Civil and Environmental Engineering Commons^™

Location Of Cerium In Coal-Combustion Fly Ashes: Implications For Recovery Of Lanthanides, James C. Hower, John G. Groppo, Prakash Joshi, Shifeng Dai, David P. Moecher, Michelle N. Johnston

Coal Combustion and Gasification Products Journal Archive

Given the worldwide demand for rare earth elements (REEs) in modern electronics, all potential sources of the REEs should be investigated. Coal-combustion fly ash represents a potential source of REEs. Fly ashes, derived from the combustion of coals from Kentucky in the United States and Jungar in China, were examined by wavelength-dispersive spectrometry electron microprobe analysis of epoxy-bound polished pellets. From previous studies, it was known that the REEs did not show any enrichment relative to flue gas temperature at the point of collection or to the particle size, that is, external surface area, of the particles. Cerium, the most …

Chemical Partitioning And Mobility Of Trace Elements In Dry Disposed Weathered Ash Conditioned With High-Saline Effluents, S.A. Akinyemi, A. Akinlua, W.M. Gitari, R.O. Akinyeye, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

Weinvestigated the mobility of inorganic elements in the ash dump due to chemical interaction of weathered dry disposed ash conditioned with high-saline effluents and ingressed CO2 from atmosphere and percolating rainwater. Drilled ash core samples collected from dry disposed ash dump at a South African coal-burning power station were characterized using X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses. A modified sequential extraction procedure was selected to determine the mineralogical association of the investigated elements in the 1-year-old drilled ash cores. Major mineral phases are quartz and mullite and other minor phases included hematite, lime, calcite, anorthite, mica, and enstatite. …

Effects Of Coal Combustion By-Product–Encapsulated Ammonium Nitrate On Wheat Yield And Uptake Of Nitrogen And Metals, Eton E. Codling

Coal Combustion and Gasification Products Journal Archive

Ammonium nitrate (AN) is an essential plant nutrient for plant growth. Ammonium nitrate is also an ingredient in explosives. Research is being conducted on reducing the explosiveness of AN by encapsulating it with the use of coal by-products. The objective of this greenhouse pot study was to determine the effects of class C and F fly ash and flue gas desulfurization-gypsum-encapsulated AN on biomass, grain, and straw yield and nitrogen and metals uptake by wheat. Encapsulated AN was mixed with a low-nitrogen soil at 56 and 112 kg N ha^-1^, as well as unencapsulated AN as a control, and planted …

Geotechnical Characterization Of Clinker-Stabilized Fly Ash–Coal Mine Overburden Mixes For Subbase Of Mine Haul Road, Soumya Ranjan Mallick, Manoj Kumar Mishra

Coal Combustion and Gasification Products Journal Archive

Fly ash is a major by-product of thermal power plants that adversely affects land, water, and air. Its gainful utilization in many areas is being continuously explored. Use of fly ash in opencast coal mine haul road construction is one such option. This article reports detailed laboratory investigations carried out on clinker-stabilized fly ash–mine overburden mixes to evaluate their suitability for subbase of mine haul roads. Composite materials were prepared from fly ash, mine overburden, and clinker at different proportions. Proctor compaction test, unconfined compressive strength (UCS), and ultrasonic pulse velocity tests were carried out at different curing periods. UCS …

Variability Of Extreme Precipitation In Coastal River Basins Of The Southern Mexican Pacific Region, Nancy Perez-Morga, Thomas Kretzschmar, Tereza Cavazos, Stephen V. Smith, Francisco Munoz-Arriola

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Extreme wet and dry years (± 1 standard deviation, respectively), as well as the top 95 percentile (P95) of daily precipitation events, derived from tropical cyclone (TC) and nontropical cyclone (NTC) rainfall, were analyzed in coastal river basins in Southern Oaxaca, Mexico (Río Verde, Río Tehuantepec, and the Southern Coast). The study is based on daily precipitation records from 47 quality-controlled stations for the 1961 to 1990 period and TC data for the Eastern Tropical Pacific (EPAC). The aim of this study was to evaluate extreme (dry and wet) trends in the annual contribution of daily P95 precipitation events and …

