Environmental Engineering Commons^™

Fate And Impacts Of Priority Pollutant Metals In Coal Fly Ash–Soil–Switchgrass Plant Mesocosms, Olushola M. Awoyemi, E. Kudjo Dzantor

Coal Combustion and Gasification Products Journal Archive

Coal fly ash (CFA) is a coal combustion by-product containing heavy metals (HMs) that can enter and accumulate in environmental matrices. The current study assessed the fate and effects of HMs contained in CFA on Armour silt loam (ASL) soil, switchgrass plant, and leachate. Soil impact indices compared levels of HMs in the CFA-soil admixtures to control soil (without CFA). These indices include contamination factor (*C*~f~), modified degree of contamination (m*C*~d~), and pollution load index (PLI). The ratio of the levels of HMs in switchgrass root and shoot tissues to their levels in the CFA-soil admixtures were used to determine …

A Novel Diffuse Fraction-Based Two-Leaf Light Use Efficiency Model: An Application Quantifying Photosynthetic Seasonality Across 20 Ameriflux Flux Tower Sites, Hao Yan, Shao-Qiang Wang, Kai-Liang Yu, Bin Wang, Qin Yu, Gil Bohrer, Dave P. Billesbach, Rosvel Bracho, Faiz Rahman

Department of Agricultural and Biological Systems Engineering: Faculty Publications

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Diffuse radiation can increase canopy light use efficiency (LUE). This creates the need to differentiate the effects of direct and diffuse radiation when simulating terrestrial gross primary production (GPP). Here, we present a novel GPP model, the diffuse-fraction-based two-leaf model (DTEC), which includes the leaf response to direct and diffuse radiation, and treats maximum LUE for shaded leaves (ε_msh defined as a power function of the diffuse fraction (D_f)) and sunlit leaves (ε_msu defined as a constant) separately. An Amazonian rainforest site (KM67) was used to calibrate the model by simulating the linear relationship between …

Geopolymerization Of Coal Ash To Produce Cementless Binders, Hamid Akbari, Robert Mensah-Biney, Jonathan Simms

Coal Combustion and Gasification Products Journal Archive

The main objective of this study was to evaluate geopolymer concrete made from coal combustion by-products, disposed of in landfills, as a potential substitute for the ordinary Portland cement (OPC), which is responsible for 5-8% of the total CO2 emissions in the world. In this study, a coal fly ash sample from the Carolinas was used in a chemical process known as geopolymerization to produce a “geopolymer” binder. The developed geopolymer binder could competently substitute the OPC binder in regular concrete applications. An experimental design program was conducted to optimize parameters of the geopolymerization affecting the strength of the final …

Groundwater Monitoring And Data Analysis Under The Coal Combustion Residuals Rule, Bruce Hensel

Coal Combustion and Gasification Products Journal Archive

No abstract provided.

Ponded And Landfilled Fly Ash As A Source Of Rare Earth Elements From A Kentucky Power Plant, James C. Hower, John G. Groppo, Kevin R. Henke, Uschi M. Graham, Madison M. Hood, Prakash Joshi, Dorin V. Preda

Coal Combustion and Gasification Products Journal Archive

Twenty samples, with one composite sample built out of the 20 individual samples, of ponded ash were collected at a Kentucky power plant. The coal feed throughout the history of the power plant was central eastern Kentucky low- to moderate-S high volatile A bituminous coal. The pond was in the process of being excavated, with the ash moved to a landfill on another company property. In spite of the long history of the pond and the expected variation in coal supply, and perhaps because of the mixing due to the excavation, there is little variation in ash-basis rare earth elements …

Rare Earth Element Distribution In Fly Ash Derived From The Fire Clay Coal, Kentucky, Madison M. Hood, Ross K. Taggart, Ryan C. Smith, Heileen Hsu-Kim, Kevin R. Henke, Uschi Graham, John G. Groppo, Jason M. Unrine, James C. Hower

