Civil and Environmental Engineering Commons^™

Adsorption Of Long And Short Per- And Polyfluoroalkyl Substances (Pfas) Onto Granular Activated Carbon And Porous Organic Polymers, Yan Zhang

USF Tampa Graduate Theses and Dissertations

Per- and polyfluoroalkyl substances (PFAS) are man-made environmental contaminants causing increasing global concern due to their adverse effect on environmental and human health. Conventional treatment methods are ineffective in removing short-chain PFAS because of their hydrophilicity and resistance to degradation. This study is to design an appropriate adsorption system to remove both long- and short-chain PFSA at environmentally relevant concentrations and conditions. Four primary research tasks were designed to evaluate the performance of a structurally-tunable and chemically-stable porous organic polymers (POPs) for PFAS removal under realistic environmental conditions, including the assessment of POPs’ performance without co-contaminants (Chapter 2), the assessment …

Exploratory Data-Driven Models For Water Quality: A Case Study For Tampa Bay Water, Sandra Sekyere

USF Tampa Graduate Theses and Dissertations

Water, a crucial resource for sustaining life, covers approximately 70% of the earth's surface. Nonetheless, the quality of water is deteriorating rapidly due to the rapid growth of urban areas and industries, which is a worrying trend causing harm to human health and the ecosystem. Water quality forecasting has a key role in water resources management by enabling effective pollution control, ecosystem monitoring, and decision-making.

Previously, traditional statistical models were used to forecast water quality, but they were unable to examine the non-linear relationships between water quality parameters, and they assumed that all datasets were distributed normally. This study uses …

Resource Recovery From Crew Metabolic Wastes In Lunar And Martian Habitats: Reuse Of Effluent From An Anaerobic Membrane Bioreactor Treating Fecal Organic Matter As Fertilizer Source For Plants, Alexandra A. Smith

USF Tampa Graduate Theses and Dissertations

As humans set their sights on exploration of the Moon and Mars human focused challenges like providing potable water, supplying nutritious food to the astronaut crew, and managing their waste present themselves. There are no readily available resources on the Moon and Mars, therefore nothing should be considered unusable including the organic wastes (i.e., feces and urine) produced by the crew. Fecal matter is not currently recycled and is treated as solid waste. After collection, it is discarded out of the International Space Station where it is incinerated upon re-entry. This approach will not work on the Moon’s surface. There …

Anaerobic Digestion Of Brewery Waste Including Spent Yeast And Hops, Dhanashree Rawalgaonkar

USF Tampa Graduate Theses and Dissertations

Florida is home to more than 300 craft breweries, that brew over a million barrels of beer annually. Brewing is an energy intensive process and produces large quantities of high strength waste including spent grains, yeast, hops, and high strength wastewater. Brewery wastewater, and spent yeast have high Chemical Oxygen Demand (COD) concentrations between 5000 mg/L – 10,000 mg/L, and 200,000 mg/L – 300,000 mg/L respectively. Brewery effluent wastewater is sent to Publicly Owned Treatment Works (POTWs) which implement high surcharges based on the strength of brewery effluent (COD concentration). While some of the spent yeast and hops can be …

Exploring Alternative Electron Donors For Heterotrophic Denitrification At A Water Reclamation Facility In Tampa Bay, Tejas Athavale

USF Tampa Graduate Theses and Dissertations

An excess of nitrogen in water can pose problems, ranging from algal blooms to creating toxic environments for marine life. Therefore, wastewater treatment plants need to remove nitrogen from wastewater during the treatment process. Biological nitrogen removal is one process these plants may use, which commonly involves nitrification and denitrification, converting nitrogen in the form of ammonia to nitrate, and then ultimately nitrogen gas. The process of denitrification often requires an electron donor, and methanol is a common choice. However, it is flammable, and therefore there is a need to explore alternative electron donors. Alternative donors can include manufactured chemicals …

Characteristics And Hydraulic Behavior Of Adsorptive Media For Use In Permeable Reactive Barriers, Shelby Rocha

