Environmental Engineering Commons^™

Ultrasound To Decontaminate Organics In Dredged Sediments, Kanya Veerawat

Theses

In this research, it was attempted to decontaminate and separate dredged sediments contaminated with organic compounds by the application of ultrasound energy coupled with sub-atmospheric pressures. The decontamination and separation of contaminated sediments was achieved by integrated two processes. For Process 1, ultrasound energy was used to decontaminate the sandy fraction in dredged sediments, and sub-atmospheric pressure was used to separate and remove fines. For Process 2, ultrasound was again used to decontaminate fines with bulk fluid, and sub-atmospheric pressure was used to remove the contaminants with water. Process 1 was evaluated and found to have four variables contributing to …

Production Of Submicron Aerosols By Powder Depressurization, Amit Haryani

Theses

Disaggregation of dry powders in shear flow has limitations in producing submicron particles. This study explores a new method for the production of submicron particles by the depressurization of powder aerosols. The depressurization mechanism is based on the rapid depressurization of the aggregated powder through a specially designed nozzle. As the pressure suddenly decreases from very high values inside the aggregates (800 psi) to ambient at the surface of such aggregates, disaggregation takes place due to the force exerted by the gas escaping through their pore structure.

he effect of various process parameters, namely: nozzle diameter, pressure and pretreatment with …

Analysis And Modeling Of Ultrasound To Decontaminate Heavy Metals In Dredged Sediments, Ruvini Perera

Theses

Sediments contaminated with heavy metals due to past disposal practices threatens the environment and requires remediation. This research is an attempt to develop a technology to decontaminate heavy metals in the dredged sediments with an integrated set of processes using ultrasound. Acoustic cavitation caused by ultrasound energy can be used to remove chromium from the sediments. Two coupled processes were used to treat both coarse (Process#1) and fine (Process#2) fractions of the sediments. Full factorial experimental designs were carried out to evaluate the treatment technique and to statistically model and optimize the processes. The model for Process#1 had four contributing …

Coagulation And Disinfection By-Products Formation Potential Of Dissolved Organic Matter Fractions, Neeraj S. Pipada

Theses

Both the proposed United States Environmental Protection Agency (USEPA) Disinfectants- Disinfection By-Products and Enhanced Surface Water Treatment rules have provisions for minimizing the formation of undesirable precursors of disinfection by-products (DBPs) in drinking water Natural Organic Matter (NOM) contains many of the precursors to the DBPs formed following disinfection of drinking water. DAX-8 resin procedures were used to isolate and fractionate NOM into six dissolved organic matter (DOM) fractions; Hydrophobic acid (FA), base (FB), neutral (FN), and hydrophilic acid (PA), base (PB) and neutral (PN). Aluminum sulfate (alum) jar coagulation tests were performed to determine the optimum coagulation ranges of …

The Determination Of 2-Methylisoborneol And Geosmin In Water Using Fluorescence Spectroscopy, Ramesh Chandra Sharma

Theses

Geosmin and 2-Methylisoborneol are responsible for imparting earthy, musty taste and odor qualities to water. The human threshold odor concentrations (TOCs) for 2-MIB and Geosmin vary over a wide range. TOCs of 10ng/1 for Geosmin and 30ng/1 for 2-MIB have been reported.

Currently available methods are time consuming and require use of sophisticated technique and expensive equipment.

Fluorescence spectroscopy has been successfully used in the identification of many organic compounds. Geosmin and 2-MIB have organic origin. This research explores the possibility of using the technique of fluorescence spectroscopy in the determination of Geosmin and 2-MIB. The excitation and emission wavelengths …

Stabilization Of Water Treatment Plant (Wtp) Residuals Using Sorbond, Rituraj Sinha

Theses

Disposal of water treatment plant (WTP) residuals has always been an important consideration for the water industry. Stringent water quality standards, environmental regulations, and unavailability of land for ultimate disposal affect disposal of large amounts of this residual. The search for alternate economical disposal options and beneficial use are probably the next most logical and economical step to take.

