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Full-Text Articles in Environmental Engineering

Wind Flow Characteristics Of Multi-Vortex Tornadoes And Their Wind Effects On Residential Houses, Yi Zhao Aug 2022

Wind Flow Characteristics Of Multi-Vortex Tornadoes And Their Wind Effects On Residential Houses, Yi Zhao

Doctoral Dissertations

"Tornadoes strike the USA very frequently, with an average of 1200 reports per year, and the average annual tornado-induced property loss has reached $10B. The devastation from recent tornadoes have prompted a renewed interest in better understanding tornado dynamics, their interactions with the built environment, and the performance of civil structures during tornadoes. In the past, the wind effects caused by single-vortex tornadoes have been widely studied, while the multi-vortex tornadoes were rarely considered. In fact, many previous deadly, costly tornadoes involved multiple vortices. Therefore, it is important to understand the wind flow characteristics of multi-vortex tornadoes in order to …


Efficiency Of Bank Filtration In The Removal Of Cyanotoxins Under Different Levels Of Nutrients, Luke Walkenhorst Jul 2022

Efficiency Of Bank Filtration In The Removal Of Cyanotoxins Under Different Levels Of Nutrients, Luke Walkenhorst

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Harmful Algal Blooms (HABs) are an increasing concern not only in Nebraska, but across the world. Increasing global temperatures in conjunction with overuse of synthetic fertilizers are leading causes to the increasing frequency and concern of HABs. In the present work, the effectiveness of simulated bank filtration (BF), as an economical water treatment option, to remove cyanotoxins under different levels of nutrients (nitrates and phosphates) was investigated. Vertical flow-through columns pre-acclimated with two levels of nutrients (e.g., nitrate and phosphate—10 vs. 50 mg/L) were exposed to two different levels of cyanotoxins (10 vs. 75 μg/L). Results from the study confirmed …


Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot Jul 2022

Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot

LSU Master's Theses

Coastal wetlands provide an abundance of ecosystem services that benefit society, such as essential habitat for commercial species, storm protection, nutrient cycling, and carbon storage. Louisiana faces rapid rates of relative sea level rise (natural subsidence and eustatic sea levels) that threaten wetland survival, which are amplified by a reduction of riverine sediment input. An important determining factor of marsh survival is the formation of wetland platform elevation, known as vertical accretion, which is determined by several processes including sediment deposition & erosion, below ground biomass (BGB) productivity, decomposition of organic matter, shallow & deep subsidence, and soil compaction. Feldspar …


Investigating The Proper Use Of Litani River Basin Based On Water Quality, Mohamad Diab, Mohamad Soliman Jun 2022

Investigating The Proper Use Of Litani River Basin Based On Water Quality, Mohamad Diab, Mohamad Soliman

BAU Journal - Science and Technology

Litani River Basin (LRB) with a 170km length and annual river flow of 750 MCM is considered the most important water resource in Lebanon. Unfortunately, the river is facing water contamination as a result of human practices. Water Quality assessments was performed in the Litani River Basin using a combination of Principal Component Analysis method (PCA) and Water Quality Index method (WQI). Results revealed the improvement of the water quality significantly after passing lake Qaraoun. Moreover, according to WQI, Lower LRB water is ranked ‘’Good’’ for irrigation and ‘’BAD’ for drinking purposes. Microbial contamination is found to be the key …


Mechanical And Durability Properties Of Geopolymer Concrete – A Review, Lelian Elkhatib, Fadi Al Aridi, Adel Elkordi, Jamal Khatib Jun 2022

Mechanical And Durability Properties Of Geopolymer Concrete – A Review, Lelian Elkhatib, Fadi Al Aridi, Adel Elkordi, Jamal Khatib

BAU Journal - Science and Technology

Owing to the ongoing increase in human population, there is a need for more construction projects including residential buildings and other amenities. Concrete is by far the dominant material used in construction and cement is a main ingredient. Cement manufacture is an energy intensive process and emit large amounts of carbon dioxide into the atmosphere. A reduction in the amount of cement used in construction is greatly beneficial. The use of geopolymer or alkali activated materials can serve this purpose as it attempts to totally replace cement in concrete. Geopolymers are materials that consist mainly of silica and alumina materials …


Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias Jun 2022

Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias

USF Tampa Graduate Theses and Dissertations

Electrocoagulation (EC) is a sustainable water treatment process involving the generation of coagulants on-site through the application of a voltage on metal (usually aluminum or iron alloys). The factors that impact EC system performance have been well researched, however further research is needed on the factors that impact anodic dissolution of aluminum electrodes, especially when the technology is transferred to full-scale applications. Electrode fouling is one of the factors that can impact dissolution of the anode during EC due to the formation of a protective oxide/hydroxide layer on the electrode surface. Previous studies have addressed electrode fouling by reversing polarity, …


Characterizing The Chemical And Microbial Fingerprint Of Unsheltered Homelessness In An Urban Watershed, Daniel Gerrity, Katerina Papp, Eric Dickenson, Meena Ejjada, Erica Marti, Oscar Quinones, Mayra Sarria, Kyle Thompson, Rebecca A. Trenholm Jun 2022

Characterizing The Chemical And Microbial Fingerprint Of Unsheltered Homelessness In An Urban Watershed, Daniel Gerrity, Katerina Papp, Eric Dickenson, Meena Ejjada, Erica Marti, Oscar Quinones, Mayra Sarria, Kyle Thompson, Rebecca A. Trenholm

Civil and Environmental Engineering and Construction Faculty Research

Unsheltered homelessness is rapidly becoming a critical issue in many cities worldwide. The worsening situation not only highlights the socioeconomic plight, but it also raises awareness of ancillary issues such as the potential implications for urban water quality. The objective of this study was to simultaneously leverage diverse source tracking tools to develop a chemical and microbial fingerprint describing the relative contribution of direct human inputs into Las Vegas' tributary washes. By evaluating a wide range of urban water matrices using general water quality parameters, fecal indicator bacteria (FIB), human-associated microbial markers [e.g., HF183, crAssphage, and pepper mild mottle virus …


Using Metal-Organic Frameworks (Mof) To Reduce The Carbon Footprint Of Concrete, Mona Ibrahim El-Hallak Jun 2022

Using Metal-Organic Frameworks (Mof) To Reduce The Carbon Footprint Of Concrete, Mona Ibrahim El-Hallak

Theses

The production of concrete by the construction industry has a massive impact on the environment. The process of manufacturing its main component, cement, releases a considerable amount of anthropogenic carbon dioxide. This thesis is concerned with the production of sustainable and eco-friendly concrete that integrates metal-organic frameworks (MOF) to capture and offset the CO2 emissions emitted during the production of cement. The main objective is to synthesize a MOF capable of capturing CO2 in concrete through accelerated carbonation curing and to assess its impact on concrete performance. Different parameters were examined, including the MOF content, initial curing duration, …


Numerical Modelling Of Externally-Bonded Fiber Reinforced Polymer Shear-Strengthened Reinforced Concrete Beams Subjected To Fatigue Loading, Nagwa Ibrahim Fares Jun 2022

Numerical Modelling Of Externally-Bonded Fiber Reinforced Polymer Shear-Strengthened Reinforced Concrete Beams Subjected To Fatigue Loading, Nagwa Ibrahim Fares

Theses

An extensive number of existing structures persistently exposed to fatigue loading such as bridges, offshore structures, pavements, and highways, are in urgent need of repairing and strengthening. This may be attributed to the continuous increase in the load requirements, change of the structure’s function, and meeting current load standards. Among the potential methods of rehabilitation and strengthening of existing reinforced concrete structures, the externally bonding fiber reinforced polymers (FRP) composites are gaining massive popularity and becoming a viable and cost-effective method. Shear failure of reinforced concrete (RC) beams is known to be brittle, which occurs without prior sufficient warnings; therefore, …


Effects Of Experimental Scale On The Adsorption Of Two Pharmaceutical Drugs Detected In Municipal Wastewater Effluent, Michael Moore Jun 2022

Effects Of Experimental Scale On The Adsorption Of Two Pharmaceutical Drugs Detected In Municipal Wastewater Effluent, Michael Moore

Master's Theses

Pharmaceutical drugs are being produced and consumed in increasing quantities every year and are poorly treated by conventional wastewater treatment processes, leading to increasing detection of such compounds in surface water, groundwater, and municipal drinking water. Soil aquifer treatment (SAT) is a promising method for treating these emerging compounds through combined adsorption and degradation of target compounds in soil. This thesis examines the consistency of results from typical studies like adsorption isotherms and soil columns utilized in analysis of SAT performance, across varying experimental scales. The adsorption behavior of two pharmaceuticals was investigated as a function of experimental scale and …


