Civil and Environmental Engineering Commons^™

Positive Matrix Factorization Of Pm2.5 - Eliminating The Effects Of Gas/Particle Partitioning Of Semivolatile Organic Compounds, Mingjie Xie, Kelley Barsanti, Michael P. Hannigan, Steven J. Dutton, Sverre Vedal

Civil and Environmental Engineering Faculty Publications and Presentations

Gas-phase concentrations of semi-volatile organic compounds (SVOCs) were calculated from gas/particle (G/P) partitioning theory using their measured particle-phase concentrations. The particle-phase data were obtained from an existing filter measurement campaign (27 January 2003-2 October 2005) as a part of the Denver Aerosol Sources and Health (DASH) study, including 970 observations of 71 SVOCs (Xie et al., 2013). In each compound class of SVOCs, the lighter species (e.g. docosane in n-alkanes, fluoranthene in PAHs) had higher total concentrations (gas + particle phase) and lower particle-phase fractions. The total SVOC concentrations were analyzed using positive matrix factorization (PMF). Then the results were …

Analyzing Experimental Data And Model Parameters: Implications For Predictions Of Soa Using Chemical Transport Models, Kelley Barsanti, Annmarie G. Carlton, Serena H. Chung

Civil and Environmental Engineering Faculty Publications and Presentations

Despite critical importance for air quality and climate predictions, accurate representation of secondary organic aerosol (SOA) formation remains elusive. An essential addition to the ongoing discussion of improving model predictions is an acknowledgement of the linkages between experimental conditions, parameter optimization and model output, as well as the linkage between empirically-derived partitioning parameters and the physicochemical properties of SOA they represent in models. In this work, a "best available" set of SOA modeling parameters is selected by comparing predicted SOA yields and mass concentrations with observed yields and mass concentrations from a comprehensive list of published smog chamber studies. Evaluated …

Estimation Of Performance Indices For The Planning Of Sustainable Transportation Systems, Alexander Paz, Pankaj Maheshwari, Pushkin Kachroo, Sajjad Ahmad

Civil and Environmental Engineering and Construction Faculty Research

In the context of sustainable transportation systems, previous studies have either focused only on the transportation system or have not used a methodology that enables the treatment of incomplete, vague, and qualitative information associated with the available data. This study proposes a system of systems (SOS) and a fuzzy logic modeling approach. The SOS includes the Transportation, Activity, and Environment systems. The fuzzy logic modeling approach enables the treatment of the vagueness associated with some of the relevant data. Performance Indices (PIs) are computed for each system using a number of performance measures. The PIs illustrate the aggregated performance of …

Terpene And Terpenoid Emissions And Secondary Organic Aerosol Production, Rosa M. Flores

Dissertations, Master's Theses and Master's Reports - Open

Approximately 90% of fine aerosol in the Midwestern United States has a regional component with a sizable fraction attributed to secondary production of organic aerosol (SOA). The Ozark Forest is an important source of biogenic SOA precursors like isoprene (> 150 mg m^-2 d^-1), monoterpenes (10-40 mg m^-2 d^-1), and sesquiterpenes (10-40 mg m^-2d^-1). Anthropogenic sources include secondary sulfate and nitrate and biomass burning (51-60%), vehicle emissions (17-26%), and industrial emissions (16-18%). Vehicle emissions are an important source of volatile and vapor-phase, semivolatile aliphatic and aromatic hydrocarbons that are important …

A Novel Approach To Carbon Dioxide Capture And Storage, Brett P. Spigarelli

Dissertations, Master's Theses and Master's Reports - Open

The novel approach to carbon capture and storage (CCS) described in this dissertation is a significant departure from the conventional approach to CCS. The novel approach uses a sodium carbonate solution to first capture CO₂ from post combustion flue gas streams. The captured CO₂ is then reacted with an alkaline industrial waste material, at ambient conditions, to regenerate the carbonate solution and permanently store the CO₂ in the form of an added value carbonate mineral. Conventional CCS makes use of a hazardous amine solution for CO₂ capture, a costly thermal regeneration stage, and the underground storage …

Investigation Of Wastewater Treatment Plant Sustainability Potential In Terms Of Resource Recovery Essentials, Aoife Moloney

Theses

This thesis aims to explore the sustainability potential which exists in Wastewater Treatment Plants (WWTP's); particularly focusing on nutrient, energy, and water recovery and reuse. The core of the research will focus on the establishment of a sustainable Resource Recovery Treatment Plant (RRTP) plan for Limerick Main Drainage (LMD) WWTP, and potentially utilising this as a case study plant which could act as a foundation example within the sector.