Coal Combustion and Gasification Products Journal Archive

Fly ash was collected from individual mechanical and electrostatic precipitator (ESP) hoppers at a 130-MW pulverized-coal utility unit burning a southeastern Kentucky moderate- to high-S Pennsylvanian Fire Clay coal. The fly ash particle size is generally similar within each row of the mechanical and ESP hoppers, with the mean particle diameter decreasing from >36 μmin the mechanical hoppers to 6 μm in the last ESP row. Rare earth element (REE)–bearing phases occur within fine minerals and, possibly, as part of the fly ash glass phase. Transmission electron microscopy was used to identify Y-Ce-Nd-La–bearing regions within a glassy matrix. Y- and …

The Relative Impact Framework For Evaluating Coal Combustion Residual Surface Impoundment Closure Options: Applications And Lessons Learned, Ari S. Lewis, Andrew B. Bittner

Coal Combustion and Gasification Products Journal Archive

In response to the U.S. Environmental Protection Agency’s new rule regarding the disposal of coal combustion residuals (CCRs), many utilities need to re-examine their waste disposal practices and make decisions regarding if and how unlined surface impoundments (SIs) should be closed. The two primary options for closing SIs are in-place closure, with capping and engineering controls, and excavation of the CCR for transport to and re-disposal in a lined landfill. To help inform closure option decisions, we supported the Electric Power Research Institute’s development of a practical, science-based decision framework that comprehensively evaluates the potential impacts to human health and …

Evaluation Of Woodchip Bioreactor Denitrification Kinetics, Abdoul Aziz Kouanda

Electronic Theses and Dissertations

Agricultural subsurface drainage is a water management practice used to remove excess water in poorly drained soil. The use of fertilizers combined with subsurface drainage practice affects negatively surface water quality due to nutrient loss. Woodchip bioreactors have previously been used as a technology for removing nitrate from agricultural subsurface drainage. Understanding the mechanism that governs nitrate removal in woodchip bioreactors is crucial for field bioreactor design and application. The objective of this project is to determine woodchip bioreactor denitrification kinetics parameters under different operating conditions including hydraulic retention time, temperature and influent nitrate concentrations. Laboratory column experiments were conducted …

Nebraska Public Water Supply Program Summary Report 2017

Nebraska Department of Environmental Quality: Reports

The United States Environmental Protection Agency (EPA) established the Public Water System Supervision (PWSS) Program under the authority of the 1974 Safe Drinking Water Act (SDWA). Under the SDWA and the 1986 Amendments, EPA sets national limits on contaminant levels in drinking water to ensure that the water is safe for human consumption. These limits are known as Maximum Contaminant Levels (MCLs) and Maximum Residual Disinfectant Levels (MRDLs). For some regulations, EPA establishes treatment techniques in lieu of an MCL to control unacceptable levels of contaminants in water.

2017 Nebraska Groundwater Quality Monitoring Report

Nebraska Department of Environmental Quality: Reports

The 2001 Nebraska Legislature passed LB329 (Neb. Rev. Stat. §46-1304) which, in part, directed the Nebraska Department of Environmental Quality (NDEQ) to report on groundwater quality monitoring in Nebraska. Reports have been issued annually since December 2001. The text of the statute applicable to this report follows: “The Department of Environmental Quality shall prepare a report outlining the extent of ground water quality monitoring conducted by natural resources districts during the preceding calendar year. The department shall analyze the data collected for the purpose of determining whether or not ground water quality is degrading or improving and shall present the …

Trend Analysis In Rainfall, Reference Evapotranspiration And Aridity Index In Southern Senegal: Adaptation To The Vulnerability Of Rainfed Rice Cultivation To Climate Change, Komlan Koudahe, Koffi Djaman, Ansoumana Bodian, Suat Irkmak, Mamadou Sall, Lamine Diop, Alpha B. Balde, Daran Rudnick

