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Full-Text Articles in Environmental Engineering

Aerosol Delivery As A Method For Enhancing Remedial Application In Contaminated Vadose Zones, Richard Hall May 2013

Aerosol Delivery As A Method For Enhancing Remedial Application In Contaminated Vadose Zones, Richard Hall

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Remediation of contaminated vadose zones is often hindered by an inability to effectively distribute liquid- or solid-phase amendments. Many amendment-based approaches, such as bioremediation, chemical oxidation, and reactive barriers have been successful in saturated formations. However, these remedial approaches have seen limited application in unsaturated materials, largely because of difficulties delivering amendments.
Aerosol delivery is a promising approach for distributing amendments in contaminated vadose zones. The amendments are aerosolized, creating a cloud of micron to sub-micron-scale liquid droplets held suspended in a gas by Brownian motion. During injection into porous media, the aerosol particles are transported along with the gas …

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Laboratory Characterization And Theoretical Analysis Of Contaminant Mass Transfer, Xiaoling Liu Aug 2012

Laboratory Characterization And Theoretical Analysis Of Contaminant Mass Transfer, Xiaoling Liu

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Chlorinated volatile organic compounds (CVOCs) in fractured, low permeability material can be a long-term source of groundwater contaminants and they are among the most difficult remediation challenges. Thermal methods are a possible remediation option, where heat is used to boil water and the volatile compounds are stripped out by partitioning into the resulting water vapor. Theoretical analysis indicates that only a small fraction of pore water removal may lead to a significant geometric reduction in the dissolved concentration [(Udell(, 1998]. Previous modeling studies [(Falta and Murdoch(, 2011; (Pruess(, 1983] suggest that a lower permeability limit exists for effective mass transfer …

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Assessing Ongoing Sources And Fate Of Dissolved Polychlorinated Biphenyls (Pcbs) In A Stream, Viet Dang May 2012

Assessing Ongoing Sources And Fate Of Dissolved Polychlorinated Biphenyls (Pcbs) In A Stream, Viet Dang

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Polychlorinated biphenyls (pcbs) contamination remains a concern due to their persistence and the risk to human health associated with them. Once released into the environment, these substances are mainly associated with sediment particles and sediment organic carbon matter. They bioaccumulate in organisms via contaminated food and only a small faction is desorbed from sediment into the water column. Given the discontinuity of active discharge, pcbs are currently entering the water via groundwater inputs, soil erosion, and/or ongoing leakage from the point source. It is the dissolved form that 1) can be either absorbed by biofilm attached to stream leaves, which …

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Contaminant Mass Transfer During Boiling In Fractured Geologic Media, Fei Chen Aug 2011

Contaminant Mass Transfer During Boiling In Fractured Geologic Media, Fei Chen

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Remediation of fractured geologic media contaminated with chlorinated volatile organic compounds that diffuse into the matrix is challenging using isothermal methods. Due to the low permeability of the matrix material and uncertainty of fracture networks, it is difficult to flush the system with any type of fluid or deliver remediation agents into the matrix. However, thermal methods have some promises. When the matrix is heated above water boiling temperature, depressurization in the fractures may trigger water boiling in the matrix, which, as a result, generates a large volumetric steam flow toward adjacent fractures, stripping the adsorbed or dissolved volatile contaminants …

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Applications Of Moderate-Resolution Remote Sensing Technologies For Surface Air Pollution Monitoring In Southeast Asia, Arika Bridhikitti May 2011

Applications Of Moderate-Resolution Remote Sensing Technologies For Surface Air Pollution Monitoring In Southeast Asia, Arika Bridhikitti

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Retrievals from Earth observation satellites are widely used for many applications, including analyzing dynamic lands and measuring atmospheric components. This research aims to evaluate appropriateness of using satellite retrievals to facilitate understanding characteristics of Southeast Asian (SEA) surface air pollution, attributed to regional biomass burnings and urban activities. The studies in this dissertation focused on using satellite retrievals for 1) mapping potential SEA air pollution sources; which are forests, rice paddies, and urban areas, 2) understanding dynamic optical characteristics of SEA biomass-burning aerosols, and 3) inferring surface ozone level. Data used in this study were from three NASA's Earth Observing …