There is a genuine need to investigate more sustainable options in wastewater treatment (WWT); increasing energy and sludge management costs are a real issue for non-sustainable WWTP's given that thousands of …

A Common Methodology To Assess The Sustainability Of Different Stages Of The Water Cycle In An Urban Environment In An Irish Context, Áine Mcgrath

Theses

The project proposes to devise a common methodology to assess the sustainability of different stages of the water cycle in an urban environment in an Irish context. With the reduction in infrastructure investment by the governing bodies, the concept of sustainable development is becoming more important.

The project involves using the principals and procedures of a system analysis along with sustainable key performance indicators to assess the sustainability of water cycle system, which includes water treatment, the water distribution system, wastewater treatment and flood risk management.

A sustainability assessment of the combined stages of an urban water cycle will provide …

Embodied Energy And Carbon Footprint Of Household Latrines In Rural Peru: The Impact Of Integrating Resource Recovery, Christopher M. Galvin

USF Tampa Graduate Theses and Dissertations

Over seventy percent of the 2.5 billion people who still lack access to basic sanitation worldwide live in rural areas (WHO/UNICEF, 2012). Despite concerns of water scarcity, resource depletion, and climate change little research has been conducted on the environmental sustainability of household sanitation technologies common in rural areas of developing countries or the potential of resource recovery to mitigate the environmental impacts of these systems. The environmental sustainability, in terms of embodied energy and carbon footprint, was analyzed for four household sanitation systems: (1) Ventilated Improved Pit (VIP) latrine, (2) pour-flush latrine, (3) composting latrine, and (4) biodigester latrine. …

Assessment Of A Modified Double Agar Layer Method To Detect Bacteriophage For Assessing The Potential Of Wastewater Reuse In Rural Bolivia, Sakira N. Hadley

USF Tampa Graduate Theses and Dissertations

Water scarcity is a global concern that impacts many developing countries, forcing people to depend on unclean water sources for domestic, agricultural, and industrial needs. Wastewater is an alternative water source that contains nutrients needed for crop growth. Wastewater reuse for agriculture can cause public health problems because of human exposure to pathogens. Pathogen monitoring is essential to evaluate the compliance of wastewater with established World Health Organization (WHO) and U.S. Environmental Protection Agency (EPA) wastewater reuse guidelines. Indicator organisms are commonly used to detect pathogens in water and wastewater because they are quick and easy to measure, non-pathogenic, and …

Effect Of Solids Retention Time On The Denitrification Potential Of Anaerobically Digested Swine Waste, Maureen Njoki Kinyua

USF Tampa Graduate Theses and Dissertations

Three continuously stirred tank reactors (CSTR) were operated in semi continuous mode treating swine waste using anaerobic digestion. The reactors were used to test the effect of solid retention time (SRT) on CH4 yield, total ammonia nitrogen (TAN) concentrations, % volatile solids (VS), chemical oxygen demand (COD) and volatile fatty acids (VFA) removal, readily biodegradable COD concentration and the denitrification potential for the effluent in a biological nutrient removal (BNR) system. During Phase I of the study, the three reactors were operated at the same 28 day SRT for 16 weeks. SRTs were then changed during the 12 week Phase …

Modeling And Design Of Photocatalytic Reactors For Air Purification, Yangyang Zhang

USF Tampa Graduate Theses and Dissertations

Photocatalysis is a promising technique for the remediation of indoor air pollution. Photocatalysis utilizes semiconductor photocatalysts (such as TiO₂ or ZnO) and appropriate light to produce strong oxidizing agents (OH*) that are able to break down organic compounds and inactivate bacteria and viruses. The overall goal of the research is to develop an efficient photocatalytic reactor based on mass transfer for indoor air purification. This study has focused on the enhancement of the effectiveness of the photocatalytic process by the introduction of artificial roughness on the reactor catalyst surface. The major effect of artificial roughness elements on the catalytic …

Effects Of Solvent Composition And Hydrogen Pressure On The Catalytic Conversion Of 1,2,4,5-Tetrachlorobenzene To Cyclohexane, Margaret Elizabeth Cone

