Civil and Environmental Engineering Commons^™

Modified Biosand Filtration Using Aluminum Hydroxide Filter Media To Enhance Fluoride Removal, Joshelyn Guimaray

USF Tampa Graduate Theses and Dissertations

There are over 20 countries whose citizens consume groundwater containing high levels of fluoride, including Nigeria, Mexico, India, China, and Ghana, which all have major health crises when it comes to the safety of their drinking water. Minerals like fluorite contain fluoride which is often found in groundwater aquifers. The minerals release fluoride into the groundwater. Per the World Health Organization (WHO) standard, the maximum contaminant limit for fluoride consumption should be less than 1.5 mg/L. Chronic exposure of elevated levels of fluoride can cause people to suffer debilitating health effects, such as dental and skeletal fluorosis. Dental fluorosis causes …

A Convergent Approach To Aqueous Lead (Pb) Mitigation Of A Supplemental Self-Supply Shallow Groundwater Source Accessed By Handpumps In Madagascar, Adaline Marie Buerck

USF Tampa Graduate Theses and Dissertations

The World Health Organization (WHO) has consistently listed lead (Pb) as one of the ten chemicals of major public health concern. Though the toxic nature of lead has been known since the 20th century it is still utilized in a wide variety of products due to its favorable properties. Exposure to lead still accounts for approximately 900,000 deaths annually and disproportionately impacts those in low- and middle-income countries (LMIC) due to a variety of reasons such as poverty, malnutrition, and lack of knowledge on the toxic nature of lead. Lead exposure routes include air, soil, dust, diet, and water. Though …

Fragmentation Of Chemically Herded Oil Slicks By Obstacles: Visualizations, Flow Measurements, And Spatial Distributions, Ali Alshamrani

USF Tampa Graduate Theses and Dissertations

Chemical herders are a promising technique for treatment of oil spills in icy waters at high latitudes. However, obstacles on the water surface such as floating ice affects or interferes with all spill response countermeasures including chemical herder operations by fracturing the contracting oil slick and trapping small oil patches. Chemical herders are likely to be especially useful in containing oil spills in remote, ice-infested Arctic waters, where using booms to contain an oil slick is difficult. Much of the previous research into chemical herder has focused on the effectiveness of different types of chemical herder agents to thicken oil …

Exploring Toluene Biosynthesis In Microbial Consortia Derived From Sediments And Superfund Site Groundwater, Raymond J. Poche

LSU Master's Theses

While the aromatic hydrocarbon toluene is widely regarded as a contaminant associated with discharges of crude oil and refined petroleum products (e.g., gasoline), the enzyme phenylacetate decarboxylase catalyzes the decarboxylation of phenylacetate to yield toluene. Research described in this thesis further investigated toluene biosynthesis by a microbial consortium originating from chlorinated solvent-contaminated groundwater near Baton Rouge, Louisiana. In anoxic growth media supplemented with phenylacetate as a precursor, toluene accumulation was found to be maximal at near-neutral to slightly acidic pHs (toluene accumulation greater than 1 mg/L at pH in the range of 5.6 to 7.6, but was not observed for …

Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias

USF Tampa Graduate Theses and Dissertations

Electrocoagulation (EC) is a sustainable water treatment process involving the generation of coagulants on-site through the application of a voltage on metal (usually aluminum or iron alloys). The factors that impact EC system performance have been well researched, however further research is needed on the factors that impact anodic dissolution of aluminum electrodes, especially when the technology is transferred to full-scale applications. Electrode fouling is one of the factors that can impact dissolution of the anode during EC due to the formation of a protective oxide/hydroxide layer on the electrode surface. Previous studies have addressed electrode fouling by reversing polarity, …

Design And Commissioning Of An E-Beam Irradiation Beamline At The Upgraded Injector Test Facility At Jefferson Lab, Xi Li, Helmut Baumgart, Charles Bott, Gianluigi Ciovati, Shaun Gregory, Fay Hannon, Mike Mccaughan, Robert Pearce, Matthew Poelker, Hannes Vennekate, Shaoheng Wang