USF Tampa Graduate Theses and Dissertations

The Cargill ditch is located on the property of Se7en Wetlands, a 1600-ac treatment wetland system in Lakeland, Polk County, Florida. The Se7en Wetlands property was previously utilized for phosphate mining prior to the construction of the system. Nonpoint nutrient sources derived from remnants of abandoned phosphate mines – known as “legacy phosphorus” – become mobilized by stormwater runoff and impair surface water bodies by promoting harmful algal blooms (HABs). Thus, the Cargill ditch likely conveys nutrient rich flow resulting from legacy phosphorus and is thought to be one contributing factor in the occurrence of HABs within the treatment wetland …

Peak And Differential Temperature Determination Of Drilled Shafts, Amanda A. Lewis

USF Tampa Graduate Theses and Dissertations

The term “mass concrete” characterizes a specific concrete condition that typically requires unique considerations to mitigate extreme temperature effects on a structure. Mass concrete has historically been defined by the physical dimensions of a “mass”-ive concrete element with the intent of identifying when differential temperatures may induce early-onset cracking, leading to reduced service life. More recently, in addition to differential temperature considerations, extreme upper temperature limits have been imposed by the American Concrete Institute to prevent long-term concrete degradation. Studies dating back to 2007 show shafts as small as 48 inches in diameter can exceed both differential and peak temperature …

Adiabatic Temperature Rise And Durability Performance Of Slag Blended Concrete, Hai Zhu

USF Tampa Graduate Theses and Dissertations

Performance and durability of slag blended concrete was investigated in this study focusing on slag and cement characteristics. Seven slags with variable Al2O3 content, Al2O3/MgO ratio and fineness were selected for investigation. The eight selected cements included ASTM Type I, Type I(HA), Type II(MH), Type II(MH)(HA), and Type IL(10 and 14). Cementitious materials studied here were subjected to a battery of tests including physical, chemical and mineralogical characterization. Performance and durability testing included heat of hydration measurements, sulfate optimization, external sulfate resistance, adiabatic temperature rise and chloride ingress.

Adiabatic temperature rise was assessed on 60% slag blended concrete, using Type …

Modeling Leachate Treatment Processes In Adsorbent-Amended Hybrid Constructed Wetland, Ishfaqun Nisa

USF Tampa Graduate Theses and Dissertations

Due to their efficiency in removing ammonia nitrogen, Constructed Wetlands (CW) are currently considered a very useful method for on-site leachate treatment. In recent years, the use of adsorbent media in CWs, such as zeolite and biochar, to improve pollutant removal efficiency has been explored and these studies indicate that incorporating zeolite can improve the nitrification process, while the addition of biochar can enhance the denitrification process and the removal of organic compounds. However, studies on mechanistic/process models simulating performance of adsorbent-amended CWs for treating landfill leachate are limited. This study presents simulation results for both unamended and adsorbent-amended hybrid …

The Influence Of Corrosion Mitigating Fluids On Post Tensioned Tendon Grout Properties And Steel To Grout Bond Strength, Sarita Ale Magar

USF Tampa Graduate Theses and Dissertations

Corrosion has been a persistent problem causing the failure of post-tensioned tendons in segmentally constructed bridges. To address this issue, the impregnation method has been considered where the corrosion-mitigating fluids are pressure injected into the interstitial spaces between the seven wires of steel strands. A previous study showed that this method was able to arrest corrosion. However, it compromised the bond strength between the steel and the strand. For that reason, this study aims to identify a fluid that can be impregnated into the interstitial spaces without sacrificing bond performance. The most promising fluid found in the study is an …

Field-Base Exploratory Study Of Microbial Activity In Eight Potable Water Storage Tanks In Barbados, Katelyn M. Long

USF Tampa Graduate Theses and Dissertations

There have been many initiatives to combat the global phenomenon of water scarcity. Potable water storage tanks have become widely known among water insecure countries and communities to provide adequate water quantity and quality for consumer use. Despite ubiquitous use in many low- and middle-income communities (LMIC), knowledge of microbial activity inside potable water storage tanks is limited. Barbados is a Small Island Developing State (SIDS), labeled as a high income country, and also water scarce. The Barbados Water Authority (BWA) has adapted potable water storage tanks for hundreds of residents as a solution to water quantity and water quality …

The Influence Of Bipolar Electrochemical Cell Geometry On The Studies Of Pitting Corrosion, Amin Kazem Ghamsari