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Rainfall and evapotranspiration are two vital elements for food production under rainfed agriculture. This study aims at investigating the combined changes in these variables in the form of aridly index in the southern Senegal. The temporal trends in annual and monthly (from May to October) aridity index, rainfall and evapotranspiration are examined and adaptation strategies to the vulnerability of rainfed rice cultivation to the changes are developed. The results show a significant decreasing trend in annual rainfall at all study locations for the period 1922-2015. When analyzing the trends in sub-periods, there are two clear patterns in the annual rainfall …

Moving Integrated Weed Management From Low Level To A Truly Integrated And Highly Specific Weed Management System Using Advanced Technologies, S. L. Young, S. K. Pitla, F. K. Van Evert, J. K. Schueller, F. J. Pierce

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Integrated weed management (IWM) is one of the most commonly referred to approaches for sustainable and effective weed control in agriculture, yet it is not widely practiced, likely because current IWM systems fail to meet performance expectations of growers. The effectiveness and value of IWM systems should increase with increasing application specificity and true integration made possible with contemporary advances in technology, information systems and decision support. IWM systems can be classified based on their degree of application specificity and level of integration of tactics. In the application specificity pathway, a tactic is applied at a range of scales, from …

Runoff Water Quality Characteristics Following Swine Slurry Application Under Broadcast And Injected Conditions, Nicole R. Schuster, Shannon L. Bartelt-Hunt, Lisa M. Durso, John E. Gilley, Xu Li, David B. Marx, Amy M. Schmidt, Daniel D. Snow

Department of Agricultural and Biological Systems Engineering: Faculty Publications

This study was conducted to measure the effects of swine slurry application method, time following slurry application, and runoff rate on selected water quality characteristics. Slurry from a commercial swine operation was broadcast or injected on field plots at a rate required to meet annual nitrogen requirements for corn. Rainfall simulation tests were conducted at five varying periods following slurry application. During each study period, three simulated rainfall events, separated by 24 h intervals, were applied for 30 min duration at an intensity of approximately 70 mm h^-1. Following the third rainfall simulation event, inflow was applied at …

Multiple Drivers Of Seasonal Change In Pri: Implications For Photosynthesis 1. Leaf Level, Anatoly A. Gitelson, John A. Gamon, Alexei E. Solovchenko

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The goal of this study was to explore the relationships between the photochemical reflectance index (PRI) at the leaf level and pigment pools, focusing on the constitutive role of pigments in influencing PRI over seasonal or ontogenetic time frames. The purpose was to re-evaluate the role of PRI as an indicator of seasonally shifting pigment (chlorophyll, carotenoid and anthocyanin) contents, and hence photosynthetic activity, across a range of tree and crop species. We studied natural vegetation — three tree species (maple, chestnut and beech) and two managed irrigated and rain-fed crop species (maize and soybean), contrasting in photosynthetic pathway and …

Multiple Drivers Of Seasonal Change In Pri: Implications For Photosynthesis 2. Stand Level, Anatoly A. Gitelson, John A. Gamon, Alexei E. Solovchenko

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The goal of this study was to explore the relationships between stand-level photochemical reflectance index (PRI) and canopy structure/ pigment pools, as well as light use efficiency (LUE) of photosynthetically active vegetation focusing on seasonal or ontogenetic time frames. PRI was originally designed as a means of assessing the xanthophyll cycle and LUE over short (e.g. diurnal) time frames, and few studies have explored the drivers of PRI over longer, seasonal time frames, particularly in crops having different photosynthetic pathways or canopy structures. Consequently, our purpose was to understand and quantify the drivers of PRI responses over seasonal time scales …

Optical Probing Of Gastrocnemius In Patients With Peripheral Artery Disease Characterizes Myopathic Biochemical Alterations And Correlates With Stage Of Disease, Ryan A. Becker, Kim Cluff, Nithyanandhi Duraisamy, Hootan Mehraein, Hussam Farhoud, Tracie Collins, George P. Casale, Iraklis I. Pipinos, Jeyamkondan Subbiah