Electrical & Computer Engineering Faculty Publications

The Upgraded Injector Test Facility (UITF) at Jefferson Lab is a continuous-wave superconducting linear accelerator capable of providing an electron beam with energy up to 10 MeV. A beamline for electron-beam irradiation has been designed, installed and successfully commissioned at this facility, aimed at the degradation study of 1,4-dioxane and per- and polyfluoroalkyl substances (PFAS) in wastewater treatment. A solenoid with a peak axial magnetic field of up to 0.28 T and a set of raster coils were used to obtain a Gaussian beam profile with a transverse standard deviation of ∼15.0 mm at the target location. Monte-Carlo simulations using …

Characterizing The Chemical And Microbial Fingerprint Of Unsheltered Homelessness In An Urban Watershed, Daniel Gerrity, Katerina Papp, Eric Dickenson, Meena Ejjada, Erica Marti, Oscar Quinones, Mayra Sarria, Kyle Thompson, Rebecca A. Trenholm

Civil and Environmental Engineering and Construction Faculty Research

Unsheltered homelessness is rapidly becoming a critical issue in many cities worldwide. The worsening situation not only highlights the socioeconomic plight, but it also raises awareness of ancillary issues such as the potential implications for urban water quality. The objective of this study was to simultaneously leverage diverse source tracking tools to develop a chemical and microbial fingerprint describing the relative contribution of direct human inputs into Las Vegas' tributary washes. By evaluating a wide range of urban water matrices using general water quality parameters, fecal indicator bacteria (FIB), human-associated microbial markers [e.g., HF183, crAssphage, and pepper mild mottle virus …

Axial Hypersensitivity Is Associated With Aberrant Nerve Sprouting In A Novel Model Of Disc Degeneration In Female Sprague Dawley Rats, David J. Lillyman, Fei San Lee, Evie C. Barnett, Tyler J. Miller, Moreno Lozano Alvaro, Henry C. Drvol, Rebecca A. Wachs

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Chronic low back pain is a global socioeconomic crisis and treatments are lacking in part due to inadequate models. Etiological research suggests that the predominant pathology associated with chronic low back pain is intervertebral disc degeneration. Various research teams have created rat models of disc degeneration, but the clinical translatability of these models has been limited by an absence of robust chronic painlike behavior. To address this deficit, disc degeneration was induced via an artificial annular tear in female Sprague Dawley rats. The subsequent degeneration, which was allowed to progress for 18-weeks, caused a drastic reduction in disc volume. Furthermore, …

Understanding Ch4 Emissions From Compostables: An Exploration Of Local Ch4 Emissions From Landfilled Compostables And The Efficacy Of Emission Mitigation Via Anaerobic Biogas Digestion, Jordan-Yoosuf Aljbour

University Honors Theses

Methane (CH₄) is the second most abundant anthropogenic greenhouse gas within the atmosphere, comprising ~16% of the total anthropogenic greenhouse gas composition on Earth. It has an ~12-year lifetime relative to its eventual oxidation via reaction with tropospheric hydroxyl radicals (OH), and has a 100-year indirect global warming potential (GWP) approximately ranging between 28-36 [Environmental Protection Agency, 2021]. In recent years, the observed average global concentration of atmospheric CH₄ has increased by ~11.0% from 2020 (~15.3 ppb) to 2021 (~17.0 ppb) [Dlugokencky et al., 1994; National Oceanic and Atmospheric Administration, 2022]. With …

Effects Of Experimental Scale On The Adsorption Of Two Pharmaceutical Drugs Detected In Municipal Wastewater Effluent, Michael Moore

Master's Theses

Pharmaceutical drugs are being produced and consumed in increasing quantities every year and are poorly treated by conventional wastewater treatment processes, leading to increasing detection of such compounds in surface water, groundwater, and municipal drinking water. Soil aquifer treatment (SAT) is a promising method for treating these emerging compounds through combined adsorption and degradation of target compounds in soil. This thesis examines the consistency of results from typical studies like adsorption isotherms and soil columns utilized in analysis of SAT performance, across varying experimental scales. The adsorption behavior of two pharmaceuticals was investigated as a function of experimental scale and …

Using Metal-Organic Frameworks (Mof) To Reduce The Carbon Footprint Of Concrete, Mona Ibrahim El-Hallak

