Thermodynamics Commons^™

Deep Learning Based Control System For Multi-Zone Hvac Residential Buildings, Mohammad H. Z. Alghalayeeni

Mechanical Engineering Theses

Heating, ventilation, and air conditioning (HVAC) systems are major contributors to residential energy consumption. However, most homes continue to rely on single zone thermostat control, which regulates temperature based on a single sensor and cannot account for thermal variations across multiple rooms. This often leads to uneven thermal conditions and inefficient energy use in multi-zone residential buildings. This thesis presents a deep reinforcement learning based approach for improving HVAC zoning control through dynamic airflow distribution. A physics based multi zone thermal model of a residential house was developed to simulate heat transfer processes including conduction, convection, solar and internal heat …

Effect Of Inter Electrode Distance On Electrochemical Mineralization Of Calcium Carbonate In Mildly Acidic Environments, Irene Walker, Ivy Wu, Steven Decaluwe, Robert Bell, Kerry Rippy

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

The effect of inter electrode distance (IED) on electrochemical mineralization in a parallel plate cell with a stainless-steel working electrode is presented. Three IEDs were tested, 6.5 mm, 15.5 mm, and 22.0 mm, for their water reduction effectiveness to create a region of local alkalinity that stimulates calcium carbonate precipitation in mildly acidic conditions. Chronoamperometry at -1.6 V for 30 minutes with ex-situ optical microscopy and scanning electron microscopy (SEM) were used. At the smallest IEDs, crystal clusters formed in growth-favored regimes as compared to the largest IED, where nucleation dominated, leading to encasement of the SS mesh. Rapid precipitation …

Root Cause Analysis Of Performance Degradation For An Xyz Thermal Power Plant In Tanzania, Simon I. Marandu

Tanzania Journal of Engineering and Technology (TJET)

Thermal power plants in Tanzania have been experiencing performance degradation, typically arising from component and subsystem failures, which contribute to power system instability and unreliability. This paper presents a case study of the root causes of performance degradation of an XYZ thermal power plant. The study was conducted by reviewing plant documentations, including maintenance and operational data logbooks, and by standardising the approach through the adoption of ISO 14224:2016 for maintenance and reliability data exchange. Data evaluation was carried out using principal component analysis and scree plot analytical techniques to enhance the depth and accuracy of root cause identification. Additionally, …

Fabrication And Performance Of Scalable Bio-Engineered Porous Layers For Efficient Co2 Capture, Mary Sharon Rose Bondugula

Theses and Dissertations

This dissertation addresses the critical challenge of mitigating climate change by advancing CO2 capture technologies. As global CO2 emissions continue to rise, effective methods for capturing and separating CO2 from industrial processes are essential to combat climate change. Existing CO2 capture systems, such as Pressure Swing Adsorption (PSA) and Temperature Swing Adsorption (TSA), often rely on packed bed designs that face limitations, including poor heat and mass transfer, slow gas diffusion, and low thermal conductivity, reducing their efficiency. To overcome these challenges, this dissertation explores innovative solutions by developing advanced adsorbent coatings and scalable bed configurations.

This research begins by …

Synthesis Of Durable Zeolite 13x Insertion Coatings And Scaled-Up Experimental Demonstration For Co2 Capture, Daniel Jamil Hocheimy

Theses and Dissertations

Minimizing the energy requirement for capturing carbon dioxide (CO₂) from post-combustion sources is critical to efficient industrial decarbonization and subsequent mitigation of the effects of climate change. The current portfolio of CO₂ capture technologies includes absorption, membrane separation and packed bed adsorption, which suffer from high energy and temperature requirements, scalability, and location dependency issues. Adsorption-based systems could cater to these concerns; however, their current embodiments primarily use packed adsorbent bed design and electricity-driven vacuum pumps to regenerate them. While simple and easy to fabricate, these designs are not scalable and cannot use heat to regenerate them …