A Note On The Occurrence Of Yttrium And Rare Earth Elements In Coal Combustion Products, James C. Hower, Shifeng Dai, Vladimir V. Seredin, Lei Zhao, Irena J. Kostova, Luis F.O. Silva, Sarah M. Mardon, Gulbin Gurdal

Coal Combustion and Gasification Products Journal Archive

There is an international need for a variety of lanthanide elements (rare earth elements, or REEs) in modern electronic and related components. This has led to a desire to broaden production from both previously productive locations and to expand production to new sources, possibly including coal-derived fly ash. The concentration of lanthanides in coal-combustion fly ash depends on a number of factors, one of the most important being the concentration of the elements in the feed coal. Unlike some elements, such as Zn and As, the REE concentration is largely not a function of element volatility. In this study, we …

Fouling Intensity Of Three Indian Coals, S. Balakrishnan, R. Nagarajan

Coal Combustion and Gasification Products Journal Archive

Ash particles can arrive at heat-transfer surfaces either in solid (solidified) state or in molten state, depending on the factors such as location inside the boiler, temperature, and residence time. In this study, arrival of ash particles in solid state, which can occur in the convective section of the boiler, was considered. Apart from the inertial force that drives particles .10 mmto the surface, the low-melting inorganic alkali vapors play a vital role in deposit formation by promoting sticking. Chemical equilibrium calculations were performed to calculate the equilibrium composition of flue gas, as well as the amount of condensable inorganic …

Investigation Into The Measure, Correlate And Predict Methodologies Used In Wind Farm Design Software, Brendan O'Sullivan

Theses

This paper is focused on the Measure Correlate and Predict (MCP) methodologies used to estimate long term wind resource at a prospective site. The first common step in all MCP methodologies is a successful wind measurement campaign at the prospective site. This campaign involves the erection of a wind measurement mast (ideally to the hub height of the proposed turbine) and careful selection of booms, mountings and anemometers. The wind measurement campaign is a vital part of the process as the correlation and prediction analysis is only as accurate as the measured wind data. Correlation is a measure of the …

Product Characterization And Headspace Analysis Of Solar Irradiated Aqueous C60 Clusters, Dan Su

Open Access Theses

Buckminsterfullerene (C60) is an important fullerene material that has drawn much attention and is currently being applied in many different fields. It was discovered in 1985. As its production has largely increased to meet these industrial needs, it is obvious that its environmental occurrence, especially in aqueous systems, will occur. To further provide information for environmental toxicity studies and for its risk assessment, this thesis focuses on the photo transformation processes of aqueous C60 clusters (Aqu/nC60), with a particular interest in measuring any mineralization that occurs under different irradiation conditions. Two sets of experiments were conducted to test for CO2 …

Degradable Plastics And Solid Waste Management Systems, David J. Tonjes, Krista L. Thyberg

Technology & Society Faculty Publications

Plastics, which are woven into the fabric of modern life, have consequential impacts on the environment. Many of these are associated with end-of-lifetime processes, and include chemical contamination of the environment and effects from litter. Plastics also complicate waste management processes, causing contamination in composting operations, and having poor recovery rates through recycling. Plastics that are not as biologically recalcitrant, that decompose when use is done, have been perceived as solutions to at least some of these problems. The first generation of degradable plastics did not meet marketing claims; some of the more recent formulations, partly as a consequence of …

Municipal Waste Management: Suffolk County Municipal Systems, Services And Infrastructure, Krista L. Greene, Susan Lienau, David J. Tonjes

Technology & Society Faculty Publications

This report describes the municipal waste management systems used by local governments to manage solid waste in Suffolk County, Long Island, New York. There are ten Towns that serve as the primary planners for waste systems in Suffolk County. Many of the 33 villages in Suffolk County have established their own waste management programs and policies. All programs tend to follow the same general plan of the approaches used by their respective Towns, however. All programs provide some degree of recycling services, although the scope of the services varies tremendously.