This study was performed to explore the possibility of stabilization of water treatment plant (WTP) residuals using additives. Three water treatment plant (WTP) residuals from treatment plants in New Jersey were used for the analysis. The objective of this research is …

The Study Of Permeability In Concrete, Jie Yuan

Theses

In this study, samples of regular, high performance, expansive and the polymer concrete and mortar were prepared for test of permeability and mechanical property. In the permeability measurement, water and an aqueous chemical solution were employed as the permeant.

The test results of the samples, ranging from 5.7 x 10-9 cm/sec to 1.0 x cm/sec for the permeability and 3800 psi to 10600 psi for compression strength, indicated that the polymer coated concrete has the lowest permeability among the concretes and high performance concrete has the highest compression strength . The finding leads to the possibility that a high strength …

Enhancing The Bioavailability Of Sorbed Pollutants From Sediments Using Ultrasound, Rachel Mathew

Theses

Many organic compounds, that enter aquatic systems have a strong tendency to sorb onto particulate matter which may be present in suspension or as sediment. Numerous studies have shown that the sediment in aquatic systems concentrate contaminants several orders of magnitude greater than the concentration in the aqueous phase. Particulate associated contaminants in sediments are not easily bioavailable. Hence the efficacy of any treatment technology would be strongly undermined if the contaminants are not made available for microbial utilization. Sediment associated contaminants can be made biologically available to various microorganisms under certain conditions.

In this study, desorption studies were conducted …

An Analytical Approach To Toxic Substance Replacement In Support Of Pollution Prevention, Ithan B. Zimmer

Theses

In support of pollution prevention and in accordance with Executive Order 12356 concerning pollution prevention, all federal agencies must comply with the Toxic Release Inventory (TRI) chemical release reduction and pollution prevention planning. The inventory lists hundreds of chemicals and choosing those to replace and finding actual replacement chemicals or procedures is not always clear. This study focuses on an analytical approach to this problem by understanding the application of two substances. The representative chemicals are two volatile organic compounds (VOC), ethyl ether and ethanol, used as solvents in ammunition manufacturing.

Thirteen military specifications provide the cases involving ether. Ethanol's …

A Methodology For The Design Of An Integrated Air Stripping/Biofiltration Process To Clean Contaminated Aquifers, Pothitos Ioannis Stamatiadis

Theses

This thesis deals with the conceptual design of an integrated air stripping/biofiltration process for cleaning aquifers contaminated with volatile organic pollutants. In this technology, the pollutant is transferred from the aquifer to an air stream which is subsequently treated in a biofilter. The work presented here is an effort to develop a design methodology for the integrated process and suggests a general, quantitative approach which can be used in preliminary technology evaluation. This methodology involves relatively simple equations for the stripping process and detailed (oftentimes complex) models for biofiltration under conditions of continuous variation of the properties of the polluted …

Biodegradation And Landfill Settlement, Shailesh Pisolkar

Theses

The most widely used method for the final disposal of solid waste is landfilling, which is also economical and simpler than most other disposal systems. Long term settlement in a landfill occurs mainly due to biodegradation of the refuse which is a very slow microbiological process. However, if the rate of biodegradation is enhanced, it may be possible to achieve early stabilization, faster settlement, consequently more capacity of the landfill to handle waste.

The objective of this research is to study the effects of enhanced biodegradation on settlement and to compare these results to other models used for predicting landfill …

Solidification/Stabilization Of Petroleum Contaminated Soils With Cold Mix Asphalt Concrete, Nazhat Aboobaker

Theses

In this research Petroleum Contaminated Soils (PCSs) are recycled in Cold Mix Asphalt (CMA), to produce a useful product that can control potential environmental threats. The stability, durability, and hydraulic conductivity are three important engineering parameters that need to be considered when using petroleum contaminated soils (PCSs) in cold mix asphalt (CMA). In this research, stability, durability, and hydraulic conductivity due to the addition of six different PCSs into CMA is investigated. The stability test were performed to determine if cold mix asphalt made with petroleum contaminated soil can withstand heavy traffic. The freeze-thaw, and wet-dry tests were performed to …

Advanced Characterization And Leaching Behavior Of Hexavalent And Trivalent Chromium From Waste Material, Erik Moerman

Theses

In this thesis we employed advanced characterization techniques such as XRF, XRD, XPS, SEM, and EDS to provide detailed information about the chromium waste _ specifically chromium valence states (Cr(VI) and Cr(III)), and their chemical association with other phases in the waste matrix.

