Civil and Environmental Engineering Commons^™

Comparison Of The Effectiveness Of Alternative Ferrate (Vi) Synthesis Formulas As Disinfectants For Wastewater And River Water, Rachelle Ginart

Electronic Theses and Dissertations

Ferrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of hypochlorite (Low Chlorine Formula) while the other ferrate (VI) synthesis formula uses more than the stoichiometric requirement of hypochlorite (Standard Chlorine Formula). For applications requiring low chlorine residual effluent …

Impact Of Corrosion Inhibitor Blended Orthophosphate On Water Quality In Water Distribution Systems, Abdulrahman Alshehri

Electronic Theses and Dissertations

The impact of blended orthophosphate (BOP) inhibitor addition on the corrosion of iron, copper, and lead in drinking water distribution systems was studied under changing water quality environment. Release of iron, copper, and lead were monitored at varying inhibitor doses and changing blends of source waters (groundwater, surface water, and desalinated water). Solid corrosion products on pipe surfaces under BOP treatment were evaluated with surface characterization techniques. Performance of the BOP inhibitor was compared to other corrosion control strategies. Iron scales for iron and galvanized steel coupons incubated in different blended waters in the presence of BOP inhibitor were analyzed …

The Effects Of Phosphate And Silicate Inhibitors On Surface Roughness And Copper Release In Water Distribution Systems, David Macnevin

Electronic Theses and Dissertations

The effects of corrosion inhibitors on water quality and the distribution system were studied. This dissertation investigates the effect of inhibitors on iron surface roughness, copper surface roughness, and copper release. Corrosion inhibitors included blended poly/ortho phosphate, sodium orthophosphate, zinc orthophosphate, and sodium silicate. These inhibitors were added to a blend of surface water, groundwater, and desalinated brackish water. Surface roughness of galvanized iron, unlined cast iron, lined cast iron, and polyvinyl chloride was measured using pipe coupons exposed for three months. Roughness of each pipe coupon was measured with an optical surface profiler before and after exposure to inhibitors. …

Nutrient Removal From Stormwater By Using Green Sorption Media, Fahim Hossain

Electronic Theses and Dissertations

High nitrogen and phosphorus content in storm water runoff has affected groundwater, springs and surface water by impacting ecosystem integrity and human health. Nitrate may be toxic and can cause human health problem such as methemoglobinemia, liver damage and even cancers. Phosphorus may trigger the eutrophication issues in fresh water bodies, which could result in toxic algae and eventually endanger the source of drinking waters. Sorption media with mixes of some recycled materials, such as sawdust and tire crumb, combined with sand/silt and limestone, becomes appealing for nutrient removal in environmental management. This paper presented is a specific type of …

Removal Of 2, 4-Dinitrophenol By Ferrate, Gianna Cooley

Electronic Theses and Dissertations

Ferrate (molecular formula, FeVIO42-) has been studied increasingly since the 1970s as a disinfectant and coagulant for domestic wastewater and also as an oxidant for industrial wastewaters (Murmann and Roginson, 1974, Gilbert et al., 1978, Kazama, 1994, Jiang et al., 2002, and Sharmaet al., 2005). This research was performed to explore whether ferrate could possibly be used as chemical treatment for industrial wastewaters from plastic, chemical, dye, soap, and wood stain producing plants that contain 2, 4-Dinitrophenol (DNP). DNP is listed on the United States Environmental Protection Agency (EPA) Drinking Water Contaminant Candidate List (CCL). This list includes compounds which …

The Effectiveness Of Specifically Designed Filter Media To Reduce Nitrate And Orthophosphate In Stormwater Runoff, Mikhal Moberg

Electronic Theses and Dissertations

Throughout Central Florida surface water and ground water are decreasing in quantity and quality in part because of excess Nitrate and Phosphorus nutrients. Stormwater runoff serves as a medium for transport of Nitrate and Phosphorus to surface water and ground water. The goal of this experiment is assess the Nitrate and Phosphorus removal in stormwater using select media. The results of a literature search, batch test experimentation and column test experimentation are used to determine an optimal media blend that may be implemented in detention ponds to reduce Nitrate and Phosphorus. The extensive literature search revealed 32 different media that …

