Petroleum Engineering Commons^™

Seismicity Characteristics Of The Gulf Of Aqaba Seismogenic Zone And Their Hazard Implications In Northwestern Saudi Arabia, Ali Abdelfattah, Mohamed Ezzelarab, Hazem Badreldin, Hassan Alzahrani, Saleh Qaysi, Bassam Abuamarah, Neil Lennart Anderson

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The seismogenic characteristics of the Gulf of Aqaba zone have been assessed using the maximum likelihood method to estimate various earthquake recurrence parameters. These parameters encompass the β-value, annual recurrence rate (λ), and maximum probable magnitude (Mmax). This assessment has identified three sub-seismogenic zones, each corresponding to specific structural faults within the Gulf. These zones are associated with the Aragonese, Arnona and Aqaba faults, delineating pull-apart basin structures in the Gulf of Aqaba. An updated earthquake catalogue has been compiled using a unified moment magnitude (Mw) scale to improve the analysis, established by developing two empirical relationships. According to the …

Valorization Of The Polymeric Constituents In Plastic Wastes Through Thermo-Chemical Processes By Using Viable Metal Oxides Additives, Labeeb Hamad Ali

Dissertations

The rapid accumulation of different types of plastic waste necessitates the development of effective and economically viable waste management operations. Such a process should ideally not only mitigate associated environmental burdens but also recycle and recover value-added products. Through incineration or pyrolysis, thermal processing has emerged as a mainstream approach to waste management of the ever-increasing loads of different categorized plastic wastes. Throughout the work of the thesis, we have utilized a multitude of complementary techniques spanning material characterizations, catalysis, kinetic modelling, and density functional theory (DFT) to comprehend the complex chemistry that underpins catalytic chemical recycling of plastic wastes. …

Formate Dehydrogenase Immobilized On Metal Organic Framework For Enhanced Conversion Of Co2 To Formate, Shadeera Rouf

Dissertations

Enzymatic hydrogenation of carbon dioxide (CO₂) to formate by formate dehydrogenase (FDH) is a promising technology for reducing CO₂ concentrations in an environmentally friendly manner. For practical and economical implementation of the process, however, enhanced reusability of the enzyme is essential, which requires easy separation from the reaction mixture, coupled with sustained stability. One way to achieve this is by using the enzyme in an immobilized form. In this work, the effectiveness of using different metal organic frameworks (MOFs) as promising alternative supports for FDH immobilization has been assessed. A highly stable zirconium-based MOF, UiO66 and its …

Cfd Study On Two-Phase Flow Patterns In A Pipe With 90º Elbow In Different Operating Conditions, Hagar Alm-Eldin Bastawissi, Mohammed Ahmed Khafagy, E. A. El Shenawy Prof. Dr., Ahmed M. Salem Dr

Journal of Engineering Research

Recently, CFD has offered a technological solution for modelling multi-phase flow in which we can make endless simulations with reduced expenses and effort in high accuracy results; we shall also mention that experimental studies have limitations for safety considerations when experimenting with flow in high temperature or pressure values or medium nature as in nuclear or chemical flows.In this paper, we used the ANSYS FLUENT CFD program to simulate the two-phase flow in a pipe to study the effect of attaching a 90-degree elbow fitting to the piping system, seeking to find out the change in the pattern and resulting …

Investigation Of Gas Dynamics In Water And Oil-Based Muds Using Das, Dts, And Dss Measurements, Temitayo S. Adeyemi

LSU Master's Theses

Reliable prediction of gas migration velocity, void fraction, and length of gas-affected region in water and oil-based muds is essential for effective planning, control, and optimization of drilling operations. However, there is a gap in our understanding of gas behavior and dynamics in water and oil-based muds. This is a consequence of the use of experimental systems that are not representative of field-scale conditions. This study seeks to bridge the gap via the well-scale deployment of distributed fiber-optic sensors for real-time monitoring of gas behavior and dynamics in water and oil-based mud. The aforementioned parameters were estimated in real-time using …

Understanding Effective Elastic Properties And Stress-Strain Evolution In Composite Granular Rocks Using Discrete Element Modeling, Prasad Pothana, Fernando E. Garcia, Kegang Ling