Theses

The production of concrete by the construction industry has a massive impact on the environment. The process of manufacturing its main component, cement, releases a considerable amount of anthropogenic carbon dioxide. This thesis is concerned with the production of sustainable and eco-friendly concrete that integrates metal-organic frameworks (MOF) to capture and offset the CO₂ emissions emitted during the production of cement. The main objective is to synthesize a MOF capable of capturing CO₂ in concrete through accelerated carbonation curing and to assess its impact on concrete performance. Different parameters were examined, including the MOF content, initial curing duration, …

Numerical Modelling Of Externally-Bonded Fiber Reinforced Polymer Shear-Strengthened Reinforced Concrete Beams Subjected To Fatigue Loading, Nagwa Ibrahim Fares

Theses

An extensive number of existing structures persistently exposed to fatigue loading such as bridges, offshore structures, pavements, and highways, are in urgent need of repairing and strengthening. This may be attributed to the continuous increase in the load requirements, change of the structure’s function, and meeting current load standards. Among the potential methods of rehabilitation and strengthening of existing reinforced concrete structures, the externally bonding fiber reinforced polymers (FRP) composites are gaining massive popularity and becoming a viable and cost-effective method. Shear failure of reinforced concrete (RC) beams is known to be brittle, which occurs without prior sufficient warnings; therefore, …

Understanding The Interfacial Processes Of Reactive Nanobubbles Toward Agricultural Applications, Xiaonan Shi

Dissertations

There is a growing interest in nanobubble (NB) technology because of its diverse applications (e.g., detergent-free cleaning, water aeration, ultra-sound imaging and intracellular drug delivery, and mineral processing). NBs have a higher efficiency of mass transfer compared to bulk scale bubbles due to the high specific surface areas. The high specific surface also facilitates physical adsorption and chemical reactions in the gas liquid interface. Furthermore, the collapse of NBs creates shock waves and the formation of hydroxyl radicals (OH).

However, it remains elusive why or how NBs are stabilized in water and particularly, the states of internal pressures of NBs …

Reactive Iron Mineral Coatings In Redox Transition Zones Of A Site With Historical Contamination: Abiotic Attenuation, Xin Yin

Dissertations

Reactive iron mineral coatings are found throughout reduction-oxidation (redox) transition zones and play a significant role in contaminant transformation processes. In this study, an 18.3-meter core is collected, subsampled, and preserved under anoxic conditions to maintain its original redox state. Screening analyses are conducted at sampling increments of 5.08 cm in depth for the following: elemental concentrations with X-ray fluorescence (XRF), sediment pH, sediment oxidation-reduction potential (ORP), total volatile organic carbon (TVOC) in the sample headspace, and abundant bacteria (16S rRNA sequencing). Using the Fe and S gradients correlated with microbial data, five RTZs are delineated. To characterize iron mineral …

Hydrodynamic Limitations To Mangrove Seedling Retention In Subtropical Estuaries, Kelly M. Kibler, Christian Pilato, Linda Walters, Melinda Donnelly, Jyotismita Taye

Flow-biota Interaction and Natural Infrastructure Design

Mangrove forest sustainability hinges upon propagule recruitment and seedling retention. This study evaluates biophysical limitations to mangrove seedling persistence by measuring anchoring force of two mangrove species (Rhizophora mangle and Avicennia germinans). Anchoring force was measured in 362 seedlings via lateral pull-tests administered in mangrove forests of two subtropical estuaries and in laboratory-based experiments. Removal mechanism varied with seedling age: newly-established seedlings failed due to root pull-out while seedlings older than 3 months failed by root breakage. Anchoring force of R. mangle seedlings was consistently and significantly greater than A. germinans (GLM: p = 0.002), however force to …

A Circular Economy Approach To Improve E-Waste Recycling In California: Economic Potential And Policy Options, Kripa Shah

Master's Projects and Capstones

The higher consumption rates of electronic devices along with their short life cycles and few repair options poses a huge challenge for E-waste industries to manage them effectively. E-waste comprises of hazardous materials and toxic constituents that can affect the environment and public health through improper disposal. However, they also contain few valuable materials that, if recovered, can reduce the dependence on virgin raw materials. Circular economy has the potential to utilize these valuable materials and gain environment and socio-economic benefits. The research explains how the adoption of a circular economy approach can help improve the E-waste recycling in California …

A Segmentation-Guided Deep Learning Framework For Leaf Counting, Xijian Fan, Rui Zhou, Tardi Tjahjadi, Sruti Das Choudhury, Qiaolin Ye