Performance Based Decision System In Determining Post Closure Care (Pcc) Duration In Florida Landfills, Asawari Kulkarni

Electronic Theses and Dissertations

This study is an evaluation of Post Closure Care (PCC) duration of landfills using performance based methodology. The post closure care phase begins once the landfill is closed. As required by the Resource Conservation Recovery Act (RCRA) Subtitle D, PCC duration for municipal solid waste landfills is 30 years. During the PCC period, the landfill operator/owner is required to conduct monitoring for leachate, landfill gas, and ground-water and maintain the integrity of the cap so that the landfill does not impose a threat to surrounding human health and environment (HH&E). The duration of PCC can be reduced by the director …

A Kinetics Study Of Selected Filtration Media For Nutrient Removal At Various Temperatures, Elizabeth Henderson

Electronic Theses and Dissertations

In recent years the nutrient levels of the Upper Floridan aquifer have been increasing (USGS, 2008). An example of this is found in Ocala, Florida where Silver Springs nitrate concentrations have risen from 0.5 mg/L in the 1960 s to approximately 1.0 mg/L in 2003 (Phelps, 2004). Because stormwater is a contributor to surficial and groundwater aquifer recharge, there is an increasing need for methods that decrease nitrogen and phosphorus levels. A laboratory column study was conducted to simulate a retention pond with saturated soil conditions. The objectives of the column studies reported in this thesis were to investigate the …

Erosion Function Apparatus, Ryan Larsen

The Journal of Undergraduate Research

The Erosion Function Apparatus (EFA) test uses site-specific soil samples acquired via thin-walled tubes to generate the erosion rate and shear stress which is plotted to create an erosion plot. The information produced by the test can help an engineer accurately determine the depth of scour as a function of time for bridge design, and thereby determine the depth a foundation system should be constructed. During EFA testing, a data acquisition system records the velocity and amount of soil eroded. This data is used to calculate the Reynolds Number, friction factor, erosion rate, and shear stress. Once the data has …

Screening The Phytoremediation Potential Of Native Plants Growing On Mine Tailings In Arizona, Usa, Md Nazmul Haque

Open Access Theses & Dissertations

Mining companies have been playing an important role for the utilization of the Earth's natural resources for the prosperity of human society. However, the mining of resources has generated solid wastes called tailings that have become a serious environmental threat worldwide. Technologies such as soil caping have been used to remediate the problem. Nevertheless, the remediation of mine tailings using conventional technologies is costly and environmentally unpleasant. Since the last few decades, a plant based technology known as phytoremediation has appeared as a promising alternative. Several plant species have demonstrated to have phytoremediation capabilities; though, best results have been obtained …

Feasibility Of Utilising Construction And Demolition Waste And Dredge Material As Landflll Liner, John David Riordan

Theses

Construction and demolition (C&D) waste and dredge material are significant bulk waste streams in the Republic of Ireland. This thesis examines the feasibility of combining these waste streams to produce a viable novel geotechnical clay liner for landfill.

This thesis includes a literature review and a detailed study of C&D waste, dredge material and landfill liners in Ireland. The research for this thesis includes a geotechnical laboratory test programme. Samples of C&D waste and dredge material were collected and tested to establish relevant characteristics. In addition, a senes of tests were commissioned on test samples to establish their chemical and …

Effects Of Orthophosphate Corrosion Inhibitor In Blended Water Quality Environments, Erica Stone

Electronic Theses and Dissertations

This study evaluated the effects of orthophosphate (OP) inhibitor addition on iron, copper, and lead corrosion on coupons exposed to different blends of groundwater, surface water, and desalinated seawater. The effectiveness of OP inhibitor addition on iron, copper, and lead release was analyzed by statistical comparison between OP treated and untreated pilot distribution systems (PDS). Four different doses of OP inhibitor, ranging from zero (control) to 2 mg/L as P, were investigated and non-linear empirical models were developed to predict iron, copper, and lead release from the water quality and OP doses. Surface characterization evaluations were conducted using X-ray Photoelectron …

The Acute Toxicity Of Ground Recycled Automobile Tires On Aquatic Life With Model Species P. Promelas, Trillian Baldassari

