Environmental Engineering Commons^™

Influence Of Beach Hydrodynamics On Saltwater Transport And Oil Persistence In Beaches, Ali Abdollahi-Nasab

Dissertations

The exchange of water and solutes across the aquifer-ocean interface plays an important ecological role in both aquifer and the open water. Saltwater intrusion could prevent utilization of groundwater for either drinking water or irrigation. In addition, the flux of solutes, such as nutrients, from inland groundwater sources plays an important role in shoreline ecology, especially in embayments. This research relies on a three-pronged approach, involving a laboratory beach experiment, field scale experiments and numerical analyses. The laboratory beach experiment is designed to investigate the fundamental processes occurring in beach aquifers. It explores the effects of buoyancy (or lack thereof) …

Leaching Of Metals And Metalloids From Highway Marking Glass Beads And The Potential Environmental Impact, Nimrat K. Sandhu

Dissertations

Glass beads are embedded in pavement markings to obtain retroreflectivity which plays a crucial role in the lighting-up effect needed for safe driving. Elevated metal and metalloid concentrations of As, Sb, and Pb have recently been observed in imported glass beads. The main objective of this research was to assess the environmental impact associated with applying these imported glass beads in highway markings. To achieve this objective, total metal concentrations were measured using two techniques: hydrofluoric acid digestion followed by inductively coupled plasma mass spectroscopy (HF/ICP-MS), and field portable x-ray fluorescence (FP-XRF) spectroscopy. A number of leaching studies were conducted …

Challenges Of Permitting Ballast Water Discharges From Commercial Vessels In U.S. Waters, Paul Rodriguez

Theses

On February 5, 2009, the US Environmental Protection Agency (US EPA) issued the Vessel General Permit (VGP), under the Clean Water Act (CWA), for discharges incidental to the normal operation of vessels, including ballast water discharges. This set forth permit requirements for most commercial vessel discharges within 3 nautical miles of U.S. shore. Since it will expire in December 2013, the US EPA recently issued a draft 2013 VGP. One of the significant changes is the proposal of numerical ballast water discharge standards requiring most commercial vessels to install ballast water treatment systems onboard.

The objective of this thesis is …

Magnetic Seeding Aggregation To Enhance The Removal Efficiency Of Tio2 Nanoparticles From Water, Ashish Dhananjay Borgaonkar

Dissertations

Engineered nanoparticles, such as titanium dioxide (TiO₂), are important building blocks for the evolution of nanotechnology in industries and commercial products. Ever so increasing use of the engineered nanoparticles is bound to result in a substantial fraction of these nanoparticles ending up in wastewater; or surface water and groundwater, which are sources of intake for drinking water treatment. Removal of these engineered nanoparticles in wastewater and drinking water treatment processes is a very important step towards the protection of environmental and public health as well as protecting water treatment units from fouling and other issues.

Experimental studies showed …

A Study Of The New York / New Jersey Coastal Water : Bio-Optical Characteristics Of The Harbor Estuary And The Effects Of Heavy Metals On Brown Tide Alga Of The Bight, Bin Wang

Dissertations

The New York / New Jersey (NY/NJ) coastal area is one of the most productive regions around the world and a major natural and scenic resource for New York and New Jersey. As a result of excessive nutrient loading in the water, algal blooms have been observed since 1950’s. The NY/NJ coastal area includes the NY/NJ Bight and the NY/NJ Harbor Estuary, and in the former, brown tides (Aureococcus anophagefferens) were first observed in 1985 becoming a more serious water quality problem over the last 25 years. The influence of micronutrients, namely trace metals, on A. anophagefferens that are widespread …

Phosphate And Thermal Stabilization Of Heavy Metals In Dredged Sediments, Peter Kuria Ndiba

Dissertations

Treatment and reuse of dredged harbor sediments in construction as an alternative to disposal reduces costs and conserves resources. This research focused on leachability of metal contaminants subsequent to phosphate addition and thermal treatment at 700 °C. X- ray absorption spectroscopy (XAS) in combination with principal component analysis, target transformation, and linear combination revealed that in the untreated sediments Zn precipitated as the relatively soluble smithsonite (ZnCO₃) (67%) and adsorbed to hydrous iron oxides (15%) and hydrous manganese oxides (18%). Phosphate addition and calcination resulted in sparingly soluble phases, hopeite (Zn₃₍PO₄)₂.4H_{2 …}