Hydrodynamic Limitations To Mangrove Seedling Retention In Subtropical Estuaries, Kelly M. Kibler, Christian Pilato, Linda Walters, Melinda Donnelly, Jyotismita Taye May 2022

Hydrodynamic Limitations To Mangrove Seedling Retention In Subtropical Estuaries, Kelly M. Kibler, Christian Pilato, Linda Walters, Melinda Donnelly, Jyotismita Taye

Flow-biota Interaction and Natural Infrastructure Design

Mangrove forest sustainability hinges upon propagule recruitment and seedling retention. This study evaluates biophysical limitations to mangrove seedling persistence by measuring anchoring force of two mangrove species (Rhizophora mangle and Avicennia germinans). Anchoring force was measured in 362 seedlings via lateral pull-tests administered in mangrove forests of two subtropical estuaries and in laboratory-based experiments. Removal mechanism varied with seedling age: newly-established seedlings failed due to root pull-out while seedlings older than 3 months failed by root breakage. Anchoring force of R. mangle seedlings was consistently and significantly greater than A. germinans (GLM: p = 0.002), however force to …


The Living Breakwaters Pdr Efforts: Conceptual Scheduling, Calvin O. Walters Jr. May 2022

The Living Breakwaters Pdr Efforts: Conceptual Scheduling, Calvin O. Walters Jr.

Publications and Research

On October 29, 2012, Superstorm Sandy caused nearly $19 billion in damages in New York City including 69,000 residential units across the five boroughs. This disaster precipitated a post-disaster-rebuilding (PDR) project including roughly $4.2 billion in a Community Development Block Grant allocated towards PDR projects. A portion of the grant was used to construct a living breakwater in Tottenville, Staten Island, consisting of a resiliency approach to risk reduction through erosion prevention, wave energy attenuation, and enhancement of ecosystems and social resiliency to improve resistance to storms for the community of Tottenville. The ridges of each breakwater are designed with …


Sustainability In Construction Practices As Emphasis On Environmental Investing In Esg Model Grows, Maddie Heal May 2022

Sustainability In Construction Practices As Emphasis On Environmental Investing In Esg Model Grows, Maddie Heal

Management Undergraduate Honors Theses

The purpose of this research is to emphasize the importance of growing investment on environmental initiatives in business ESG models in regard to sustainable practices in construction. The ESG acronym is known as the environmental, social, and governance efforts that businesses strive to incorporate in their models to increase the responsibility of operations.

Investors continue to seek out responsible businesses when choosing which ventures to pursue. The analysis of the current construction crisis, current investments in the right direction of Eco-friendly design regarding construction, and the threats and benefits incentivizing those investments elucidates the need to emphasize socially responsible investment …


Port Infrastructure Resilience Through Combined Wind-Surge Demand Characterization, Kaley Callaway May 2022

Port Infrastructure Resilience Through Combined Wind-Surge Demand Characterization, Kaley Callaway

Graduate Theses and Dissertations

The United States economy is reliant on maritime transportation for 70% of imports and exports. Structures that are integral to the operation of ports, such as cranes, are jeopardized when tropical storms approach land. While wind is the only environmental load used to design dockside container cranes, storm surge often accompanies severe wind events and can create large structural loads. This study focuses on determining coupled storm-surge demands and the effect of waves on dockside container cranes. A damage index prediction tool that considers both maximum wind speed and storm surge height is developed and applied to historical hurricane data …


Community Transportation Needs And Willingness To Use Shared Micromobility: A Case Study Of Fort Smith, Arkansas, Anthony Michael Kammerer May 2022

Community Transportation Needs And Willingness To Use Shared Micromobility: A Case Study Of Fort Smith, Arkansas, Anthony Michael Kammerer

Civil Engineering Undergraduate Honors Theses

Shared micromobility is utilized in “targeted service areas with the usage generally intended for short trips such as "first- and last-mile" connections to complete trips made via other modes, including transit” (Price et al., 2021). In the United States, this practice has especially taken off with the implementation of sharing-based systems. This is evidenced by ridership numbers in the United States growing from 84 million riders nationwide in 2018 to 136 million riders in 2019 (NACTO, 2020). Users often use their smart phone or another similar device to unlock the vehicle after paying a fee on the device through their …