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Peripheral artery disease (PAD) is a condition caused by atherosclerotic blockages in the arteries supplying the lower limbs and is characterized by ischemia of the leg, progressive myopathy, and increased risk of limb loss. The affected leg muscles undergo significant changes of their biochemistry and metabolism including variations in the levels of many key proteins, lipids, and nucleotides. The mechanisms behind these changes are poorly understood. The objective of this study was to correlate the severity of the PAD disease stage and associated hemodynamic limitation (determined by the ankle brachial index, ABI) in the legs of the patients with alterations …

Soil Water Content Monitoring For Irrigation Management: A Geostatistical Analysis, J. Burdette Barker, Trenton E. Franz, Derek M. Heeren, Christopher M.U. Neale, Joe D. Luck

Department of Agricultural and Biological Systems Engineering: Faculty Publications

With the increasing attention to site-specific or variable rate irrigation management, it is helpful to reconsider the quantity and placement of soil water monitoring locations in this context. Volumetric soil water content (θ_v) was monitored using a neutron probe (NP) at 72 locations in a center pivot irrigated field in eastern Nebraska. Variance reduction and temporal stability analyses were performed on θ_v from shallow (∼top 46 cm) and full profile (∼122 cm) readings for four monitoring cycles in the 2015 growing season and 2016 preseason. Eleven additional cycles were included for a subset of the data for …

Fuel Consumption Models For Tractor Test Reports, Michael F. Kocher, Bryan J. Smith, Roger M. Hoy, Jeffrey C. Woldstad, Santosh Pitla

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Five models for estimating fuel consumption for agricultural tractors with partial drawbar loads were compared. Data were collected from eight John Deere tractors, JD 7230R (e23), 7250R (e23), 7270R (e23), 7290R (e23), 8320R (16 speed), 7290R (IVT), 8345RT (IVT), 8370R (IVT), on the drawbar test track at the Nebraska Tractor Test Lab. The tractors were tested with seven load levels per speed at three different travel speeds as close as possible to 7.5, 10, and 13 km h-1. The IVT tractors were operated in auto mode, and the geared tractors were shifted up three gears and throttled back to the …

Creation Of An Injectable In Situ Gelling Native Extracellular Matrix For Nucleus Pulposus Tissue Engineering, Rebecca A. Wachs, Ella N. Hoogenboezem, Hammad I. Huda, Shangjing Xin, Stacy L. Porvasnik, Christine E. Schmidt

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Background Context: Disc degeneration is the leading cause of low back pain and is often characterized by a loss of disc height, resulting from cleavage of chondroitin sulfate proteoglycans (CSPGs) present in the nucleus pulposus. Intact CSPGs are critical to water retention and maintenance of the nucleus osmotic pressure. Decellularization of healthy nucleus pulposus tissue has the potential to serve as an ideal matrix for tissue engineering of the disc because of the presence of native disc proteins and CSPGs. Injectable in situ gelling matrices are the most viable therapeutic option to prevent damage to the anulus fibrosus and future …

In Vitro Porcine Blastocyst Development In Three-Dimensional Alginate Hydrogels, Jeremy R. Miles, Taylor D. Laughlin, Catherine Sargus-Patino, Angela K. Pannier

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Appropriate embryonic and fetal development significantly impact pregnancy success and, therefore, the efficiency of swine production. The pre-implantation period of porcine pregnancy is characterized by several developmental hallmarks, which are initiated by the dramatic morphological change that occurs as pig blastocysts elongate from spherical to filamentous blastocysts. Deficiencies in blastocyst elongation contribute to approximately 20% of embryonic loss, and have a direct influence on within-litter birth weight variation. Although factors identified within the uterine environment may play a role in blastocyst elongation, little is known about the exact mechanisms by which porcine (or other species’) blastocysts initiate and progress through …

Tractor Power Take-Off Torque Measurement And Data Acquisition System, James Bw Roeber, Santosh Pitla, Roger M. Hoy, Joe D. Luck, Michael F. Kocher