The removal of Cr(VI) was accomplished by leaching with aqueous solutions containing inorganic anions such as Cl^-, SO₄^2-, PO₄^3- and others. Cr(VI) can be released from the waste by a combination of desorption and ion exchange processes. The efficiency and kinetics of displacing CrO₄^2- from the waste by …

Separation Of Polycyclic Aromatic Hydrocarbons By Using Micellar Electrokinetic Chromatography, Patricia Simmons

Theses

In this work, the use of micellar electrokinetic chromatography (MEKC) for the separation of five polycyclic aromatic hydrocarbon (PAH) compounds is investigated. All of the compounds studied are listed by the United States Environmental Protection Agency as priority pollutants.

In micellar electrokinetic chromatography, solutes partition between the aqueous phase and the micellar phase. This partition is based on the hydrophobicity of each compound. In some cases, organic modifiers are added to the electrophoretic solution to enhance the separation efficiency. The organic modifier used in this study is y-cyclodextrin (y-CD), and sodium dodecyl sulfate (SDS) is used as the micellar phase. …

Sensivity Analysis And Design Calculations With Biofiltration Models, Michael Lawrence Cohen

Theses

Biofiltration is a new technology for biological treatment of volatile organic compounds present in airstreams. It is a complex process and thus, engineering models which attempt to describe it are by necessity very involved and contain a large number of parameters.

In this study, two models describing biofiltration of airstreams carrying a single pollutant (VOC) were used in detailed parameter-sensitivity studies. One model concerned biofiltration under steady-state conditions, while the second described the transient behavior of the process. The intent of the sensitivity studies was to determine which model parameters need to be known with accuracy in order to allow …

Remediation And Reuse Of Chromium Contaminated Soils Through Cold Top Ex-Site Vitrification, Wiwat Kamolpornwijit

Theses

More than 150 sites in Hudson County, New Jersey are identified as chromium contaminated sites. Hexavalent chromium, highly soluble in water, is considered as an environmental and health hazard, classified as a group A human carcinogen. In this research, the feasibility was performed to study the possibility of remediation of chromium contaminated soil by ex-situ vitrification and to evaluate reuse potential of vitrified products as highway construction aggregate. A series of physical and chemical analysis was conducted on nine soil samples collected from different chromium contaminated sites. Results were analyzed for their compatibility for vitrification. Sand and carbon were added …

Reverse Osmosis As A Pretreatment Of Ion Exchange Equipment At Pse & G'S Hudson Generation Station, Steven Leon

Theses

Public Service Electric and Gas Company's Hudson Generating Station has historically had problems providing sufficient high quality water for its two once through, supercritical design boilers. The station requires over 60 million gallons annually to compensate for system losses.

The stations' ion exchange demineralizers proved to be costly to operate and overall inefficient in performance. Drawbacks include: short service cycles, periodic contamination of storage tanks due to premature breakthrough, prohibitively high chemical regenerant costs, excessive labor requirements, frequent resin replacement, and overall unreliable plant operations.

A reverse osmosis unit was installed as a pretreatment to the demineralizers to offset these …

A Study Of Settlement In Landfills Due To Biodegradation, Michael Guasconi

Theses

Finding new space for landfills is difficult due to land availability, stringent environmental regulations, and public sentiment. So other means of waste disposal, such as hauling it to a distant landfill, or incinerating it, will have to be resorted to. These methods may be unpopular with the public involved. By studying settlement due to biodegradation, ways to increase settlement can be found, allowing for additional waste disposal capacity in operating, and closed landfills.