Benchmarking Of A Sco2 Heat Exchanger Flow Loop, David Velasco

Doctoral Dissertations and Master's Theses

Heat transfer of supercritical carbon dioxide (sCO2) was studied experimentally by commissioning a sCO2 flow loop featuring a horizontal tube-in-tube counterflow heat exchanger with a circular cross section. The main objective was to establish experimental heat transfer research capabilities for sCO2 at Embry-Riddle Aeronautical University’s (ERAU) Thermal Science Lab. sCO2 experiences a drastic change in thermophysical properties near its critical point that results in unique heat transfer characteristics. The high pressures at which sCO2 exists make the large gradients in thermophysical and transport properties difficult to study, experimentally and numerically. However, understanding the heat transfer characteristics and thermophysical behavior of …

Mathematical Modeling Of Coupled Heat And Mass Transfer In Metal-Hydride Hydrogen Storage Systems, Muhammad Hasnain

College of Graduate Studies: Theses & Dissertations

As a promising clean energy carrier hydrogen has recently gained significant interest, but its efficient and safe storage is a major challenge. Compared to the gaseous state and liquid state, metal hydrides (MH) offer a potentially more effective storage approach for hydrogen. However, the main challenge in this approach is the low thermal conductivity of the MH bed that leads to low heat transfer and ultimately to higher charging and discharging times. The purpose of this work is to develop an in-house comprehensive heat and mass transfer model for hydrogen sorption in MH reactors to simulate the dynamic behavior of …

Numerical Modeling Of Thermal Runaway In Lithium-Ion Batteries Using Decomposition Kinetics And Inter-Cell Contact Resistance, Shehzad Khan

College of Graduate Studies: Theses & Dissertations

Lithium-ion batteries (LIBs) are central in numerous high-demand applications due to their high energy density and prolonged cycle life. Despite these advantages, their susceptibility to thermal runaway (TR) poses a significant safety risk, with the potential for catastrophic failures. This study focuses on the thermal behavior of prismatic lithium-ion cells, using a finite volume-based partial differential equation (PDE) solver developed in MATLAB and JULIA to model TR behavior. This solver accurately simulates transient behaviors, convection, diffusion, and source terms across various coordinate systems. By engaging in a series of increasing complex case studies, this research aims to identify the critical …

Data-Driven Modeling Of Oxygen Kinetics In La0.6sr0.4co0.2fe0.8o3−Δ (Lscf) For High-Temperature Reduction Of Co2 In An Electrolysis Cell, Ferron Campbell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Electrolysis systems are critical to several societal applications, particularly energy storage and conversion. Developing these systems requires a detailed knowledge of the chemistry and thermodynamics of the materials used in the electrolysis cell. This work focuses on using embedded scientific machine learning as an efficient way to build an interpretable model for the reaction and transport kinetics in the LSCF electrode, whose performance directly influences the electrolysis system’s performance. The models developed in this study are trained using the publicly available machine learning package, FoKL-GP. This package incorporates a robust Gibbs sampler that employs a forward variable selection process to …

Employment Of Intelligent Predictive Maintenance On Thermal Power Plant Component Parts Taking Condenser Vacuum As A Case Study, Titus Ajewole

Tanzania Journal of Engineering and Technology (TJET)

This work proposes deployment of machine learning in the maintenance of individual constituent parts of steam power plant assemblages. With the condenser vacuum of a steam turbine (in a six-turbine plant assemblage) taken as a case study, information on the past operating parameters of the selected plant component was used to forecast its future working condition. Based on Exponential Gaussian Process of Regression, a model was developed, trained using the diachronic operational data, and employed in determining the future. A quantitative evaluation was employed to provide the distribution of the test values of the data about the lines of regression, …

Attrition Study Of Copper-Supplemented Iron-Based Oxygen Carrier For Chemical Looping Combustion, Neng Huang

Theses and Dissertations--Mechanical and Aerospace Engineering

Chemical looping combustion (CLC) is a promising technology that can mitigate the carbon emissions for power generation. The cost of oxygen carriers (OCs) impedes the scale up of CLC. Compared to synthetic iron-based OCs, red mud (RM), an abundant iron-based solid waste from industry, is a cost-effective choice due to its intrinsic inclusion of both inert and catalytic phases that are crucial for CLC. It was anticipated that the addition of copper oxide to RM using a mechanical mixing method that can be easily scaled up would enhance both reactivity and oxygen transport capacity (OTC), and the heat of reaction …

