HEC-RAS model was initially applied to the Blue Nile by representing the river as a single reach. The resulting original model was subsequently improved by including the two tributaries of the river, Rahad and Dindir, and also the two existing reservoirs, Rosaries and Sinnar, to the model. The original and the improved models were calibrated using 1988 flood data for the period from June to September …

2012 Nebraska Water Monitoring Programs Report, Marty Link, Mike Archer

Nebraska Department of Environmental Quality: Reports

The following Nebraska Department of Environmental Quality staff have contributed to this report with their photos, maps, numbers, words, and editing. Their efforts are greatly appreciated and gratefully acknowledged here: Mike Archer, Ken Bazata, Dave Bubb, Ryan Chapman, Jason Garber, Patrick Hartman, Tom Heatherly, Dave Ihrie, Dan Inman, Greg Michl, Will Myers, Patrick O’Brien (NARD), Brad Routt, and Dave Schumacher.

Synthesis And Evaluation Of Naturally Occuring Halogenated Bipyrroles In A Relevant Marine Species, Fundulus Heteroclitus, Kimberly Sheree Foster

Electronic Theses and Dissertations

Halogenated dimethyl-2-2'-bipyrroles (HDBPs) have recently been discovered in seabird eggs and have been shown to bioaccumulate in trophic organisms. HDBPs are suspected to be biogenic in nature, derived from evidence of marine natural products that are persistent in the environment and widespread in the Pacific and Atlantic Ocean. The HDBPs exhibit chlorinated and brominated substitution patterns that closely resemble anthropogenic pollutants like the polychlorinated biphenyls (PCBs), polybrominated biphenyls (PBBs), and polybrominated diphenyl ethers (PBDEs). Environmental health concerns exists regarding these naturally occurring HDBPs because several of these analogs were shown to induce the cytochrome P4501A (CYP1A) gene through activation of …

Bacterial And Sediment Transport In An Artificial Sand Bed Stream During Unsteady Flow, Mary Alexandra Mccaskill

Electronic Theses and Dissertations

Storms cause a substantial increase in the fecal indicator bacteria (FIB) concentrations in stream water. Causes for this concentration increase include FIB-laden stormwater runoff and the release of bacteria from stream-bottom sediments. Studies were carried out to quantify this second cause of water quality impairment. Coliform bacteria are a group of FIB, indicate the presence of pathogenic microorganisms, and have been shown to be transported in streams far from their source areas, especially during storms. FIB transport is dependent on several factors including water velocity, size and transport rates of bed sediments, and the FIB concentration in bed sediment. The …

Sustainable Riparian Restoration - The Utilization Of Sewage Effluent To Construct Wetlands Along The Rio Grande: A String Of Pearls Approach To Replenishment, Michael Earl Landis

Open Access Theses & Dissertations

The Rio Grande, from Elephant Butte Dam to El Paso, has been transformed from a free-flowing wild river into a highly engineered irrigation system. The Rio Grande Project, authorized by Congress in 1905, mandated the Bureau of Reclamation to store and deliver water exclusively to farmers. The river, maintained by the International Boundary and Water Commission, has been straightened and channelized between levees. The laws and policies governing the use of the waters of the Rio Grande are prohibitive to ecological restoration. Prior Appropriation doctrine allows for the exclusive use of these waters.

One sustainable tactic for replenishing the denuded …

Alternatives To Piloting In Bracksih Waters: Accuracy And Precision Of Commerical Reverse Osmosis Membrane Design Model Projections, Erika Mancha

Open Access Theses & Dissertations

In a time of economic recession and drought, the Texas Water Development Board is reviewing alternatives to the current Texas Commission on Environmental Quality requirement of demonstration-scale pilot testing membrane desalination to decrease permitting costs and project construction delays. One alternative is to use engineering judgment with membrane manufacturer's software models to predict membrane performance and ensure that product water quality requirements will be met. To comply with state permitting requirements, the first few months of successful full-scale operation can be submitted in lieu of pilot demonstration.

The goal of this research is to characterize the accuracy and precision of …

A Comparison Of Aluminum And Iron-Based Coagulants For Treatment Of Surface Water In Sarasota County, Florida, David Yonge

Electronic Theses and Dissertations

In this research, five different coagulants were evaluated to determine their effectiveness at removing turbidity, color and dissolved organic carbon (DOC) from a surface water in Sarasota County, Florida. Bench-scale jar tests that simulated conventional coagulation, flocculation, and sedimentation processes were used. Iron-based coagulants (ferric chloride and ferric sulfate) and aluminum-based coagulants (aluminum sulfate, polyaluminum chloride (PACl) and aluminum chlorohydrate (ACH)) were used to treat a highly organic surface water supply (DOC ranging between 10 and 30 mg/L), known as the Cow Pen Slough, located within central Sarasota County, Florida. Isopleths depicting DOC and color removal efficiencies as a function …