USF Tampa Graduate Theses and Dissertations

Halogenated hydrophobic organic compounds (HHOCs) such as 1,2,4,5-tetrachlorobenzene (TeCB) present a threat to both human health and the environment. The common occurrence and recalcitrant nature of HHOCs as soil contaminants necessitate an effective soil remediation method. Wee and Cunningham (2008, 2011, 2013) proposed a clean-up technology called Remedial Extraction and Catalytic Hydrodehalogenation (REACH), which pairs solvent extraction of HHOC contaminants from soil with catalytic hydrodehalogenation to destroy contaminants. Wee and Cunningham (2008, 2011, 2013) utilized a palladium (Pd) catalyst to hydrodehalogenate TeCB to benzene. However, benzene is still a toxic contaminant. Prior research has demonstrated that Pd-catalyzed hydrodehalogenation (HDH) can …

Modeling Nitrogen Transformations In A Pilot Scale Marine Integrated Aquaculture System, Brian Mccarthy

USF Tampa Graduate Theses and Dissertations

Integrated aquaculture systems (IAS) are a type of recirculating aquaculture systems (RAS) where the wastewater is treated and returned to the fish tanks. The important difference between the two is that in an IAS, wastes from the aquaculture component are recovered as fertilizer to produce an agricultural product whereas in an RAS, waste organics, nutrients and solids are treated and discharged. A pilot marine IAS at Mote Aquaculture Research Park in Sarasota, FL was studied for this project. Water quality monitoring, measurements of fish health and growth rates of fish and plants were performed over a two-year period to determine …

Evaluation Of A Pilot Land-Based Marine Integrated Aquaculture System, Suzanne Boxman

USF Tampa Graduate Theses and Dissertations

Recirculating aquaculture systems (RAS) produce aquaculture products on land with minimal discharge of waste products and minimal water loss. High costs associated with waste treatment for RAS have triggered the growth of integrated aquaculture systems (IAS) which incorporate macrophytes (aquatic plants) into the treatment train. The objective of this research was to examine a pilot scale inland marine IAS with three different methods for solids treatment: a sand filter followed by a plant bed, only a plant bed, and geotextile bags. Florida Pompano (Trachinotus carolinus) were grown along with Smooth Cordgrass (Spartina alterniflora), Black Needle Rush …

Socioeconomic Factors' And Water Source Features' Effect On Household Water Supply Choices In Uganda And The Associated Environmental Impacts, Christine M. Prouty

USF Tampa Graduate Theses and Dissertations

Over the last twenty years or more, Uganda has benefitted from significant strides in water and sanitation initiated by the United Nations' Millennium Development Goals. While the rapid progress towards development has been vastly beneficial, it is also important that it does not occur at the expense of the environment. The environmental impacts of these water sources must be evaluated and understood. However, to develop a robust understanding of the impact requires inclusion of the community members who use these sources and their perceptions of them. Consequently, the goal of this research is to investigate the interrelationships between socioeconomic factors, …

Community And Household Management Strategies For Water Supply And Treatment In Rural And Peri-Urban Areas In The Developing World, Ryan William Schweitzer

USF Tampa Graduate Theses and Dissertations

Eighty percent of the 780 million people worldwide that access water from an unimproved source live in rural areas. In rural areas, water systems are often managed by community based organizations and many of these systems do not provide service at the designed levels. The Sustainability Analysis Tool developed in Chapter 2 can inform decision making, characterize specific needs of rural communities in the management of their water systems, and identify weaknesses in training regimes or support mechanisms. The framework was tested on 61 statistically representative geographically stratified sample communities with rural water systems in the Dominican Republic. The results …

Investigation Of Mercury Use, Release, Deposition, And Exposures In The Tampa Bay Area, Ryan Algernon Michael

USF Tampa Graduate Theses and Dissertations

I investigate the links between mercury use, release, deposition, and population exposure in Tampa Bay, with the focus of identifying levers for reducing population mercury exposures. To achieve this, I investigated the trends in mercury use and release by products and processes in the Tampa Bay area using a Material Flow Analysis. Analysis of USEPA National Emissions Inventory data over time (1999 - 2008) identified relevant air source emission categories, and explored and compared state and regional trends in mercury emissions. To understand source contributions to wet deposited mercury in the Tampa Bay area, I analyzed trends in mercury deposition …

Towards Rans Parameterization Of Vertical Mixing By Langmuir Turbulence In Shallow Coastal Shelves, Nityanand Sinha

USF Tampa Graduate Theses and Dissertations

Langmuir turbulence in the upper ocean is generated by the interaction between the wind-driven shear current and the Stokes drift velocity induced by surface gravity waves. In homogenous (neutrally stratified) shallow water, the largest scales of Langmuir turbulence are characterized by full-depth Langmuir circulation (LC). LC consists of parallel counter-rotating vortices aligned roughly in the direction of the wind. In shallow coastal shelves, LC has been observed engulfing the entire water column, interacting with the boundary layer and serving as an important mechanism for sediment re-suspension.