Petroleum Engineering Posters and Presentations

The mechanical behavior of composite granular rocks is a multifaceted phenomenon relevant to various geoengineering applications. Traditional homogenization models and continuum mechanics-based numerical methods often fall short of accurately capturing the intricacies of granular materials. Granular materials exhibit heterogeneity and arching mechanisms governing the force networks that ensure system stability. Unlike continuum-based approaches, particulate discrete element methods have an advantage in assessing effective material properties by considering material heterogeneity and grain-level physical interactions. This study evaluates effective elastic properties using particle flow code using flat-joint contact law for composite binary mixtures with a stiff inclusion embedded within a matrix material. …

New Models For Estimating Minimum Miscibility Pressure Of Pure And Impure Carbon Dioxide Using Artificial Intelligence Techniques, Attia Attia, Ahmed Ashraf Soliman Eng., John Shahat Eng., Sayed Gomaa Prof., Fares Ashraf El Salamony Prof.

Petroleum Engineering and Gas

CO2 miscible flooding stands out as one of the most-commonly employed and promising processes in enhanced oil recovery. The key factor for ensuring success in designing and executing CO2 injection projects lies in the precise determination of the Minimum Miscibility Pressure (MMP). Despite significant research endeavors in measuring and predicting the MMP through the use of empirical, analytical, numerical, and experimental approaches, the need for a comprehensive, accurate, efficient, and easy-to-use model remains. In response to this gap, our study developed various predictive models with 205 datasets, including well-established ones such as Artificial Neural Network (ANN), Random Forest (RF), and …

Laboratory Evaluation Of High-Temperature Resistant Lysine-Based Polymer Gel Systems For Leakage Control, Tao Song, Xuyang Tian, Baojun Bai, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In-situ crosslinking gel known for its cost-effectiveness, has been employed for decades to plug high-permeability features in subsurface environments. However, some commonly used crosslinkers are being phased out due to the increasingly rigorous environmental regulations. As a newly discovered environmentally friendly crosslinker, lysine can crosslink the partially hydrolyzed polyacrylamide through transamidation reaction. The present work aimed to study the effect of polymer composition and concentration on the gelation behavior of lysine and high molecular weight acrylamide-based polymers. Several commercial high molecular weight polymers with different contents of 2-Acrylamido-2-methyl-1-propane sulfonic acid (AMPS) including AN-105/125, SAV-55/37/28, and SAV-10 were deployed in this …

Layered Mantle Flow Field Associated With Plate Kinematics And Slab Modulation Underneath The Horseshoe-Shaped Banda Arc-Islands, Sijia Li, Fansheng Kong, Kelly H. Liu, Stephen S. Gao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Banda Arc-Continent Collision Zone Signifies One Of The Most Seismically Active And Tectonically Intricate Zones. The High Convergence Rate Across The Region, Coupled With The Exceptionally Arcuate Arc And Subducted Slab, Makes It An Ideal Locale For Investigating Interactions Between Plate (Slab) Kinematics And Plastic Flow In The Asthenosphere, Which Can Be Diagnosed By Seismic Anisotropy From Shear Wave Splitting Analyses. In Total, 206 Pairs Of Splitting Measurements Using Teleseismic SKS, SKKS, And PKS, Along With 43 Pairs Using Local S Phases, Are Obtained By Utilizing Broadband Seismic Data From Five Permanent Seismic Stations. To Reduce The Ambiguity In …

Inverting Geodetic Strain Rates For Slip Deficit Rate In Complex Deforming Zones: An Application To The New Zealand Plate Boundary, Kaj M. Johnson, Laura M. Wallace, Jeremy Maurer, Ian Hamling, Charles Williams, Chris Rollins, Matt Gerstenberger, Russ Van Dissen

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The potential for future earthquakes on faults is often inferred from inversions of geodetically derived surface velocities for locking on faults using kinematic models such as block models. This can be challenging in complex deforming zones with many closely spaced faults or where deformation is not readily described with block motions. Furthermore, surface strain rates are more directly related to coupling on faults than surface velocities. We present a methodology for estimating slip deficit rate directly from strain rate and apply it to New Zealand for the purpose of incorporating geodetic data in the 2022 revision of the New Zealand …

