Environmental Engineering Commons^™

Passive Solar Distillation Of Acid Rock Drainage, Stephanie Shreve, Luke Galuska, Anna Stoller, Alex Raney, Agustin Caceres, Caitlyn Chambers, Chris Graham, Devin Hazlett

Chemical Engineering Undergraduate Honors Theses

Arkansas Razorback Distillers (A.R.D.) has developed a passive solar distillation system for treating acid rock drainage (ARD) from legacy (i.e., abandoned) mines. The solar still addresses the need to reduce both the metal sulfate contaminants as well as the acidity of acid rock drainage. During the design phase, A.R.D. addressed the need for the system to be low cost, simple, and effective for general use as well as a specified location. To demonstrate the applicability of the solar still, A.R.D. used the Freeport McMoRan Inc. Copper Queen legacy mine in Bisbee, Arizona, as a base case scenario. The mine was …

Evaluation Of Phosphorous Removals By Biochar Supported Nano-Scale Zero-Valent Iron, Maria S. Rossetti

Chemical Engineering Undergraduate Honors Theses

This study evaluated the effectiveness of biochar-supported nano-scale zero-valent iron (nZVI/BC) in removing phosphorus (P) from water. Samples of nZVI/BC were prepared using aqueous nanoparticles synthesis techniques, and were mixed with a stock phosphorus solution. To determine P reductions water samples were tested for P content using the ascorbic acid method. This procedure was repeated for samples of stock P solution, zero-valent iron (ZVI), biochar, and ZVI/BC. nZVI/BC reduced P content by 86% whereas ZVI, biochar, and ZVI/BC removed 6%, -23%, and 17% respectively. This suggests that nZVI/BC has the potential to be an effective method of stormwater remediation.

Analysis Of Lid Implementation To Combat Flooding And Erosion At The University Of Arkansas Campus, Madison E. Crowl

Biological and Agricultural Engineering Undergraduate Honors Theses

The city of Fayetteville, Arkansas has experienced rapid urbanization throughout recent years as it continues to grow. Within the city, the University of Arkansas has been constantly expanding, with increased impervious surfaces as more parking lots and facilities are built. This has caused issues including flooding and stream bank erosion, specifically in Mullins Creek, which receives runoff from a large part of campus. A portion of the creek was restored, but there are still downstream issues. Low Impact Development (LID) is a type of green infrastructure that has been shown to decrease runoff and increase infiltration. EPA SWMM, a hydrologic …

Chlorpyrifos Removal For Wastewater Reuse, Indran Kamalanathan

Chemical Engineering Undergraduate Honors Theses

Approximately 1.2 billion people around the world live in areas of physical water scarcity. This could increase to half of the world’s population by 2030 and could displace 24 to 700 million people unless steps are taken to ensure adequate water supply.¹ Water scarcity is an escalating issue within the United States, specifically in Western inland states with arid climates. This scarcity is encouraging communities to investigate tertiary level municipal wastewater treatment, allowing for reuse of wastewater. Unfortunately, wastewater contains numerous contaminants that are not regulated by the Environmental Protection Agency (EPA) under the Safe Drinking Water Act (SDWA). …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Nanofiltration Rejection Of Contaminants Of Emerging Concern From Municipal Water Resource Recovery Facility Secondary Effluents For Potable Reuse Applications, Steven Michael Jones

Graduate Theses and Dissertations

As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient and the upcycling of contaminants of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place.

There are no federal Safe Drinking Water Act (SDWA) regulations in place specifically for direct potable reuse (DPR) of WRRF effluent. Out of necessity, some states are developing their own DPR reuse regulations. Currently, reverse osmosis (RO) is the default full advanced treatment (FAT) …

Assessing Toxicity Of Endocrine Disrupting Compounds In Wastewater For Water Reuse, Ryan Duchanois

Civil Engineering Undergraduate Honors Theses

Reclaiming treated wastewater for potable water use may be necessary to supplement drinking water sources in water scarce regions. However, Snyder et al. (2003) indicates that endocrine disrupting compounds (EDCs) are commonly found in wastewater effluents and natural waters around the world. These compounds with endocrine disrupting potential are typically found in personal care products, pharmaceuticals, and pesticides. Furthermore, according to Lemanik et al. (2007), typical wastewater treatment plants are not designed to remove EDCs.