A Classification Methodology For Landfill Leachates, David J. Tonjes

Technology & Society Faculty Publications

A characterization scheme based on landfill leachate chemical signatures could support studies of leachate evolution over time, liner performance, and help confirm or disprove potential leachate contamination of groundwater. Wide variations in single constituents across time, sites, and site practices, and inconsistencies related to common bivariate measures suggest a robust, multivariate analysis could be useful. A variant Stiff diagram approach (a subjective analytical comparison of soluble salts) has been developed, and supports graphical depictions of multiple samples. The hypothesis is that leachates with similar chemistry form clusters, and this was tested using a data set of 652 samples from 26 …

Derivation Of A Fuzzy National Phosphorus Export Model Using 84 Irish Catchments, Ahmed Nasr, Michael Bruen

Articles

Implementation of appropriate management strategies to mitigate diffuse phosphorus (P) pollution at the catchment scale is vitally important for the sustainable development of water resources in Ireland. An important element in the process of implementing such strategies is the prediction of their impacts on P concentrations in a catchment using a reliable mathematical model. In this study, a state-of-the-art adaptive neuro-fuzzy inference system (ANFIS) has been used to develop a new national P model capable of estimating average annual ortho-P concentrations at un-gauged catchments. Data from 84 catchments dominated by diffuse P pollution were used in developing and testing the …

Biomass Production And Hydrological/Water Quality Impacts Of Perennial Crop Production On Marginal Land, Qingyu Feng

Open Access Theses

Marginal land has been proposed to be a viable choice for biomass production to meet the biofuel development goal set by Energy Independence and Security Act (EISA). However, very little information is currently available for quantifying biomass production potential and impacts on hydrology and water quality. The objectives of this study were to: (1) quantify availability of marginal land in a typical agricultural watershed; (2) test whether the biomass feedstock produced from marginal land in the study watershed can support a hypothetical small bio-refinery with annual capacity of 50 million gallons of ethanol produced; and (3) evaluate the hydrological/water quality …

Photochemical Reactions Of Naproxen, Ibuprofen And Tylosin, Yang He

Open Access Theses

Pharmaceuticals and personal care products (PPCPs) include a wide range of compounds that are used extensively and sometimes daily by people. Some PPCPs have been detected in surface water (streams, rivers, lakes) due to incomplete removal in wastewater treatment plants. The water contaminated by PPCPs is harmful to aquatic organisms and human. Naproxen (NXP), ibuprofen (IBP) and tylosin (TYL) are chosen as representative PPCPs in the current research, because they are consumed in large quantities throughout the world and there is limited data about photodegradation of these compounds in aqueous solution at the wavelength of 254 nm.

The combination of …

An Evaluation Of Spatial Variability Of Water Stress Index Across The United States: Implications Of Supply And Demand In The East Vs The West, Jennifer Ann Roath

Open Access Theses

In order to support both human and environmental needs, high quality fresh water must be available when and where it is required. As a metric for indicating unsustainable water usage, WSI is only useful when the values reflect accurate interactions between supply and demand; however, the complexity of temporal and spatial variability of available fresh water complicates the analysis of water stress.

The overall goal of this project was to investigate the spatial variability of water stress across the United States and the appropriate spatial scale for management decisions. To accomplish this, a national dataset describing spatial distribution and breakdown …

Nutrient Recovery From Anaerobically-Digested Dairy Manure By Struvite Formation And Its Effect On Gas Releases, Zhong Qiao

Open Access Theses

Manure management practices such as anaerobic digestion and lagoon storage have become important issues for large dairy farms partially due to water quality and air quality concerns caused by excess nitrogen and phosphorus. Prior research efforts have proven that struvite formation is an effective method for nutrients recovery from both municipal and agricultural wastewaters. However, little is known about nutrient recovery through struvite formation from anaerobically-digested dairy manure effluents.The effects of struvite precipitation on the releases of gases such as NH3, H2S, and CO2 are also unclear.

In this thesis, both bench-scale tests and pilot-scale storage tests were conducted to …

Chemical Weathering And Mobility Of Inorganic Species In Dry Disposed Ash: An Insight From Geochemical Fractionation And Physicochemical Analysis, S.A. Akinyemi, W.M. Gitari, A. Akinlua, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

The burning of low-grade coal produces vast amounts of ash and other solid by-products. In South Africa, coal combustion by-products undergo disposal on land as dry heaps or slurried to dams. In this study, the geochemical partitioning, transport, and mobility of elements in dry disposed ash dumps were investigated using a modified sequential extraction scheme. The chemical and mineralogical compositions of 50 drilled core samples were investigated by X-ray fluorescence (XRF), X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry. Ternary plots of major elements as determined by XRF showed that the 15-year-old and 2-week-old dry disposed ashes are sialic, …

