Petroleum Engineering Commons^™

Understanding Inhibition Of A Biodesulfurization Enzyme To Improve Sulfur Removal From Petroleum, Yue Yu

Theses and Dissertations--Chemical and Materials Engineering

The biodesulfurization 4S-pathway is a promising complementary enzymatic approach to remove sulfur from recalcitrant thiophenic derivatives in petroleum products that remain from conventional hydrodesulfurization method without diminishing the calorific value of oil. The final step of this pathway involves the carbon-sulfur bond cleavage from HBPS, and the production of the final products 2-hydroxybiphenyl (HBP) and sulfite, has been recognized as the rate-limiting step, partially as a result of product inhibition. However, the mechanisms and factors responsible for product inhibition in the last step have not been fully understood. In this work, we proposed a computational investigation using molecular dynamic simulations …

An Integrated Method For Forecasting Well Deliverability In Gas Condensate Reservoirs With Bottom Aquifer Drive, Abdulaziz Ellafi, Ralph E. Flori, Shari Dunn-Norman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Gas condensate reservoirs constitute a significant portion of global hydrocarbon reserves. In these reservoirs, liquids develop in the pore space once bottomhole pressure falls below dew point. This results in the formation of a liquid bank near the wellbore region which decreases gas mobility, which then reduces gas inflow. In such complex reservoirs, it is important to correctly describe PVT impacts, adjustments to well test analysis and inflow performance, and then combine all effects in the reservoir analysis. The literature contains many references to individual adjustments of PVT analysis, well testing, or inflow performance for gas condensate reservoirs, but few …

Miscible Gases Based Eor In Unconventional Liquids Rich Reservoirs: What We Can Learn, Dheiaa Alfarge, Mortadha Alsaba, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Over the last decade, Unconventional Liquids Rich Reservoirs (ULR) have become the main target for oil and gas investors as conventional formations started to deplete and diminish in numbers. These unconventional plays have a huge oil reserve; however, the primary oil recovery factor is predicted to be less than 10%. Unconventional Improved Oil Recovery (UIOR) techniques are still a new concept in the oil industry since there is no commercial project reported for any IOR technique yet. Miscible gas based EOR technique might be the most potential strategy to improve oil recovery in such complex plays. In this study, a …

New Insights Of Low Salinity Water Flooding In Low Permeability-Low Porosity Clay Rich Sandstone Reservoir, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Waleed H. Al-Bazzaz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

One of the EOR technologies is low-salinity water flooding (LSWF) is an EOR method that operates at a lower cost than other EOR methods, which makes it a preferred area of interest for oil industry economists, who continue to call for EOR costs to come down. The aim is to minimize the possible cost to recover as much oil as possible. The performance of low salinity waterflooding in decreasing residual oil saturation in low permeability-porosity clay-rich sandstone reservoir. Porosity test, core flooding test, XRD and scanning electron microscopy (SEM) tests were achieved in this study. Salinity effect on the porosity, …

Application Of Integrated Reservoir Geomechanics For Well Planning Of High-Angled Wells In A Mature Oil Field, Ahmed K. Abbas, Ralph E. Flori, Yousif M.B. Al-Asadi, Mortadha Alsaba, Nasser A. Al-Hamad

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Zubair oil reservoir has a significant potential to contribute to the petroleum supply in Iraq. Drilling highly deviated wells is a commonly used approach to enhance the production in mature fields. Drilling these wells in the Zubair Formation has been a challenge due to severe wellbore instability issues. This study presents how integrated reservoir geomechanics was used for efficient well planning and safe drilling of nearly horizontal wells (75° Inclination) through Zubair depleted sandstone oil reservoir. In this study, an integrated workflow was implemented mainly to build a geomechanical model using offset well data. The in-situ principal stresses and their …

Learning From Experience: An Automatic Ph Neutralization System Using Hybrid Fuzzy System And Neural Network, Ethar H.K. Alkamil, Seaar Al-Dabooni, Ahmed K. Abbas, Ralph Flori, Donald C. Wunsch

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In oil and gas industry, the pH level is one of the most important indicators of mud contamination while drilling. Although the process has simple components, the pH neutralization process is complicated in the mud circulation system. This difficulty is due to the high nonlinearity of the process. In this paper, the fuzzy neural network (FNN) is integrated to the fuzzy logic controller (FLC) to create a system which identifies pH fluctuation into a drilling mud system, assesses and signals its severity. And then, it automatically actuates a chemical treating fluids valve (CTFV), such as Caustic Soda (CS), for neutralizing …

Using Managed Pressure Drilling To Reduce Stuck Pipe Problem, Ethar H.K. Alkamil, Husam R. Abbood, Ralph E. Flori, George Medley, Sagar Nauduri, Mortadha Alsaba

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Differences between mud pressure in a wellbore and pore pressure in high permeability rocks can lead to differential sticking, particularly when drilling deviated wells and encountering mud losses. Several solutions, all challenging, can be used to address this problem, where the conventional mitigation method of managing the mud weight (MW) is often used. However, managed pressure drilling (MPD) offers a promising solution with a positive risk-adjusted cost and other benefits. Wells in the E oilfield in southern Iraq are typically drilled overbalanced and therefore often experience a high percentage of non-productive time (NPT) due to differential sticking. This study evaluates …

A Novel Ultra-Low Interfacial Tension Nanofluid For Enhanced Oil Recovery In Super-Low Permeability Reservoirs, Derong Xu, Baojun Bai, Ziyu Meng, Qiong Zhou, Zhe Li, Yao Lu, Hairong Wu, Jirui Hou, Wanli Kang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The exploration and development of super-low permeability reservoirs have become a global focus in recent years. However, conventional flooding systems commonly face problems of high injection pressure and poor displacement efficiency in super-low permeability reservoirs. Thus, it is imperative to find new flooding agents that tackle such problems. In this study, a novel ultra-low interfacial tension (IFT) nanofluid was formulated, consisting of surfactants to achieve ultra-low IFT and silica nanoparticles to reduce injection pressure. The compatibility test between the surfactants and silica nanoparticles in 10,000 mg/L NaCl solution at 90 °C was conducted to ensure their adaption to harsh reservoir …

Using Artificial Intelligence And Machine Learning To Develop Synthetic Well Logs, Marwan Mohammed Alnuaimi

Graduate Theses, Dissertations, and Problem Reports (ETD)

There has been an increase in the need for energy in the recent past. Oil and gas stand as the source of energy that are widely used. The oil and gas reservoirs are targeted for the purposes of field development. The conventional methods of reservoir characteristics require computing techniques that are unique and complex, some of which are labor and time intensive. Mohaghegh argues that all efforts must be tried and made possible to apply Petroleum Data analytics in production and management of reservoir so as to earn a maximum return (Mohaghegh, Shale Analytics, 2017). Different methodologies have been applied …

Advanced Ion Management To Improve Oil Recovery In Oil-Wet Carbonate-Sandstone Composite Reservoirs, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Waleed H. Al-Bazzaz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Waterflooding with different ionic composition called advanced ion management which play a role with ionic composition of injected water to enhance the oil production. In the last decade, many studies pointed out that the composition of injected water could changes rock wettability during waterflooding. The main purpose of this study is to evaluate the effects of SO4 and low salinity water on improving oil recovery in oil-wet carbonate reservoirs. Sulfate ion concentration, low salinity water, rock composition, porosity, and permeability were examined using a designed model. Typical seawater, increase SO₄, two and three times in the seawater, and …

Effectiveness Of Ammonium Ion In Low Salinity Waterflooding In Shaly-Sandstone Reservoir, Hung Vu Quoc

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this study was presented the pre-feasibility study of silica sand processing plant in Sihanoukville province. The resources approximately 8,750,000 tons, would be a high potential deposit for the glass industry. In this study focuses on the characteristics of the silica sand, methodology to remove the impurities which contained high Fe2O3, Al2O3 and another major oxide element, and economic evaluation technique. To identification of silica sand which used sieve analysis, Frantz isodynamic magnetic separator following by electrical microscope, XRD, and XRF. Therefore, to upgrade the quality of silica sand, which is using Shaking Table, Wet High-Intensity Magnetic Separator, and Reverse …

Comprehensive Evaluation Of A Novel Eor Method-Coupling Low Salinity Water Flooding And Preformed Particle Gel To Enhance Oil Recovery In Fractured Reservoirs, Ali K. Alhuraishawy

Doctoral Dissertations

"Excess water production in oil fields is becoming a challenging economic and environmental problem as more reservoirs are maturing. Water channeling, one of the primary reservoir conformance problems, is caused by reservoir heterogeneities that lead to the development of high-permeability streaks. The recovery of oil from carbonate reservoirs is usually low due to their extreme heterogeneity caused by natural fractures and the nature of oil-wet matrix. Also, oil recovery from fractured sandstone reservoirs is often low due to areal heterogeneity. Gel treatments have proven to be a successful and inexpensive fluid diversion method when used to plug the thief zones …

Geomechanical Characterizations And Correlations To Reduce Uncertainties Of Carbonate Reservoir Analysis, Farqad Hadi

Doctoral Dissertations

"Although carbonate reservoirs hold a wealth of hydrocarbon, they are among the most difficult types of reservoirs to be characterized. Carbonate reservoirs by nature have complex depositional environments and diagenetic processes in which brittle, ductile, fractured rocks, and vugular pores may all exist within small interval. This huge variance in the rock mechanical properties can cause challenges in the reservoir's development, especially in applications related to geomechanics.

The main objective of this research is to geomechanically characterize and correlate the carbonate mechanical properties with their petrophysical properties. A comprehensive review for the geomechanical-petrophysical properties of carbonates was conducted from previous …

Characterization Of Free-Radical Solution Polymerizations Of Acrylamide Initiated By Persulfate Initiator Systems, Yashu Chen

Masters Theses

”In order to reduce the water production and improve the oil recovery of mature reservoir, various conformance control technologies have been extensively developed. Preformed particle gel (PPG), a cost-effective plugging agent, has been successfully applied to block the high permeability zone and thus to displace the water to up-swept zone.

A common PPG based on polyacrylamide hydrogel have been wildly used. Identifying the parameters that affect gelation performance and understand how these parameters affect the performance is very useful to predict and manipulate the gelation time and to control the performance of gels.

The objective of this research is to …

Monobore Completion Design: Classification, Applications, Benefits And Limitations, Anwar Khaled Al-Fadhli

Masters Theses

"A monobore completion is a simple completion design that uses the same internal diameter from the bottom of the well to surface. This may be accomplished by cementing a string of casing in a well, or by having tubing stabbed into a polished bore receptacle on a casing liner the same size as the tubing. Monobore completions have been applied extensively in oil and gas fields around the world, both onshore and offshore, from very low reservoir flow to extremely high production rates, since the late 1980s. They have proven beneficial due to their simplicity and cost savings. This study …

Data Analysis Of Low-Salinity Waterflooding To Enhance The Oil Recovery In Sandstone Reservoirs, Nadia Ariani

Masters Theses

"The lack of a single reasonable general mechanism to describe how low-salinity waterflooding can improve oil recovery in both laboratory and field pilot projects has increased the interests of many researchers and stakeholders. There has not been observed the relationship of formation brine salinity and injected brine salinity to see how much salinity is reduced to produce the maximum enhanced oil recovery by LSWF. There is no guidance in what EOR stage the LSWF is best implemented. This work collects data from various published literature to develop a comprehensive data set regarding low-salinity waterflooding in sandstone reservoirs. The LSWF mechanisms …

New Wellbore-Integrity Classification For Gas Migration Problems And New Cement Formulations Using Graphene Nano Platelets To Prevent Gas Migration Through Cement, Mohammed Mousa M. Alkhamis

Masters Theses

"Gas migration, one of the primary problems related to the integrity of oil wells, is caused by cement failures. Gas migration can result in costly well repairs and may endanger personal, equipment, and result in severe operational difficulties and environmental issues. The ultimate objectives of this research were to provide a comprehensive review of the problem and to provide a solution to the problem using Graphene Nano Platelets (GNPs).

An intensive review was performed to understand the cement failures. The reasons behind these failures were analyzed and classified with respect to their locations in the wellbore. Recommendations and potential solutions …

An Integrated Method For Understanding The Fluid Flow Behavior And Forecasting Well Deliverability In Gas Condensate Reservoirs With Water Aquifer Drive, Abdulaziz Mustafa Em. Ellafi

Masters Theses

"Gas condensate reservoirs constitute a significant portion of global hydrocarbon reserves. In these reservoirs, as bottomhole pressure falls below the dew point, liquid develops in the pore space. This results in the formation of a liquid bank near the wellbore region that decreases gas mobility, which then reduces gas inflow. Some gas condensate reservoirs have bottom aquifer drive, which also negatively impacts gas production. This research used a field case study to demonstrate an integrated workflow for forecasting well deliverability in a gas condensate field in Libya. The workflow began with the interpretation of open-hole log data to identify the …

Numerical Simulation Study Of Factors Affecting Production Well Gel Treatment Using Linear Models With Crossflow, Kewei Shi

Masters Theses

"Conformance control is an inevitable topic related to water-flooding. Polymer gel has been proved to enhance oil recovery by blocking the existing water-breakthrough channels. Water that is injected subsequently will be directed to the unswept portion of the reservoir, replacing part of the remaining oil and increasing the oil-recovery factor. Prior to pilot tests of polymer gel treatment, laboratory experiments and numerical simulations are used to design the tests. Understanding physical meanings of key parameters that affect polymer gel treatment and relating the parameters from lab data and the simulator benefit field operation design.

This thesis study tries to evaluate …

Proppant Transport With Varying Injection Points And Its Impact On Proppant Development Inside A Fracture, Shail Janakbhai Soni

Masters Theses

"This study presents experimental work which examines the effect of perforation placement and density on proppant placement within a hydraulic fracture. The study also investigates the effect of proppant angularity.

Experiments were conducted with ceramic proppant injected in a fracture slot model consisting of three injection points at the bottom, middle and top of the fracture slot, and two outlets, at the bottom and top of the fracture model. The effect of single point injection height was investigated by injecting solely at the bottom, middle or top of the apparatus, for both bottom and top outlet conditions. Multiple injection points …

The Role Of Flexural Slip In The Development Of Chevron Folds, Yuxing Wu

Masters Theses

"Chevron folds are characterized by straight limbs and narrow hinge zones. One of the conceptual models to initiate and develop chevron folds involves flexural slip during folding. While some kinematical models show the necessity for slip to initiate during chevron folding, recent numerical modeling studies of visco-elastic effective single layer buckle folding have shown that flexural slip does not result in chevron folds. In this study, several 2D finite element analysis models are run, distinguished by 1) geometry of the initial perturbation (sinusoidal and white noise), 2) varying thewavelength of the initial perturbation (10%, 50%, and 100% of the dominant …

The Development Of A New Formulation Of Fly Ash Class C Based Geopolymer And Assessing Its Performance In Presence Of Drilling Fluid Contamination, Mohamed Saad Ahdaya

Masters Theses

"Cementing is one of the most critical steps in the drilling and completion of oil wells. Traditionally, Portland cement is used for oil cementing operations; however, geopolymer materials have recently attracted much attention because they are more cost-effective and have less environmental impacts.

An intensive laboratory work was conducted to obtain a new formulation of fly ash class C based geopolymer cement to be used as a potential alternative cementing material to Portland cement in oil and gas cementing. Twenty-four variations of fly ash class C based geopolymers were prepared, and by comparing several of their properties using API standard …

New Nanoparticle Water-Based Drilling Fluid Formulation With Enhanced Thermal Stability And Inhibition Capabilities In The Woodford Shale, Jose Aramendiz Pacheco

Masters Theses

"Drilling fluid design for unconventional reservoirs aims at preventing formation instability problems associated with fluid invasion, shale swelling, and cuttings dispersion. Although oil-based mud (OBM) can be used to achieve these goals, environmental and economic concerns limit its application. This experimental study evaluated the potential use of nanoparticles (NP) to improve water-based mud (WBM) inhibition capabilities and its ability to enhance the overall drilling fluid thermal stability while providing a cleaner technology to the industry.

Characterization of Woodford shale was completed with X-ray diffraction, cation exchange capacity, and scanning electron microscopy, silica, and graphene NP were characterized with aqueous stability …

Investigation Of Proppant Static Settling Velocity In Hydraulic Fractures Using Viscoelastic Linear Gel, Vismay Manishbhai Shah

Masters Theses

"Few studies have quantified proppant transport in static conditions using actual proppant and validated previously established correlation. The objective of this study is to investigate the rheological properties of the linear gel, and determine the effect of size, shape and specific gravity of the proppant, fracture walls and rheological properties of the fluid on the proppant settling velocity in static condition and validate the previously established correlation.

Shear viscosity and dynamic frequency sweep tests were performed to investigate the viscous and viscoelastic behaviour of the HPG linear gel with five different concentrations. Proppant settling experiments were conducted with different proppant …

Hydraulic Fracture Design Optimization For Nubian Sandstone Formation In Libya, Housameddin Mohamed Sherif

Masters Theses

There is growing interest in developing unconventional oil and gas reserves in Libya, such as the tight portions of the Nubian sandstone.

Well-X7 is a development well drilled to a TD of 13,005' penetrating the Upper Nubain Sandstone (UNSS) at 12,122'-12,207' and the Lower Nubain Sandstone (LNSS) at 12,524'-12,880' KB. Based on open hole logs, the UNSS has 71 ft of net pay and the LNSS was found to have 295 ft of net pay. Openhole logs also showed low permeabilities of 2.5 and 3 md for the UNSS and LNSS, respectively. The well was initially perforated in both zones …

Conical Folds -- An Artifact Of Using Simple Geometric Shapes To Describe A Complex Geologic Structure, Avery Joseph Welker

Masters Theses

"Accurate representation of the 3D shapes of natural folds is essential to characterization of the dynamic models for fold formation. Geometrical analysis of folds commonly relies upon analyzing patterns defined by the variation in the orientation of poles to planar surfaces deformed by a shortening event when plotted using graphical calculators (e.g., stereogram, polar tangent diagrams) to interpret the shape of folds. Stereograms for which orientation data define small circles are classified as non-cylindrical regular folds and are interpreted as "conical folds," where the shape of the fold is represented by a cone that terminates at a point. Utilizing similar …

Ore Reserves Estimation Of The Nam Nga Coal Deposit, Lao Pdr, Using Geostatistical Method, Tongvang Bliachongvang

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research study focuses on estimating the coal deposit quantity and qualities as CV and AC at Nam Nga coal deposit, Lao PDR using OK and SGS geostatistical methods. A total of 295 assays data from 51 exploration drill holes collected from LID Company were used. The results reveal that OK produces geological resource of 2.2 MT with an average CV of 3,733 kcal/kg and an average AC of 48.68 %. The mineable reserve computed from OK's ultimate pit design and pit adjustment are 0.55 MT. The OK method produces 9.32 MT of wastes, yielding a stripping ratio of 10.4:1. …

Designing Binary Low Ift Surfactant System Using Hld Concept For Oil Recovery, Tukta Jamprakhon

Chulalongkorn University Theses and Dissertations (Chula ETD)

Surfactant-based microemulsion technology is widely used in tertiary enhanced oil recovery applications (EOR). The formulation of suitable surfactant system is a key success in production and economic feasibility of this technology. The middle phase or Winsor Type III microemulsions, employed for selecting appropriate surfactant system, can offer an optimal salinity at which the high oil solubilization capacity and minimum interfacial tension (IFT) or ultralow IFT (<0.01 mN/m) are obtained. By this technology, more remaining oil in the reservoir can be solubilized and mobilized which leads to an improvement of oil recovery. This study aims to formulate surfactant systems for the oil recovery through microemulsion formulation. The novel mixed anionic surfactant system of a sodium dioctyl sulfosuccinate (AOT) and an internal olefin sulfonates (IOS) with different alkyl chain lengths (C15-18, C19-23, C24-28) were used due to its mixture avoiding the surfactant precipitation. The result found that the binary mixture of AOT and (IOS C15-18 and IOS C19-23) can form the middle phase at the mixing ratios of 5:5 to 9:1 (by molar ratio) with heptane and decane. When the fraction of IOS increased in the mixed AOT/IOS system, the optimal salinity (S*) also increased. For the effects of a carbon tail length of IOS surfactant was observed that the tail length increased with decreasing the optimal salinity. The hydrophilic-lipophilic deviation (HLD) for the mixed surfactant system was investigated to individually determine the K and Cc values for the IOS surfactants. The finding from this work provided a guide for surfactant selection through HLD concept to formulate microemulsion-based surfactant flooding for EOR application.

Integrated Study On The Applicability Of Co₂-Eor In Unconventional Liquids Rich Reservoirs, Dheiaa Khafief Khashan Alfarge

Doctoral Dissertations

"Unconventional Liquids Rich Reservoirs (ULR) such as Bakken, Niobrara, and Eagle Ford have become the main target for oil and gas investors as conventional formations started to deplete and diminish in number. These unconventional plays have a huge oil reserve; however, the predicted primary oil recovery is still low as an average of 7.5 %. Unconventional Improved Oil Recovery (UIOR) techniques are still a new concept in the oil industry because there is no commercial project for any IOR technique so far. Injecting carbon dioxide (CO₂) might be the most potential strategy to improve oil recovery in such complex plays. …

Limiting Key Drilling Parameters To Control Mud Losses In Basra's Oil Fields, Iraq, Abo Taleb Tuama Al-Hameedi

Doctoral Dissertations

"Wells in Basra's oil fields are highly susceptible to lost circulation problems when drilling through the Dammam, Hartha, and Shuaiba formations. Drilling engineers are challenged to select the optimum value for key drilling parameters such as ECD, Yp, MW, WOB, ROP, and RPM to mitigate mud losses in these formations. Many of these drilling parameters are inter-related and the overall impact of changing key parameters require extensive drilling experience and study. A multi-regression analysis was performed on mud loss event data for more than 300 wells drilled in Basra's oil fields. From this analysis, a model was developed to predict …