Characterization Of Natural Organic Matter And Precursors To Trihalomethanes Using Spectral Flourescence Signatures, Krit Punburananon

Dissertations

Disinfection is an essential process to kill pathogens (i.e., disease causing organisms) in source water during the production of drinking water. Chlorine is most widely used disinfectant because it is effective, affordable, and also provides chlorine residual to ensure that the water is safe through the distribution system. Nonetheless, chlorine reacts with Natural Organic Matter (NOM) and forms potentially carcinogenic Disinfection By-products (DBPs). The major chlorination DBPs are dominantly Trihalomethanes (THMs). However, not all organic compounds are equally reactive to THMs formation.

NOM in water samples collected from the Delaware & Raritan Canal and its tributaries (Central New Jersey) was …

Evaluation Of Environmental Carrying Capacity And Application Of The Sustainability Target Method, Chatpet Yossapol

Dissertations

The environmental carrying capacity (CC) is defined as the capacity of the earth to absorb or tolerate potentially stressful burdens imparted at various scales and locations, that is, to accommodate the ecological stresses without showing permanent damage. The CC can be used as a reference dataset for Life Cycle Assessment (LCA) purposes and as a baseline for other environmental studies.

In this research, a set of impact-oriented U.S. CC is developed for both input- and output-related impacts. CC for eight common impact categories is evaluated: resource depletion, global warming, ozone depletion, acidification, eutrophication, photochemical ozone formation, human toxicity, and eco-toxicity. …

The Impact Of Abiotic And Biogenic Mn Oxide Coatings On Contaminant Mobility, Bioavailability, And Attenuation, Thipnakarin Boonfueng

Dissertations

Abiotic and biogenic manganese oxide coatings significantly impact the mobility and bioavailability of metals in soils and sediments. While sorption to discrete Mn oxides has been investigated in a number of studies, coatings have not received as much attention. Abiotic nanocrystalline (hydrous manganese oxide (HMO)) and crystalline Mn oxides (bimessite and pyrolusite) coated on montmorillonite were studied for formation, structure, stability, and surface properties. Coatings dominated the clay surface characteristics where the surface charge behaved similar to that of the discrete oxide and the local structure was consistent with the pure oxide phase. Furthermore, in sorption studies, Zn and Pb …

Heavy Metal Adsorption On Iron Oxide And Iron Oxide-Coated Silica : Macroscopic, Spectroscopic, And Modeling Studies, Ying Xu

Dissertations

To accurately model metal mobility and bioavailability in soils and sediments, systematic sorption studies are needed using representative and well-characterized minerals. Two important surfaces are iron oxide and silica, which are ubiquitous and associated with one another in the environment playing important roles in metal distribution. The objectives of this research are to develop models for predicting speciation and mobility of toxic trace metal ions in groundwater, soils, and sediments when competing ions are present. A model system for soils and sediments, iron oxide-coated silica, was synthesized; the degree of coatings was highly sensitive to the particle size of silica …

Development Of Adsorption Filtration Process For Virus Removal For Drinking Water Treatment, Vishal Vijay Gawarikar

Dissertations

Recent monitoring studies have indicated that many ground water (GW) sources would benefit from the development of effective technologies for removing viruses. Although reverse osmosis can achieve high log removal it is not economical. The main objective of this study is to test and validate a novel adsorption filtration (AF) technology for removing viruses from GW sources for drinking water production in New Jersey.

The convective diffusion of viruses to adsorbent particle surfaces in flow packed beds (FPB) enhances their removal efficiency if the adsorbent particle size can be decreased to about 100 microns. The development of effective virus removal …

Corrosion Studies On Alpha Tantalum And Beta Tantalum Coated Steel, Sung Min Maeng

Dissertations

Tantalum coating by sputtering, one form of physical vapor deposition (PVD), has been investigated as a replacement for chromium coatings on gun bores to protect them from erosion and corrosion due to its high ductility and high corrosion resistance in aggressive environments. When deposited as a film on steel substrates by sputtering, either α-Ta, β-Ta, or a mixture of both phases have been observed under varying deposition conditions. To evaluate corrosion behavior of Ta coatings, electrochemical impedance spectroscopy and potentiodynamic polarization were conducted as a function of coating thickness. The coating porosity was observed to decrease with increasing coating thickness …

Development And Application Of Fractionation Procedure For Drinking Water Organic Matters, Yong Pu