In this research, large-eddy simulations (LES) of Langmuir turbulence with full-depth LC in a …

Improving Implementation Of A Regional In-Line Chlorinator In Rural Panama Through Development Of A Regionally Appropriate Field Guide, Benjamin A. Yoakum

USF Tampa Graduate Theses and Dissertations

Access to safe drinking water has a direct effect on improving human health and their quality of life. One country still struggling with providing access to safe drinking water to all of its population is Panama. Panama's largest indigenous group, the Ngöbe people, is disproportionately affected by lack of access to safe drinking water. One way Panama's Ministry of Health (MINSA) is attempting to increase access to safe drinking water to the Ngöbe people is by disinfecting the water already captured by rural gravity fed water systems constructed within in the Ngöbe-Bugle reservation. This is accomplished using an in-line chlorinator …

Characterization Of Nano-Scale Aluminum Oxide Transport Through Porous Media, Sasha Norien Norwood

Dissertations and Theses

Land application of biosolids has become common practice in the United States as an alternative to industrial fertilizers. Although nutrient rich, biosolids have been found to contain high concentrations of emerging contaminants (e.g. pharmaceuticals, personal care products) while containing a significant fraction of inorganic nano-scale colloidal materials such as oxides of iron, titanium, and aluminum.

Given their reactivity and small size, there are many questions concerning the potential migration of these nano-sized colloidal materials through the soil column and into our surface and groundwater bodies. Transport of emerging pollutants of concern through the soil column, at minimum, is impacted by …

Determinants Of Neighborhood Exposure To Extreme Heat: A Spatial Examination Of El Paso And Juárez, 2010, Faraj Mohamad Aboargob

Open Access Theses & Dissertations

Numerous studies have been conducted on the modification of local weather by the urban environment. In studying urban environmental effects on the urban heat island (UHI), researchers have investigated influences such as land use, vegetation density, topography, population density, and neighborhood socioeconomic status. Many studies have used data collected from field observations, while other studies relied solely on computer modeling. This Dissertation research used a spatial analysis approach, which has been less widely employed, to investigate neighborhood level biophysical, built environmental and socio-demographic determinants of the El Paso and Juárez UHI. The research utilized inexpensive data obtained from US and …

Method Development For A Chemical And Biological Analysis Of Glucocorticoids In Wastewater, Maria Carmen Lozano

Open Access Theses & Dissertations

Glucocorticoids are a class of steroid hormones that can either be produced synthetically or naturally by the adrenal glands. The synthetic glucocorticoids are highly prescribed in the United States for their anti-inflammatory and immunosuppressive properties to treat a variety of ailments and diseases; however, these have been implicated in a number of adverse human conditions such as obesity, metabolic syndrome, immune-suppression, delayed puberty, adrenal insufficiency and Cushing Syndrome, among others. Ongoing research has shown that synthetic and natural hormones are transported to aquatic environments via mammalian excretion or wastewater effluent, and as a result, the release of glucocorticoids into the …

Synthetic Asphaltene As A Novel Dye In Dye Sensitized Solar Cells Dsscs, Hassan Sharif

Open Access Theses & Dissertations

This dissertation approves the possibility of the first time use of synthetic asphaltene as new dye in dye sensitized solar cells. In which the conversion efficiency of synthetic asphaltene DSSC has improved up to 2.0 %. Synthetic asphaltene sample was prepared from the starting material as in literature and applied for various solar cell parameters of TiO2 based dyesensitized solar cell DSSC. DSSCs were fabricated using the synthetic asphaltene as dye. Different variables and parameters were carried out to test the photovoltaic performance of the cells, these parameters include open-circuit voltage, short-circuit current; fill factor. The first result was obtained …

Adsorption Of Arsenic, Chromium, And Uranium From Saline Water On Clinoptilolite And The Treatment Of The Spent Regenerant By Duffusion Dialysis, Mutiu Olaitan Tanimola