Department of Agricultural and Biological Systems Engineering: Faculty Publications

With the mechanization of agricultural operations, agricultural machinery management has become an extensive research field. Sizing tractors and implements to provide the most efficient power transfer has become an ongoing process with advances in technology. Utilization of the rotational power transferred through gear trains from the tractor engine to the power take-off (PTO) shaft is one of the most efficient methods of power transfer to an implement. This research used commercially available torque sensors that were installed on a tractor PTO shaft for measuring the torque delivered to an implement. The torque sensor was calibrated using the Nebraska Tractor Test …

Laboratory And Full Boom-Based Investigation Of Nozzle Setup Error Effects On Flow, Pressure, And Spray Pattern Distribution, Shane H. Forney, Joe D. Luck, Michael F. Kocher, Santosh Pitla

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Pesticide application is an integral part of crop production, and ground-based agricultural boom sprayers are used extensively to apply pesticides to the crop canopy or soil surface across millions of acres in the United States. Efficient application is necessary to minimize costs and limit adverse environmental impacts. The goals of this study were to provide quantified measurements on the effects of nozzle setup errors on spray pattern uniformity and evaluate how laboratory patternator-based simulations would compare to measurements on a full spray boom. More specific objectives were to determine the effects of factors such as nozzle lateral angle, nozzle spacing, …

Tractor Power Take-Off Torque Measurement And Data Acquisition System, James B. W. Roeber, Santosh K. Pitla, R. M. Hoy, J. D. Luck, Michael F. Kocher

Department of Agricultural and Biological Systems Engineering: Faculty Publications

With the mechanization of agricultural operations, agricultural machinery management has become an extensive research field. Sizing tractors and implements to provide the most efficient power transfer has become an ongoing process with advances in technology. Utilization of the rotational power transferred through gear trains from the tractor engine to the power take-off (PTO) shaft is one of the most efficient methods of power transfer to an implement. This research used commercially available torque sensors that were installed on a tractor PTO shaft for measuring the torque delivered to an implement. The torque sensor was calibrated using the Nebraska Tractor Test …

Laboratory And Full Boom-Based Investigation Of Nozzle Setup Error Effects On Flow, Pressure, And Spray Pattern Distribution, S. H. Forney, J. D. Luck, Michael F. Kocher, Santosh K. Pitla

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Pesticide application is an integral part of crop production, and ground-based agricultural boom sprayers are used extensively to apply pesticides to the crop canopy or soil surface across millions of acres in the United States. Efficient application is necessary to minimize costs and limit adverse environmental impacts. The goals of this study were to provide quantified measurements on the effects of nozzle setup errors on spray pattern uniformity and evaluate how laboratory patternator-based simulations would compare to measurements on a full spray boom. More specific objectives were to determine the effects of factors such as nozzle lateral angle, nozzle spacing, …

Chitosan-Zein Nano-In-Microparticles Capable Of Mediating In Vivo Transgene Expression Following Oral Delivery, Eric Farris, Deborah M. Brown, Amanda Ramer-Tait, Angela K. Pannier

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The oral route is an attractive delivery route for the administration of DNA-based therapeutics, specifically for applications in gene therapy and DNA vaccination. However, oral DNA delivery is complicated by the harsh and variable conditions encountered throughout gastrointestinal (GI) transit, leading to degradation of the delivery vector and DNA cargo, and subsequent inefficient delivery to target cells. In this work, we demonstrate the development and optimization of a hybrid-dual particulate delivery system consisting of two natural biomaterials, zein (ZN) and chitosan (CS), to mediate oral DNA delivery. Chitosan-Zein Nano-in-Microparticles (CS-ZN-NIMs), consisting of core Chitosan/DNA nanoparticles (CS/DNA NPs) prepared by ionic …

Development And Validation Of A Tractor Drawbar Force Measurement And Data Acquisition System (Daq), James Roeber, Santosh Pitla, Roger M. Hoy, Joe D. Luck, Michael F. Kocher

