Environmental Engineering Commons^™

Quantifying Cyanide Inhibition Of Nitrification And Developing Cost-Effective Treatment Processes, Germano M. Salazar-Benites

Civil & Environmental Engineering Theses & Dissertations

All wastewater treatment plants that operate multiple hearth furnaces (MHF) and are required to nitrify must manage the inhibitory effects of free cyanide (HCN, CN-) in the scrubber return flows due to inhibitory impacts on nitrifying bacteria.

HRSD Boat Harbor Treatment Plant (BHTP) a 25 MGD facility consisting of primary and secondary treatment, employs an anoxic selector process for nitrification and partial denitrification and operates a MHF. There is a desire to improve TN removal performance at BHTP due to an annual mass-based bubble permit limit on a combined discharge from seven HRSD plants, and there are no discharge limitations …

Effects Of Surrounding Water Table On A Forested Wetland Habitat In East Coast Of Virginia, Lane Stokes

Civil & Environmental Engineering Theses & Dissertations

Exchanges into and out of a wetland, including surface water flow, groundwater flow, and constituents in the flows, usually determine the wetland physicochemical characteristics and biodiversity. To date, of these three exchanges, groundwater flow is the least studied, particularly in the United States of America. In this thesis, field observations were conducted at a forested non-tidal wetland, located on a flat hilltop. The position of the wetland is such that groundwater outflow is the only significant exchange that could be impacted by the surrounding land use. In addition, a spatially variable steady-state model was set up to extrapolate the observations …

Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino

Civil & Environmental Engineering Theses & Dissertations

The longitudinal dispersion coefficient is a parameter used to evaluate the effect of cross-sectional variations on substance mixing mechanisms in estuaries influenced by tide, wind and internal density variations. Considering a two dimensional approach, this study aims at evaluating a tidal area of the lower James River at approximately 19 miles upstream from the mouth at the Chesapeake Bay, in the City of Newport News, and applies an experimental procedure based on in-situ salinity concentrations to estimate the dispersion coefficient in the area where receives a discharge from the HRSD James River Wastewater Treatment Plant, and further characterizes Total Suspended …

Impacts Of Operating Parameters On Extracellular Polymeric Substances Production In A High Rate Activated Sludge System With Low Solids Retention Times, Matthew S. Elliot

Civil & Environmental Engineering Theses & Dissertations

The Adsorption/Bio-oxidation (A/B) process accomplishes carbon capture via bio-flocculation in the adsorption stage (A-stage) to maximize energy recovery while simultaneously providing an optimal carbon to nitrogen (C/N) ratio for denitrification in the Bio-oxidation stage (B-Stage). The present study evaluated the influence of the solids retention time (SRT), dissolved oxygen (DO) concentration, and production of extracellular polymeric substances (EPS) on bio-flocculation and subsequent carbon capture using a pilot-scale A-stage process. A mixed liquor suspended solids (MLSS)-based control strategy was implemented to manage carbon capture by maintaining a constant MLSS concentration of 3,000 mg/L in response to diurnal variations in organic loading. …

Comparing Nutrient Recovery Via Rapid (Flash Hydrolysis) And Conventional Hydrothermal Liquefaction Processes For Microalgae Cultivation, Caleb Richard Talbot

Civil & Environmental Engineering Theses & Dissertations

Algal biofuels have the potential to provide a scalable source of renewable fuels in the near future. The high nutrient use in algae cultivation and its recovery and recycling is one of the challenges that may limit the scalability and sustainability of algal biofuels. The present study evaluates the use of Hydrolysate obtained after Flash Hydrolysis (FH) of Scenedesmus at 280 C as a nutrient source for microalgae cultivation. FH Hydrolysate nutrient recycling was compared with low temperature batch Hydrothermal Liquefaction (HTL) nutrient recycling. Oocystis and Scenedesmus were cultivated using Hydrolysate as a partial phosphorous (P) and nitrogen (N) source. …

Techno-Economic Analysis Of Protein Concentrate Produced By Flash Hydrolysis Of Microalgae, Alexander Nana Yaw Asiedu

Civil & Environmental Engineering Theses & Dissertations

Process simulation and techno-economic analysis of 95wt.% protein concentrate from microalgae has been performed using SuperPro Designer v. 9.0. This work, first of its kind, is focused on the economic analysis of protein concentrate that includes processes such as microalgae cultivation, harvesting, protein extraction and drying steps. A baseline capacity of 160 MT/day protein concentrate production on commercial basis has been analyzed. This throughput requires 336 MT/day dry algae (54 wt.% protein). The amount of carbon dioxide required to grow this quantum of algae is estimated to be 648 MT/day, which is produced from an in situ 21 MW power …

