Civil and Environmental Engineering Commons^™

The Effect Of Diffusive Transport On Mineral Carbonation In Geologic Carbon Sequestration, Wei Xiong

McKelvey School of Engineering Graduate Student Theses & Dissertations

Geologic carbon sequestration (GCS) is an effective method to mitigate environmental problems due to excessive anthropogenic CO2 emissions. It involves injecting supercritical CO2 into deep geologic formations in which CO2 will ultimately be converted to solid carbonate minerals. Basalt is a promising host rock that is rich in the divalent cations Ca, Mg and Fe that are important for mineral trapping of CO2. Fractures and pores in basalt reservoirs provide substantial surface area for geochemical reactions during carbon sequestration. The transport in fractures and pores is controlled by diffusion. The coupling of diffusive transport and geochemical reactions leads to carbonate …

2017 Spring Engr333 Seminar Presentation, Jonah Engel, Rich Floro, Björn Krebs, Ethan Postmus, Brendan Biesboer, Kyle Mailhot, Nate Zylstra, Ryan Beezhold, Dillon Carhuff, Ian Mcclaskie, Jared Vanderklay, Rounak Chatterjee, Toby Dalla Santa, Jennifer Haney, Joel Hoskins, Caleb Senyshyn, Alex Meador, Scott Bokach, Devin Auld, Joshua Bronner, Elliot Slenk, Matthew Lenko, Robert Lanser, Ryan Hoek, Cameron Bell, Caleb Bieske, Chris Griffin, Bernice Portugal, Sam Hanover, Dan Wharton, Jay Noyola, Zachary Mouw, John Lee, Daniel Dick, Jonathan Sager, Nathan Swaim, Ellen Reidy, Jordan Swets, Joel Van Dyke, Connor Macdonald, Josiah Markvluwer, Justin Rohlicek, Adam Christensen, Scott Stamper, Aaron Tucker, Bethany Waanders, Joel Schaefer, Maddie Collins, Matthew Cok, Philip Kim, Steve Vanden Berg

ENGR 333

File for student presentation, given by students in the Spring 2017 class of ENGR333.

College Of Engineering Senior Design Competition Spring 2017, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

Development Of A Multiband Remote Sensing System For Determination Of Unsaturated Soil Properties, Cyrus D. Garner

Graduate Theses and Dissertations

A multiband system including active microwave sensing and visible-near infrared reflectance spectroscopy was developed to measure unsaturated soil properties in both field and laboratory environments. Remote measurements of soil volumetric water content (θv), soil water matric potential (ψ), and soil index properties (liquid limit [LL], plastic limit [PL], and clay fraction [CF]) were conducted. Field-based measurement of θv was conducted using a ground-based radar system and field measurements within 10 percentage points of measurements acquired with traditional sampling techniques were obtained. Laboratory-based, visible and near infrared spectroscopy was found to be capable of obtaining empirical, soil specific regression functions (partial …

Generalized Clusterwise Regression For Simultaneous Estimation Of Optimal Pavement Clusters And Performance Models, Mukesh Khadka

UNLV Theses, Dissertations, Professional Papers, and Capstones

The existing state-of-the-art approach of Clusterwise Regression (CR) to estimate pavement performance models (PPMs) pre-specifies explanatory variables without testing their significance; as an input, this approach requires the number of clusters for a given data set. Time-consuming ‘trial and error’ methods are required to determine the optimal number of clusters. A common objective function is the minimization of the total sum of squared errors (SSE). Given that SSE decreases monotonically as a function of the number of clusters, the optimal number of clusters with minimum SSE always is the total number of data points. Hence, the minimization of SSE is …

Using An Altimeter-Derived Internal Tide Model To Remove Tides From In Situ Data, Edward D. Zaron, Richard D. Ray

Civil and Environmental Engineering Faculty Publications and Presentations

Internal waves at tidal frequencies, i.e., the internal tides, are a prominent source of variability in the ocean associated with significant vertical isopycnal displacements and currents. Because the isopycnal displacements are caused by ageostrophic dynamics, they contribute uncertainty to geostrophic transport inferred from vertical profiles in the ocean. Here it is demonstrated that a newly developed model of the main semidiurnal (M2) internal tide derived from satellite altimetry may be used to partially remove the tide from vertical profile data, as measured by the reduction of steric height variance inferred from the profiles. It is further demonstrated that the internal …

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Water, Sanitation And Hygiene In Rwamwanja Refugee Settlement, Katelyn Bergl

Independent Study Project (ISP) Collection

No abstract provided.