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Identification And Characterization Of Polychlorinated Biphenyl Dechlorinating Microorganisms From Lake Hartwell, Sc, Tess Brothersen May 2011

Identification And Characterization Of Polychlorinated Biphenyl Dechlorinating Microorganisms From Lake Hartwell, Sc, Tess Brothersen

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To date, all attempts to isolate PCB dechlorinators using traditional isolation techniques have failed. In addition, the study of PCB dechlorinating organisms has been hampered because researchers were unable to grow the organisms in sediment-free, defined media. Three microbial species capable of reductive dechlorination of polychlorinated biphenyls have been identified. These three species are from two phylogenetically distinct branches, Dehalococcoides (Bedard et al., 2007) and the DF-1/o-17 group (Wu et al., 2002a; Cutter et al., 2001). The three cultures from which polychlorinated biphenyl dechlorinators have been identified used similar strategies to 'wean' the microbes from the sediments. In this research, …

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Sensitivity Analysis Of Uranium Speciation Modeling In Groundwater Systems With A Focus On Mobility, Andrew Scott Dec 2010

Sensitivity Analysis Of Uranium Speciation Modeling In Groundwater Systems With A Focus On Mobility, Andrew Scott

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Uranium is an important natural resource used in production of nuclear reactor fuel and nuclear weapons. The mining and processing of uranium has left a legacy of environmental contamination that remains to be addressed. There has been considerable interest in manipulating the oxidation state of uranium in order to put it into an environmentally immobile form. Uranium forms two stable oxidation states in nature, uranium (IV) being much less soluble than uranium (VI), and therefore the preferred state with regard to limiting the potential exposure of man. One of the tools used in evaluating potential effects of manipulating the natural …

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Energy And Nutrient Recovery From Anaerobic Treatment Of Organic Wastes, Christian-Dominik Henrich May 2010

Energy And Nutrient Recovery From Anaerobic Treatment Of Organic Wastes, Christian-Dominik Henrich

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The objective of the research was to develop a complete systems design and predictive model framework of a series of linked processes capable of providing treatment of landfill leachate while simultaneously recovering nutrients and bioenergy from the waste inputs. This proposed process includes an 'Ammonia Recovery Process' (ARP) consisting of: 1) ammonia de-sorption requiring leachate pH adjustment with lime or sodium hydroxide addition followed by, 2) ammonia re-absorption into a 6-molar sulfuric acid spray-tower followed by, 3) biological activated sludge treatment of soluble organic residuals (BOD) followed by, 4) high-rate algal post-treatment and finally, 5) an optional anaerobic digestion process …

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Biodegradation And Bioremediation Of Hexachlorocyclohexane Isomers, Chlorinated Ethenes, Chlorinated Benzenes And Benzene, Vijaikrishnah Elango May 2010

Biodegradation And Bioremediation Of Hexachlorocyclohexane Isomers, Chlorinated Ethenes, Chlorinated Benzenes And Benzene, Vijaikrishnah Elango

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ABSTRACT
Groundwater at an industrial site is contaminated with γ -hexachlorocyclohexane (HCH) and α-HCH (i.e., lindane) (0.3-0.5 ppm). Other contaminants in the 1-15 ppm range include 1,2,4-trichlorobenezene (TCB), 1,2-dichlorobenzene (DCB), 1,3-DCB, 1,4-DCB, chlorobenzene (CB), benzene, trichloroethene (TCE) and cis-1,2-dichloroethene (cDCE). The aquifer consists of a shallow layer of soil over fractured dolomite, where most of the contaminant mass resides. The objective of this study was to compare 1) anaerobic reductive dechlorination of the polychlorinated contaminants, followed by aerobic biodegradation of the daughter products (mainly DCBs, CB, and benzene); and 2) aerobic biodegradation of α- and γ-HCH, TCB, DCBs, CB and …