Dissertations

USEPA mandates a control of disinfection by-products (DBPs) in finished drinking water and recommends reduction of natural organic matters (NOM), DBP precursors, to achieve this regulatory goal. Studies relating NOM with DBP include fractionation of water samples, characterization of collected organic fractions, fractions' formation potential tests, and jar or similar tests to remove NOM. This study discussed a current resin fractionation procedure on principle, procedure, and its efficiency when applied to water samples of low NOM (< 5mgIL). The primary objective of this research is to develop a fractionation procedure intended for water of low NOM by carefully applying mass balance concept through each fraction's fractionation and a selection of stable ion exchange resins. A new protocol was presented with triple columns of XAD-8 adsorption resin, one column of AG-MP-50 cationic resin, and another column of WA 10 weak anionic resin in sequence. This protocol was experimented and confirmed for its efficiency (±10% loss of mass) with samples from Canal Road (CR) and Raritan Millstone (RM) surface water treatment plants (WTPs) in central New Jersey. The second objective of this study is to develop a statistical model with a potential of online delineation of organic fractions of NOM. The resulting model based on samples of Passaic Valley Water Commission (PVWC) WTP in northern New Jersey was applied to predict organic fractions of samples from CR and RM plants. Paired T-test (paired t ratio 1.15 < t critical 2.02) indicated a good correlation between the predicted and actual fraction concentration. Finally, samples of Middlesex Water Company (MWC) were fractionated and Trihalomethane formation potential tests (THMFP) on collected fraction showed hydrophilic matters possessed a higher potential to produce TTHM in finished water than hydrophobic matter. Jar tests indicated while coagulation was effective in removing hydrophobic matter, it may not be optimum for removal of hydrophilic matter.

This study developed an accurate fractionation procedure for low NOM waters. It provided a better understanding of organic matter transformation at different treatment …

Tide-Influenced Contaminant Transport In Coastal Aquifers, Yong Peng

Dissertations

Coastal aquifers are distinguished from other aquifers because of tidal effects which cause complicated groundwater flow and contaminant transport phenomena in regions immediately adjacent to the coast. This study is designed to address the significance of tidal influence on contaminant transport by focusing on one-dimensional homogeneous coastal aquifers.

This study formulates a conceptual model and corresponding flow and transport equations, analyzes coastal boundary conditions, solves numerically the transport equation, and uses experiments to verify the numerical results.

Results of numerical and experimental studies conclude that tides can have a significant impact on contaminant transport, especially when under unconfined conditions, subject …

Modeling Contaminant Transport And Fate And Subsequent Impacts On Ecosystems, Ming Fan

Dissertations

Assessing risks associated with the release of metals into the environment and managing remedial activities requires simulation tools that depict speciation and risk with accurate mechanistic models and well-defined transport parameters. Such tools need to address the following processes: (1) aqueous speciation, (2) distribution mechanisms, (3) transport, and (4) ecological risk. The primary objective of this research is to develop a simulation tool that accounts for these processes. Speciation in the aqueous phase can be assessed with geochemical equilibrium models, such as MINEQL+. Furthermore, metal distribution can be addressed mechanistically. Studies with Pb sorption to amorphous aluminum (HAG), iron (HFO), …

The Use Of A Water Quality Model To Evaluate The Impacts Of Combined Sewer Overflows On The Lower Hudson River, Wen-Pin Shu

Dissertations

CSO discharges have long been recognized as a significant source of water pollution. While many sources of water pollution have been controlled over the past 20 years, CSOs continue to be a main environmental concern in several areas, especially in old cities. In the past, most CSO research focused on the CSO control processes, including floatables and suspended solids removal. Few studies have been conducted in the area of the impacts of CSO discharge on the receiving water quality. To achieve this purpose, a powerful water-modeling tool, WASP 6.1, is utilized in this study. The Lower Hudson River is selected …

Remediation Of Chromium Contaminated Soils With Colloidal Silica, Netnapid Yossapol

Dissertations

The low-viscosity stabilizer, colloidal silica, is extensively used as a grouting material in the construction of grout curtains. It has low viscosity and is non-toxic, which is suitable for injection to stabilize fine-grained soils. It is also applied as a stabilizer in the in-situ treatment of hazardous waste. Once the colloidal silica solution is injected into contaminated soil, it moves through the pores inside the soil matrix, initiating the stabilization process. The viscosity of the colloidal silica mixture increases while it moves until solidifications. This process is called gelation and results in the creation of a gel barrier around contaminated …