Quality Of Water In Relation To Diarrheal Disease Incidence In Obunga, Tianna Herman

Independent Study Project (ISP) Collection

Kenyan cities are experiencing a serious dilemma in dealing with the large influx of people from rural parts of the country to the cities. Most people come to the city in pursuit of better opportunities and jobs. Rapid urban growth with little planning and preparation by the national and county governments has led to the development of informal settlements. These informal settlements are characterized by poor environmental conditions that predispose their residents for poor health conditions. Because of their illegal status, most residents of informal settlements in Kenya do not receive government services such as water, drainage, sewerage, and rubbish …

Solid Waste Management In The Developing World: The Role Of Local Government In Kisumu, Kenya, Rachel Schlueter

Independent Study Project (ISP) Collection

As the world becomes more urbanized, more waste is being produced. According to United Nations projections in 2014, 66% of the world’s population will be living in cities by 2050 with the majority of growth occurring in African cities. Managing urban waste in lower-middle income countries, such as Kenya, poses a particular challenge as income levels rise, municipal capacities are stretched, and foreign loans complicate accountability. This project sought to assess the practical role of local government when managing solid waste in the context of long-term development strategies. The objectives of this study are to first establish the current role …

Remote Measurements Of Tides And River Slope Using An Airborne Lidar Instrument, Austin S. Hudson, Stefan A. Talke, Ruth Branch, Chris Chickadel, Gordon Farquharson, Andrew Jessup

Civil and Environmental Engineering Faculty Publications and Presentations

Tides and river slope are fundamental characteristics of estuaries, but they are usually undersampled due to deficiencies in the spatial coverage of water level measurements. This study aims to address this issue by investigating the use of airborne lidar measurements to study tidal statistics and river slope in the Columbia River estuary. Eight plane transects over a 12-h period yield at least eight independent measurements of water level at 2.5-km increments over a 65-km stretch of the estuary. These data are fit to a sinusoidal curve and the results are compared to seven in situ gauges. In situ– and lidar-based …

Hydrologic Response Caused By Wetland Expansion At Huntley Meadows Park In Hybla Valley, Virginia, Stephen Fraser Stone

OES Theses and Dissertations

The goal of this study was to understand the effects of wetland expansion across a watershed. The 2013 restoration and expansion of the wetlands at Huntley Meadows Park (Fairfax County, VA) performed by Wetland Studies and Solutions, Inc. provided the opportunity to study this process. The 630 ha park contains more than 364 ha of freshwater emergent and freshwater forested wetlands. The restoration and expansion project used a subsurface vinyl-piling dam that impedes groundwater flow leaving the wetland, thus expanding the existing pond and the surrounding wetland.

This study used a network of more than twenty monitoring instruments making observations …

Influence Of Internal Variability On Population Exposure To Hydroclimatic Changes, Justin S. Mankin, Daniel Viviroli, Mesfin Mekonnen, Arjen Y. Hoekstra, Radley M. Horton, Jason E. Smerdon, Noah S. Diffenbaugh

Daugherty Water for Food Global Institute: Faculty Publications

Future freshwater supply, human water demand, and people’s exposure to water stress are subject to multiple sources of uncertainty, including unknown future pathways of fossil fuel and water consumption, and ‘irreducible’ uncertainty arising from internal climate system variability. Such internal variability can conceal forced hydroclimatic changes on multi-decadal timescales and near-continental spatial-scales. Using three projections of population growth, a large ensemble from a single Earth system model, and assuming stationary per capita water consumption, we quantify the likelihoods of future population exposure to increased hydroclimatic deficits, which we define as the average duration and magnitude by which evapotranspiration exceeds precipitation …