USF Tampa Graduate Theses and Dissertations

Bipolar electrochemistry (BPE) is a technique that provides a wireless alternative totraditional electrochemistry to elicit redox reactions. It has been utilized in different applications, including studying localized corrosion, gradient electrodeposition, propulsion of micromotors, and water treatment. The popularity of the method is not solely dependent on its wirelessness but more due to the simultaneous presence of cathodic and anodic poles on the same surface, which also begets its name as bipolar. The concept of the method is based on the polarization of conductive objects in an electric field in the presence of an electrolyte. In BPE, instead of controlling the …

Rehabilitation Technologies To Abate Infiltration In Sanitary Sewers, Steve Youssef

USF Tampa Graduate Theses and Dissertations

In urban coastal environments, sewer infrastructure is plagued by infiltration which seeps into aging and compromised pipes. Infiltration increases pumping costs, reduces treatment efficiency, and may trigger release of partially treated wastewater at water reclamation facilities. To restore pipes and abate infiltration, local utilities rely on structural and non-structural trenchless rehabilitation technologies. These methods are commonly used throughout the United States and the world due to their numerous benefits compared to traditional open-cut construction. However, limited data is available regarding their efficacy in reducing infiltration in sewer systems. In this study, we analysed infiltration in a small urban sewershed in …

Load And Resistance Factor Design (Lrfd) Resistance Factors For Tip Grouted Drilled Shafts, Anhar Sarsour

USF Tampa Graduate Theses and Dissertations

Pressure grouting beneath the tip of drilled shafts, also known as postgrouting, has been used for more than fifty years throughout the world and has shown to be an effective means to enhance both the usable and ultimate end bearing resistance. In short, postgrouting is a form of compaction grouting beneath the shaft tip (performed after concrete has cured) that can improve the soil strength and increase the axial shaft stiffness. Until 2006, there was no published design methodology and hence the anticipated performance was speculated to be a function of injected grout volume, shaft uplift and/or the achieved grout …

Biochar Amended Biological Systems For Enhanced Landfill Leachate And Lignocellulosic Banana Waste Treatment, Xia Yang

USF Tampa Graduate Theses and Dissertations

Biochar is an inexpensive and environmentally friendly carbonaceous pyrolysis byproduct with a high surface area, pore volume, and adsorption capacities for inorganic and organic compounds. The goal of this dissertation is to evaluate the feasibility of biochar application in biological treatment systems for enhanced waste management. Three major objectives guided this research to provide a compressive understanding of biochar enhancement effects on biological treatment systems for contaminant removal, energy recovery, and environmental impacts as well as essential factors influencing biochar production and properties.

In Objective 1 a low-cost hybrid Constructed Wetland (CW) system modified with biochar/zeolite was developed for enhanced …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …

Optimizing Lake Okeechobee Watershed Management And Reservoir Operations For Water Quality Improvement, Osama Mahrous Mossad Tarabih

USF Tampa Graduate Theses and Dissertations

Rivers around the globe have been altered as people have constructed water resources infrastructure to store water for different human needs, causing negative impacts on ecosystem processes and functions. Environmental flows have been introduced to restore deteriorated riverine ecosystems; however, environmental flows have not always been practical or adequate to restore environment conditions in rivers globally. Lake Okeechobee is a large subtropical lake that plays a pivotal role in South Florida water system providing various water demands for the surrounding communities as well as providing crucial services to the ecosystem of South Florida. However, hydrologic alterations and nutrient (phosphorus and …

Corrosion Performance Of Carbon And Galvanized Steel In Calcium Silicate Cement, Maria Cardoso

USF Tampa Graduate Theses and Dissertations

The concrete manufacturing industry has faced challenges with reducing carbon dioxide emissions as it currently produces about 8% of the world’s anthropogenic carbon dioxide emissions. With global atmospheric carbon dioxide concentrations being higher than ever, the solution is urgent. Due to this, a more sustainable type of concrete has been proposed.Calcium silicate cement (CSC) composed of essentially the same raw materials as ordinary portland cement (OPC) cures through the consumption of carbon dioxide rather than hydration like OPC. CSC is being explored as a potential alternative to OPC, however, there is little to no information on its corrosion related durability. …

Statistical Models Of Traffic Injury Severities: The Effects Of Driver Nationality And The Time-Of-Day On Pedestrian Injuries, Asim Alogaili

USF Tampa Graduate Theses and Dissertations

Roadway accidents have long been a major cause of casualties among all roadway users including drivers and pedestrians. Researchers have used various advanced methodologies to precisely identify affecting factors to help policy makers implement safety measures that effectively mitigate such losses. For a variety of reasons such factors, especially those related to roadway users, are subject to constant changes over time. This work investigates, in depth, the effect of multiple variables on the injury severity levels of both drivers and pedestrians using the most recent and advanced methodological approaches.