Development Of Inorganically Cross-Linked Sulfonated Polyacrylamide Preformed Particle Gels For Conformance Control: Impact Of Anionic Groups, Reem Elaf, Ahmed Hamza, Hassan Nimir, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Modern oil and gas extraction faces challenges, notably from the surplus of produced water, hampering hydrocarbon recovery and raising environmental and economic concerns. A promising solution is the injection of preformed particle gels (PPGs) into the reservoir's fractures and high permeability zones, facilitating production processes. This study introduces a novel class of inorganically cross-linked PPGs with exceptionally high swelling capacities, comprising sulfonated polyacrylamide cross-linked with aluminum attached to acetate, nitrate, sulfate, and lactate anions individually. These PPGs function as superabsorbents, capable of absorbing water at a ratio of 100-700 times their dry weight while maintaining adequate gel strength up to …

Radiation-Induced Polymerization Of Thermo-Responsive Polymers And Comprehensive Characterization For Improved Performance, Attia Attia, Islam Mohamed Eng., Mohamed El-Deab Prof., Nabila Maziad Prof.

Petroleum Engineering and Gas

Early water breakthrough with high water cut through highly conductive thief zones is a prevalent problem in many water-flooded oil reservoirs. Smart polymers that are sensitive to temperature changes, also known as thermo-responsive polymers, e.g., polyethylene glycol (PEG) have great advantages over conventional polymers that can be exploited to solve the problem of conductive thief zones. Thus, this study aims at designing and synthesizing a thermo-responsive polymer using Gamma Ray Induced radiation with good tolerance against high temperature, and high salinity reservoir conditions with feasible and economic synthesis procedure for application in Egyptian oil reservoirs. That is a combined use …

Integrated Petrophysical Evaluation And Rock Physics Modeling Of Broom Creek Deep Saline Aquifer For Geological Co2 Storage, Prasad Pothana, Ghoulem Ifrene, Kegang Ling

Petroleum Engineering Student Publications

Fossil fuels, such as coal and hydrocarbons, are major drivers of global warming and are primarily responsible for worldwide greenhouse gas emissions, including carbon dioxide CO₂. The storage of CO₂ in deep saline reservoirs is acknowledged as one of the top practical and promising methods to reduce CO₂ emissions and meet climate goals. The North Dakota Industrial Commission (NDIC) recently approved the fourth Class VI permit for a carbon capture and storage project in the Williston basin of North Dakota for the geological CO₂ storage in the Broom Creek formation. The current research aimed to …

Geodetic Strain Rates For The 2022 Update Of The New Zealand National Seismic Hazard Model, Jeremy Maurer, Kaj Johnson, Laura M. Wallace, Ian Hamling, Charles A. Williams, Chris Rollins, Matt Gerstenberger, Russ Van Dissen

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Geodetic data in plate boundary zones reflect the accrual of tectonic strain and stress, which will ultimately be released in earthquakes, and so they can provide valuable insights into future seismic hazards. To incorporate geodetic measurements of contemporary deformation into the 2022 revision of the New Zealand National Seismic Hazard Model 2022 (NZ NSHM 2022), we derive a range of strain-rate models from published interseismic Global Navigation Satellite Systems velocities for New Zealand. We calculate the uncertainty in strain rate excluding strain from the Taupō rift–Havre trough and Hikurangi subduction zone, which are handled separately, and the corresponding moment rates. …

Upper Plate And Subduction Interface Deformation Models In The 2022 Revision Of The Aotearoa New Zealand National Seismic Hazard Model, Russ J. Van Dissen, Kaj M. Johnson, Hannu Seebeck, Laura M. Wallace, Chris Rollins, Jeremy Maurer, Matthew C. Gerstenberger, Charles A. Williams, Ian J. Hamling, Andrew Howell, Christopher J. Dicaprio

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

As part of the 2022 revision of the Aotearoa New Zealand National Seismic Hazard Model (NZ NSHM 2022), deformation models were constructed for the upper plate faults and subduction interfaces that impact ground-shaking hazard in New Zealand. These models provide the locations, geometries, and slip rates of the earthquake-producing faults in the NZ NSHM 2022. For upper plate faults, two deformation models were developed: a geologic model derived directly from the fault geometries and geologic slip rates in the NZ Community Fault Model version 1.0 (NZ CFM v.1.0); and a geodetic model that uses the same faults and fault geometries …

Development Of A New Approach Using An Artificial Neural Network For Estimating Oil Formation Volume Factor At Bubble Point Pressure Of Egyptian Crude Oil, Attia Attia, Abdelrahman Gouda Eng.