Modeling The Movement Of Septic Water Chloride Through A Soil Profile, Shawkat Kochary, Tom Byl, Bahzad Noori

Civil and Architectural Engineering Faculty Research

The purpose of this study was to investigate the movement of chloride through a vadose zone located under failed and non-regulated septic tanks of Duhok city, Kurdistan of Iraq, potentially contaminating its groundwater. A physical vadose model (PVM) of a vertical flow direction was built in the laboratory to represent the city soil profile. The size of the PVM was 210 × 122 × 9.7 cm (height, width, and depth). Preliminary soil tests were conducted to better represent the lithology of study area. The PVM was then packed with regional silt clay soil, after modifying its texture, using an innovative …

The Impacts Of Climate Change And Anthropogenic Processes On Permafrost Soils And Usaf Infrastructure Within Northern Tier Bases, Alexander J. Graboski

Theses and Dissertations

The Department of Defense is planning over $552M in military construction on Eielson Air Force Base within the next three fiscal years. Although many studies have been conducted on permafrost and climate change, the future of our climate as well as any impacts on permafrost soils, remains unclear. This research focused on future climate predictions to determine likely scenarios for the United States Air Force’s Strategic Planners to consider. The most recent 2013 International Panel on Climate Change report predicts a 2.2ºC to 7.8ºC temperature rise in Arctic regions by the end of the 21st Century in the Representative Concentration …

Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt

Theses and Dissertations

This research investigated the efficacy of granular activated carbon (GAC) as a method to treat water impacted with aqueous film forming foam (AFFF) after a firefighting response. Bench-top experiments were conducted and compared to field scale adsorber performance removing mg/L concentrations of PFAS in water contaminated with Military Specification AFFF. Batch tests compared four adsorbents, and determined Calgon F600 GAC and Rembind Plus mixed carbon media had the greatest perfluorooctane sulfonate (PFOS) capacities. Additional batch isotherm experiments using AFFF and higher PFOS concentrations (mg/L) indicated larger amounts of GAC are required (>30mg/L) for effective removal. Full-scale testing simulated an …

Proof Of Concept: Development Of Snow Liquid Water Content Profiler Using Cs650 Reflectometers At Caribou, Me, Usa, Carlos L. Pérez Díaz, Jonathan Muñoz, Tarendra Lakhankar, Reza Khanbilvardi, Peter Romanov

Publications and Research

The quantity of liquid water in the snowpack defines its wetness. The temporal evolution of snow wetness’s plays a significant role in wet-snow avalanche prediction, meltwater release, and water availability estimations and assessments within a river basin. However, it remains a difficult task and a demanding issue to measure the snowpack’s liquid water content (LWC) and its temporal evolution with conventional in situ techniques. We propose an approach based on the use of time-domain reflectometry (TDR) and CS650 soil water content reflectometers to measure the snowpack’s LWC and temperature profiles. For this purpose, we created an easily-applicable, low-cost, automated, and …

Application Of Numerical Modeling To Study River Dynamics: Hydro-Geomorphological Evolution Due To Extreme Events In The Sandy River, Oregon, Sarkawt Hamarahim Muhammad

Dissertations and Theses

The Sandy River (OR) is a coastal tributary of the Columbia River and has a steep hydroshed 1316 square kilometers which is located on the western side of Mount Hood (elevation range 3 m to 1800 m). The system exhibits highly variable flow: Its average discharge is ~40 m³/s, and the highest recorded discharge was 1739 m³/s in 1964. In this study I model the geomorphic sensitivity of an 1800m reach located the downstream of the former Marmot Dam, which was removed in 2007. The hydro-geomorphic response to major flood has implications for system management and …

A Comparison Of Modis/Viirs Cloud Masks Over Ice-Bearing River: On Achieving Consistent Cloud Masking And Improved River Ice Mapping, Simon Kraatz, Reza Khanbilvardi, Peter Romanov