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Occurrence And Formation Of Disinfection By-Products In Indoor Swimming Pools Water, Amer Kanan May 2010

Occurrence And Formation Of Disinfection By-Products In Indoor Swimming Pools Water, Amer Kanan

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Chlorination is used to prevent the spread of waterborne infectious diseases from swimming pools. This required disinfection practice also results in the formation of undesirable disinfection by-products (DBPs) from the reactions of chlorine with the organic matter (released by swimmers or present in the filling water of the pool) and bromide. Some of these DBPs have important adverse public health effects; as a result their concentrations in drinking waters are regulated. Unfortunately, DBPs formation and control in swimming pools have not been studied and investigated to the same extent as their formation and control in drinking water.
The main objective …

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Probabilistic Remediation Evaluation Model For Chlorinated Solvents Considering Uncertainty, Hailian Liang Dec 2009

Probabilistic Remediation Evaluation Model For Chlorinated Solvents Considering Uncertainty, Hailian Liang

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The complex processes and expensive costs of source and plume remediation of dense, non-aqueous phase liquid (DNAPL) complicate the decision-making process for site remediation. Selection of remediation alternatives has been a big challenge due to the lack of tools that simultaneously evaluate the effectiveness of source and plume remediation and access the uncertainties in all major parameters. In this research, a new probabilistic remediation model, Probabilistic Remediation Evaluation Model for Chlorinated solvents sites (PREMChlor), has been developed. This is achieved through linking the analytical model REMChlor to a Monte Carlo modeling simulation package GoldSim via a FORTRAN Dynamic Link Library …

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Development Of Strategies For Enhanced In Situ Bioremediation Of High Concentrations Of Halogenated Methanes, Huifeng Shan May 2009

Development Of Strategies For Enhanced In Situ Bioremediation Of High Concentrations Of Halogenated Methanes, Huifeng Shan

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ABSTRACT
Bioremediation of high concentrations of halomethanes e.g., carbon tetrachloride (CT), trichlorofluoromethane (CFC-11) and chloroform (CF) has seldom been addressed before and remains highly challenging. A microcosm study was conducted to investigate bioremediation strategies for groundwater contaminated with CT (6 to 10 mg/L), CFC-11 (1 to 26 mg/L), CF (3-500 mg/L), and 1,1-dichloroethene (1,1-DCE; up to 9 mg/L) at a former industrial site in California. Biostimulation with corn syrup and catalytic amounts of vitamin B12 was demonstrated as a feasible remedial strategy and bioaugmentation with B12 represents the most promising bioremediation method of the ones studied. Halomethane transformation …

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An Examination Of Confined Aquifer Gradient Behavior Under Pumping Conditions, Stefanie Fountain May 2009

An Examination Of Confined Aquifer Gradient Behavior Under Pumping Conditions, Stefanie Fountain

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Accurate and reliable estimates of groundwater flow and contaminant transport models are dependent on an understanding of the aquifer properties used to create the models. The borehole flowmeter has been used with increasing frequency at a variety of sites to produce high resolution vertical hydraulic conductivity (K(z)) distributions [Boggs et al. 1990; Rehfeldt et al. 1989b; Molz et al. 1989, Boman et al. 1997; Dinwiddie et al. 1999]. In theory, the validity of measurements obtained using borehole flowmeters is contingent on the hydraulic head gradients near the well at each discrete depth resulting from the pumping-induced flow having reached quasi-steady-state. …

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Experimental And Modeling Studies For Optimizing Flocculant-Aided Sediment Retention Ponds, Byung Joon Lee Dec 2008

Experimental And Modeling Studies For Optimizing Flocculant-Aided Sediment Retention Ponds, Byung Joon Lee