A Risk Assessment Of The Impacts Of Coastal Flooding And Sea Level Rise On The Existing And New Pump Stations 113, Norfolk, Va, David A. Pezza

Civil & Environmental Engineering Theses & Dissertations

The author assessed the risk to a wastewater pump station and a planned replacement located nearby due to coastal flooding and rising sea levels. The locations for the pump stations are in the Larchmont neighborhood by the Lafayette River tidal estuaries in Norfolk, Virginia. The Lafayette River is a tributary to the Elizabeth River, which flows to the Chesapeake Bay. The low-lying areas along the river are subject to coastal surges caused by tropical and extra-tropical storms that flood the bay.

The region is considered one of the urban areas most exposed to the accelerating rate of rising sea levels. …

Impact Of Limited Organic Carbon Addition On Nitrogen Removal In A Mainstream Anammox Moving Bed Biofilm Reactor, Johnnie Wayne Godwin

Civil & Environmental Engineering Theses & Dissertations

Excessive nitrogen compounds are a growing problem in the world and are leading to further environmental degradation. For future nitrogen pennit limits, conventional water treatment processes tend to not meet the requirements to drive these concentrations to low levels, and if they do, it can be rather costly. However, in mid 1990s a new bacterium was discovered that has allowed for nitrogen removal to occur at a considerably reduced cost. The use of anaerobic ammonia oxidizing bacteria (anammox or AMX) is well established in sidestream deammonification (partial nitritation and anammox). However, as of late there has been discussion of applying …

Life Cycle Assessment Using Argonne Greet Model Of Algae Based Biofuels Produced Using Flash Hydrolysis Process, Andrew P. Bessette

Civil & Environmental Engineering Theses & Dissertations

Traditional processing methods of algae to biofuels require dewatering after harvesting of the algae before the lipids can be extracted. This is typically the most energy intensive and therefore the most expensive step. Old Dominion University has successfully utilized a flash hydrolysis process where proteins are solubilized into the liquid phase of product and the remainder lipid-rich, low nitrogen product is separated into a solid phase. The solid phase (lipid-rich) is then an ideal candidate for biofuel feedstock and the liquid phase, or hydrolysate, can be used for coproducts such as a source of nutrients for new batches of algal …

Hydrothermal Catalytic Liquefaction And Deoxygenation Of Biomass For Renewable Fuel Production, Sergiy Popov

Civil & Environmental Engineering Theses & Dissertations

In recent years, sub- and supercritical water technologies received an increasing attention because of the numerous advantages they offer for biomass converting into biofuels. Water at elevated temperatures and pressures provides an ideal medium for chemical transformations. It serves as a reactant, reaction medium, and catalyst that helps biomass compounds undergo hydrolysis, depolymerization, dehydration, decarboxylation, and condensation/repolymerization reactions. Biomass is the fourth largest source of energy in the world after coal, oil, and natural gas that has the potential to provide the large scale substitution of hydrocarbon-based liquid transportation fuels and minimize the environmental issues. Biomass typically contains 40-60% oxygen. …

Adsorption-Style Activated-Sludge: Is It A Practical Treatment Process In North America?, Jon Dearmond

Civil & Environmental Engineering Theses & Dissertations

Adsorption/Bio-Oxidation (A/B) processes occupy a small footprint and can be exceptionally energy efficient to the point of being energy positive in optimum conditions. They have the ability to handle industrially influenced municipal wastewater with high pH and BOD swings. The A/B plant configuration also appears to be a great platform for shortcut nitrogen removal processes because of the controlled carbon diversion capabilities of the adsorption stage (A-stage). In Europe, these plants have been successfully implemented at full scale since the early 1980s. However, in the U.S. there is a false conventional wisdom that plants operating at very low SRT's will …

Polychlorinated Biphenyl Source Identification In Fish Tissue Using A Multivariate Statistical Evaluation Of Congeners And Stable Isotope Ratio Mass Spectrometry, William Edward Corl Iii

Civil & Environmental Engineering Theses & Dissertations

Polychlorinated biphenyls (PCBs) were commercially produced mixtures primarily utilized as dielectric fluids in the electrical industry. However, due to their stability, they were widely used in many other applications. Although production of PCBs ceased in the 1970's, they continue to be a contaminant in the environment due to their widespread use, their recalcitrant behavior, and their proposed toxicological effects.