For the purpose of water reuse, benchmarking wastewater treatment for endocrine disrupting compounds (EDCs) is necessary. The cytotoxicities of five EDCs (namely, amoxicillin, acetaminophen, triclosan, …

Removal Of Endocrine Disrupting Compounds From Secondary Municipal Wastewater, Dustin R. Resz

Chemical Engineering Undergraduate Honors Theses

Approximately 1.2 billion people around the world live in areas of physical water scarcity. This could increase to half of the world’s population by 2030 and could displace 24 to 700 million people unless steps are taken to ensure adequate water supply.1 Water scarcity is an escalating issue within the United States, specifically in Western inland states with arid climates. This scarcity is encouraging communities to investigate tertiary level municipal wastewater treatment, allowing for reuse of wastewater. Unfortunately, wastewater contains numerous contaminants that are not regulated by the Environmental Protection Agency (EPA) under the Safe Drinking Water Act (SDWA). Many …

Werc Task #1 - Efficiency And Particulate Matter Emissions Testing Of Wood Burning Heating Units, Jonathan A. Shumaker

Chemical Engineering Undergraduate Honors Theses

A design of a method for calculating the efficiency and particulate matter emission rates was developed for use on wood stoves. The project was completed for the WERC competition which is an international design contest. The prevalence of wood burning as a form of heating, current EPA regulations, and current market conditions were major factors in forming the necessity of this testing method. Design was not limited to outlining the design specifications, the apparatus was built and run. Optimization of the method continued until completion of the project. If the method would continue to be improved then it would be …

Municipal Composting And Organic Waste Diversion: The Case Of Fayetteville, Arkansas, Michael E. Hoppe

Biological and Agricultural Engineering Undergraduate Honors Theses

It is estimated that 40% of food is wasted in the United States; representing $165 billion in wasted resources. A vast majority of that wasted food is ultimately placed in landfills where it decomposes and releases harmful greenhouse gases (GHGs). In fact, food waste alone is responsible for 23% of annual methane emissions for the US. This has a huge impact on global climate change due to the potency of methane as a greenhouse gas. Currently only 5% of the food waste produced is recovered across the nation. Source reduction would be the best solution to reducing this food waste, …

Biofilm-Related Materials As Total N-Nitrosamine (Tono) Precursors And Hydroxylamine-Based Interferences In Tono And N-Nitrosodimethylamine (Ndma) Measurements, David Allen Meints

Graduate Theses and Dissertations

In this study, a chemiluminescence-based total N-nitrosamine (TONO) assay was adapted to include a solid-phase extraction (SPE) step to assess the role of biologically derived materials as N-nitrosamine precursors. Methanol was determined to be a suitable solvent for the SPE-TONO assay, with N-nitrosodimethylamine (NDMA) losses estimated to be 30% by SPE alone and an additional 15% from concentration of the methanol extracts by N2-gas blowdown. Three biofilm-derived materials - poly-N-acetylglucosamine (PNAG), Pseudomonas aeruginosa, and tryptophan - were individually chloraminated and dose-response relationships were observed with the SPE-TONO assay, indicating biofilm are potential N-nitrosamine precursors. The role of hydroxylamine - a …

Achieving Enhanced Treatment Of Produced Fluids Using Ozone, Hydrogen Peroxide And Electrochemical Oxidation: Full Scale Evaluations, Jamar Willis Blackmon

Graduate Theses and Dissertations

The main focus of the present work was to expand the existing knowledge in using an advanced oxidation process for produced water treatment. Produced water is a phrase used in the oil and gas industry to describe water that is produced as a waste byproduct together with oil and gas. Historically produced water was pumped down disposal wells as a waste product. Due to increasing demand, limited supply and stricter regulation on fresh water sources, exploration and production companies have been compelled to recycle produced waters in many parts of their operations around the world.