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Deep learning-based methods have recently provided a means to rapidly and effectively extract various plant traits due to their powerful ability to depict a plant image across a variety of species and growth conditions. In this study, we focus on dealing with two fundamental tasks in plant phenotyping, i.e., plant segmentation and leaf counting, and propose a two-steam deep learning framework for segmenting plants and counting leaves with various size and shape from two-dimensional plant images. In the first stream, a multi-scale segmentation model using spatial pyramid is developed to extract leaves with different size and shape, where the fine-grained …

Towards A Cybersecurity Testbed For Agricultural Vehicles And Environments, Mark Freyhof, George Grispos, Santosh Pitla, Cody Stolle

Department of Agricultural and Biological Systems Engineering: Faculty Publications

In today’s modern farm, an increasing number of agricultural systems and vehicles are connected to the Internet. While the benefits of networked agricultural machinery are attractive, this technological shift is also creating an environment that is conducive to cyberattacks. While previous research has focused on general cybersecurity concerns in the farming and agricultural industries, minimal research has focused on techniques for identifying security vulnerabilities within actual agricultural systems that could be exploited by cybercriminals. Hence, this paper presents STAVE – a Security Testbed for Agricultural Vehicles and Environments – as a potential solution to assist with the identification of cybersecurity …

Environmental Impact And Life Cycle Assessment Of Biomass Supported Power Systems For Rural Communities, Hariteja Nandimandalam

Theses and Dissertations

Dependence on fossil fuels in the electric sector is one of the major contributors towards Greenhouse gas (GHG) emissions. The increase in renewable contribution has been observed in recent years but there is still potential to utilize wood waste in rural communities for electricity generation promoting energy independence and sustainable development. For this study, a life cycle assessment approach was utilized to estimate the emissions of electricity produced from wood residue in a rural community. Therefore, the process from planting to supply for bioenergy facility to generate electricity are included. The results showed a decrease of 92-96 % in global …

The Living Breakwaters Pdr Efforts: Conceptual Scheduling, Calvin O. Walters Jr.

Publications and Research

On October 29, 2012, Superstorm Sandy caused nearly $19 billion in damages in New York City including 69,000 residential units across the five boroughs. This disaster precipitated a post-disaster-rebuilding (PDR) project including roughly $4.2 billion in a Community Development Block Grant allocated towards PDR projects. A portion of the grant was used to construct a living breakwater in Tottenville, Staten Island, consisting of a resiliency approach to risk reduction through erosion prevention, wave energy attenuation, and enhancement of ecosystems and social resiliency to improve resistance to storms for the community of Tottenville. The ridges of each breakwater are designed with …

Sustainability In Construction Practices As Emphasis On Environmental Investing In Esg Model Grows, Maddie Heal

Management Undergraduate Honors Theses

The purpose of this research is to emphasize the importance of growing investment on environmental initiatives in business ESG models in regard to sustainable practices in construction. The ESG acronym is known as the environmental, social, and governance efforts that businesses strive to incorporate in their models to increase the responsibility of operations.

Investors continue to seek out responsible businesses when choosing which ventures to pursue. The analysis of the current construction crisis, current investments in the right direction of Eco-friendly design regarding construction, and the threats and benefits incentivizing those investments elucidates the need to emphasize socially responsible investment …

Port Infrastructure Resilience Through Combined Wind-Surge Demand Characterization, Kaley Callaway

Graduate Theses and Dissertations

The United States economy is reliant on maritime transportation for 70% of imports and exports. Structures that are integral to the operation of ports, such as cranes, are jeopardized when tropical storms approach land. While wind is the only environmental load used to design dockside container cranes, storm surge often accompanies severe wind events and can create large structural loads. This study focuses on determining coupled storm-surge demands and the effect of waves on dockside container cranes. A damage index prediction tool that considers both maximum wind speed and storm surge height is developed and applied to historical hurricane data …

Improving Efficiency At El Paso Water Canal Plant, Angel Bustamante

Open Access Theses & Dissertations

AbstractThis project focused on the savings associated with filter backwash and rewash water at the Canal plant. Canal plant is a conventional surface water plant owned and operated by El Paso Water. Approximately 330,000 gallons of backwash water and 84,500 gallons of rewash water are lost daily during normal operational conditions. The combined 414,500 gallons of water are equivalent to 1.27 acre feet per day. During a full eight-month surface water season, this is 305 acre feet. With the goal of optimizing the plant, residuals waste streams can be recycled to the head of the treatment plant. However, there is …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Exploring The Effects Of Varied Land Use On Elemental Concentrations Within Streams, Logan Jennings

