Environmental Engineering Commons^™

Dolomite Dissolution And Contaminant Adsorption In The Presence Of Edta In Different Ionic Strength Solutions, Alexis Vento

FIU Electronic Theses and Dissertations

The long-term storage and disposal of radioactive waste is considered a challenging and costly endeavor to the U.S. Department of Energy (DOE) tasked with the safe management of radioactive wastes. The search for effective ways to manage radioactive waste has increasingly grown due to the large inventory of legacy transuranic wastes (TRU) from defense programs in the 1940s and nuclear power plants. The U.S. Department of Energy’s (DOE) Waste Isolation Pilot Plant (WIPP) is a unique repository for the permanent disposition of Transuranic Waste (TRU). The WIPP, located near Carlsbad in New Mexico, is sited ~655 m below the surface …

Low-Cost And Reliable Integrated Hardware And Software Framework For Remotely Operated Water Release From Storage Units, Vivek Verma

FIU Electronic Theses and Dissertations

The main contribution of this research is towards the broader area of water management that can be used for multiple purposes. For instance, floods can be mitigated using a novel approach based on the integrated dynamic management of water storage units such as reservoirs, wetlands, and ponds. This approach will enable adaptive water release from storage units hours or days ahead of rainfall events, thereby maximizing storage capacity and minimizing flooding.

This approach can be implemented by retrofitting water storage units using siphon hydraulic systems and are remotely controlled in an integrated manner using the decision support system. To make …

Unit Energy Consumption, Production, And Cost Of Innovative Treatment Systems Of Different Wastewater Streams, Jinze Li

FIU Electronic Theses and Dissertations

Innovative technologies such as micro-sieving, Anammox, and up-flow anaerobic sludge blanket (UASB) hold the key in the sustainable design of Water Resource Recovery Facility (WRRF). In the past, assessment metrics on the effectiveness and economic feasibility of these technologies have not been systematically investigated. According to the twelve design principles of Sustainable Environmental Engineering, Unit energy and cost metrics could provide universal benchmarks in the design of WRRF. Therefore, the objectives of this study are to design innovative WRRF systems to achieve energy positive. These WRRFs were modeled by developing an Excel model to estimate the unit energy metrics. Database …

Evaluating The Sustainability Of Infrastructure Projects During Front-End Planning Phase, Valentina Ferrer Rivero

FIU Electronic Theses and Dissertations

Front-End Planning (FEP) for Sustainable Infrastructure (SI) projects is a promising process that can support addressing multiple challenges in infrastructure projects (i.e. cost overruns, schedule delays, and poor sustainability). This study aims to investigate synergies between sustainability and FEP tools for infrastructures through stakeholders’ surveys, multiple case-study analyses, and a Problem-Based Learning (PBL) activity with students. The PBL activity enhanced students’ knowledge on FEP for SI projects, and, together with other analyses, it helped in defining three different frameworks that correlate sustainability and FEP tools for infrastructure projects. The findings of this thesis contribute to the infrastructure, engineering and construction …

A Holistic Process Model For Evaluating Alternative Biosolids Technologies And Operational Methodologies To Improve Performance And Sustainable Decision-Making At High Purity Oxygen Wastewater Treatment Plants, Manuel E. Moncholi

FIU Electronic Theses and Dissertations

In the span of the last decade the regulatory, public and commercial sentiments in Florida towards wastewater biological sludges, termed biosolids, have resulted in more restrictive land application rules, public cynicism about quality and agricultural benefits, and defensive posturing and marketing to appease public opinion. To determine and recommend the most cost effective and sustainable combination of biosolids treatment technologies to achieve Class B biosolids at the MDWASD facilities, the author created a holistic process model that is novel in the realm of wastewater treatment.

The research methodology focused on the analyses of historical data, analyses of pilot-testing data, development …

Design Of Low Impact Development And Green Infrastructure At Flood Prone Areas In The City Of Miami Beach, Florida, Usa, Noura Alsarawi

FIU Electronic Theses and Dissertations

This thesis investigates the effectiveness of Low Impact Development Infrastructure (LIDI) and Green Infrastructure (GI) in reducing flooding resulting from heavy rainfall events and sea-level rise, and in improving stormwater quality in the City of Miami Beach (CMB). InfoSWMM was used to simulate the 5, 10, and 100-year, 24-hour storm events, total suspended solids (TSS), biochemical oxygen demand (BOD), and chemical oxygen demand (COD) loadings, and in evaluating the potential of selected LIDI and GI solutions in North Shore neighborhood.