Publications and Research

The capability of frequently and accurately monitoring ice on rivers is important, since it may be possible to timely identify ice accumulations corresponding to ice jams. Ice jams are dam-like structures formed from arrested ice floes, and may cause rapid flooding. To inform on this potential hazard, the CREST River Ice Observing System (CRIOS) produces ice cover maps based on MODIS and VIIRS overpass data at several locations, including the Susquehanna River. CRIOS uses the respective platform’s automatically produced cloud masks to discriminate ice/snow covered grid cells from clouds. However, since cloud masks are produced using each instrument’s data, and …

Application Of Gis To Prioritize Brownfield Sites For Green Building Construction Based On Leed Criteria, Can B. Aktas, Paul Bartholomew, Sabrina Church

Civil Engineering Faculty Publications

Although there are many initiatives to create incentives for investors and developers to invest in and redevelop brownfield sites, efficient prioritization of brownfields by taking into account environmental, economic, and social constraints remains a challenge. This study introduces a method to screen numerous brownfields over large geographic areas by using geographic information systems (GIS) and to assess and prioritize such sites for green building suitability based on leadership in energy and environmental design (LEED) criteria. A case study was completed for the greater Bridgeport, Connecticut region. With 279 brownfield sites, the city has among the highest number of brownfields in …

Carnarvon Artesian Desalination Feasibility Study, Ghd, Carnarvon Growers Association, Gascoyne Water Co-Operative

Research Reports

Study scope

The scope of the study is summarised below;

 Review existing data and previous work,

 Visit Carnarvon (1 day), inspect water system facilities and convene Stakeholder Workshop No 1 with representatives from Carnarvon Growers Association, Gascoyne Water Co-operative and DAFWA. Agree 3 – 4 possible system configuration options to be investigated.

 Obtain and examine existing water quality data for artesian bore(s) incorporated within the study. Assess probable long term water quality and pumping heads.

 Develop preliminary design details for the agreed options in terms of pre-treatment, desalination and other system modifications required (eg bores, pump …

Air Exchange Rates And Alternatuve Vapor Entry Pathways To Inform Vapor Intrusion Exposure Risk Assessments, Rivka Reichman, Mohammadyousef Roghani, Evan J. Willett, Elham Shirazi, Kelly G. Pennell

Civil Engineering Faculty Publications

Vapor intrusion (VI) is a term used to describe indoor air (IA) contamination that occurs due to the migration of chemical vapors in the soil and groundwater. The overall vapor transport process depends on several factors such as contaminant source characteristics, subsurface conditions, building characteristics, and general site conditions. However, the classic VI conceptual model does not adequately account for the physics of airflow around and inside a building and does not account for chemical emissions from alternative “preferential” pathways (e.g. sewers and other utility connections) into IA spaces. This mini-review provides information about recent research related to building air …

Benzene Formation In Electronic Cigarettes, James F. Pankow, Kilsun Kim, Kevin J. Mcwhirter, Wentai Luo, Jorge O. Escobedo, Robert M. Strongin, Anna K. Duell, David H. Peyton

Chemistry Faculty Publications and Presentations

The heating of the fluids used in electronic cigarettes (“e-cigarettes”) used to create “vaping” aerosols is capable of causing a wide range of degradation reaction products. We investigated formation of benzene (an important human carcinogen) from e-cigarette fluids containing propylene glycol (PG), glycerol (GL), benzoic acid, the flavor chemical benzaldehyde, and nicotine.

Mass Exchange Dynamics Of Surface And Subsurface Oil In Shallow-Water Transport, Saeed Moghimi, Jorge Ramirez, Juan M. Restrepo, Shankar Venkataramani

Civil and Environmental Engineering Faculty Publications and Presentations

We formulate a model for the mass exchange between oil at and below the sea surface. This is a particularly important aspect of modeling oil spills. Surface and subsurface oil have different chemical and transport characteristics and lumping them together would compromise the accuracy of the resulting model. Without observational or computational constraints, it is thus not possible to quantitatively predict oil spills based upon partial field observations of surface and/or sub-surface oil. The primary challenge in capturing the mass exchange is that the principal mechanisms are on the microscale. This is a serious barrier to developing practical models for …