2013 Nebraska Groundwater Quality Monitoring Report

Nebraska Department of Environmental Quality: Reports

The 2001 Nebraska Legislature passed LB329 (Neb. Rev. Stat. §46-1304) which, in part, directed the Nebraska Department of Environmental Quality (NDEQ) to report on groundwater quality monitoring in Nebraska. Reports have been issued annually since December 2001. The text of the statute applicable to this report follows: “The Department of Environmental Quality shall prepare a report outlining the extent of ground water quality monitoring conducted by natural resources districts during the preceding calendar year. The department shall analyze the data collected for the purpose of determining whether or not ground water quality is degrading or improving and shall present the …

Sustainability Of Water And Wastewater Infrastructure: Using A Public-Private Partnership Model For Project Financial Assessment, Rebecca Werner Trotter

Electronic Theses and Dissertations

To supplement current and future budget shortfalls for improvements to water and wastewater infrastructure, Public-Private Partnerships (PPPs or P3) are being advocated by the American Society of Civil Engineers (ASCE) and others as a practical mechanism to ensure financial sustainability. A PPP involves a partnership between a government entity and a concessionaire--consisting of one or more private companies acting as a single, private incorporation--who make an agreement on funding, building, and operating a usually government-provided service, such as drinking water and wastewater infrastructure. This is different from a traditional contract between a government entity and a contractor because the concessionaire …

Characterization Of Particulate Matter Concentrations (Pm10, Pm10-2.5, And Pm2.5) At High-Altitude School And Residential Mircroenvironments In Quito, Ecuador, Teresa Montoya

Open Access Theses & Dissertations

Air quality issues in Latin American countries are especially challenging because of the limited availability of resources to address them, lack of stringent standards and the rapid and uncontrolled growth of their cities increasing the number of vehicles on the road and the expansion of the industry. In particular, the city of Quito, Ecuador exacerbates its environmental issues by its high-altitude (2800 m above sea level) coupled by its location around a mountain valley and frequent temperature inversions.

This study focused on evaluating the spatial variation of the PM concentrations and the effectiveness of a central monitoring network in representing …

Classification Of Irish Beaches To Determine Their Potential For Erosion, Aidan O'Connell

Theses

The objective of this literature review is to gather the relevant information regarding beach characteristics and beach erosion in order to undertake the project development stage of the thesis project. The background information that was reviewed was the different zones that are located on a beach; the functions of a beach and what most beaches are commonly used for; how beaches were formed; the legislation that is related to the beach or any work that is required to be carried out on a beach and some background information on the erosion of beaches.

The most relevant beach characteristics that impact …

Biological Control Of Manganese In Water Supplies In The Presence Of Humic Acids, Michael S. Snyder

Theses and Dissertations--Civil Engineering

The main objective of this study was to improve our understanding of biological filtration (biofilm type) treatment for manganese (Mn) removal in drinking water. Biological filtration treatment involves biofilms of Mn(II)-oxidizing microorganisms attached to solid filter material that remove and immobilize dissolved Mn(II) in raw water by conversion to black MnO_2(s) precipitates. Mn-biological filtration is an emerging green technology that can serve as an alternative to conventional physicochemical treatments but its full potential is hindered by various factors. These include lack of understanding the: (1) optimal removal conditions for Mn, (2) mechanisms for Mn releases of the accumulated Mn …

Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine

Theses and Dissertations--Biosystems and Agricultural Engineering

Impervious surfaces such as roads, sidewalks, and roofs increase the volume of runoff generated in a watershed. Traditional stormwater management techniques emphasize conveyance of runoff away from impervious surfaces in order to reduce flooding. Rain gardens are becoming popular as a different means to manage stormwater in such a way that runoff is captured and infiltrated onsite rather than conveyed offsite. A stormwater management system consisting of a rainwater harvest system, rain garden, and infiltration chamber was built at the Coca-Cola Refreshments USA, Inc. distribution center in Lexington, Kentucky during the fall of 2011. Precipitation, inflow, and water level were …

Froth Flotation Performance Enhancement By Feed Cavitation And Magnetic Plastic Particle Addition, Mehmet Saracoglu

Theses and Dissertations--Mining Engineering

Froth flotation is the most commonly used process to recover and upgrade the portion of the coal preparation plant feed that has a particle size smaller than 150 microns. Problems that occur when employing froth flotation in the coal industry include i) coal surfaces that are weakly-to-moderately hydrophobic, and ii) flotation systems that are overloaded and limited by insufficient retention time.