Electronic Theses and Dissertations

Used tires have the potential for becoming popular in pollution control media used in stormwater applications including pervious pavement sub bases, green roof growth media, and upflow filters. Using tire crumb to decrease nutrients can minimize impacts on ecology while reducing the human footprint left by used tires. However, if tire crumb is not examined for toxicity, the ecological balance could unknowingly be disrupted. This research tested the acute toxicity of tire crumb in aquatic systems by finding the Lethal Concentration for 50% kill (LC50). Using an extreme tire crumb load, P. promelas (fathead minnow) were exposed to leachates created …

Reducing Effluent Phosphorus And Nitrogen Concentrations From A Stormwater Detention Pond Using A Chamber Upflow Filter And Skim, Patrick Ryan

Electronic Theses and Dissertations

Stormwater runoff is a known pollutant source capable of causing surface water degradation, especially in highly populated areas such as Central Florida. Wet detention ponds manage this stormwater, but most of the ponds do not remove enough nutrients, specifically nitrogen and phosphorus, to meet TMDL regulations. This research provides a possible addition to a detention pond in Seminole County, Florida using a Chamber Upflow Filter and Skimmer (CUFS), which can increase the removal of phosphorus and nitrogen by the system. Water enters the system through the skimmer, which floats on the surface of the detention pond. It travels from the …

Determining Florida Landfill Odor Buffer Distances Using Aermod, Veronica Figueroa

Electronic Theses and Dissertations

As U.S. landfills continue to grow in size, concerns about odorous gas emissions from landfills are increasing. For states that are expanding in population, such as Florida, odors from landfills are a major concern because new housing developments, needed to accommodate the rapid population growth, are creeping closer and closer to the existing landfills. As homes get closer to landfills, odor complaints are likely to become more frequent, causing landfill managers increased problems with public interactions. Odor buffer zones around landfills need to be established to give municipalities tools to help prevent the building of future homes too close to …

A Comparative Analysis Of Green Roof Designs Including Depth Of Media, Drainage Layer Materials, And Pollution Control Media, Matt Kelly

Electronic Theses and Dissertations

Population growth has lead to an increase in development and impervious areas in urban settings. Post-development conditions cause several problems for stormwater management such as limited space for stormwater storage systems and the conveyance of pollution picked up by runoff to near by water bodies. Green Roofs with cisterns have been shown to attenuate the peak flow of storm events and reduce the pollution load leaving a site and entering nearby water bodies. The purpose of this research is to expand the available research data on green roofs with cisterns by investigating the water quality and hydrology effects of different …

Coupling The Hydrodynamic And Water Quality Model Ce-Qual-W2 With A Multi-Trophic Fish Bio-Energetics Model For Lake Roosevelt, Washington, Michael Lee Mckillip

Dissertations and Theses

Grand Coulee Dam created Franklin D. Roosevelt Lake as part of the Columbia Basin Project. Located in northeastern Washington State, the Project provides economically important hydropower (19 billion kilowatt hours per year), irrigation (225,000 ha), flood control, and sport fishing ($5 to 20 million annually). A good system understanding aids in balancing these beneficial uses for the 230 km long reservoir. The reservoir's atypical 45-day mean residence time is much shorter than a typical lake, and much longer than for a riverine dam. The spring freshet requires drawdowns of 15 to 20 m for flood control—the driving characteristic of reservoir …

Noise Abatement And Night Deliveries, Hugh Finlay

Masters

ABSTRACT The hypothesis is tested that – Acoustic materials are available or can be developed and applied to Heavy Goods Vehicles and ancillaries, which effectively and economically abate the noise caused by night deliveries The MPhil is a part of a wider innovation research partnership that aimed to develop sustainable solutions for the growing trend to night deliveries in Dublin city centre. The methodology involves; a review of international best practice for urban traffic noise abatement: a social and commercial justification for developing low noise products and procedures: field trials of kerb-side deliveries to city centre shops to identify the …