Produced water quality varies dramatically …

Microbial Community Shifts Caused By Changes In The Primary Oxidant At A Drinking Water Treatment Plant, Connie Marie Moloney

Graduate Theses and Dissertations

Microbial communities resistant to common oxidants can cause concerns for water treatment plants (WTPs). If a bacterium is not fully oxidized during disinfection, these species can impede upon filtration processes or seed biofilms in the distribution system. In an effort to minimize disinfection by-products (DBP's) that result from the reaction of chlorine (Cl2) with natural organic matter, water treatment plants have the option to change their primary oxidant to chlorine dioxide (ClO2). The following study examines the change in microbial communities during the sedimentation process under differing oxidation regimes, specifically chlorine (Cl2) and ClO2 at the local water treatment plant …

Assessment Of Nitrifying Bacteria In Massard Plant Using Molecular Tools, Jennifer Puanani Holmes-Smith

Civil Engineering Undergraduate Honors Theses

The discharge of nutrients (such as nitrogen and phosphorus) from wastewater treatment plants (WWTP) has become an increasingly important issue in the United States. Ammonia (NH3) is a common contaminant found in domestic wastewater and agricultural runoff. It can cause toxicity in fish if left untreated. The United States Environmental Protection Agency (EPA) recommends low national criteria for ammonia limits in freshwater. With these greater restrictions, ammonia-nitrogen limit compliance (5 mg/L) has become an issue at the Massard WWTP in Fort Smith, Arkansas. The purpose of this research is to assess the ammonia removal in the Massard WWTP in order …

Lab-Scale Experiment For Assessing The Effect Of Resuspension And Oxygenation On Sediment Oxygen Demand, Grace Richardson

Graduate Theses and Dissertations

This study examined the effects of resuspending lake sediment for different time periods in a lab-scale tank under both oxic and anoxic conditions on sediment oxygen demand (SOD) and other related sediment properties. This lab-scale study was conducted as a first step to determine if a proposed method for reducing SOD by treating sediments in lakes and reservoirs is feasible. SOD is a critical process responsible for the formation of anoxic hypolimnia in lakes and reservoirs. A reduction in SOD may delay or eliminate the onset of anoxia in the hypolimnia, preventing adverse ecosystem effects and improving water quality and …

Comparing Ferrous Chloride And Ferrous Sulfate As Secondary Coagulants At The Beaver Water District Drinking Water Treatment Plant, Jenny Doyle

Graduate Theses and Dissertations

In November 2012, the Beaver Water District (BWD) switched primary oxidants from free chlorine to chlorine dioxide (ClO2) to curb formation of trihalomethanes, a regulated group of organic disinfection byproducts (DBPs). Because ClO2 is reduced to chlorite (ClO2-), a regulated inorganic DBP, BWD incorporated ferrous salt into their coagulation regime to quench chlorite to chloride. In this study, two ferrous salts - ferrous chloride (FC) and ferrous sulfate (FS) - were compared as secondary coagulants in combination with alum, the primary coagulant. Ferrous salts were dosed stoichiometrically to reduce chlorite and alum was dosed at percentages (0-100%) relative to a …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

Full Depth Reclamation: Bringing Developing Countries' Transportation Up To Speed, Sadie Smith

Civil Engineering Undergraduate Honors Theses

Often, a direct correlation is observed between a country’s transportation network and economic development. Evidence of this is observed all over the world. Full Depth Reclamation (FDR) is a roadway recycling technique that mills and mixes the existing roadway with a stabilizing agent and then re-compacts the mixture to create a thicker, stabilized pavement layer. This method is both cost effective and environmentally friendly, making it a very appealing option as the need to rehabilitate or increase the structural capacity of existing roads grows. In this study, the material characterization of FDR was examined as a composite material of both …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

The Effects Of Temperature On Indicator Species Tests For Water Quality, Maranda Guinn

Civil Engineering Undergraduate Honors Theses

This study sought to investigate the different response of two indicator species tests: Hach® PathoScreenâ„¢ Field Test and IDEXX Colilert® using the Quanti-Tray/2000® enumeration method. Both tests were carried out according to the instructions enclosed in the packages using diluted water samples taken from the secondary clarifier at the West Side Waste Water Treatment Plant in Fayetteville, AR. The tests were carried out at various temperatures in an attempt to reflect conditions that could be encountered in the field, where electricity, equipment, and expertise may not be available. The PathoScreenâ„¢ test responded adequately at a relatively wide range of temperatures, …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

New Insights Into Disinfection Byproduct Formation And Control: Assessing Dissolved Organic Matter Diffusivity And Chemical Functionality, Ashley Pifer