Post-development results revealed a decrease of 48%, 46%, and 39% in runoff, a decrease of 57%, 60%, and 62% in …

The Effects Of Frequent Atmospheric Events And Hydrologic Infrastructure On Flow Characterization In Tims Branch And Its Major Tributary, Sc, Mohammed Albassam

FIU Electronic Theses and Dissertations

Hydrological models are powerful tools used to predict water systems behavior such as flow and water level characteristics for rivers and streams. In this research, a fully dynamic 1-D model was developed using the MIKE 11 model for a specific stream called A-014, this stream is in the Savannah River Site (SRS), SC.

A field study was conducted in order to collect data needed as inputs for the model development. Data like water velocity and cross-section measurement played a major role in understanding the behavior of the A-014 and the validation of our model.

Results showed a correlation capable to …

The Stability Of Uranium-Bearing Precipitates Created As A Result Of Ammonia Gas Injections In The Hanford Site Vadose Zone, Alberto Javier Abarca Betancourt

FIU Electronic Theses and Dissertations

Uranium (U) is a crucial contaminant in the Hanford Site. Remediation techniques to prevent contaminant migration of U located in the soils to other important water resources such as the Columbia River are of paramount importance. Given the location of the contaminant in the deep vadose zone, sequestration of U caused by ammonia (NH₃) gas injections appears to be a feasible method to decrease U mobility in the contaminated subsurface via pH manipulation, ultimately converting aqueous U mobile phases to lower solubility precipitates that are stable in the natural environment. This study evaluated the stability of those U-bearing …

Uranium Sequestration By Ph Manipulation Using Nh3 Injection In The Vadose Zone Of Hanford Site 200 Area, Claudia Cardona

FIU Electronic Theses and Dissertations

Past nuclear weapon production activities have left a significant legacy of uranium (U) contamination in the vadose zone (VZ) of the Department of Energy (DOE) Hanford Site. This U is a source of groundwater (GW) contamination. There is a concern that elevated U concentration would slowly infiltrate through the VZ, reach the GW water table, and then end up in nearby rivers and lakes. Remediation of U-contaminated low moisture content soil is a challenging task considering the VZ depth, where contamination is found between 70 and 100 m below the ground surface, and the formation of highly soluble and stable …

Capture And Densification Of Floating Hydrophobic Liquids By Natural Granular Materials, Daria Boglaienko

FIU Electronic Theses and Dissertations

Densification and submergence of floating crude oil is proposed as a novel oil spills treatment method. Surface application of dry granular materials (e.g., quartz sand, limestone) on top of a floating oil layer increases the density of the floating oil phase/granule mixture and leads to formation of relatively large and stable aggregates with significant amounts of captured oil. The aggregates separate from the floating hydrophobic phase and settle by gravity. Implementation of this method will reduce the impact radius of a spill and its mobility, preventing direct contamination of beaches, coastal flora and fauna.

The major objective of this research …

Water Quality Modelling Using Multivariate Statistical Analysis And Remote Sensing In South Florida, Mohammad Hajigholizadeh

FIU Electronic Theses and Dissertations

The overall objective of this dissertation research is to understand the spatiotemporal dynamics of water quality parameters in different water bodies of South Florida. Two major approaches (multivariate statistical techniques and remote sensing) were used in this study. Multivariate statistical techniques include cluster analysis (CA), principal component analysis (PCA), factor analysis (FA), discriminant analysis (DA), absolute principal component score-multiple linear regression (APCS-MLR) and PMF receptor modeling techniques were used to assess the water quality and identify and quantify the potential pollution sources affecting the water quality of three major rivers of South Florida. For this purpose, a 15-year (2000–2014) data …

Hydrogeochemical Modeling Of Saltwater Intrusion And Water Supply Augmentation In South Florida, Yonas T. Habtemichael

FIU Electronic Theses and Dissertations

The Biscayne Aquifer is a primary source of water supply in Southeast Florida. As a coastal aquifer, it is threatened by saltwater intrusion (SWI) when the natural groundwater flow is altered by over-pumping of groundwater. SWI is detrimental to the quality of fresh groundwater sources, making the water unfit for drinking due to mixing and reactions with aquifer minerals. Increasing water demand and complex environmental issues thus force water utilities in South Florida to sustainably manage saltwater intrusion and develop alternative water supplies (e.g., aquifer storage and recovery, ASR).