First, the dissertation starts by investigating factors that significantly contribute to …

Comparison Study Of Consumer’S Perception Toward Urban Air Mobility In The United States And Rest Of The World Using Social Media Information, S M Toki Tahmid

USF Tampa Graduate Theses and Dissertations

Urban Air Mobility (UAM) is a wide concept that will enable access to on-demand air mobility, cargo delivery, medical applications, and emergency services that is run through a connected and integrated transportation system. This study aims to investigate social media data to compare the major topics discussed in the United States and rest of the world and perform a sentiment analysis to see if the comments are positive, negative, or neutral. Twitter was the primary source of information that was used in this thesis, as it is a place where people interact, create, and share information and ideas online. In …

Assessment And Prevention Of Bacterial Regrowth In Stored Household Water In Eastern Coastal Madagascar, Lauren Judah

USF Tampa Graduate Theses and Dissertations

As of 2020, diarrheal diseases were the leading cause of death in Madagascar. A major cause of diarrheal illness is contaminated water, and one crucial aspect of preventing contaminated water is safe household storage. Bacterial regrowth between point-of-collection and household storage has been well established in literature. A frequently implicated source of regrowth is the storage container’s biofilm, which is a community of varying bacteria enclosed in a “slimy” extracellular polymeric substance that forms on surfaces in wet environments and anchors bacteria to those surfaces. The overall goal of this thesis was to quantify and control bacterial regrowth in household …

Elemental Sulfur And Metal Sulfide Minerals For Autotrophic Denitrification: Applications To Aquaculture, Groundwater Treatment, And Domestic Wastewater Treatment, Erica Amah Dasi

USF Tampa Graduate Theses and Dissertations

Nutrient pollution of waterways, from excess N and P, is a global concern that results in harmful impacts the environment, human health, and aquatic animals. This dissertation harnesses sulfur autotrophic denitrification to remove nutrients from groundwater, domestic wastewater, and wastewaters produced from marine recirculating aquaculture systems (RAS). Part 1 evaluates the denitrification performance of woodchips and elemental sulfur in cyclic denitrification filters (WS-CDFs) integrated into marine RAS operated under saline conditions. Part 2 investigates the use of metal sulfide minerals, with and without oyster shells, for supporting nutrient removal from groundwater in batch reactors. Part 3 assesses …

Modified Biosand Filtration Using Aluminum Hydroxide Filter Media To Enhance Fluoride Removal, Joshelyn Guimaray

USF Tampa Graduate Theses and Dissertations

There are over 20 countries whose citizens consume groundwater containing high levels of fluoride, including Nigeria, Mexico, India, China, and Ghana, which all have major health crises when it comes to the safety of their drinking water. Minerals like fluorite contain fluoride which is often found in groundwater aquifers. The minerals release fluoride into the groundwater. Per the World Health Organization (WHO) standard, the maximum contaminant limit for fluoride consumption should be less than 1.5 mg/L. Chronic exposure of elevated levels of fluoride can cause people to suffer debilitating health effects, such as dental and skeletal fluorosis. Dental fluorosis causes …

A Convergent Approach To Aqueous Lead (Pb) Mitigation Of A Supplemental Self-Supply Shallow Groundwater Source Accessed By Handpumps In Madagascar, Adaline Marie Buerck

USF Tampa Graduate Theses and Dissertations

The World Health Organization (WHO) has consistently listed lead (Pb) as one of the ten chemicals of major public health concern. Though the toxic nature of lead has been known since the 20th century it is still utilized in a wide variety of products due to its favorable properties. Exposure to lead still accounts for approximately 900,000 deaths annually and disproportionately impacts those in low- and middle-income countries (LMIC) due to a variety of reasons such as poverty, malnutrition, and lack of knowledge on the toxic nature of lead. Lead exposure routes include air, soil, dust, diet, and water. Though …