Petroleum Engineering and Gas

Understanding the phase behavior and volumetric changes of reservoir fluids throughout the extent of reservoir lifetime are crucially required for effective-commercial oil recoveries. Ideally, reservoir fluid properties are experimentally measured by laboratory experiments known as PVT tests nonetheless, these tests are prohibitive, time-consuming, and required to restrict sampling and transporting procedures. For these discernible reasons, several modeling approaches have been developed. By reviewing the literature, one crucial obstacle that encounters field applicability of most extant models is the selection of input variables. Moreover, a great percentage of extant models employ the results of lengthy experimental tests such as differential gas …

Development Of Tio2/Nh2-Mil-125 Nanocomposite For The Removal Of Ciprofloxacin Under Induced Solar Irradiation, Bilkis Mojisola Ajiwokewu

Thesis/ Dissertation Defenses

This research focuses on the development and application of Metal-Organic Frameworks (MOFs)-based nanocomposites for the photocatalytic removal of pharmaceutical contaminants, with a specific emphasis on ciprofloxacin (CIP). The photocatalytic degradation of CIP was investigated using as-synthesized photocatalysts of TiO₂ nanowires (TiO₂NWs), bare MOF of NH₂-MIL-125, TiO₂NW/NH₂-MIL-125 composite, and Lanthanum (La)-doped composite. Intriguingly, the TiO2NW/NH2-MIL-125 composite exhibited the highest efficiency, achieving a photodegradation rate of 0.0111 min-1, surpassing the independent performances of bare MOF of NH₂-MIL-125 and TiO2NW. The observed efficiency was attributed to the formation of a Z-scheme heterojunction …

Characterizing Nonlinear Fluid Flow In 3d Printed Rock Fractures: Effects Of Roughness, Aperture, And Intersection Angles, Ghoulem Ifrene, Prasad Pothana, Sven Egenhoff, Nicholas Bittner, Kuldeep Singh

Petroleum Engineering Posters and Presentations

Understanding fluid flow behavior at fracture intersections is vital to geothermal energy extraction, underground water flow, and CO₂ storage. Here, laboratory experiments were performed to study the effect of surface roughness, intersection angles, and aperture on nonlinear flow behavior in simple fracture networks. A FormLabs (3B+) 3D printer was used to fabricate 8 samples of 38.1mm in diameter and 59.43mm or 54.9mm in length with 2 intersecting fractures of 10^o and 40^o respectively. The surface roughness of the fractures was based on laser profilometry measurements from two induced mode 1 rock fractures, with a joint roughness coefficient …

Prediction Of Surfactant Performance From Surfactant Huff-Puff In Carbonate Reservoirs Using A Data-Driven Approach And Desktop Application Development, Y. Yao, Mingzhen Wei, Y. Cui, M. Ali, J. Leng, Y. Qiu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactants have been widely used to alter the wettability of carbonate rocks from oil-wetness to water-wetness and enhanced oil recovery. One of primary methods implemented in filed applications for enhanced oil recovery is surfactant huff-puff. Currently, a large number of surfactant treatments are conducted in laboratories prior to field applications to optimize the design of surfactant huff-puff, test the performance of surfactants, and minimize failure risk. This process is time-consuming since a treatment could last from several days to more than 300 days. Moreover, a fraction of treatments could not improve oil recovery as reported in the literature. In this …

Evaluating Medium Decision Tree Model, Support Vector Machine Rational Quadratic Gaussian Process Regression To Estimate The Total Organic Carbon Of Shale Gas Reservoirs, Attia Attia, Sayed Gomaa, Mohamed Mongy Eng., Ramadan Emara Prof., Ashraf Fahmy Prof.