Biological and Agricultural Engineering Undergraduate Honors Theses

It is well documented that human activity influences the chemistry of surrounding waters. As such, it is possible that there is a link between land use within a watershed and the chemical composition of the stream. The objectives of this study are to determine if varied land use does affect the concentrations of macronutrients and trace elements present in the streams of Northwest Arkansas, and if so, to determine what extent urban and agricultural development are responsible for these changes. Water samples were collected across 19 streams in the Northwest Arkansas region between January and March of 2022. Water samples …

The Control Strategies Of Brominated Organic Disinfection By-Products: Adsorption With Pre-Chlorination And Photodegradation, Cagri Utku Erdem

All Dissertations

Increasing water pollution, scarcity, and seasonal events force water treatment plants to improve existing treatment techniques and/or implement new methods to enhance drinking water treatment and comply with disinfection by-product (DBP) regulations. A limited number of studies examine the pre-chlorination prior to activated carbon (AC) adsorption for the removal of DBP precursors, and there are no comprehensive and representative treatment conditions in current literature. Although many studies investigated photodegradation of individual DBPs by low pressure ultraviolet (UV₂₅₄) light, there is still lack of information and limited understanding of photodegradation of total organic halogens and practical implications of UV …

Calcium Ferrite As A Semiconductor For Microbially Assisted Photocatalytic Reduction Of Carbon Dioxide, Lauren King

Honors Scholar Theses

The pressing issue of global climate change has been found to be attributed to the increasing concentration of greenhouse gases in the atmosphere, especially carbon dioxide. One mitigation idea to close the carbon loop is to utilize redox reactions and photocatalysis to reduce carbon dioxide to a useable fuel source, like methane or methanol. This thesis will study the possibility of using calcium ferrite as the semiconductor to perform photocatalytic reduction of carbon dioxide with the assistance of a microbial fuel cell, which will help minimize the energy required from sunlight photons. A calcium ferrite thin film was produced through …

Floating Treatment Wetlands For Brackish Waters: Plant Selection And Nutrient Uptake Potential., Andrea Landaverde

All Theses

Brackish water bodies in coastal regions provide critical ecosystem services that support human and environmental health. Anthropogenic activities such as agricultural and industrial activities, construction, urban settlements, and tourism contribute to increased inputs of nitrogen (N) and phosphorus (P) in brackish coastal ecosystems. Excess nutrients can lead to impaired water quality and affect marine organisms. Floating treatment wetlands (FTWs) are a vegetated-base technology used to remove contaminants from water column, that has been mainly studied and applied in freshwater systems. Application of FTWs in brackish systems requires further investigation, as high salinity in brackish waters could result in toxicity to …

Wetland Uranium Transport Via Iron-Organic Matter Flocs And Hyporheic Exchange, Connor J. Parker

All Dissertations

Uranium (U) released from the M-Area at the Department of Energy Savannah River Site into Tims Branch, a seasonal wetland and braided stream system, is estimated to be 43,500 kg between 1965 and 1984. The motivation for this work is the uranium’s persistence in the wetland for decades, where it is estimated that 80% of the U currently remains in the Tims Branch wetland. U has begun to incorporate into wetland iron (Fe) and carbon cycles, associating with local Fe mineralogy and deposits of rich wetland organic matter (OM). The objective of this work is to characterize the chemical phases …

Characterization Of Water Flow And Solute Transport Driven By Preferential Flow In Soil Vadose Zone, Abdullah Al Mamun

All Dissertations

The vadose zone acts as a buffer zone between the ground surface and the aquifers underneath and controls the transmission of infiltrating water and contaminants, for example, pesticides and chemical spills. Therefore, understanding the flow and transport processes that dominate the vadose zone is important. Macropores are ubiquitous and particularly found in abundance in the vadose zone. These macropores facilitate preferential flow, through which water travels rapidly deep into the soil, bypassing most of the porous matrix. Preferential flow and transport have environmental significance as their processes impact hydrology, ecology, agriculture, subsurface contamination, and waste management sectors. Thus, the overall …