Environmental Engineering Commons^™

Implications Of Surface Runoff Recharge In Semi-Arid Regions On Groundwater Sustainability, Omar M. Al-Qudah

Open Access Theses & Dissertations

Amargosa Desert, Nevada regional groundwater studies show that the surface runoff infiltration occurring in the arroyos following runoff producing storms, and this infiltration is considered to be a major source of groundwater recharge. Groundwater infiltration through alluvium was investigated in the Amargosa Desert using borehole drill cuttings, groundwater chemistry, and applying a novel method for collecting runoff water. The sampling process included sediment, precipitation, and runoff water. In total, 176 runoff, 182 sediment, and 45 precipitation samples were collected between January, 2009 and January, 2011.Water chemistry, chloride concentrations, and stable isotopes of water collected from specially designed runoff samplers, placed …

Cactus Mucilage-Assisted Heavy Metal Separation: Design And Implementation, Dawn Iona Fox

USF Tampa Graduate Theses and Dissertations

Natural contamination of groundwater by arsenic (As) has become a critical public health threat in many parts of the world. The well-known regions associated with As contamination of groundwater are Bangladesh and West Bengal, India where approximately 100 million people are exposed to high levels of arsenic by drinking arsenic-contaminated groundwater and about 35 million are already affected. Long-term drinking of arsenic-contaminated water leads to arsenicosis, which is characterized by cancers of the skin, organ disease and certain other types of cancer. Affected developing communities are at higher risk because they may not have access to conventional water treatment facilities. …

Extraction Of Chromium From Wastewater By Emulsion Ionic Liquid Membrane., Rahul Kumar Goyal

Student Works (2010-2019)

Emulsion liquid membrane (ELM) has been proven to be a competent extraction technology to extract heavy metals or organic compounds from industrial wastewaters. In this process, a prepared emulsion is dispersed into a feed phase which contains the solute to be removed. Single stage operation and less power consumption make this technology more favorable over pressure-driven membrane process and solvent extraction. Despite its comparative advantages, ELM process suffers from emulsion instability and swelling under high shear and stress during extraction, causing breakage in the membrane. The instability and swelling of the emulsion allow extracted solute and internal reagent to mix …

Arsenite Oxidation By Pure Cultures Of Thiomonas Arsenivorans Strain B6 In Bioreactor Systems, Aniruddha Dastidar

University of Kentucky Doctoral Dissertations

The removal of arsenic toxicity from water is accomplished by a preliminary preoxidative step transforming the most toxic form, arsenite (As (III)), to the least toxic form, arsenate (As (V)). The potential of As (III) oxidation to As (V) was initially investigated in batch reactors using the chemoautotrophic Thiomonas arsenivorans strain b6 under varying initial As (III) and cell concentrations and at optimal pH and temperature conditions (pH 6.0 and temperature 30°C). The strain b6 completely oxidized As (III) to As (V) during exponential growth phase for lower levels of As (III) concentrations (≤ 100 mg/L) but continued into stationary …

Temperature Influence And Heat Management Requirements Of Microalgae Cultivation In Photobioreactors, Thomas Hagen Mehlitz

Master's Theses

Microalgae are considered one of the most promising feedstocks for biofuel production for the future. The most efficient way to produce vast amounts of algal biomass is the use of closed tubular photobioreactors (PBR). The heat requirement for a given system is a major concern since the best algae growth rates are obtained between 25-30 °C, depending on the specific strain. A procedure to determine temperature influence on algal growth rates was developed for a lab-scale PBR system using the species Chlorella. A maximum growth rate of 1.44 doublings per day at 29 °C (optimal temperature) was determined. In addition, …

Transition Metal Catalysts For Hydrodesulfurization Reactions Applied To Petroleum Industry, Brenda Torres

Open Access Theses & Dissertations

Catalysis plays a fundamental role in petroleum refining and basic petrochemical industries creating new routes in the development of industrial processes. Moreover, catalysis has become indispensable to the solution of environmental pollution problems and therefore on public health. World wide concerns for preservation of the environment has motivated the development of "Green" catalyst based technologies, to achieve a better utilization of petroleum resources and demands for cleaner transportation fuels. These environmental concerns have led to increasingly drastic regulations on sulfur, nitrogen and aromatics content in fuels. Sulfur content in the motor and diesel fuels is continuously reduced by regulations to …

Kinetics Determination Of Soybean Oil Transesterification In The Design Of A Continuous Biodiesel Production Process, Irwin Jacob, Ed Clausen, Danielle Julie Carrier