The objectives of this study were to develop and use calibrated …

A Study On The Dissolution Of Autunite Minerals By Facultative Bacteria In Bicarbonate Media, Sandra C. Herrera Landaez

FIU Electronic Theses and Dissertations

Uranium (U) is a key contaminant at the Hanford site. The formation of uranyl-phosphate bearing minerals such as autunite as a result of tripoliphosphate injections has been used as a U immobilization strategy. Bacteria are known as key factors governing the fate and transport of soil contaminants. This research evaluated the interaction of facultative bacteria Shewanella Oneidensis MR-1 with autunite mineral in bicarbonate-amended media solutions. The concentration of several elements such as U, calcium (Ca) and phosphorous (P) released as a result of autunite mineral biodissolution were determined as a function of time; changes in cell density and protein assay …

On The Role Of The Pore Water Chemistry Of Deficient Post-Tension Grout To Promote Steel Corrosion, Samanbar Permeh

FIU Electronic Theses and Dissertations

Corrosion failure of post-tension tendons with pre-packaged thixotropic grout was documented in Florida Bridges in less than 10 years of service. Analysis of deficient grout in Florida post-tensioned (PT) bridges where severe corrosion developed indicated enhanced sulfate ion concentration, high pore water pH, enhanced moisture and low chloride content. The corrosion wasn’t consistent with the conventional causes of steel corrosion such as bleed water accumulation in grout void spaces, chloride contamination and pore water carbonation. Corrosion development was associated with deficient grout with enhanced sulfate levels. However, limited information is available on the corrosion behavior of PT strand in grout …

A Multi-Criteria Gis-Based Route Selection Tool For Hazardous Material Transport: Consideration Of Environmental Consequence, Traffic Congestions And Costs, Bahareh Inanloo

FIU Electronic Theses and Dissertations

Hazardous materials are substances that, if not regulated, can pose a threat to human populations and their environmental health, safety or property when transported in commerce. About 1.5 million tons of hazardous material shipments are transported by truck in the US annually, with a steady increase of approximately 5% per year.

The objective of this study was to develop a routing tool for hazardous material transport in order to facilitate reduced environmental impacts and less transportation difficulties, yet would also find paths that were still compelling for the shipping carriers as a matter of trucking cost. The study started with …

Label-Free Surface-Enhanced Raman Spectroscopy-Linked Immunosensor Assay (Slisa) For Environmental Surveillance, Vinay Bhardwaj

FIU Electronic Theses and Dissertations

The contamination of the environment, accidental or intentional, in particular with chemical toxins such as industrial chemicals and chemical warfare agents has increased public fear. There is a critical requirement for the continuous detection of toxins present at very low levels in the environment. Indeed, some ultra-sensitive analytical techniques already exist, for example chromatography and mass spectroscopy, which are approved by the US Environmental Protection Agency for the detection of toxins. However, these techniques are limited to the detection of known toxins. Cellular expression of genomic and proteomic biomarkers in response to toxins allows monitoring of known as well as …

Emergence And Fate Of Siloxanes In Waste Streams: Release Mechanisms, Partitioning And Persistence In Three Environmental Compartments, Sharon C. Surita

FIU Electronic Theses and Dissertations

Siloxanes are widely used in personal care and industrial products due to their low surface tension, thermal stability, antimicrobial and hydrophobic properties, among other characteristics. Volatile methyl siloxanes (VMS) have been detected both in landfill gas and biogas from anaerobic digesters at wastewater treatment plants. As a result, they are released to gas phase during waste decomposition and wastewater treatment. During transformation processes of digester or landfill gas to energy, siloxanes are converted to silicon oxides, leaving abrasive deposits on engine components. These deposits cause increased maintenance costs and in some cases complete engine overhauls become necessary.

The objectives of …

Numerical Modeling Of The Effects Of Hydrologic Conditions And Sediment Transport On Geomorphic Patterns In Wetlands, Mehrnoosh Mahmoudi

FIU Electronic Theses and Dissertations

This dissertation focused on developing a numerical model of spatial and temporal changes in bed morphology of ridge and slough features in wetlands with respect to hydrology and sediment transport when a sudden change in hydrologic condition occurs. The specific objectives of this research were: (1) developing a two-dimensional hydrology model to simulate the spatial distribution of flow depth and velocity over time when a pulsed flow condition is applied, (2) developing a process-based numerical model of sediment transport coupled with flow depth and velocity in wetland ecosystems, and (3) use the developed model to explore how sediment transport may …