Combustion Characteristics Of Methane, Ethane, Propane, And Butane Blends Under Conditions Relevant Of A Dual-Fuel Diesel And Natural Gas Engine, Christopher Joseph Ulishney

Graduate Theses, Dissertations, and Problem Reports (ETD)

As natural gas production infrastructure is already in place in most of the world and will continue expanding for the foreseeable future, natural gas is an alternative to traditional liquid petroleum fuels in heavy-duty engines. Dedicated natural gas or dual-fuel diesel-natural gas heavy-duty engines are alternatives to diesel-only power generation equipment. One challenge is the large variation in the natural gas composition available for such applications, which is known to significantly affect engine’s combustion characteristics and the emissions composition. As the literature on dual-fuel combustion under low load engine operating conditions that use more realistic natural gas mixtures (i.e., mixtures …

Evaluating Electrification Of Fossil Fuel-Fired Boilers For Decarbonization Using Discrete Event Simulation, Nahian Ismail Chowdhury

Graduate Theses, Dissertations, and Problem Reports (ETD)

Decarbonizing fossil fuel usage is crucial in mitigating the impacts of climate change. CO2, which comprises the major portion of greenhouse gas, is emitted from burning fossil fuels. One of the significant sources of fossil fuel user is industrial process heating, and most of the heating in industrial processes is achieved through boilers. Electrification is a promising solution for decarbonizing these boilers, as it enables renewable energy sources to generate electricity, which can then be used to power the electric boilers. The electrification of boilers can reduce greenhouse gas emissions, improve air quality, and increase energy efficiency. However, it requires …

Development Of Advanced Models For Pre-Ignition Prediction In Gas Engines And Analytical Model For Wallfilm Evaporation, Ankith Ullal

Dissertations, Master's Theses and Master's Reports

Ever-changing regulations aimed at improving efficiency and reducing harmful emissions have resulted in many power-generation device (engine) manufacturers to adopt new strategies. Computer simulation of these new strategies of power generation requires more accurate and higher fidelity modelling tools. In the present study, two such models are developed. The first model deals with pre-ignition phenomena driven by lubricant (lube) oil in natural gas engines and the second model is relevant to prediction of wallfilm evaporation by employing analytical solutions to transport governing equations for boundary layers.

Pre-ignition in engines has been the subject of current research with the advent of …

Nonmetallic Jet Impingement Thermal Management For Power Electronics Via Additive Manufacturing, Reece Whitt

Graduate Theses and Dissertations

The increase in energy demanded by transportation and energy sectors has necessitated highly efficient thermal management for reliable power electronics operations. Conventional cooling techniques are limited by their inability to target switching location hot spot temperatures, leading to non-uniform thermal gradients. These devices, such as cold plates and heat sinks, also utilize heavy metallic structures that can accentuate electromagnetic interferences generated by high voltage switching processes. This work proposes a non-metallic jet impingement cooler for more customized thermal management, while simultaneously reducing the harmful effects of electromagnetic interferences. Additive manufacturing is utilized to enable jet impingement zones to target individual …

Economic Feasibility Of Mixed Plastic Waste Pyrolysis Using Twin Reactor System In Northwest Arkansas, Carol Rogers, Patricia Means, Renato Gonzalez, Kaida Sheets, Hayden Townsend

Chemical Engineering Undergraduate Honors Theses

Plastic waste generation is increasing at an unsustainable rate while recycling solutions remain stagnant. As a chemical means of recycling, mixed plastic waste pyrolysis can generate synthetic oil appropriate for use as fuel in power generation from plastic waste that otherwise accumulates in landfills. With the scaling of a commercial plastic pyrolysis process in Northwest Arkansas (NWA) modeled after an operational sawdust pyrolysis unit in Huntsville, Arkansas, economic analysis resulted in 26.3% internal rate of return. Therefore, construction of a commercial mixed plastic-to-fuel pyrolysis plant is economically justified and should be pursued. To effectively implement the proposed design, NWA must …

Thermodynamic Analysis And Optimization Of Organic Rankine Cycles Using 1-Butylpyridinium Tetrafluoroborate As A Geothermal Fluid, Kazemi Shabnam

Student Works (2020-2029)