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Matching agricultural tractors to implements towed by the drawbar is one of the important aspects of machinery management for ensuring optimum performance and fuel cost savings. A field deployable tractor draft force measurement and data acquisition system was developed and evaluated as part of this research project. A drawbar instrumented to measure draft force in field operating conditions was developed and statically calibrated. The drawbar was calibrated by applying loads from 4.45 to 134 kN using a hydraulic cylinder connected to a 444.8 kN load cell. Testing was conducted with the drawbar installed on a tractor on a concrete track. …

Comparison Of Four Nitrate Removal Kinetic Models In Two Distinct Wetland Restoration Mesocosm Systems, Tiffany L. Messer, Michael R. Burchell, François Birgand

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The objective of the study was to determine the kinetic model that best fit observed nitrate removal rates at the mesocosm scale in order to determine ideal loading rates for two future wetland restorations slated to receive pulse flow agricultural drainage water. Four nitrate removal models were investigated: zero order, first order decay, efficiency loss, and Monod. Wetland mesocosms were constructed using the primary soil type (in triplicate) at each of the future wetland restoration sites. Eighteen mesocosm experiments were conducted over two years across seasons. Simulated drainage water was loaded into wetlands as batches, with target nitrate-N levels typically …

Correction: Messer, T.L.; Burchell, M.R.; Birgand, F. Comparison Of Four Nitrate Removal Kinetic Models In Two Distinct Wetland Restoration Mesocosm Systems. Water 2017, 9, 517, Tiffany L. Messer, Michael R. Burchell, François Birgand

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The authors wish to make the following corrections to this paper [1]:

(1): The author name “François Bírgand” should be François Birgand.

(2): Reference 38 should be the following:

Birgand, F.; Aveni-Deforge, K.; Smith, B.; Maxwell, B.M.; Horstman, M.; Gerling, A.B.; Carey, C.C. First report of a novel multiplexer pumping system coupled to a water quality probe to collect high temporal frequency in situ water chemistry measurements at multiple sites. Limnol. Oceanogr. Methods 2016, 14, 767–783, doi:10.1002/lom3.10122.

(3): Reference 49 should be the following:

Christensen, P.B.; Nielsen, L.P.; Sørensen, J.; Revsbech, N.P. Denitrification in Nitrate-Rich Streams: Diurnal and Seasonal Variation …

Green And Sustainable Technology For High-Efficiency And Low- Damage Manipulation Of Densely Crosslinked Proteins, Helan Xu, Kaili Song, Bingnan Mu, Yiqi Yang

Department of Agricultural and Biological Systems Engineering: Faculty Publications

A two-step technology using nontoxic and ecofriendly chemicals is developed for the durable setting of densely/highly crosslinked proteins, such as wool and hair. Currently, most technologies for morphological modification are effective only for materials from non-highly-crosslinked proteins and cellulose. Before their morphological change, only water is needed to interrupt hydrogen bonds and ionic linkages, which stabilize the relative positions of molecules in non-highlycrosslinked proteins and cellulose. However, highly crosslinked proteins contain disulfide crosslinks, which are insusceptible to water. Thus, the controlled cleavage of disulfide bonds is required for creating new morphologies of highly crosslinked protein materials, such as hair and …

Differences In Soil Biological Activity By Terrain Types At The Sub-Field Scale In Central Iowa Us, Amy L. Kaleita, Linda R. Schott, Sarah K. Hargreaves, Kirsten S. Hofmockel

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Soil microbial communities are structured by biogeochemical processes that occur at many different spatial scales, which makes soil sampling difficult. Because soil microbial communities are important in nutrient cycling and soil fertility, it is important to understand how microbial communities function within the heterogeneous soil landscape. In this study, a self-organizing map was used to determine whether landscape data can be used to characterize the distribution of microbial biomass and activity in order to provide an improved understanding of soil microbial community function. Points within a row crop field in southcentral Iowa were clustered via a self-organizing map using six …