In 2008, a routine environmental investigation of an abandoned, concrete-lined pool at a Department of Defense (DoD) training facility in Williamsburg, Virginia led to the discovery of a PCB release from the facility into an adjacent reservoir. A forensic study was …

Hydro-Climate Temporal Variations And Their Influences On Net Primary Production In A Eurasian Steppe Watershed, Xiaomin Yang

Civil & Environmental Engineering Theses & Dissertations

Climate, which is the most important factor that influences Net Primary Productivity, has been detected changing all over the world. The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann-Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large anomalies. In this research, by formulating a trend analysis approach that considers nonstationary due to step changes, trends and extreme occurrences of precipitation, temperature, and runoff in annual, seasonal, and monthly scales were analyzed in a mid-latitude Eurasian steppe watershed in northeast China, and …

Evaluation Of The Epa Swmm Model To Simulate Low Impact Development Features In An Urban Stormwater Environment, Holly Ann Carpenter

Civil & Environmental Engineering Theses & Dissertations

This research thesis explores the use of the Environmental Protection Agency's (EPA) Stormwater Water Management Model (SWMM) to model an urban watershed with a developed stormwater management system and test the SWMM model's ability to simulate Low Impact Development (LID) features by proposing typical LID features that can be retrofitted to the developed study area. The SWMM model is established with an existing survey of the study area's stormwater management system, and due to the lack of field data for the study area, the model developed in this research thesis is calibrated with the consideration of a published stormwater model …

Feasibility Of Mainstream Nitrite Oxidizing Bacteria Out-Selection And Anammox Polishing For Enhanced Nitrogen Removal, Pusker Raj Regmi

Civil & Environmental Engineering Theses & Dissertations

Short-cut nitrogen removal avoids nitrite oxidation to nitrate by nitrite oxidizing bacteria (NOB) and allows a) reduction of formed nitrite to nitrogen gas via heterotrophic denitrification and/or b) oxidation of remaining ammonia with formed nitrite to nitrogen gas via anaerobic ammonia oxidation (anammox). The precondition for achieving shortcut nitrogen removal is suppression of NOB, which is favored by warm and high ammonia strength conditions found in internally generated ammonia-rich waste streams through anaerobic digestion of waste solids referred to as sidestreams or reject water. The discovery of anammox bacteria in the mid-1990s, which are capable of transforming NH₄+ …

Flash Hydrolysis Of Microalgae Biomass For Biofuels Intermediates Production, Protein Extraction, And Nutrients Recycle, Jose Luis Garcia Moscoso

Civil & Environmental Engineering Theses & Dissertations

Microalgae have shown much higher growth rates and productivity when compared to conventional agricultural crops, aquatic plants and tree species, requiring much less land area than other biodiesel feedstock. To harness that potential the hydrothermal liquefaction of algae biomass was studied and a new process called "Flash Hydrolysis" was developed to use water under subcritical conditions, this process capitalizes on the difference in reaction kinetics of algae polymeric components and fractionates proteins in liquid phase in seconds of residence time.

The main objectives for this study are: Analyze the effect of temperature in FH process to maximize the extraction of …

Dimensionless Criteria For Selecting Tidally-Influenced Advective-Dispersive Desalination Brine Mixing Plume Characterization Models, Alireza Shahvari

Civil & Environmental Engineering Theses & Dissertations

The very nature of requirements for implementing a desalination process is highly spatial due to the need to secure both a source for the operation and sink for brine dilution. Thus, the applicable coastal location is bound to natural tidal mixing characteristics and subjected to a near- or a far-field availability for source and sink. Mixing characteristics of coastal waters are very different from one point to another due to the spatiotemporal tidal characteristic in loco in a manner that it can vary from being highly advective to completely dispersive dominant. Once a location is identified, estimation of corresponding water …

Operation And Modification Of A B-Stage For Efficient Nitrogen Removal In An A/B Process Pilot Study, Ryder Bunce

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District's Chesapeake-Elizabeth Wastewater Treatment Plant is a High-Rate Activated Sludge (HRAS) plant with no primary clarifiers. The plant operates at an SRT of 1.5 - 2 days and does not perform biological nitrogen removal (BNR). By 2021 HRSD anticipates the plant will be included in a bubble permit, resulting in a total nitrogen (TN) effluent target of approximately 5-8 mg/L. Converting the plant to a conventional BNR process would require a significant increase in reactor volume. Capital costs for the upgrade are estimated at 125 -150 million dollars, with a dramatic increase in operating costs as well. …