Development Of A Methodology That Couples Satellite Remote Sensing Measurements To Spatial-Temporal Distribution Of Soil Moisture In The Vadose Zone Of The Everglades National Park, Luis G. Perez

FIU Electronic Theses and Dissertations

Spatial-temporal distribution of soil moisture in the vadose zone is an important aspect of the hydrological cycle that plays a fundamental role in water resources management, including modeling of water flow and mass transport. The vadose zone is a critical transfer and storage compartment, which controls the partitioning of energy and mass linked to surface runoff, evapotranspiration and infiltration. This dissertation focuses on integrating hydraulic characterization methods with remote sensing technologies to estimate the soil moisture distribution by modeling the spatial coverage of soil moisture in the horizontal and vertical dimensions with high temporal resolution.

The methodology consists of using …

Development Of An Enhanced Hydro-Geochemical Model To Address Mercury-Speciation Fate And Transport In Aquatic Environments, Nantaporn Noosai

FIU Electronic Theses and Dissertations

An awareness of mercury (Hg) contamination in various aquatic environments around the world has increased over the past decade, mostly due to its ability to concentrate in the biota. Because the presence and distribution of Hg in aquatic systems depend on many factors (e.g., pe, pH, salinity, temperature, organic and inorganic ligands, sorbents, etc.), it is crucial to understand its fate and transport in the presence of complexing constituents and natural sorbents, under those different factors. An improved understanding of the subject will support the selection of monitoring, remediation, and restoration technologies.

The coupling of equilibrium chemical reactions with transport …

Xpswmm Analysis Of The Ornl Stormwater Collection System Up To Outfall 211, Heidi Belle Henderson

FIU Electronic Theses and Dissertations

The Oak Ridge National Laboratory, Tennessee, was the site for a number of US Government projects during the 1940s and 1950s including the development of thermonuclear weapons. Chemical processes conducted at the site as part of these projects resulted in contamination of certain building areas at the ORNL. The purpose of this study is to develop a hydraulic-hydrologic computer model via XPSWMM to determine surface water flow rates and water stages within the drainage system during rainfall events and introduce a conservative contaminant into the system to trace peak concentrations of contaminants.

The model was calibrated by simulating actual rainfall …

Climate, Land Use And Hydrologic Sensitivities Of Stormwater Quantity And Quality In Complex Coastal Urban Watersheds, Shams Al-Amin

FIU Electronic Theses and Dissertations

The study analyzed hydro-climatic and land use sensitivities of stormwater runoff and quality in the complex coastal urban watershed of Miami River Basin, Florida by developing a Storm Water Management Model (EPA SWMM 5). Regression-based empirical models were also developed to explain stream water quality in relation to internal (land uses and hydrology) and external (upstream contribution, seawater) sources and drivers in six highly urbanized canal basins of Southeast Florida. Stormwater runoff and quality were most sensitive to rainfall, imperviousness, and conversion of open lands/parks to residential, commercial and industrial areas. In-stream dissolved oxygen and total phosphorus in the watersheds …

Integration Of A Sedimentation Module To A Hydrologic Model And Its Application To A Mercury Tmdl Analysis, Lilian Marrero

FIU Electronic Theses and Dissertations

This research is part of continued efforts to correlate the hydrology of East Fork Poplar Creek (EFPC) and Bear Creek (BC) with the long term distribution of mercury within the overland, subsurface, and river sub-domains. The main objective of this study was to add a sedimentation module (ECO Lab) capable of simulating the reactive transport mercury exchange mechanisms within sediments and porewater throughout the watershed. The enhanced model was then applied to a Total Maximum Daily Load (TMDL) mercury analysis for EFPC. That application used historical precipitation, groundwater levels, river discharges, and mercury concentrations data that were retrieved from government …

Mercury Interactions With Suspended Solids At The Upper East Fork Poplar Creek, Oak Ridge, Tennessee, Elsa Cabrejo

FIU Electronic Theses and Dissertations

A water quality model was developed to analyze the impact of hydrological events on mercury contamination of the Upper East Fork Poplar Creek, Tennessee. The model simulates surface and subsurface hydrology and transport (MIKE SHE and MIKE 11) and it is coupled with the reactive transport of sediments and mercury (ECOLAB). The model was used to simulate the distribution of mercury contamination in the water and sediments as a function of daily hydrological events.