Organic Rankine cycle (ORC) is a promising technology for electricity generation by utilizing heat sources at low to moderate temperature that ranges between 80-350° C. In the present work, an ionic liquid (1-butylpyridinium tetrafluoroborate, C9H14NBF4), a known green chemical and non-volatile compound with good thermal and chemical stability, significant heat capacity, low vapor pressure and a wide liquid temperature range (25 to 459 °C), is utilized as a geothermal fluid. Simulation and optimization were conducted for a basic organic Rankine cycle (basic ORC), a regenerative organic Rankine cycle (RORC) and a two-stage evaporative organic Rankine cycle (TSORC) by maximizing exergy …

What Difference Does A Catalyst Make?, Tammy Guthrie, Mike Jackson, Holly Haney

High School Lesson Plans

Students will use different catalysts for the decomposition of Hydrogen Peroxide, to determine if different catalysts affect the energy that is generated during the reaction.

Coarse-Grained Dynamically Accurate Simulations Of Ionic Liquids At Vacuum-Interface, Tyler D. Stoffel

Theses and Dissertations--Mechanical and Aerospace Engineering

Ionic liquids, possessing improved properties in many areas of technical application, are excellent candidates as components in development of next-generation technology, including ultra-high energy batteries. If they are thus applied, however, extensive interfacial analysis of any selected ionic configuration will likely be required. Molecular dynamics (MD) provides an advantageous route by which this may be accomplished, but can fall short in observing some phenomena only present at larger time/length scales than it can simulate. Often times this is approached by coarse-graining (CG), with which scope of simulation can be significantly increased. However, coarse-grained MD systems are generally known to produce …

Electrification Of Domestic Hot Water To Aid The Integration Of Renewable Energy In The California Grid, Alejandro Cervantes

Cal Poly Humboldt theses and projects

Water heating in residential buildings, also known as domestic hot water (DHW), is the third largest use of energy after appliances and space conditioning. About 90% of the residential buildings in the state use natural gas fueled water heaters, 6% use electricity, and a small percent use liquefied petroleum gas (LPG) or solar water heaters. The current energy use associated with residential water heating is small relative to the total amount of energy consumption in the residential building sector, but it is still a contributor of greenhouse gas (GHG) emissions. Improving hot water systems can be beneficial for bill customer …

Capillary Forces And Wetting Dynamics By Diffuse-Interface Modeling, Fanny Thomas

Dissertations and Theses

Wetting phenomena underlie many natural and industrial processes, from the proper functioning of the lungs to the thin coating of surfaces. The three-phase interactions involved at microscopic scales play a critical role. Adding solid particles to an emulsion, for example, can drastically change the flow behavior due to capillary bridging between the particles. The study of these three-phase systems is especially relevant to the petroleum industry, where gas hydrates forming large clusters in subsea pipelines during crude oil transportation is a major concern. The dynamics of such systems is also of great interest from a fundamental perspective. Indeed describing non-equilibrium …

Experimental And Computational Characterization Of Sodium Nitrate @ Silica Nano Capsules For Thermal Energy Storage Applications, Wataru Hashimoto

Graduate Research Theses & Dissertations

In this investigation, a nanocapsule composed of a sodium nitrate core and a silicon dioxide shell is synthesized, characterized, and analyzed utilizing a mixture of analytical and computational tools. The sol-gel method was selected as the process of nanoencapsulation. Analytical characterization techniques employed in this investigation include differential scanning calorimetry (DSC) to measure melting temperatures and enthalpies of fusion, dynamic light scattering (DLS) to calculate particle size distributions, scanning electron microscopy (SEM) to analyze surface characteristics, transmission electron microscopy (TEM) to perform shell characterization, and energy dispersive X-ray spectroscopy (EDS) to determine chemical composition. Preliminary results indicated a decrease in …

The Potentials Of Faecal Sludge Treatment Using Local Conditioners In Tanzania: A Review, Doglas Benjamin1

Tanzania Journal of Engineering and Technology (TJET)

Worldwide, every day human beings generate millions of tons of Faecal Sludge (FS), which is rich in water, nutrients, energy, and organic compounds. Yet FS is not being managed in a way that permits us to derive value from its reuse, while at the same time, millions of farmers struggle with depleted soils and lack of water. In most of the developing countries, energy for cooking is mainly derived from cutting of trees, either as wood or charcoal. Resource recovery and reuse from FS can create livelihoods, enhance food security, support green economies, reduce waste and contribute to cost recovery …

Energy Transformation And Conservation Investigation, Mike Jackson, Holly Haney

High School Lesson Plans

Students will use a thermoelectric generator module to analyze the relationship between thermal and electrical energies. Using data collection sensors and analysis software, students will investigate the relationship between the temperature gradient across a thermoelectric generator module and the resulting electrical potential. Students will then use their data and analysis to solve problems relating to waste thermal energy in electrical systems and communicate their work to their peers and teacher.