Petroleum Engineering and Gas

As a result of an energy crisis due to the Russian-Ukrainian war, the eyes of great countries such as America and others began to turn strongly towards exploiting unconventional resources to increase the oil and gas production. The first step in exploiting unconventional sources is to estimate the Total Organic Carbon (TOC). TOC measurements are expensive as well as time consuming, as samples of cuttings or core samples must be present to do the required lab tests. This issue encouraged the researchers to develop mathematical correlation to estimate the TOC. The paper aims at evaluating three of machine learning models …

Pattern Recognition For Wettability Alteration With Surfactants In Carbonate Reservoirs By Using Machine Learning, Y. Yao, Mingzhen Wei, M. Ali, Y. Qiu, Y. Cui, J. Leng

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactants Are Widely Applied Agents to Interact with the Adsorbates on Carbonate Rock Surface, Which Could Alter Wettability from Oil-Wetness to Water-Wetness and Thus Enhance Oil Recovery. Surfactant Huff-Puff is Often Conducted to Achieve Wettability Alteration and Has Been Applied under Various Conditions. Currently, Many Investigations Have Been Reported to Apply Conventional Data Analysis Methods to Analyze Different Sets of Surfactant Huff-Puff Projects. Yet the Application of Machine Learning Algorithms to Reveal the Inherent Patterns is Rarely Reported. in This Study, We Integrate Principal Component Analysis (PCA) with Hierarchical Clustering Algorithm (HCA) to Uncover the Hidden Patterns Embedded in Global …

Assessing The Potential Of Uav-Based Multispectral And Thermal Data To Estimate Soil Water Content Using Geophysical Methods, Yunyi Guan, Katherine R. Grote

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Knowledge of the soil water content (SWC) is important for many aspects of agriculture and must be monitored to maximize crop yield, efficiently use limited supplies of irrigation water, and ensure optimal nutrient management with minimal environmental impact. Single-location sensors are often used to monitor SWC, but a limited number of point measurements is insufficient to measure SWC across most fields since SWC is typically very heterogeneous. To overcome this difficulty, several researchers have used data acquired from unmanned aerial vehicles (UAVs) to predict the SWC by using machine learning on a limited number of point measurements acquired across a …

Geochemical Assessment Of Mineral Sequestration Of Carbon Dioxide In The Midcontinent Rift, Alsedik Abousif, David J. Wronkiewicz, Abdelmoniem Masoud

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This Study Examines The Potential Of Midcontinent Rift Rocks To Facilitate Long-Term CO2 Sequestration By Providing The Necessary Ca And Mg For Carbonate Mineralization. Surface Samples Were Collected From The Oronto And Bayfield-Jacobsville Groups Around Lake Superior And Used For Petrography And X-Ray Diffraction To Determine Their Mineral Composition. Also, X-Ray Fluorescence Was Also Used To Assess Their Bulk Chemical Composition. The Samples Were Then Exposed To CO2 And Deionized Water In Teflon-Lined Vessels At 90°C, And The Resulting Leachate Fluids Were Analyzed For The Cation Released During The Testing. SEM Microscopy Was Used To Examine The Samples For Potential …

Would Self-Supported Fracture Contribute To The Hydrocarbon Production In Shale Reservoir Besides Proppant-Supported Fracture, Y. Sun, G. Li, S. Zeng, J. Wu, J. Liu, M. Xu, C. Dai, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

During hydraulic fracturing in deep shale gas reservoirs, it is difficult to pump proppants long distances, and self-supported fractures are formed at the far and upper ends of the fractures. The self-supported fracture could hold the fracture space by its surface structure again fracture closure. However, it faces various aspects of impairment during shale gas reservoir development, which affect its conductivity. Among the impairment, long-term production results in a decline of bottom hole pressure, which will compact the fracture space, and self-supported fractures without proppant are more sensitive than those with proppant. In this paper, we conducted a series of …

Fe-Ni-Cu-Pge Sulfide Transport Mechanisms And Carbon-Sulfur Interactions In Lower Crustal Magmatic Settings: A Study From The Valmaggia Ultramafic Pipe, Ivrea-Verbano Zone, Italy, Shelby Leann Clark

Masters Theses

"Constraining the processes that control the transport and deposition of sulfides in the deep lithosphere is an important step in expanding ore deposit exploration search space to include exhumed lower crustal rocks. The ultramafic sulfide ore-bearing Valmaggia pipe in the Ivrea-Verbano Zone of NW Italy, an exhumed cross section of the overlying lower continental crust and subcontinental lithospheric mantle, gives critical insight into metallogenic processes in lower crustal settings. The ~300 m wide metasomatized pipe hosts Fe-Ni-Cu-(PGE±Co±Au) sulfide mineralization that is commonly associated with locally abundant carbonates and hydrous silicates (phlogopite, amphibole). Previous studies suggested that sulfides were physically transported …

Fiber Assisted Re-Assembly Preformed Particle Gel For Conformance Control, Zhe Sun

Masters Theses

"In Enhanced Oil Recovery technology today, gel treatments have been implemented as a cost-effective method to improve the oil sweep efficiency in reservoirs by plugging the high permeability zones. This study presents a novel gel composition to be used in conformance control in order to improve oil recovery for mature oilfields.