Analysis Of Number And Mass Concentration Of Coarse And Fine, Nancy Garcia

Open Access Theses & Dissertations

There is currently much concern over particles suspended in the ambient air, their effects on people and the environment throughout the world. The suspended particles can cause adverse health effects, reduce visibility and over the course of time wear buildings. Primary air quality concerns are of particles, their effects and their key characteristics. Particle number concentration (NC) of traffic emissions is an important element of the study, specifically heavy duty diesel engine emissions. Particle number concentration is the number of particles of a specific size in a unit of air; in this study they are measured by the number of …

System And Method For Analyzing Material Properties Using Hyperspectral Imaging, Jeyamkondan Subbiah, Chris Richard Calkins, Ashok Samal

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Systems and methods are provided for analyzing material properties of an object using hyperspectral imaging. An exemplary method includes obtaining a hyperspectral image of an object; analyzing the hyperspectral image according to an algorithm; and correlating data obtained from the analysis with material properties of the object.

Suspended Sediment Fluxes At An Intertidal Flat: The Shifting Influence Of Wave, Wind, Tidal, And Freshwater Forcing, Stefan A. Talke, Mark T. Stacey

Civil and Environmental Engineering Faculty Publications and Presentations

Using in situ, continuous, high frequency (8–16 Hz) measurements of velocity, suspended sediment concentration (SSC), and salinity, we investigate the factors affecting near-bed sediment flux during and after a meteorological event (cold front) on an intertidal flat in central San Francisco Bay. Hydrodynamic forcing occurs over many frequency bands including wind wave, ocean swell, seiching (500–1000 s), tidal, and infra-tidal frequencies, and varies greatly over the time scale of hours and days. Sediment fluxes occur primarily due to variations in flow and SSC at three different scales: residual (tidally averaged), tidal, and seiching. During the meteorological event, sediment fluxes are …

New Particle Formation In The Front Range Of The Colorado Rocky Mountains, Micahel Boy, Thomas Karl, Andrew Turnipseed, Roy Lee Mauldin, Edward Kosciuch, James Greenberg, Jeff Rathbone, James Smith, Andreas Held, Kelley Barsanti, Alex Guenther

Civil and Environmental Engineering Faculty Publications and Presentations

New particle formation is of interest because of its influence on the properties of aerosol population, and due to the possible contribution of newly formed particles to cloud condensation nuclei. Currently no conclusive evidence exists as to the mechanism or mechanisms of nucleation and subsequent particle growth. However, nucleation rates exhibit a clear dependence on ambient sulphuric acid concentrations and particle growth is often attributed to the condensation of organic vapours. A detailed study of new particle formation in the Front Range of the Colorado Rocky Mountains is presented here. Gas and particle measurement data for 32 days was analyzed …

Optimal Bus Stop Spacing For Minimizing Transit Operation Cost, Huan Li, Robert L. Bertini

Civil and Environmental Engineering Faculty Publications and Presentations

With the increasing attention to finance issues relative to transit operation, a bus stop spacing model is generated with the aim at minimizing the operation cost without impact on transit accessibility. Two cost functions are considered in the model including passenger access cost and in-vehicle passenger stopping cost aiming at minimizing total cost. A bus route in Portland, Oregon, USA is examined as an example using Archived Bus Dispatch System (BDS) data provided by TriMet, the regional transit provider for the Portland, Oregon metropolitan area. Based on the optimization model, the theoretical optimized bus stop spacing is 930 feet comparing …

Lipid Productivity Of Algae Grown On Dairy Wastewater As A Possible Feedstock For Biodiesel, Ian C. Woertz

Master's Theses

The objective of this thesis is to develop a biological wastewater treatment system that utilizes algal growth to simultaneously create renewable energy in the form of biodiesel and digester biogas, remove polluting nutrients, and abate greenhouse gases. Research under the Department of Energy Aquatic Species Program during 1978-1996 concluded that cultivating algae for biofuels was cost prohibitive at that time and that an integrated approach should be studied that combined wastewater treatment with algal biofuel production. Nutrient removal, in particular nitrogen and phosphorus, from wastewater is a growing regulatory need and the use of algae cultivation could create a unique …

Massive Spatiotemporal Watershed Hydrological Storm Event Response Model (Mhserm) With Time-Lapsed Nexrad Radar Feed, Changqing Song