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Attempts to control sediment-containing runoff and associated water quality problems have involved the establishment of many small to medium sediment retention ponds and the injection of nonionic and anionic polyacrylamide (PAM) flocculants to enhance colloid removal. However, to date use has been driven more by practicing engineers and trial-and-error approaches than by logical and consistent design approaches. Therefore, the purpose of this research was to optimize colloidal clay removal in PAM-aided sediment retention ponds by applying experimental and theoretical methodologies.
Initially, simple measurement techniques for the molecular weight (MW) and charge density (CD) of various PAMs were tested and their …

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Anaerobic Biodegradation Of Ethylene Dibromide And 1,2-Dichloroethane In The Presence Of Fuel Hydrocarbons, James Henderson May 2008

Anaerobic Biodegradation Of Ethylene Dibromide And 1,2-Dichloroethane In The Presence Of Fuel Hydrocarbons, James Henderson

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Field evidence from underground storage tank (UST) sites where leaded gasoline leaked indicates the lead scavengers 1,2-dibromoethane (ethylene dibromide, or EDB) and 1,2-dichloroethane (1,2-DCA) may be present in groundwater at levels that pose unacceptable risk. These compounds are seldom tested for at UST sites. Although dehalogenation of EDB and 1,2-DCA is known to occur, the effect of fuel hydrocarbons on their biodegradability under anaerobic conditions is poorly understood. Microcosms (2 L glass bottles) were prepared with soil and groundwater from a UST site in Clemson, South Carolina, using samples collected from the source (containing residual fuel) and less contaminated downgradient …

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Laboratory Evaluation Of Chlorinated Ethene Transformation Processes In Fractured Sandstone, Ramona Darlington May 2008

Laboratory Evaluation Of Chlorinated Ethene Transformation Processes In Fractured Sandstone, Ramona Darlington

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A fractured sandstone aquifer at an industrial site in southern California is contaminated with trichloroethene (TCE) to depths in excess of 244 m. Field monitoring data suggest that TCE is undergoing reduction to cis-DCE and that additional attenuation is occurring. However, vinyl chloride (VC) and ethene have not been detected in significant amounts, so that if transformation is occurring, a process other than reductive dechlorination must be responsible. The overall objective of this study was to evaluate the occurrence of biotic and abiotic transformation processes at this site for TCE, cis-DCE and VC. Anaerobic microcosms were constructed with site groundwater …

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Modeling Long-Term Plutonium Transport In The Savannah River Site Vadose Zone, Deniz Demirkanli Dec 2006

Modeling Long-Term Plutonium Transport In The Savannah River Site Vadose Zone, Deniz Demirkanli

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Improved understanding of flow and radionuclide transport in vadose zone sediments is fundamental to future planning involving radioactive materials. Long-term experiments were conducted at the Savannah River Site (SRS), where a series of lysimeters containing sources of different Pu oxidation states were placed in the shallow subsurface and exposed to the environment for 2 to 11 years. After the experiments, Pu activity concentrations were measured along vertical cores. The distributions were anomalous in nature, with irregular downward migration and unexpected upward migration. Previous studies suggested that surface-mediated, oxidation/reduction (redox) reactions may be responsible for the anomalies. This hypothesis is tested …

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Controlling Steam Flood Migration With Air Injection Wells, Rex Hodges Dec 2006

Controlling Steam Flood Migration With Air Injection Wells, Rex Hodges

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Steam flooding is an aggressive remediation technology for removing volatile organic chemical (VOC) sources that slowly dissolve into passing groundwater. Plume concentrations can be reduced, accelerating cleanup, and decreasing plume management costs. Steam injected in wells surrounding the source spreads outward and develops into a front that drives contamination to a system of groundwater pumping wells in the saturated zone and soil vapor extraction wells in the vadose zone. The process can be modeled with the non-isothermal multi-phase flow simulator T2VOC to include operation designs and factors at individual sites.
A pilot field-scale test at the Savannah River Site (SRS) …

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