The product is a fiber-assist re-assembly preformed particle gel which could be generalized to the preformed particle gels (PPG). The product developed in this study could be injected into the reservoir act as a conformance control agent by plugging water thief zones and channels in the beginning process. Due …

Experimental Study: Evaluating The Effect Of Low High Viscosity Friction Reducer Concentrations To Transport Proppant Across Static And Dynamic Models, Ghith Biheri, Abdulmohsin Imqam, Shari Dunn-Norman, Khaled Elmaleh

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Hydraulic fracturing treatments may significantly improve the oil production from wells in unconventional reservoirs by enhancing the fracture conductivities. Fracture conductivity can be improved by efficiently transporting and distributing the proppant through the lengths of the fractures. The main target of this study is to evaluate the viscosity and elasticity of high viscosity friction reducer (HVFR) for the purpose of transport and suspend the proppant at a temperature of 25°C. This study an alyzes the settling of proppant across HVFR using two different concentrations, 0.5 and 1 gallon per thousand of gallon (gpt). The tests were conducted using two static …

A Review Of Dielectric Barrier Discharge Cold Atmospheric Plasma For Surface Sterilization And Decontamination, Kolawole Adesina, Ta Chun Lin, Yue-Wern Huang, Marek Locmelis, Daoru Frank Han

Biological Sciences Faculty Research & Creative Works

Numerous investigations have shown that non-equilibrium discharges at atmospheric pressure, also known as "cold atmospheric plasma" (CAP) are efficient to remove biological contaminants from surfaces of a variety of materials. Recently, CAP has quickly advanced as a technique for microbial cleaning, wound healing, and cancer therapy due to the chemical and biologically active radicals it produces, known collectively as reactive oxygen and nitrogen species (RONS). This article reviews studies pertaining to one of the atmospheric plasma sources known as Dielectric Barrier Discharge (DBD) which has been widely used to treat materials with microbes for sterilization, disinfection, and decontamination purposes. To …

Carbon Dioxide Gasification Of Biochar: A Study On Utilizing Captured Co2 To Mitigate Greenhouse Gas Emission And Improving Carbon Conversion Efficiency, Nnamdi Ofuani

College of Graduate Studies: Theses & Dissertations

With rapidly growing global economies and world population, fossil fuel continues to play a major role in meeting current energy demands. Carbon capture and storage (CCS) technologies have, hence, been implemented to reduce CO₂ emissions in the atmosphere. With the implementation of CCS technologies comes the need to utilize the captured CO₂. This research, therefore, proposes CO₂ gasification of biochar as a viable carbon utilization pathway. With captured CO₂ coming at various concentrations, there is a need to understand how CO₂ concentration affects biochar conversion to useful products. This study, therefore, evaluates the effects …

Development Of Tio2/Nh2-Mil-125 Nanocomposite For The Removal Of Ciprofloxacin Under Induced Solar Irradiation, Bilkis Mojisola Ajiwokewu

Theses

This research focuses on the development and application of Metal-Organic Frameworks (MOFs)-based nanocomposites for the photocatalytic removal of pharmaceutical contaminants, with a specific emphasis on ciprofloxacin (CIP). The photocatalytic degradation of CIP was investigated using as-synthesized photocatalysts of TiO₂ nanowires (TiO₂NWs), bare MOF of NH₂-MIL-125, TiO₂NW/NH₂-MIL-125 composite, and Lanthanum (La)-doped composite. Intriguingly, the TiO₂NW/NH₂-MIL-125 composite exhibited the highest efficiency, achieving a photodegradation rate of 0.0111 min-1, surpassing the independent performances of bare MOF of NH₂-MIL-125 and TiO₂NW. The observed efficiency was attributed to …