Existing theoretical models are based on rheological concepts, not on biodegradation. So, they do not realistically model settlement. In this study, a model to determine the rate, …

Hydrodynamic And Water Quality Modeling Of The Whippany River, John E. Krohn

Theses

The Whippany River is located in northern New Jersey and is a major tributary to the Passaic River System. This waterway accepts a wide variety of wastes from the diverse communities within its watershed. These wastes contribute to a rather complex network of biological, chemical and physical interactions.

The purpose of this study is to develop a water quality model using QUAL2E. This model will be used as a tool to simulate the complex interactions that take place within the river system. The river must he considered from physical, biological and chemical perspectives. A successful model can determine current water …

Integration Of Pneumatic Fracturing And In Situ Vitrification In Coarse Grained Soils, Sean Thomas Mcgonigal

Theses

This thesis investigates conceptual integration of the Pneumatic Fracturing (PF) process with In Situ Vitrification (ISV) for remediation of contaminated soil. Integration will permit ISV melts to be initiated below the ground surface and extend the depth of the ISV process.

Bench scale experiments were conducted in 4.9 ft³ (0.14 m³) Plexiglas tanks filled with a test soil that was specifically blended to simulate the Hanford Formation in Richland, WA. Discrete pneumatic fractures were successfully created and filled with the ISV starter path material. Conductivity measurements made across two graphite electrodes exhibited a pre-fracture soil resistance of …

Integration Of Surfactants And Time Release Nutrients With Pneumatic Fracturing Process, Atiqur Md. Rahman

Theses

The objective of this laboratory study was the development of two novel improvements to the pneumatic fracturing process which would extend its present application. The first involved use of surfactant during pneumatic injection, and the second was subsurface injection of "time-release" dry nutrient pellets for enhancement of in situ biodegradation.

Bench scale tests demonstrated that pneumatic fracturing can be successfully performed with air containing a surfactant solution (foam fracturing). The results showed that foam fracturing followed by increased the rate of surrogate contaminant removal from 8% to 10% compared with regular pneumatic fracturing. These increases were attributed to enlarged fracture …

The Use And Evaluation Of Cleaner Wicks To Accelerate In Situ Bioremediation Of Organically Contaminated Groundwater And Soil, Brian Michael Sielski

Theses

The adaptation of Cleaner Wicks to accelerate in situ bioremediation of organically contaminated ground water and soil can be accomplished by making minor modifications to the Cleaner Wick design.

Once these changes in the Cleaner Wick design have been made the two primary ingredients necessary for aerobic microorganisms, nutrients and oxygen, can be delivered via the Cleaner Wick to the subsurface environment both above and below the water table to stimulate microbial growth and activity. Therefore, the microbial population will be able to biodegrade the target contaminants, rendering them harmless products such as carbon dioxide and water.

An adequate understanding …

Fluid Flow Modeling For Pneumatically Fractured Formations, Deepak Nautiyal

Theses

This thesis investigates the flow of compressible fluids in pneumatically fractured formations. Pneumatic fracturing is a recently developed technique for increasing permeability in geologic formations by the controlled injection of high pressure air. The artificially induced fractures enhance the flow rate of liquids and vapors in the subsurface, and can be applied to in situ remediation of hazardous waste sites, and for other hydrogeological applications.

A flow model for discrete fractures is derived based on the assumptions of viscous, laminar fluid flow through planar fractures (Poiseuille type flow). The model takes into account non-linearity introduced by gas compressibility effects. Provision …

Modeling Arsenic Transformation In Clay Soils, Chao-Yi Chung

Theses

This project is designed to estimate the possible transformation forms of arsenic in clay soil. A computer model was established to simulate arsenic transformations. The amount of arsenic species adsorbed, dissolved, and the predominant soluble species are calculated by the model, which is mainly based on the Freundlich adsorption isotherm, solubility data collected by Keaton and Kardos, and pH-Eh diagram established by Ferguson and Garvis. The computer language used is Turbo PASCAL version 5.5.