Hydrodynamic Signatures Of Recreational Boat Wakes And Their Influence To Sediment Entrainment Along The Shoreline Of A Shallow Estuary, Kelly M. Kibler Apr 2022

Hydrodynamic Signatures Of Recreational Boat Wakes And Their Influence To Sediment Entrainment Along The Shoreline Of A Shallow Estuary, Kelly M. Kibler

Predicting Boat Wake Bank Erosion Risk

Wave energy from recreational boat wakes is associated with erosion and degradation of shoreline ecotones. However, wake effects are often assumed to be negligible when boating lanes are located far from shore. In this study, field experiments were conducted to characterize hydrodynamics of recreational boat wakes at the shoreline of a shallow estuary as offshore sailing-line distance varied from 50 to 200m. Results indicate that wake events were considerably more energetic than ambient conditions, with an average 20% increase in wave height, 190% increase in near-bed orbital velocity, and 110% increase in wave-induced shear stress. Wake events generated farther from …


A Smart Illicit Discharge Monitoring System, Alexander Campbell, Henry S. Armstrong, Tien Yee Apr 2022

A Smart Illicit Discharge Monitoring System, Alexander Campbell, Henry S. Armstrong, Tien Yee

Symposium of Student Scholars

In the present study, we attempt to use a variety of sensors to monitor illicit discharges that are present near the Kennesaw State University Marietta Campus. The US Environmental Protection Agency defines an illicit discharge as “any discharge into a storm drain system that is not composed entirely of stormwater”. Each year, approximately 860 billion gallons of sewage spills are reported throughout the country. In Georgia, sewer spills data shows that spills may range from hundreds of gallons to millions of gallons depending on the severity of the leak. The undetected sewer leaks may degrade the water quality in nearby …


Implementation Of Secondary And Tertiary Treated Wastewater In Concrete Manufacturing, Amany G. Micheal Prof., Haidy Abd El Salm, Gouda Ghanem Prof. Mar 2022

Implementation Of Secondary And Tertiary Treated Wastewater In Concrete Manufacturing, Amany G. Micheal Prof., Haidy Abd El Salm, Gouda Ghanem Prof.

Centre for Advanced Materials

Water scarcity is a problem that faces many regions. In a developing and arid country like Egypt, the need for freshwater is exponentially increasing. This research is an evaluation of the recycled wastewater to be used in concrete manufacturing. The treated wastewater is blended with potable water with percentages of 25%, 50%, and 100%. The mixture of the two types of water is used in concrete mixing and curing. Control specimens with pure potable water are cast for comparison. The setting time for Ordinary Portland Cement is tested using the different water mixes. The hardened concrete is tested in compression …


Comparison Of Phosphorus Removal And Recovery Methods And Proposed Design Of High Rate Algal Pond For Swine Wastewater, Taylor Fauth Jan 2022

Comparison Of Phosphorus Removal And Recovery Methods And Proposed Design Of High Rate Algal Pond For Swine Wastewater, Taylor Fauth

Civil and Environmental Engineering Graduate Students Plan B Capstone Projects

High phosphorus concentrations in wastewater effluent can have harmful effects to aquatic environments and water quality. An excess of nutrients such as phosphorus in water bodies will cause eutrophication, which depletes the available oxygen within the water and is detrimental to aquatic life. Additionally, phosphorus leaching from wastewater discharge has negative impacts to groundwater quality. The depletion of phosphorus as a natural resource is also of concern as phosphorus is an essential product for agricultural and industrial production. Phosphorus is a non-renewable resource, and natural sources are becoming more difficult and expensive to access. Therefore, the removal and recycle of …


Maximum Profit Facility Location And Dynamic Resource Allocation For Instant Delivery Logistics, Darshan Chauhan, Avinash Unnikrishnan, Stephen D. Boyles Jan 2022

Maximum Profit Facility Location And Dynamic Resource Allocation For Instant Delivery Logistics, Darshan Chauhan, Avinash Unnikrishnan, Stephen D. Boyles