Predicting Thermodynamic And Transport Parameters For Metal Contaminant Sorption To Hydrated Metal Oxides In Aquatic Systems, Paras Trivedi

Dissertations

Hydrated oxides such as HAO,'HFO, goethite, and BA40 are prevalent in soils and sediments as discrete particles or as coatings. These microporous oxides have large surface areas and high affmity for metal ions, and hence they act as both a sink and a source for anthropogenically released metal contaminants. To better understand risks posed by metals in the environment and to develop effective waste management programs, mechanistic models are needed to accurately predict their fate in soils and sediments.

To achieve this objective, sorption of metal ions Sr, Cd, Zn, Ni, and Ca to these oxides were studied with macroscopic …

Assessing The Economic Impact Of Aircraft Noise On Communities, Ithan B. Zimmer

Dissertations

The impact of aircraft noise on communities is complex and multi-dimensional. This matter cannot be resolved without careful analysis of a complex array of related problems and issues including the environment, the economy, and quality-of-life concerns of people living in proximity to airports or aircraft routes. The effects of community noise are widespread and varied. Impacts can include sleep and speech interference, activity interference, general annoyance, and property value decrease. In order to improve public policy and provide a foundation for additional research, it is imperative to establish the extent of a problem. Dollars are often the least common denominator …

Development And Application Of A Computer Simulation Tool For Ecological Risk Assessments, Haiyi Lu

Theses

In an effort to improve tools in ecological risk assessment (ERA), an ERA software tool was developed and applied. Based on a preliminary evaluation of existing ecorisk models, the relative deficiencies were identified and included the need for a user-friendly interface, an interactive database management system (DBMS), and a comprehensive evaluation of exposure pathways. In this research, Visual Basic (VB) 6.0 and Microsoft SQL server were selected for developing the Windows-based interface and local DBMS, respectively. For the exposure estimate, Yuma and Aberdeen Proving Grounds were identified as baseline ecosystems. Terrestrial and aquatic plant and animal receptor selection was based …

Optimization Of Nitrogen Removal In Sequencing Batch Reactor, Suppakit Poonyachat

Theses

Operating parameters for sequencing batch reactor have the influenceon each substrate concentration. Concentration profile changes as operationparameters are changed. The study was conducted to model the variationin effluent concentration from sequencing batch reactor. MLVSS and cycletime are the parameters that were varied. Concentration in Fill, React,and Settle Period were calculated by using kinetic equations.

The results can show that these parameters have effects on the concentrationprofile. The increase of MLVSS can lower the concentration of BOD andammonium concentration in React period. Increasing MLVSS can show thatmore substrate utilization and nitrification process occur more rapidly.Concentration of nitrate at the end of …

Measurement Of Microcarrier Weighted Floc Using The Environmental Electron Microscope, Viriya Vithayaveroj

Theses

Utilizing the concept of coagulation in conjunction with the sediment enhancement by microcarrier, the microcarrier process has been demonstrated in a laboratory investigation as an effective and economic operation in removing colloidal particles in an aquatic system. The microcarrier, an inert aluminum silicate particulate (Ottawa Sand) of 53 to 75 micrometers in diameter was used in this study. The interaction between the flocs and the microcarriers plays an important role in the mixing process. The principal objective of this study is to examine the structural interaction between the flocs and the microcarrier.

The study was designed into two stages, the …

Intelligent Process For Uasb Reactors, Sita Mohan

Theses

The Upflow Anaerobic Sludge Blanket (UASB) reactor is widely used for the anaerobic treatment of concentrated municipal / industrial wastewaters and sludges. Ability to handle high organic loading rates and cost effectiveness are often the most cited merits of the UASB process. Numerous mathematical models have been developed to describe the process and mechanistic phenomena in these systems. However, evidence in the literature of these models having been applied, either as control or diagnostic tools is limited. The use of intelligent process control mechanisms can greatly ease problems associated with operating these reactor systems.

The objective of this study is …

Characterization Of Steel Corrosion In An Aggressive Environment, Sung Min Maeng

Theses

As part of the Sustainable Green Manufacturing Program, the corrosion resistance of sputtered tantalum is being studied in order to evaluate it as a replacement coating for electroplated chrome. To accomplish this, studies were conducted to evaluate corrosion properties of the gun barrel steel by employing corrosion rate and bulk measurements including x-ray diffraction (XRD), scanning electron microscopy (SEM)/energy dispersive x-ray spectroscopy (EDX), and x-ray fluorescence (XRF), as well as synchrotron-based x-ray absorption spectroscopy (XAS).