Using Satellite Observations To Characterize The Response Of Estuarine Turbidity Maxima To External Forcing, Austin S. Hudson, Stefan A. Talke, David A. Jay

Civil and Environmental Engineering Faculty Publications and Presentations

This study explores the spatial and temporal character of turbidity maxima in the Columbia River Estuary (CRE) using satellite observations. Surface reflectance data measured by the Moderate Imaging Spectroradiometer (MODIS) were calibrated against in situ measurements of surface turbidity (R2 = 0.85 for 205 measurements). More than 1500 satellite images from 2000 to 2015 were then conditionally sampled to explore the physical processes that drive the spatial distribution of the turbidity field. We find satellite measurements are able to describe seasonal, spring–neap, and spatial features of the estuarine turbidity maxima (ETM) that are not easily observable by other means. System-wide …

Hydrodynamic And Water Quality Modeling Of The Chehalis River Using Ce-Qual-W2, Sarah Van Glubt

Dissertations and Theses

The Chehalis River Basin is located in the southwest region of Washington State, originating in the Olympic Mountains and flowing to Grays Harbor and the Pacific Ocean. The Chehalis River is over 125 miles, exists within five counties, and flows through agricultural, residential, industrial, and forest land areas. Four major rivers discharge to the Chehalis River, as well as many smaller creeks, five wastewater treatment plants, and groundwater flows.

Flooding is a major problem in the relatively flat areas surrounding the cities of Chehalis and Centralia, with severe consequences for property, safety and transportation. As a result, construction of a …

Nitrate Radicals And Biogenic Volatile Organic Compounds: Oxidation, Mechanisms And Organic Aerosol, Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Hermann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert Mclaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, Rahul A. Zaveri

Chemistry Faculty Publications

Oxidation of biogenic volatile organic compounds (BVOC) by the nitrate radical (NO₃) represents one of the important interactions between anthropogenic emissions related to combustion and natural emissions from the biosphere. This interaction has been recognized for more than 3 decades, during which time a large body of research has emerged from laboratory, field, and modeling studies. NO₃-BVOC reactions influence air quality, climate and visibility through regional and global budgets for reactive nitrogen (particularly organic nitrates), ozone, and organic aerosol. Despite its long history of research and the significance of this topic in atmospheric chemistry, a number …

Wildfire In Utah: The Physical And Economic Consequences Of Wildfire, Paul Mark Jakus, Man-Keun Kim, Randy S. Martin, Ian Hammond, Edd Hammill, Nancy O. Mesner, Jacob Stout

Watershed Sciences Faculty Publications

PRELUDE

On June 26, 2012 a lightning strike ignited a wildfire in the Manti-La Sal National Forest of central Utah’s Carbon and Emery counties (Figure P.1). By the time the Seeley wildfire was contained three weeks later, some 48,000 acres of federal, state, and private land had been burned and $8.7 million in suppression costs expended (Styler 2012). According to the Monitoring Trends in Burn Severity (MTBS.gov) project, nearly one-third of the acreage was severely burned, damaging vegetation and soils for years to come. Severe burns vastly increase the erosion potential of burnt landscapes, and the steep lands of Huntington …

Remediating 1,4-Dioxane-Contaminated Water With Slow-Release Persulfate And Zerovalent Iron, Ann Kambhu, Megan Gren, Wei Tang, Steve D. Comfort, Clifford Harris

Nebraska Water Center: Faculty Publications

1,4-dioxane is an emerging contaminant that was used as a corrosion inhibitor with chlorinated solvents. Metal-activated persulfate can degrade dioxane but reaction kinetics have typically been characterized by a rapid decrease during the first 30 min followed by either a slower decrease or no further change (i.e., plateau). Our objective was to identify the factors responsible for this plateau and then determine if slow-release formulations of sodium persulfate and Fe⁰ could provide a more sustainable degradation treatment. We accomplished this by conducting batch experiments where Fe⁰-activated persulfate was used to treat dioxane. Treatment variables included the timing …