Biological and Agricultural Engineering Undergraduate Honors Theses

One-step batch transesterification consisting of three stepwise reversible reactions of pure soybean oil with methanol was conducted at two different mixing speeds (600 and 300 rpm) to produce soybean oil fatty acid methyl esters (biodiesel). In both batch reactions, sodium methoxide (1.09 wt% based on soybean oil) was used as the catalyst, the reaction temperature was 60oC, and the methanol-to-oil molar ratio was 6:1. The objectives were to determine and/or investigate: 1) the mechanism and order of the reaction, 2) the reaction rate constants, 3) the effect of changes in mixing intensity on the reaction rate, 4) the comparison of …

Catalytic Wet Air Oxidation Of Mono Azo Dye Orange Ii: Catalyst Selection, Reaction Kinetics, And Modeling, Pinar Ozdural

Civil & Environmental Engineering Theses & Dissertations

Wastewaters generated as byproducts of dyeing processes are not treatable with conventional methods. It has been estimated that among the 900,000 tons of different dyes produced annually in the world, approximately 10–15% are lost in wastewater streams during manufacturing and processing operations. Once in rivers and streams, dyes cause major problems, such as reducing light penetration, or displaying toxic effects on aquatic life. Therefore, it is essential that dyes are removed from wastewaters before being discharged into the environment.

This study focuses on the catalytic wet air oxidation (CWAO) of Orange II, a mono azo dye used in large amounts …

Procedure To Quantify Biofilm Activity In Carriers Used In Wastewater Treatment Systems, James Bolton, Archana Tummala, Chirag Kapadia, Manoj Dandamudi, Joanne M. Belovich

Chemical & Biomedical Engineering Faculty Publications

A procedure is presented for evaluating and comparing the biological activity of biofilms attached to various biofilm carriers by measurement of the glucose consumption rate. This technique allows for the economical design and selection of small particulate biofilm carriers that will maximize substrate removal when used in industrial-scale fluidized bioreactors. Methods for ensuring reproducible results are described. To support the glucose consumption rate findings, biofilm dry weights were obtained at the conclusion of activity rate experiments, and scanning electron micrographs were taken to evaluate the presence of biofilm and to view surface characteristics. Fourteen different biofilm carriers were evaluated ranging …

Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole

Civil & Environmental Engineering Theses & Dissertations

Halonitromethanes (HNMs) are low molecular weight halogenated disinfection-by-products (DBPs) found to be formed during ozonation, chlorination, or chloramination of waters containing natural bromide ion and nitrogenous organic matter. This work identifies the absolute rate constants for the oxidative hydroxyl radical (•OH) and reductive hydrated electron e^- _aq extinction of HNM compounds. Three forms of HNMs included in this study are the chlorinated, brominated, and mixed halogenated compounds. Electron pulse radiolysis and transient absorption spectroscopy were used to measure •OH and e^- _aq radical absolute reaction rate constants for a total of nine HNMs. To elucidate the decomposition reaction …

Studies On Use Of Carbon Slurry, A Waste From Fertilizer Plant, In Treatment Of Waste Water, Sanjay Tewari

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

"Non biodegradable materials like heavy metals, refractory organics are not removed during the conventional treatment process. In order to meet the regulatory standards and for safe disposal, it is necessary to go for tertiary treatment. Various tertiary treatment methods include adsorption, membrane separation process, ultra filtration, reverse osmosis etc. Adsorption has been found to be efficient for the removal of most of heavy metals in waste water at lower concentrations. Activated carbon is commonly used adsorbents, however, due to its high cost and loss in regeneration, various low cost adsorbents have been investigated during recent years.

The aim of the …

Biological Reduction Of Perchlorate In Ion Exchange Regenerant Solutions Containing High Salinity And Ammonium Levels, Tina M. Gingras, Jacimaria R. Batista

Civil and Environmental Engineering and Construction Faculty Research

The most promising technologies to remove perchlorate from water are ion exchange and biological reduction. Although successful, ion exchange only separates perchlorate from water; it does not eliminate it from the environment. The waste streams from these systems contain the caustic or saline regenerant solutions used in the process as well as high levels of perchlorate. Biological reduction could be used to treat the regenerant waste solutions from the ion exchange process. A treatment scheme, combining ion exchange and biodegradation, is proposed to completely remove perchlorate from the environment. Perchlorate-laden resins generate brines containing salt concentrations up to 6% or …

Stabilization And Solidification Of Palm Oil Mill Effluent Sludge And A Pure Model Study Using Cementitious Technique, Nor Asikir Mamat

Student Works (2000-2009)