Denitrification And Biological Phosphorus Removal Using Focused, Pulse-Treated, Thickened Waste Activated Sludge As An Internal Carbon Source, Holly Anne Hillard

Civil & Environmental Engineering Theses & Dissertations

Recent research shows that an internal carbon source, derived from the treatment of waste activated sludge (WAS), could be used as an alternative to external carbon sources for denitrification in biological wastewater treatment processes. In this study, a thickened waste activated sludge (TWAS) treatment technology, developed by the company OpenCEL, was used to treat TWAS with pulsed electric fields (PEF) to transform it into an organic substrate for heterotrophic denitrification in a biological nutrient removal (BNR) system. If effective, this technique could significantly reduce the external carbon source demand.

To determine the utility of OpenCEL-treated TWAS as an internal carbon …

Optimization Of Demon® Sidestream Treatment And Potential For Anammox Mainstream Bioaugmentation, Andrea Lauren Nifong

Civil & Environmental Engineering Theses & Dissertations

Anaerobically digested sludge dewatering liquors (e.g. centrate) can represent 15-25% of the total kjeldahl nitrogen (TKN) load on a typical municipal waste water treatment plant (WWTP). Sidestream nitrogen removal has been demonstrated to be an effective tool for improving nitrogen removal performance and reliability with a savings in aeration energy, chemicals (supplemental alkalinity and carbon), and sludge production.

Deammonification, partial nitritation by ammonia oxidizing bacteria (AOB) combined with anaerobic ammonium oxidation (AMX or anammox), provides near complete nitrogen removal with a 65% reduction in energy and 100% reduction in supplemental carbon and alkalinity requirements as compared to traditional nitrification-denitrification. The …

Evaluating Alternatives For Augmented Water Quality Improvement Utilizing Oyster Restoration As Best Management Practice (Bmp), Stephanie Roberts Long

Civil & Environmental Engineering Theses & Dissertations

Due to several anthropogenic influences, the Chesapeake Bay has experienced a marked decrease in water quality since the colonists arrived at the Jamestown settlement in Virginia during the 1600s. Higher concentrations of nitrogen and phosphorus have enriched the estuaries and coastal waters via point sources (sewage treatment plants and industrial wastes), nonpoint sources (agricultural run-off and septic tank discharges) and the atmosphere (Newell et al., 2005). Restoring oyster beds is considered a Best Management Practice (BMP) to improve water quality as well as provide physical habitat for aquatic species and a healthier estuarine system (USACE Native Oyster Restoration Master …

Evaluation Of Hydraulic Conductivity Of Non Aqueous Phase Liquids In Partially Saturated Soils, Chijioke Ekeleme Akamiro

Civil & Environmental Engineering Theses & Dissertations

This study seeks to investigate a problem of predicting the hydraulic conductivity of NAPLs in partially saturated soils and to relate the hydraulic conductivity to basic soil parameters that are either easy to determine or are in wide use. To evaluate hydraulic conductivity in partially saturated soils, previous researchers have focused on flow geometry, soil and chemical properties, etc. used in CHEMFLO program by Nofziger et al., (1989) and saturation equations by such authors as Van Genutchen (1980) and Brooks and Corey (1964). Among those, the soil-water characteristic curve (SWCC) is the most widely used constitutive relations for unsaturated soils …

Analysis Of Primary-Secondary Incident Events On Urban Freeways, Hongbing Zhang

Civil & Environmental Engineering Theses & Dissertations

The objective of this study is to understand the nature of primary and secondary traffic incidents, assess their impacts and explore the implications in traffic operations, safety, and planning. To achieve the objective, a queue-based secondary incident identification method was developed and applied based on detailed incident, traffic and geometric data sets from Hampton Roads, Virginia. This identification method can overcome the limitations in earlier studies and identify secondary incidents in both road directions. An innovative event categorization defines the term "primary-secondary incident event", as one characterized by a primary incident and one or more associated secondary incidents in both …

A Study Of The Correlation Of Sub-Aqueous Beach Profile Change And The Coastal Storm Impulse (Cosi) Parameter, Kevin Bryan Conner

Civil & Environmental Engineering Theses & Dissertations

The Coastal Storm Impulse (COSI) parameter is a recently developed storm-strength parameter that was first introduced at the San Diego, California International Conference of Coastal Engineering in 2006 (ICCE) and further examined in 2008 at the ICCE in Hamburg, Germany. This new parameter used the principles of conservation of horizontal momentum to combine storm characteristics such as surge, wave dynamics, currents, and duration into a relative scale used to classify and measure storm response and impacts. The resultant classification system was intended to evaluate potential coastal erosion and the associated loss of coastal infrastructure, as well as provide a storm …