What Can I Do As A Student To Make A Positive Impact On The Environment?, Tammy Guthrie, Greg Herzig, Kathy Prophet, Cassie Kautzer

Middle School Lesson Plans

Students discover ways they can make a positive impact on the environment.

Investigation On The Potential Of A Co2 Capture System, Downstream Of The Aftertreatment System For A Heavy-Duty Engine Application, Murchana Pathak

Dissertations, Master's Theses and Master's Reports

The transportation sector accounts for the second largest source of CO₂ emissions after power generation. New Corporate Average Fuel Economy (CAFE) regulations are focusing on improving energy through reduced fuel consumption and greenhouse gas emissions. This work investigates the potential of a CO₂ capture system downstream of an aftertreatment system for a heavy-duty engine application. Amine absorption has been described as one of the most effective ways to capture CO₂ from the exhaust for point sources. Therefore, using thermal-swing absorption process with potassium carbonate (K₂CO₃) as the absorbent liquid, a process was analyzed …

Energy From Chemical Reactions: Understanding The Combustion Engine, Tammy Guthrie, Kathy Prophet, Greg Herzig, Cassie Kautzer

Middle School Lesson Plans

Automobiles produce a large amount of heat generated by the burning of gasoline. Burning gasoline is a chemical reaction that causes a phase change. This is called combustible energy. During combustion fuel combines with oxygen to release energy (such as heat, light, sound) along with another product that is often considered waste. Most of the energy produced is not used to power the automobile, but is released as heat. 19.3 pounds of the greenhouse gas, carbon dioxide, is produced from the combustion of 1 gallon of U.S. gasoline according to the U.S. Energy Information Administration.

Method For Carbon Dioxide Splitting, James E. Miller, Richard B. Diver, Nathan P. Siegel

Other Faculty Research and Publications

A method for splitting carbon dioxide via a two-step metal oxide thermochemical cycle by heating a metal oxide compound selected from an iron oxide material of the general formula A_xFe_3-xO₄, where 0≦x≦1 and A is a metal selected from Mg, Cu, Zn, Ni, Co, and Mn, or a ceria oxide compound of the general formula M_aCe_bO_c, where 0

Heat Transfer Analysis In A Paddle Reactor For Biomass Fast Pyrolyis, Ankith Ullal

Dissertations, Master's Theses and Master's Reports

Heat transfer analysis was performed on a novel auger reactor for biomass fast pyrolysis. As part of this analysis, correlations for specific heat capacity and heat transfer coefficients for biomass (sawdust) and sand (used as heat transfer medium) were developed. For sand, the heat transfer coefficient followed a power law distribution with reactor fill level and temperature. For raw biomass, the heat transfer coefficient also showed similar dependence on fill level, but was independent of temperature up to 300°C. These correlations were used in a one dimensional heat transfer model developed to calculate the heating time and heating rate of …

Hybrid Metal Oxide Cycle Water Splitting, Richard B. Diver Jr., Robert D. Palumbo, Nathan P. Siegel, James E. Miller

Other Faculty Research and Publications

Hybrid thermochemical water splitting systems are disclosed that thermally reduces metal oxides particles to displace some but not all of the electrical requirements in a water splitting electrolytic cell. In these hybrid systems, the thermal reduction temperature is significantly reduced compared to two-step metal-oxide thermochemical cycles in which only thermal energy is required to produce hydrogen from water. Also, unlike conventional higher temperature systems where the reduction step must be carried out under reduced oxygen pressure, the reduction step in the proposed hybrid systems can be carried out in air, allowing for thermal input by a solar power tower with …