Corrosion behavior of steel immersed in an aggressive environment of 37.8 % hydrochloric acid at room temperature was investigated as a function of time from …

Modeling Of A Permeable Reactive Barrier, Guatam C. Ijoor

Theses

The focus of the presentstudy was centered on the modeling analysis to support the Permeable Reactive Barrier (PRB) design. The flow model formulated to simulate the Permeable Reactive Barrier System integrated the available geologic, hydro geologic and geo-chemical data from numerous recent installations to simulate a subsurface ground water scenario.

Different generic cases that a PRB system would fall into were identified based on its utility and aquifer conditions and then employed to produce different model adaptations. The different simulation codes and interfaces were evaluated, and the most expedient of them was used to simulate the Model.

The simulations were …

Utilization Of Processed Fly Ash In Mortar, Walairat Bumrongjaroen

Dissertations

Grinding process is introduced to provide fine particles of coal fly ash that enhances the strength gain of cement mortars. It is discovered that grinding can make all the studied fly ashes more suitable for concrete use at higher replacement value than previously anticipated even when the effect of high carbon content is considered.

In this study, new mechanisms for strength gain of fly ash mortars are proposed. They are dispersion and nucleation, which are results from the presence of fly ash in the cement mortar. These effects are shown to enhance the hydration of cement. The pozzolanic action of …

Ultrasound To Decontaminate Organics In Dredged Sediments, Kanya Veerawat

Theses

In this research, it was attempted to decontaminate and separate dredged sediments contaminated with organic compounds by the application of ultrasound energy coupled with sub-atmospheric pressures. The decontamination and separation of contaminated sediments was achieved by integrated two processes. For Process 1, ultrasound energy was used to decontaminate the sandy fraction in dredged sediments, and sub-atmospheric pressure was used to separate and remove fines. For Process 2, ultrasound was again used to decontaminate fines with bulk fluid, and sub-atmospheric pressure was used to remove the contaminants with water. Process 1 was evaluated and found to have four variables contributing to …

Production Of Submicron Aerosols By Powder Depressurization, Amit Haryani

Theses

Disaggregation of dry powders in shear flow has limitations in producing submicron particles. This study explores a new method for the production of submicron particles by the depressurization of powder aerosols. The depressurization mechanism is based on the rapid depressurization of the aggregated powder through a specially designed nozzle. As the pressure suddenly decreases from very high values inside the aggregates (800 psi) to ambient at the surface of such aggregates, disaggregation takes place due to the force exerted by the gas escaping through their pore structure.

he effect of various process parameters, namely: nozzle diameter, pressure and pretreatment with …

Analysis And Modeling Of Ultrasound To Decontaminate Heavy Metals In Dredged Sediments, Ruvini Perera

Theses

Sediments contaminated with heavy metals due to past disposal practices threatens the environment and requires remediation. This research is an attempt to develop a technology to decontaminate heavy metals in the dredged sediments with an integrated set of processes using ultrasound. Acoustic cavitation caused by ultrasound energy can be used to remove chromium from the sediments. Two coupled processes were used to treat both coarse (Process#1) and fine (Process#2) fractions of the sediments. Full factorial experimental designs were carried out to evaluate the treatment technique and to statistically model and optimize the processes. The model for Process#1 had four contributing …

Coagulation And Disinfection By-Products Formation Potential Of Dissolved Organic Matter Fractions, Neeraj S. Pipada

Theses

Both the proposed United States Environmental Protection Agency (USEPA) Disinfectants- Disinfection By-Products and Enhanced Surface Water Treatment rules have provisions for minimizing the formation of undesirable precursors of disinfection by-products (DBPs) in drinking water Natural Organic Matter (NOM) contains many of the precursors to the DBPs formed following disinfection of drinking water. DAX-8 resin procedures were used to isolate and fractionate NOM into six dissolved organic matter (DOM) fractions; Hydrophobic acid (FA), base (FB), neutral (FN), and hydrophilic acid (PA), base (PB) and neutral (PN). Aluminum sulfate (alum) jar coagulation tests were performed to determine the optimum coagulation ranges of …