Application Of The Coastal Storm Impulse (Cosi) Parameter To Predict Coastal Erosion, Robert Aaron Walker

Civil & Environmental Engineering Theses & Dissertations

A new coastal storm-strength parameter, the Coastal Storm Impulse (COSI) parameter, was introduced at the 2006 International Conference of Coastal Engineering (ICCE) in San Diego and further discussed at the ICCE 2008 in Hamburg. COSI is based on the conservation of linear, horizontal momentum to combine storm surge, wave dynamics, and currents over the storm duration. Both tropical storms (hurricanes) and extra-tropical storms (northeasters) can produce similar COSI parameters. Potential implications of such a storm classification system include the evaluation of potential coastal erosion and coastal infrastructure, as well as providing a universal storm strength indicator that is directly tied …

Analysis Of Fema Guidelines For Coastal Dunes Using A Numerical Model, Brenton Edward Payne

Civil & Environmental Engineering Theses & Dissertations

FEMA's current guideline for coastal dune erosion is called the 540 Rule. The intent of the 540 Rule is to act as a boolean guideline for dune protection. If a dune is validated as being substantial against the 1 % Annual Chance Storm Water Elevation Level by the 540 Rule, then the area behind the dune is considered to be susceptible to less energetic flooding. This is known as an AE Flood Zone. An immediate effect of being rezoned is a significant drop in the insurance costs behind the dune. However, if the dune is not validated by the 540 …

The Influence Of Mechanical Circulation On Water Column Stability And Dissolved Oxygen In Stratified Lakes, Paal Engebrigtsen

Civil & Environmental Engineering Theses & Dissertations

Surface circulators have been used in wastewater and industrial lagoons for many years, but only recently have they been designed for lakes and reservoirs as a water quality management tool. Their relatively low capital investment and operational costs make them an attractive chemical free option for ameliorating the symptoms of eutrophication. Little research has been conducted on their effectiveness in impacting water quality. Today many lake managers are waiting for independent research on surface circulators' performance before installing such systems.

The Occoquan Reservoir was the primary site for a study conducted to examine the influence of surface circulation on water …

3d Numerical Modeling Of Hydrodynamic Flow, Sediment Deposition And Transport In Stormwater Ponds And Alluvial Channels, Leying Zhang

Civil & Environmental Engineering Theses & Dissertations

Prediction of flow and sediment transport is an important and challenging problem for stormwater management and river engineering applications. This thesis concerns primarily the computation of flow, sediment deposition and transport processes in stormwater ponds and alluvial channels based on a multiphase flow approach in modeling sediment transport. Starting from an existing hydrodynamic Reynolds Averaged Navier-Stokes flow solver, numerical models are developed to predict flow, sediment deposition and transport under the FLUENT software package. Two types of sediment transport models are formulated to consider quantities of present sediment phase volume fractions: a Discrete Phase Model in a Lagrangian frame where …

Spatiotemporal Estuarine Water Quality Parameterization Using Remote Sensing And In-Situ Characteristics, Kwisun Park Yu

Civil & Environmental Engineering Theses & Dissertations

This dissertation develops a new paradigm in a water quality monitoring approach to parameterize spatiotemporal estuarine water quality with sustainable reliability, less cost and less time. A key underpinning of this paradigm of the spatiotemporal estuarine water quality parameterization is various water quality parameters' interrelationship with ambient water temperature as a common factor, their time dependent characteristics, and spatiotemporal characteristics of remote sensing. It has two core models to provide input data of water quality parameterization model in a system; the transfer function models of the physical system and an analytical temperature time series model. The objective of this dissertation …

Mesoscale Dispersive Flux In The Lower Reaches Of The Elizabeth River Estuary, Byron Danrich Tracy

Civil & Environmental Engineering Theses & Dissertations

Congress has mandated under Section 303(d) of the Clean Water Act that Total Maximum Daily Loads (TMDL's) be established for impaired water bodies to further identify and regulate their waste assimilative capacity. To establish a TMDL, the sources of waste loading or pollutants must be identified, and a method of determining how each should be limited or removed must be developed. Using a water quality model is a typical method for determining these limits, and since new or changed limits will likely impact local businesses and government budgets, the model must be accurate. For most tidal systems larger than small …