Passive Radiative Cooling By Spectrally Selective Nanoparticles In Thick Film Nanocomposites, David Allen Young

USF Tampa Graduate Theses and Dissertations

Passive cooling of buildings is a benefit to society since no energy input is required for space cooling which reduces electricity consumption, fossil fuel burning, and greenhouse gas emissions. When a passive cooling technology radiates heat from the earth through the atmospheric windows to space higher levels of cooling power are possible -- this phenomenon is classified as passive “radiative” cooling. Spectrally selective surface coatings provide radiative cooling to lower surface temperatures by reflecting most solar radiation, while emitting infrared radiation at wavelengths between 8-13 μm through the primary atmospheric window to the cold of space. Multiple applications of radiative …

Fragmentation Of Chemically Herded Oil Slicks By Obstacles: Visualizations, Flow Measurements, And Spatial Distributions, Ali Alshamrani

USF Tampa Graduate Theses and Dissertations

Chemical herders are a promising technique for treatment of oil spills in icy waters at high latitudes. However, obstacles on the water surface such as floating ice affects or interferes with all spill response countermeasures including chemical herder operations by fracturing the contracting oil slick and trapping small oil patches. Chemical herders are likely to be especially useful in containing oil spills in remote, ice-infested Arctic waters, where using booms to contain an oil slick is difficult. Much of the previous research into chemical herder has focused on the effectiveness of different types of chemical herder agents to thicken oil …

Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias

USF Tampa Graduate Theses and Dissertations

Electrocoagulation (EC) is a sustainable water treatment process involving the generation of coagulants on-site through the application of a voltage on metal (usually aluminum or iron alloys). The factors that impact EC system performance have been well researched, however further research is needed on the factors that impact anodic dissolution of aluminum electrodes, especially when the technology is transferred to full-scale applications. Electrode fouling is one of the factors that can impact dissolution of the anode during EC due to the formation of a protective oxide/hydroxide layer on the electrode surface. Previous studies have addressed electrode fouling by reversing polarity, …

Degradation Performance Modeling And Optimal Maintenance Planning Of Deteriorating Critical Infrastructures, Hung Q. Nguyen

USF Tampa Graduate Theses and Dissertations

Serving as the backbone of the nation’s economy, a large and growing number of deteriorating critical infrastructures, such as transportation and water infrastructures, are underperforming, aging, becoming structurally deficient, and must be repaired or replaced. Due to the influence of a variety of factors (e.g., material structure, design, operation, and environmental conditions) at different phases of lifecycle and the costly data acquisition process, field degradation of deteriorating infrastructures is highly uncertain with limited degradation data. The co-location and spatial proximity between many infrastructures, such as road and water infrastructures, further makes them physically and operationally interdependent. The sheer deterioration of …

Simulating Flood Control In Progress Village, Florida Using Storm Water Management Model (Swmm), Azize Minaz

USF Tampa Graduate Theses and Dissertations

Flooding is a natural event caused by heavy rains, melting snow, high tides, and anthropogenic impacts such as channel clogging, improper land use, and deforestation. In this study, the strategies for controlling flooding seek to establish flood prevention systems by implementing grey infrastructure and green infrastructure practices. The main objective of this thesis is to analyze the study area, Progress Village Neighborhood in Delaney Creek Watershed, regarding flood risk and flood mitigation techniques. The analysis was performed using EPA SWMM 5.1 and Arcmap 10.7.1. The study used design storms,10-years 24 hours and 25-years 24 hours, to analyze flood risk in …

Impedance Analysis Of Anodized Aluminum And Structural Bridge Tendons, Justin Silnutzer

USF Tampa Graduate Theses and Dissertations

This is a two-part thesis with the overall investigation technique being electrochemical impedance spectroscopy (EIS). In the first part, EIS is used to estimate the layer thickness of anodized aluminum oxide. This required the development of an appropriate electrical circuit model; that with parameters that correspond to physical properties of the oxide. In this work, it was found that for thicker oxides of which the outer porous layer is greater than 12 microns, impedance may be used to estimate the outer layer thickness. However, further research is required to understand the role of outer porous layer structure on the impedance …