Graduate Theses and Dissertations

Methods were developed for application of asymmetric flow field-flow fractionation (AF4) and fluorescence parallel factor (PARAFAC) analysis to raw and treated samples from drinking water sources to improve characterizations of dissolved organic matter (DOM) and discover DOM properties correlated to disinfection byproduct (DBP) formation potential (FP). Raw water samples were collected from a reservoir, adjusted to pH 6, 7, and 8 and subjected to (1) jar tests using aluminum sulfate (alum) and (2) treatment with magnetic ion exchange (MIEX^®) resin. Both treatments were followed by DBPFP tests at pH 7. AF4 was used to size DOM in raw …

Synergy Of Alum And Chlorine Dioxide For Curbing Disinfection Byproduct Formation Potential At Central Arkansas Water, Corey W. Granderson

Graduate Theses and Dissertations

Central Arkansas Water (CAW), the water utility for Little Rock, AR, draws their source water from Lake Maumelle and Lake Winona. To curb disinfection byproduct (DBP) formation, CAW has begun retrofitting their two plants to use chlorine dioxide as an alternative primary disinfectant followed by free chlorine secondary disinfection in the distribution system. In this study, fluorescence parallel factor (PARAFAC) analysis was combined with free chlorine simulated distribution system (SDS) tests and DBP formation potential (DBPFP) tests to study the benefit of chlorine dioxide primary disinfection (CDPD) with alum coagulation. Of the DBPs screened, trichloromethane (TCM) was formed in highest …

Mathematical Modeling Of Fluid Spills In Hydraulically Fractured Well Sites, Oluwafemi Michael Taiwo

Graduate Theses and Dissertations

Improved drilling technology and favorable energy prices have contributed to the rapid pace at which the exploitation of unconventional natural gas is taking place across the United States. As a natural gas well is being drilled, reserve pits are constructed to hold the drilling fluids and other materials returned from the drilling process. These reserve pits can fail, and when they do, plant and animal life of the surrounding area may be adversely affected. This project develops a screening tool for a suitable location for a reserve pit. This work will be a critical piece of the Infrastructure Placement Analysis …

Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins

Graduate Theses and Dissertations

Disinfection by-products (DBPs) form as an unintended result of drinking water disinfection, from chemical reactions between disinfectants (e.g., free chlorine) and naturally occurring dissolved organic matter (DOM). At present, 11 DBPs are regulated in treated drinking waters due to potential adverse health effects, including four trihalomethanes (THMs). Despite nearly 40 years of DBP research, compliance with DBP regulations remains a challenge for many drinking water treatment plants (DWTPs), including the four DWTPs located on the Beaver Lake Reservoir in Northwest Arkansas. Due to the high net negative surface charge on DOM, anion exchange is one potentially viable method for removing …

Water Quality Trends For Section 319 Priority Watersheds In Northwest Arkansas, 1997-2010, Bryan William Bailey

Graduate Theses and Dissertations

Northwest Arkansas contains two Section 319 Priority Watersheds that the Arkansas Natural Resources Commission (ANRC) has identified as being impacted by point and nonpoint sources of pollution (i.e., phosphorus, nitrogen, and sediment), and the Arkansas Water Resources Center (AWRC) has monitored the water quality at several sites within these watersheds. Water-quality data has been collected over the last decade within the Illinois River Watershed (HUC #11110103) and the Upper White River Basin (Beaver Reservoir HUC# 11010001), each watershed containing three sampling sites. The Illinois River Watershed sites are located on the Illinois River, Osage Creek, and Ballard Creek, and the …

Kinetics Determination Of Soybean Oil Transesterification In The Design Of A Continuous Biodiesel Production Process, Irwin Jacob, Ed Clausen, Danielle Julie Carrier

Biological and Agricultural Engineering Undergraduate Honors Theses

One-step batch transesterification consisting of three stepwise reversible reactions of pure soybean oil with methanol was conducted at two different mixing speeds (600 and 300 rpm) to produce soybean oil fatty acid methyl esters (biodiesel). In both batch reactions, sodium methoxide (1.09 wt% based on soybean oil) was used as the catalyst, the reaction temperature was 60oC, and the methanol-to-oil molar ratio was 6:1. The objectives were to determine and/or investigate: 1) the mechanism and order of the reaction, 2) the reaction rate constants, 3) the effect of changes in mixing intensity on the reaction rate, 4) the comparison of …