Open Access Theses & Dissertations

Among various water purification and recycling technologies, adsorption is a fast, inexpensive and universal method. The development of low-cost adsorbents has led to the rapid growth of research interests in this field. The objective of this present study is the optimization of process parameters in adsorption of arsenic, chromium and uranium ions. The adsorption behavior of natural zeolite (clinoptilolite) has been studied in order to determine its applicability in treating water containing arsenic, chromium and uranium. The multiple adsorption of arsenic As (V), trivalent chromium Cr (III)] and uranium (VI) on natural zeolite (clinoptilolite) in single component and multiple component …

The Investigation Of The Practice Of Frugal Innovation Across Cultures And The Introduction Of An Instructional Model For Streamlining The Design Process, Andres Efren Bolanos

Open Access Theses & Dissertations

The central objectives of this dissertation are to analyze frugal innovation, apply foundational methodologies that contribute to product design, and discover the important contextual information for successful development. This dissertation describes a systematic procedure in designing frugally innovated products. The institutional design will encompass environmental, social, and economic impacts into the entire products' life cycle. Also, a comparison is made between two developing nations' contextual factors to reveal the formulation of frugal innovation.

Evaluation Of Novel Backwashable Cartridge Filters: Efficacy And Sustainability, Michelle Brown

Open Access Theses & Dissertations

One of the important aspects of desalination pre–treatment is the removal of particles from feedwater. This is typically accomplished using a combination of gross filtration and cartridge filtration. Cartridge filters are typically single–use products, and their replacement can represent a significant portion of a desalination plant's operating budget. This research evaluated the performance of a new type of cartridge filter that is backwashable and aims to reduce the overall cost to desalination facilities and provide cleaner water. Two sets of filters were evaluated (in triplicate) with respect to particle removal efficiency and hydraulic efficiency. The initial set included four types …

Geochemical Characterization Of Mineral Dust Sources In The Chihuahuan Desert And Southern High Plains Regions, Porfirio Peinado

Open Access Theses & Dissertations

The Chihuahuan Desert (northern Chihuahua, southern New Mexico, and far west Texas) and the southern High Plains (west Texas and eastern New Mexico) regions have been identified as one of the most persistent dust producing regions of North America. Regional-scale dust storms have been observed by satellite imagery to identify sources of dust, resulting in collection and examination of physical soil samples to better understand the source signatures (geochemical characteristics) of dust origins in these two regions.

The soil characteristics were examined through several techniques: Particle Size Distribution, X-Ray Diffraction (XRD), Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), and Total …

Weather-Based Damage Prediction Models For Electric Distribution Networks, David W. Wanik

Master's Theses

From thunderstorms to hurricanes, electric distribution networks are subject to a wide range of warm weather storm events. Tropical Storm Irene (2011) and Hurricane Sandy (2012) are two events in recent memory that disrupted over half of The Connecticut Light and Power Company’s (CL&P) service territory, which left some customers without power for up to eleven days. This research study investigates a damage prediction framework for both thunderstorms and hurricanes that combines two generalized linear models to probabilistically determine the occurrence and extent of damages, known as trouble spots, to the overhead power distribution network. The models are inputted with …

Investigation Of In-Situ Immobilization Of Contaminated Sediments Using Alginate Gels For The Reduction Of Ecological Risk, Michael V. Podany Mr.

Master's Theses

Remediation methods for contaminated sediments include dredging, treatment and disposal and sediment isolation through capping. These methods are costly and adversely impact local ecosystems, in some cases causing major disturbances to the sediment bed and water column. A new remediation technique is proposed for slowly biodegradable contaminants using alginate hydrogels as a binding agent of sediment. The rational is that sediment particles bound in alginate hydrogel are less likely to be resuspended and the treatment is less disruptive than capping. Here we show addition of alginate increased the shear strength of sediment comprised of defined particle sizes. The increase in …

2012 Fall Engr333 Project Final Report, 2012 Fall Engr333

ENGR 333

Calvin College is considering an addition to the West Wing of the Spoelhof Center to provide additional space for the art and business programs. The construction of this new addition provides the opportunity to investigate the feasibility of installing new, sustainable technology. This semester the students of Engineering 333 were presented with the following challenge: “What it will take for Calvin College to install a geothermal HVAC system for the West Wing?” A geothermal HVAC (heating, ventilation, and air conditioning) system utilizes the relatively constant temperature of the earth to provide heating during winter and cooling during summer. Geothermal HVAC …