Civil & Environmental Engineering Theses & Dissertations

Correctly and efficiently estimating hydrological responses corresponding to a specific storm event at the streams in a watershed is the main goal of any sound water resource management strategy. Methods for calculating a stream flow hydrograph at the selected streams typically require a great deal of spatial and temporal watershed data such as geomorphological data, soil survey, landcover, precipitation data, and stream network information to name a few. However, extracting and preprocessing such data for estimation and analysis is a hugely time-consuming task, especially for a watershed with hundreds of streams and lakes and complicated landcover and soil characteristics. To …

Catalytic Wet Air Oxidation Of Mono Azo Dye Orange Ii: Catalyst Selection, Reaction Kinetics, And Modeling, Pinar Ozdural

Civil & Environmental Engineering Theses & Dissertations

Wastewaters generated as byproducts of dyeing processes are not treatable with conventional methods. It has been estimated that among the 900,000 tons of different dyes produced annually in the world, approximately 10–15% are lost in wastewater streams during manufacturing and processing operations. Once in rivers and streams, dyes cause major problems, such as reducing light penetration, or displaying toxic effects on aquatic life. Therefore, it is essential that dyes are removed from wastewaters before being discharged into the environment.

This study focuses on the catalytic wet air oxidation (CWAO) of Orange II, a mono azo dye used in large amounts …

2007 Fall Engr333/Biol354 Project Final Report, 2007 Fall Engr333, 2007 Fall Biol354

ENGR 333

The students of Calvin College’s Engineering 333 and Biology 354 classes were given the task of determining “What would it take to make Calvin College Carbon Neutral?” At first glance, it would not appear that classes on Advanced Thermal System Design and Investigations in Plant Ecology would have much in common. However, the biology and engineering students comprising these classes banded together to tackle the problem. Coming to a satisfactory conclusion would require:

• Creating an inventory of Green House Gas (GHG) emissions and sequestration potential
• Coming up with detailed solutions to achieve Carbon Neutrality
• Working out a practical schedule to …

Bacterial Auto-Aggregation And Co-Aggregation In Activated Sludge, Fei Chen

All Theses

Microbial auto-aggregation and co-aggregation, leading to biofilm or floc formation, widely occur in natural systems. This study was conducted to investigate the extent of bacterial auto-aggregation and co-aggregation in activated sludge and their contributions in activated sludge floc formation. In this study, an activated sludge sample was separated into a supernatant part (planktonic community) and a sediment part (floc community) by centrifugation at 650_g for 2 minutes. 197 strains were isolated from both communities. These isolates belong to 18 phylotypes based on molecular identifications. Similar phylogenetic distributions of these isolates were observed in planktonic and floc communities, suggesting a similar …

Metalloporphyrin Catalyzed Degradation Of Pce: Effects Of Reductants, Buffers And Cosolvent Concentration, Sowmya Suryanarayanan

All Theses

Reductive dechlorination of chlorinated organic contaminants using metalloporphyrins as catalysts may be an effective approach to treat widespread contamination. However, most previous studies have examined water-soluble rather than insoluble metalloporphyrins despite the fact that the latter category makes up the largest fraction found in nature. Recent studies have shown that addition of different cosolvents to water can activate otherwise non-reactive metalloporphyrin catalysts and facilitate the reduction of tetrachloroethylene (PCE), presumably by the mere process of making the otherwise insoluble metalloporphyrins dissolve in solution. Therefore, solubility has been advanced as a key factor in the ability of metalloporphyrins to catalyze organic …

Laboratory Evaluation Of Microbial Aggregation In Activated Sludge, Xiaoling Liu

All Theses

Microbial aggregation was investigated in this study using the activated sludge process as a model system, the performance of which is highly dependent on effective bioaggregation. This research includes two experiments. First, four laboratory-scale activated sludge sequencing batch reactors (SBRs) were constructed in order to evaluate the effect of solids retention time (SRT) on microbial aggregation. These SBRs were operated at SRT of 4, 8, 16, and 32 days, respectively, fed with a protein-based synthetic wastewater, and monitored over a period of 268 days for performance and sludge settling characteristics including soluble COD in the effluent (sCOD), sludge volume index …