Research was performed to evaluate techniques that could be implemented to improve flotation performance under the aforementioned scenarios. Pre-aeration of flotation feed using a cavitation system was extensively evaluated in laboratory and full-scale test programs. The benefits of adding …

Chemophysical Characteristics And Application Of Biosorption Activated Media (Bam) For Copper And Nutrient Removal In Stormwater Management, Jamie Jones

Electronic Theses and Dissertations

For high groundwater table areas, stormwater wet detention ponds are utilized as the preferred stormwater management throughout the state of Florida. Previous research has found that accumulations of nutrients, algae, heavy metals, pesticides, chlorophyll a, fecal coliform bacteria and low concentrations of dissolved oxygen (DO) are common characteristics of stormwater wet detention ponds. Although these pollutant levels are not regulated within the ponds, states are required to compute the pollutant load reductions through total maximum daily load (TMDL) programs to meet the water quality requirements addressed by the Clean Water Act (CWA). In this study, field sampling data of stormwater …

Integrated Data Fusion And Mining (Idfm) Technique For Monitoring Water Quality In Large And Small Lakes, Benjamin Vannah

Electronic Theses and Dissertations

Monitoring water quality on a near-real-time basis to address water resources management and public health concerns in coupled natural systems and the built environment is by no means an easy task. Furthermore, this emerging societal challenge will continue to grow, due to the ever-increasing anthropogenic impacts upon surface waters. For example, urban growth and agricultural operations have led to an influx of nutrients into surface waters stimulating harmful algal bloom formation, and stormwater runoff from urban areas contributes to the accumulation of total organic carbon (TOC) in surface waters. TOC in surface waters is a known precursor of disinfection byproducts …

Assessment, Optimization, And Enhancement Of Ultrafiltration (Uf) Membrane Processes In Potable Water Treatment, Christopher Boyd

Electronic Theses and Dissertations

This dissertation reports on research related to ultrafiltration (UF) membranes in drinking water applications. A pilot-scale investigation identified seasonal surface water quality impacts on UF performance and resulted in the development of a dynamic chemically enhanced backwash protocol for fouling management. Subsequent analysis of UF process data revealed limitations with the use of specific flux, transmembrane pressure (TMP), and other normalization techniques for assessing UF process fouling. A new TMP balance approach is presented that identifies the pressure contribution of membrane fouling and structural changes, enables direct process performance comparisons at different operating fluxes, and distinguishes between physically and chemically …

Evaluation Of The Biodegradability And Toxicity Of Pca And Mpca, Juan Rueda

Electronic Theses and Dissertations

The main types of hypergolic propellants used at Kennedy Space Center (KSC) are hydrazine (HZ) and monomethylhydrazine (MMH). HZ and MMH are classified as hazardous materials and they are also known to be potentially carcinogenic to humans; therefore, handling these substances and their waste is strictly regulated. The wastes streams from HZ and MMH have been estimated to be the main hazardous wastes streams at KSC. Currently at KSC these wastes are first neutralized using citric acid and then they are transported on public roads for incineration as hazardous materials. A new method using alpha ketoglutaric acid (AKGA) was proposed …

Development Of A Chemical Kinetic Model For A Fluidized-Bed Sewage Sludge Gasifier, Wyatt Champion

Electronic Theses and Dissertations

As the need for both sustainable energy production and waste minimization increases, the gasification of biomass becomes an increasingly important process. What would otherwise be considered waste can now be used as fuel, and the benefits of volume reduction through gasification are seen in the increased lifespan of landfills. Fluidized-bed gasification is a particularly robust technology, and allows for the conversion of most types of waste biomass. Within a fluidized-bed gasifier, thermal medium (sand) is heated to operating temperature (around 1350°F) and begins to fluidize due to the rapid expansion of air entering the bottom of the reactor. This fluidization …