This research studies the effectiveness of using method of stabilization and solidification ($/$) to palm oil mill effluent (POME) sludge as a pretreatment method prior to ultimate disposal to land and to investigate the effect of varying the concentration of simulated metals (zinc, copper and iron) for pure model study (PMS). The characteristics of the solidified products including unconfined compressive strength (UCS) and toxicity characteristic leaching procedure (TCLP) from USEPA were evaluated. The influence of cement replacement material (CRM), name ly pu lverized fly ash (PFA) on the effectiveness of SIS was also investigated for POME sludge. The POME sludge …

Membrane Ultrafiltration Of Treated Palm Oil Mill Effluent (Pome), Pui Wah Wong

Student Works (2000-2009)

The common practice for treatment of palm oil effluent (POME) in Malaysia employs a combination of aerobic and an anaerobic treatment. Bearing in mind that the quantity of POME produced is high, reaching 740 000 m3 in May 2001, reuse and recycling of treated POME can be an excellent practice in terms of saving of water resources. As the treated POME is already low in certain parameters required by the Department of Environment (i.e. BOD, total and ammoniacal nitrogen, oil and grease), further treatment will greatly enhance the water quality. The purpose of the advance treatment step is to allow …

Comparative Performance Of Wastewater Treatment Plants In Three Rubber Glove Manufacturing Plants, Lee Kuan Loh

Student Works (2000-2009)

During the manufacturing of rubber gloves, water is used as wash water at different stages to clean the rubber gloves, thus generating quite a substantial amount of effluent. There are four main sources of effluent. i.e. a) from the glove formers cleaning tank, which collects the acidified water used to clean these formers, b) latex dipping tank, where it collects wash water used to cool the tank during dipping process and the sludge form the tank itself, c) leaching tank, where it collects wash water used to leach out the pollutants from the gloves and lastly d) latex compounding, containing …

Waste Management In Palm-Oleo Sdn. Bhd, Ramesh Ramasamy

Student Works (2000-2009)

Oleochemical industry in Malaysia has been diversifying significantly due to the availability of raw materials (palm oil) and the high demand for downstream products such as fatty acids, fatty alcohols and glycerine. The growth of oleochemical industries is further enhanced by fluctuations io petroleum price and regular animal diseases, which made tallow-based fats unreliable. Environmental awareness is growing rapidly in Malaysia. There is growing realization of the need to balance industrial and economic development with environmental preservation and protection, as well as, with efficient use of energy sources in order to achieve sustainable development. Extensive waste management studies were focused …

Production Of Fermentable Sugars From Waterhyacinth By High-Temperature Dilute-Acid Hydrolysis Method, J. H. Y. Katima

Tanzania Journal of Engineering and Technology (TJET)

A study on acid-catalyzed hydrolysis of Waterhyacinth (WH) biomass for production of monomeric sugars has been done. Waterhyacinth (Eichhornia Crassipes) plants were obtained from Lake Victoria. A yield of 18.5% w/w fermentable sugars was achieved during hydrolysis of oven-dried Waterhyacinth (ODWH) biomass at 220°C and 1.5% w/w H₂SO₄ acid. The waterhyacinth (WH) hydrolysates obtained from a high-temperature dilute-acid hydrolysis were rich in six-carbon (C₆) sugars (glucose) which could be fermented to ethanol. The production of fermentable sugars from waterhyacinth biomass is a promising new opportunity for its economic value which can in turn accelerate its rate of harvest and utilization.

Winery Waste Utilization-A Case Study Of Dowico, J. H.Y. Katima

Tanzania Journal of Engineering and Technology (TJET)

The Dodoma Winery Company (DOWICO), is presently processing about 1000 tonnes of grapes to produce different types of wines, with left overs of about 200 as wastes. These wastes are dumped outside the factory, obviously, a poor method of waste disposition as far as the environmental significance is concerned. Since the expansion programme, to enable the plant to handle up to 30000 tonnes of grapes per year is in the pipeline the best method of disposing the huge amount of waste (about 6000 tonnes) that will result, has to be sought.

This paper highlights the financial and sanitary advantage of …

A Field Perspective On Groundwater Contamination, John A. Cherry

Maine Collection

A Field Perspective on Groundwater Contamination

Geological Society of Maine Distinguished Lecturer John Cherry, University of Waterloo, Ontario, sponsored by the Department of Geosciences, University of Southern Maine, 19th May 1988.

Contents: Lecture 1 : Contaminant Migration Processes Illustrated by Field Experiments / Lecture 2 : Behavior of Dense Non-Aqueous Phase Liquids, Illustrated by Lab Experiments and Conceptual Examples / Lecture 3 : Field Case Histories on Groundwater Contamination / Lecture 4 : Hydrogeological Concepts and Criteria for Waste Disposal / Waterloo Center for Groundwater Research Publications List