Identifying Hot-Spots Of Fecal Contamination In The Royal Spring Karstshed, Samuel C. Lee

Theses and Dissertations--Civil Engineering

The City of Georgetown, Kentucky relies on a vast karst spring network as a drinking water source. This karst feature has several inputs from sinkholes and streams in the Cane Run Watershed: a watershed associated with a variety of land uses in the recharge area. The recharge area encompasses the area from North Lexington to Georgetown and is composed of urban, suburban, agricultural and industrial usage. A serious water quality issue exists with respect to the impact of fecal contamination within the spring recharge area. Identification of fecal contamination is quantified by microbial indicators adapted from surface water applications: fecal …

Development Of Strategies To Minimize The Release Of Trace Elements From Coal Waste Sources, Mohammad Rezaee

Theses and Dissertations--Mining Engineering

To assess strategies aimed at minimizing the release of trace elements and the impact of disposal of coal waste materials on the environment, two long-term leaching experiments of up to five months duration were performed using waste materials from two plants cleaning high and low sulfur bituminous coal. The tests evaluated the mobility of major trace elements under different disposal scenarios: (i) a static leaching test designed to simulate the quiescent conditions encountered by coal waste material stored under water in a stable impoundment, and (ii) a dynamic test to simulate waste materials exposed to the atmosphere, either in variable …

Fate Of Coated Zinc Oxide In Municipal Solid Waste Landfills, Stephanie Carbone Bolyard

Electronic Theses and Dissertations

Given the increase in nanomaterial (NM) use in consumer products and the large fraction of waste placed in landfills worldwide, the probability of these products reaching municipal solid waste (MSW) landfills at the end of their useful life is high. Since nanotechnology use is still in its early stages, there are currently no regulations pertaining to the disposal of NMs and their fate in MSW landfills is still unknown. Understanding the fate of NMs in MSW landfills is vital to ensure the proper handling of these novel materials from cradle to grave; such research will provide information on how these …

Application And Optimization Of Membrane Processes Treating Brackish And Surficial Groundwater For Potable Water Production, Jayapregasham Tharamapalan

Electronic Theses and Dissertations

The research presented in this dissertation provides the results of a comprehensive assessment of the water treatment requirements for the City of Sarasota. The City’s drinking water supply originates from two sources: (1) brackish groundwater from the Downtown well field, and (2) Floridan surficial groundwater from the City’s Verna well field. At the time the study was initiated, the City treated the brackish water supply using a reverse osmosis process that relied on sulfuric acid for pH adjustment as a pretreatment method. The Verna supply was aerated at the well field before transfer to the City’s water treatment facility, either …

Evaluation Of An On-Line Device To Monitor Scale Formation In A Brackish Water Reverse Osmosis Membrane Process, Jennifer C. Roque

Electronic Theses and Dissertations

A modified two-element membrane pressure vessel assembly has been used to monitor process operational changes in a full-scale reverse osmosis (RO) water treatment plant (WTP). This study evaluated the effectiveness of the assembly as an on-line monitoring device intended to detect scale formation conditions when connected to an operating RO process train. This study was implemented to support the requirements of a larger University of Central Florida (UCF) research project ongoing at the city of Sarasota’s Public Works and Utilities (City) water treatment facilities located in Sarasota, Florida. During the time-frame of this study, the City was in the process …

Evaluation Of Biosorption Activated Media Under Roadside Swales For Stormwater Quality Improvement And Harvesting, Andrew Charles Hood

Electronic Theses and Dissertations

Stormwater runoff from highways is a source of pollution to surface water bodies and groundwater. This project develops a bio-detention treatment and harvesting system that is incorporated into roadside swales. The bio-detention system uses Bold & Gold™, a type of biosorption activated media (BAM), to remove nutrients from simulated highway runoff and then store the water in underground vaults for infiltration, controlled discharge, and/or irrigation and other non-potable applications. In order to design a bio-detention system, media characteristics and media/water quality relationships are required. Media characteristics determined through testing include: specific gravity, permeability, infiltration, maximum dry density, moisture content of …

Construction And Demolition Debris Recovery And Recycling In Orange County, Fl, Michael Stephen Toth Ii

Electronic Theses and Dissertations

In 2008, the State of Florida established a recycling goal of 75% to be achieved by 2020. In response to the Florida goal Orange County (OC), Florida has made the development and implementation of an efficient strategy for landfill diversion of its solid waste a top priority. The Florida Department of Environmental Protection (FDEP) estimated that 23 % of municipal solid waste was generated by construction and demolition (C&D) activities in 2009, with only 30 percent of C&D debris being recycled. Therefore, OC decided to create a solid waste integrated resource plan (SWIRP) initially focused on the recovery and recycling …

Turbidity Removal Efficiency And Toxicity Issues Associated With The Chitosan-Based Dual Bio-Polymer Systems, Rylee Hernandez