The clay soil environment is considered to be in standard state: 25°C 1 atm. Environmental factors of the soil system which are accounted for by the …

The Use Of Cod As An Indicator For Evaluation Of Pretreatment Of Nitrocellulose With Acid Hydrolysis, Han-Chung Lee

Theses

Nitrocellulose is a toxic waste by definition. It is widely used in military and commercial industries. Nitrocellulose fines escaped from the manufacture's process has created problems in receiving water. However, little information is available for the treatment of nitrocellulose. Nitrocellulose is difficult to treat by microorganisms without any pretreatment. Therefore, the main objective of this study is to use acid hydrolysis to break down this material before biological treatment, and find the optimal operation conditions in this process.

In this work, the results indicate that percentage of nitrocellulose decomposing in hydrolysis depends on types of acid, acid concentration, reaction temperature, …

Sulfuric Acid Resistance Of Fly Ash Mortar, Walairat Bumrongjaroen

Theses

Crown corrosion of concrete pipe and its subsequent repair is a topic much discussed in recent years. Present protective methods have not worked effectively. Due to its properties and its low cost, fly ash was used as a cement replacement of mortar to investigate its sulfuric acid resistance.

Different types and different percentages of fly ashes were mixed with and without admixtures including microsilica, and superplasticizer. The main parameters investigated included the chemical compounds, the fineness and the volume of fly ash. 2"x2" cubes were immersed in a 10% sulfuric acid pond. The weight of each cube was determined continuously …

Power Consumption In Single-Phase Agitated Vessels Provided With Multiple Impellers, Gwo-Ming Chang

Theses

A significant amount of data can be found in the literature on power consumption of single-impeller agitation systems. However, little and incomplete information is available for power consumption in multiple-impeller systems. Therefore, the main objective of this study is to experimentally determine the power consumed by multiple impellers in mixing vessels as a function of impeller type, impeller off-bottom clearance, impeller spacing, and agitation speed.

In this work, the power dissipated by combinations of one, two or three impellers of either identical types or different types was studied. The power drawn by each individual impeller was measured by means of …

Mechanism Of Pneumatic Fracturing, Trevor Compton King

Theses

This thesis investigates the mechanism of pneumatic fracturing in geologic materials such as soil and rock. Pneumatic fracturing is a recently developed technique for increasing the permeability of geologic formations by the controlled injection of high pressure air. Present applications are focusing on the in situ remediation of contaminated soil and ground water, although pneumatic fracturing has other geotechnical uses such as pumping well enhancement.

A comprehensive literature review of a related technology known as hydraulic fracturing is presented, which serves as background for development of a pneumatic fracturing model. Pressure-time histories from actual pneumatic injections are analyzed in detail …

Integration Of Pneumatic Fracturing To Enhance In Situ Bioremediation, Conan Dante Fitzgerald

Theses

The purpose of this thesis was to study the anticipated benefits of integrating pneumatic fracturing with in situ bioremediation. Since pneumatic fracturing increases subsurface air flow in low permeability formations, it has the potential to overcome many of the major limiting factors of microbial growth and activity. A new innovation called pneumatic bio-injection can further enhance in situ bioremediation by efficiently dispersing biological solutions, including microorganisms, into a formation.

Bench scale experiments were conducted to examine the ability of microorganisms to survive the pressures and stresses associated with pneumatic injection. Tests conducted at pressures ranging from 60 to 500 psi …

The Permeability Of Hot Mix Asphalt Concrete With Petroleum Contaminated Soils, Kuen-Yuan Chuang

Theses

It is estimated by the United States Environmental Protection Agency (USEPA) that there are 2 to 3.5 million underground storage tanks (USTs) throughout the nation and about 25% of these tanks are leaking. The leakage of petroleum or other organic material presents serious environmental problem due to the uncontrolled release of petroleum products to ground water. Many new techniques have developed to reuse these petroleum contaminated soils generated from sites containing leaking USTs. One such soil reuse method available since 1985 is the use of petroleum contaminated soils in the production of hot mix asphalt.

The stability, durability, and hydraulic …