Civil and Environmental Engineering Faculty Publications and Presentations

Increasing e-commerce activity, competition for shorter delivery times, and innovations in transportation technologies have pushed the industry toward instant delivery logistics. This paper studies a facility location and online demand allocation problem applicable to a logistics company expanding to offer instant delivery service using unmanned aerial vehicles or drones. The problem is decomposed into two stages. During the planning stage, the facilities are located, and product and battery capacity are allocated. During the operational stage, customers place orders dynamically and real-time demand allocation decisions are made. The paper explores a multi-armed bandit framework for maximizing the cumulative reward realized by …


Sewer Vapor Intrusion Pathway: Simulation Of Indoor Piping Systems And Operation Of Aroma-Voc Gas Analyzer, Hong Cheng Tay Jan 2022

Sewer Vapor Intrusion Pathway: Simulation Of Indoor Piping Systems And Operation Of Aroma-Voc Gas Analyzer, Hong Cheng Tay

Theses and Dissertations--Civil Engineering

Vapor Intrusion (VI) is a transport phenomenon that occurs when contaminants migrate from sub-surface sources into indoor spaces. Sewer tunnels, plumbing connections, and piping infrastructures can be important contributors to an increased potential of VI in a site, which results in indoor concentrations of volatile organic compounds (VOC). In the present work, the topic of sewer VI pathways were investigated through a prototype made from various types of indoor plumbing pipe fittings. This prototype simulates indoor piping systems and determine whether air and VOC were escaping through the pipe fittings. Moreover, this study is the first effort to use a …


Investigation Of Pfas Exposure Risks In Kentucky Using Mapping Tools, Sweta Ojha Jan 2022

Investigation Of Pfas Exposure Risks In Kentucky Using Mapping Tools, Sweta Ojha

Theses and Dissertations--Civil Engineering

Per- and polyfluoroalkyl substances (PFAS), a group of environmentally-persistent compounds, are environmentally ubiquitous and challenging to remediate. Several studies show that PFAS are detected in drinking water systems when sampling is conducted, making human exposure via drinking water an important health consideration. This research: 1) develops a mapping tool for prioritizing sampling locations; 2) establishes a method for making GIS data and meta(data) in the mapping tool accessible; 3) fosters decision making by integrating knowledge brokering and the alignment interest and influence matrix (AIIM). The tool developed is this research is a geospatial and statistical PFAS hot-spot screening model that …


Using Stream Restoration To Mitigate Stormwater Runoff In An Urban Watershed: A Case Study, Jonathan M. Brantley Jan 2022

Using Stream Restoration To Mitigate Stormwater Runoff In An Urban Watershed: A Case Study, Jonathan M. Brantley

Theses and Dissertations--Biosystems and Agricultural Engineering

The goal of this case study was to evaluate the effectiveness a 275 m regenerative stream restoration design to mitigate stormwater runoff in a highly urbanized watershed. The restoration resulted in a wide, wetland-like floodplain, comprised of a rock base that was overtopped with a filtration media (approximately 30% woodchips and 70% topsoil). The creation of the floodplain-wetland complex in tandem with filtration media lead to increased storage capacity and an increase in hyporheic exchange within the system. Significant reductions were found for the storm hydrograph parameters volume, peak discharge, and time to peak. Reductions in baseflows were also noted …


North 14th Street Corridor Improvements Project, Ashley Nguyen, Samantha Corey, Maricela Paramo Reyes, Pooja Rajeev Jan 2022

North 14th Street Corridor Improvements Project, Ashley Nguyen, Samantha Corey, Maricela Paramo Reyes, Pooja Rajeev

Honors Program: Senior Projects (Public)

The following project report was a study of the North 14th Street corridor ranging from Adams Street to Virginia Street conducted by University of Nebraska-Lincoln students for a senior design capstone project. Main focuses of the project were the intersection of Adams and 14th Street and the 14th Street bridges over Cornhusker Highway and Oak Creek. Study of this area included work in transportation, traffic, structural, geotechnical, water resources, and environmental engineering. However, this report done by students should not take the place of work done by licensed professional engineers.