Results from the model show a high correlation between suspended solids and mercury in the water due to the affinity of mercury with suspended organics. The …

A Preliminary Characterization Of Mercury Uptake By The Sulfate-Reducing Bacteria Desulfovibrio Desulfuricans, Amaury Pedro Betancourt Iii

FIU Electronic Theses and Dissertations

The focus of this research is to determine if a relationship exists between the stability constant and the initial uptake rate of a mercury species by bacteria. Cultures of the sulfate-reducing bacteria (SRB) strain Desulfovibrio desulfuricans G20 were washed with a bicarbonate buffer solution containing either lactate and sulfate or pyruvate and fumarate. The washed cell solutions were then spiked with either mercury bound to natural organic matter (Hg-NOM) or neutral mercury chloride (HgCl₂), followed by sampling over time to provide kinetic data. Despite the significantly different stability constants for Hg-NOM and HgCl₂, the calculated initial …

An Integrated Flow And Transport Model To Study The Impact Of Mercury Remediation Strategies For East Fork Poplar Creek Watershed, Oak Ridge, Tennessee, Stephanie Long

FIU Electronic Theses and Dissertations

An integrated flow and transport model using MIKE SHE/MIKE 11 software was developed to predict the flow and transport of mercury, Hg(II), under varying environmental conditions. The model analyzed the impact of remediation scenarios within the East Fork Poplar Creek watershed of the Oak Ridge Reservation with respect to downstream concentration of mercury. The numerical simulations included the entire hydrological cycle: flow in rivers, overland flow, groundwater flow in the saturated and unsaturated zones, and evapotranspiration and precipitation time series. Stochastic parameters and hydrologic conditions over a five year period of historical hydrological data were used to analyze the hydrological …

Chlorine Contribution To Quantitative Structure And Activity Relationship Models Of Disinfection By-Products' Quantum Chemical Descriptors And Toxicities, Fang Wang

FIU Electronic Theses and Dissertations

Quantitative Structure-Activity Relationship (QSAR) has been applied extensively in predicting toxicity of Disinfection By-Products (DBPs) in drinking water. Among many toxicological properties, acute and chronic toxicities of DBPs have been widely used in health risk assessment of DBPs. These toxicities are correlated with molecular properties, which are usually correlated with molecular descriptors. The primary goals of this thesis are: 1) to investigate the effects of molecular descriptors (e.g., chlorine number) on molecular properties such as energy of the lowest unoccupied molecular orbital (ELUMO) via QSAR modelling and analysis; 2) to validate the models by using internal and external cross-validation techniques; …

Long Term Monitoring Of Trichloroethylene Degradation Indicator Parameters Using Sensors, Ravi Krishna Prasanth Gudavalli

FIU Electronic Theses and Dissertations

Past operations at Savannah River Site (SRS) have resulted in significant amount of groundwater contamination with trichloroethylene. Natural attenuation of chlorinated solvents via reductive dechlorination is one of the most important processes occurring at SRS, which requires monitoring. Many traditional monitoring techniques require manual sampling and analysis at an onsite or offsite laboratory, which is costly and time consuming. Therefore the need for a system, which can accurately and cost-effectively conduct real-time analysis using automated sensors, is important. There are several characteristics of groundwater like pH, ORP, conductivity and chloride that may be monitored to assess the TCE degradation. To …

Improving Performance Of A Permeable Reactive Barrier In The Degradation Of Trichloroethylene Using Ultrasound, Jonathan A. Bulley

FIU Electronic Theses and Dissertations

The impact of ultrasound on improving the performance of a granular iron Permeable Reactive Barrier (PRB) in the degradation of Trichloroethylene (TCE) was evaluated.

Two treatment columns made of clear Plexiglas with a height of 1ft and a diameter of 2 inches and filled with granular iron were used. One was fitted with 25Khz ultrasound probes. A solution of TCE was run through at constant flow rate. Samples obtained from the column at different residence times before and after sonication were analyzed for concentrations of TCE and used to generate concentration profiles to obtain rate constants, which were compared.

An …

Process Inventory And Pollution Prevention Overview For The Citrus Industry, Carmen Alicia Aponte

FIU Electronic Theses and Dissertations

Florida citrus represents approximately 70 percent of the industry production in the United States; therefore, any associated agricultural and industrial contamination is of concern and a focus of attention. The use of synthetic organic chemicals has become a farmer's necessity in order to supply consumers with high quality products, free of pest damage. However, industrial citrus wastes and chemical residual levels worry not only government agencies but also consumers since they indicate a serious habitat risk.

This study assesses citrus industrial processes and the paths that chemical substances follow from the time the citrus seed is planted until consumers get …