Electronic Theses and Dissertations

Stormwater runoff can be a great concern in the State of Florida due to the impact the quality of the runoff water can have on the natural water bodies. Stormwater runoff can carry pollutants and sediments which can cause both physical and biological risks in an aquatic ecosystem such as a lake, river, or pond. Polymers, namely the chitosan-based dual polymer system, can be used remove the sediment from this runoff to ensure the safety of the state’s water bodies. Three soils are used in this testing: AASTO soil classifications A-3(sandy soil) and A-2- 4 (silty-sand), and a soil with …

Co Florida 2012, A Moves-Based, Near-Road, Screening Model, Mark David Ritner

Electronic Theses and Dissertations

Citizens in the United States are fortunate to have an excellent system of roadways and the affluence with which to afford automobiles. The flexibility of travel on demand for most allows for a variety of lifestyles, assists with conducting business, and contributes to the feeling of freedom that most citizens enjoy. The current vehicle fleet, which is primarily powered by internal combustion engines burning fossil fuels, does however contribute to the deterioration of air quality. This effect is particularly significant in metropolitan areas. Motor vehicle exhausts contain several combustion bi-products that pose harmful effects to the environment and human health, …

Free Troposphere Ozone And Carbon Monoxide Over The North Atlantic For 2001-2011, Aditya Kumar

Dissertations, Master's Theses and Master's Reports - Open

Carbon Monoxide (CO) and Ozone (O3) are considered to be one of the most important atmospheric pollutants in the troposphere with both having significant effects on human health. Both are included in the U.S. E.P.A list of criteria pollutants. CO is primarily emitted in the source region whereas O3 can be formed near the source, during transport of the pollution plumes containing O3 precursors or in a receptor region as the plumes subside. The long chemical lifetimes of both CO and O3 enable them to be transported over long distances. This transport is important on continental scales as well, commonly …

Analysis Of Particulate Matter Air Quality Impacts On Sunland Park, New Mexico Due To Dust Emissions From Puerto Anapra, Mexico Using A Complex Terrain Air Dispersion Model Calpuff, Grisel Edith Arizpe

Open Access Theses & Dissertations

The City of Sunland Park is located in Doña Ana County in southern New Mexico. The City has unusual boundaries which border not only with other communities in New Mexico but also the State of Chihuahua, Mexico to the south and the City of El Paso, Texas to the east. This area is considered part of the Paso del Norte Airshed (PdNA), which is comprised also by El Paso County, Texas and Ciudad (Cd.) Juarez, Mexico. Historically, this region has had air quality problems and compliance issues with National Ambient Air Quality Standards (NAAQS), including particulate matter and ozone pollution. …

Compressibility And Hydraulic Conductivity Of Zeolite-Amended Soil-Bentonite Backfills, Catherine Hong, Charles D. Shackelford, Michael A. Malusis

Faculty Journal Articles

The effect of zeolite amendment for enhanced sorption capacity on the consolidation behavior and hydraulic conductivity, k, of a typical soil-bentonite (SB) backfill for vertical cutoff walls was evaluated via laboratory testing. The consolidation behavior and k of test specimens containing fine sand, 5.8 % (dry wt.) sodium bentonite, and 0, 2, 5, or 10 % (dry wt.) of one of three types of zeolite (clinoptilolite, chabazite-lower bed, or chabazite-upper bed) were measured using fixed-ring oedometers, and k also was measured on separate specimens using a flexible-wall permeameter. The results indicated that addition of a zeolite had little impact …

Identification And Implementation Of Patterns Towards A Model Of Environmental Sustainability, S. Jimmy Gandhi, Santiago Perez, Danial Rushton, Robert Cloutier, Ipek Bozkurt, C. Ariel Pinto

Engineering Management & Systems Engineering Faculty Publications

Much like the Quality Revolution did in the 1980's, corporate sustainability has the potential to drive significant changes in the processes and structure of various organizations in the coming decade. With a rapidly growing global population and an ever increasing global demand for resources (Population-Resource-Center, 2012). Sustainability has emerged as one of the primary challenges that organizations will have to deal with in the 21st century. An increasing realization among business executives that profitability by itself is not enough as a measure of success is also driving the increased adoption of sustainable practices in the corporate world (Lowitt and Grimsley, …

Bod5 And Cod Data Analysis From The Northwest And Robert R. Bustamante Wastewater Treatment, Juan Carlos Adame

Open Access Theses & Dissertations

The objectives of this thesis are to explore the use of basic Statistical Process Control in a Wastewater Treatment Plant with secondary treatment. Additionally, to describe statistical behavior and review normality of some reportable parameters, also to analyze mainly parameters like BOD5 (Biological Oxygen Demand), Electrical Conductivity, and COD (Chemical Oxygen Demand) with seasons of the year and days of the week, using data from the Northwest (NW) and Robert R. Bustamante (RRB) Wastewater Treatment Plants from El Paso Texas.

The scope of this analysis is to understand how Statistical Process Control can help to predict peak and valleys of …