This project was done in collaboration with …


Biodegradation Of Rubber Particles In Soil: Using Acclimated Bacteria Isolated From Kansas Soil To Degrade Cryogrinds In Slurry, Shane Graham Jan 2022

Biodegradation Of Rubber Particles In Soil: Using Acclimated Bacteria Isolated From Kansas Soil To Degrade Cryogrinds In Slurry, Shane Graham

Williams Honors College, Honors Research Projects

This study investigated the viability of bioremediating rubber cryogrind using enriched indigenous bacteria. To begin the experiment, soils from three highway roadside locations in Kansas, KS 96 and West, KS 400 and 143rd, and 199th, were collected and transported to the lab to be studied. An initial soil characterization was run on the soil samples using distilled (DI) water mixture and 0.01 M CaCl2 to assess conductivity. The soils were tested to gather a baseline of the relationship between pH and conductivity and the impact of its distance from the roadside. Bacteria were isolated from …


On A New Framework For Detecting, Classifying, And Forecasting Floods For Large-Scale Flood Risk Analysis, Equisha Glenn Jan 2022

On A New Framework For Detecting, Classifying, And Forecasting Floods For Large-Scale Flood Risk Analysis, Equisha Glenn

Dissertations and Theses

Increasing trends in flooding events are projected to continue as climate changes have increased the chance of extreme weather events. Given the significant, damaging impacts of extreme floods, the ability to effectively model floods is crucial for risk management and mitigation of the impacts of these extreme flooding events. This dissertation presents a new framework for detecting and predicting large-scale flood risk in the United States using climate information. This methodology categorizes regional, simultaneous floods into an index that is used to forecast the risk of extreme flooding a season ahead. The index proposed herein, named the Spatial Flood Index …


Stormwater Sensitivities To The Climatic And Land Cover Drivers In A Heavily Urbanized Coastal Basin Along The Northern Gulf Of Mexico, Usa., Md Faisal Razy Jan 2022

Stormwater Sensitivities To The Climatic And Land Cover Drivers In A Heavily Urbanized Coastal Basin Along The Northern Gulf Of Mexico, Usa., Md Faisal Razy

Graduate Theses, Dissertations, and Problem Reports (ETD)

Stormwater runoff response in a complex coastal-urban basin varies with the changes in climatic and land cover drivers. This thesis aims to assess the runoff responses to variation in climatic and land cover variables and perform a sensitivity analysis in complex coastal-urban basins. The Buffalo San Jacinto Basin (BUSJ) of southeast Texas, USA was considered a pilot study area for this research. BUSJ is a heavily urbanized coastal basin, draining an area of 3132 km2 through the City of Houston, Texas into the northern Gulf of Mexico, USA. A process-based hydrological model was developed with fine spatio-temporal resolutions for …


Climatic And Land Cover Sensitivities Of Stormwater Runoff In A Coastal Natural-Urban Basin Of Texas, Usa., Nusrat Nasrin Khan Jan 2022

Climatic And Land Cover Sensitivities Of Stormwater Runoff In A Coastal Natural-Urban Basin Of Texas, Usa., Nusrat Nasrin Khan

Graduate Theses, Dissertations, and Problem Reports (ETD)

Changes in climatic and land use drivers typically drive stormwater runoff quantity and quality. This study focuses on determining the stormwater runoff sensitivities to variation in climatic and land cover changes in a coastal natural-urban basin. A mechanistic hydrologic model was developed for the Spring San Jacinto Basin (SSJB) of Texas, USA considering the basin as a pilot study area by using the U.S. Environmental Protection Agency (EPA)’s Storm Water Management Model 5.2. The SSJB drains an area of 1949 km2 ultimately into the northern Gulf of Mexico, USA through peripheral neighborhoods of the Greater Houston area. The model …


Stormwater Runoff Response Under Changing Climate And Land Uses Across Gradients Of Inland And Coastal Urban-Natural Basin, Mahmood Khan Jan 2022

Stormwater Runoff Response Under Changing Climate And Land Uses Across Gradients Of Inland And Coastal Urban-Natural Basin, Mahmood Khan

Graduate Theses, Dissertations, and Problem Reports (ETD)

Climatic variability has caused significant shifts in the magnitude, frequency and spatiotemporal distribution of precipitation, generating excessive runoff that leads to frequent occurrences of extreme hydrologic events such as the pluvial (rainfall accumulation) and fluvial (riverine) floods. The conversion of natural areas into urban lands is further exacerbating the rainfall accumulation by increasing surface imperviousness that hinders infiltration of water into the soil. This dissertation predicts and characterizes potential shifts in the future annual stormwater runoff
volumes and runoff extremes under the standalone and coupled changes in climate and land use across inland and coastal urban-natural settings. The research was …


Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham Dec 2021

Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham

Graduate Theses and Dissertations

NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …