Petroleum Engineering Commons^™

Mathematical Modelling And Optimisation Of The Reactor For The Esterification Process Of Safflower Oil With N-Butyl Alcohol, Sadritdin Makhamatdinovich Turabdjanov Academician, Hasan Sadriddin Ugli Fozilov, Ozoda Bakhronovna Axmedova, Sadriddin Fayzullayevich Fozilov

Technical science and innovation

This study addresses the mathematical modelling and optimisation of a reactor for the esterification of safflower oil with n-butyl alcohol. To improve process controllability and reduce the need for numerous pilot-scale trials, an ideal-mixing continuous stirred-tank reactor (CSTR) model was adopted. Incorporating reaction kinetics, the effect of contact time on the relative viscosity of the product mixture was analysed. The modelling results indicate that achieving an acceptable degree of feedstock conversion is difficult when a single ideal-mixing reactor is used. Therefore, a CSTR cascade was proposed, and the configuration with N = 2 reactors was selected as the most appropriate …

Fly Ash Proppant Developed For Hydraulic Fracturing, Raz Rzgar Haydar

Theses and Dissertations

Proppants are critical components in hydraulic fracturing, used to maintain fracture conductivity and enhance reservoir stimulation. In high-pressure and harsh reservoir environments, the use of high-strength proppants is essential to ensure well performance. Conventional proppants, being sand, ceramic, and sintered bauxite can be expensive, and their use often requires costly fracture fluids. This study investigates the possibility of utalizing fly ash geopolymers as a sustainable alternative that is also cost-effective for proppants manufacturing. Fly ash, a by-product from the combustion of coal and other materials, was explored as a base material for proppants, utilizing an alkaline solution as an activator …

Quantifying Wellbore Effects During Co2 Sequestration In A Saline Aquifer, Uzoma Johnpaul Ajugwe

USF Tampa Graduate Theses and Dissertations

Carbon capture and storage (CCS) is a strategy for mitigating climate change by reducing greenhouse gas emissions from large stationary sources like fossil-fuel-fired power stations. One method of CCS involves carbon dioxide (CO2) sequestration in deep saline aquifers, where supercritical CO2 is injected into an aquifer. The success of such projects depends on accurate predictions of CO2 behavior within the subsurface, which are obtained through numerical simulations.

TOUGHREACT, a renowned simulation tool, models subsurface fluid flow, geochemical interactions, and solute transport, providing insights into the feasibility of CO2 sequestration projects. A critical aspect of these simulations is the apportioning of …

Environmental Impacts Potential Of Natural Gas Production Through Life Cycle Assessment, Akmal Al Afghani, Mochamad Adhiraga Pratama, Astryd Viandila Dahlan

Journal of Materials Exploration and Findings

Life cycle assessment (LCA) is a methodology used to evaluate potential environmental impacts in various industry sectors, including the oil and gas industry to quantify the environmental impacts and determine the processes that have significant impacts along their production cycle. This environmental impact study adheres to ISO 14040:2016 and 14044:2017 standards, using the ReCiPe methodology within a gate-to-gate scope to analyze potential environmental impacts of 1 MMSCFD natural gas production. The impact categories analyzed in this study are Global Warming Potential (GWP), Particulate Matter Formation (PM), Ozone Formation (OF), and Terrestrial Acidification (TA). The results of this study identified several …

Experimental And Numerical Investigation Of Fluid Flow Behavior Through Fractured Wellbore Cement, Mahya Hatambeigi

Civil Engineering ETDs

Leakage from wellbores has been a major challenge in the energy industry, leading to groundwater contamination, reduced productivity, safety hazards, and increased operating costs. Cemented annulus fractures are a common type of leakage pathway in wellbores that can form due to various physical and chemical conditions. The number of wellbore leaks continues to increase globally, making it imperative to develop a better understanding of the complex mechanisms governing fluid flow through fractured wellbore cement. Understanding the behavior of fluid flow through a leaky cemented annulus is crucial for evaluating the leakage potential and risk assessments in wellbore systems, as well …

Measurement Of Volumetric Deformation, Strain Localization, And Shear Band Characterization During Triaxial Testing Using A Photogrammetry-Based Method, Sara Fayek, Xiong Zhang, Xiaolong Xia, Qingqing Fu, Jeffrey D. Cawlfield

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Triaxial Testing Has Been Routinely Used as a Standard Laboratory Test that Allows Correct Determination of Soil Characteristics. Previously the Volumetric Strain of the Triaxial Specimen Was Considered to Be Uniformly Distributed Along with the Specimen during the Isotropic and Deviatoric Loading. Although This Assumption Might Hold True under Isotropic Loading, the Effects of Restrained Ends and Disturbance during the Procedures of Specimen Installation and Testing Can Cause Nonuniform Strains throughout the Whole Specimen. This Paper Investigates the Effects of Specimen Preparation and Misalignment on the Strain Uniformity Along with the Soil Specimen during Triaxial Testing. a Series of Consolidated …

Point Density For Soil Specimen Volume Measurements In Image-Based Methods During Triaxial Testing, Sara Fayek, Xiong Zhang, Javad Galinmoghadam, Jeffrey D. Cawlfield

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Discrete Measurement Targets Were Frequently Utilized in Image-Based Methods on the Specimen's Surface to Monitor the Soil Specimen during Triaxial Testing. However, the Required Density of Measurement Targets that Should Be Used in Triaxial Testing to Achieve Highly Accurate Volume Measurement Has Not Been Investigated. to overcome This Limitation, This Paper Presents a Parametric Study to Determine the Optimum Target/point Densities to Be Utilized on the Triaxial Soil Specimen Surface to Achieve the Desired Level of Volume Measurement Accuracy in Image-Based Methods. LiDAR Scanning Was Applied to Establish the "Ground Truth" Volume of the Specimen. the Effects of Deformation and …

Optimum Geological Storage Depths For Structural H2 Geo-Storage, Stefan Iglauer

Research outputs 2022 to 2026

H₂ geo-storage has been suggested as a key technology with which large quantities of H₂ can be stored and withdrawn again rapidly. One option which is currently explored is H₂ storage in sedimentary geologic formations which are geographically widespread and potentially provide large storage space. The mechanism which keeps the buoyant H₂ in the subsurface is structural trapping where a caprock prevents the H₂ from rising by capillary forces. It is therefore important to assess how much H₂ can be stored via structural trapping under given geo-thermal conditions. This structural trapping capacity is thus …

Predictions Of Produced Water Quality And Recycled Water Optimization For Spatially-Distributed Wells In Point Pleasant Formation, Armel Quentin Mbakop

Graduate Theses, Dissertations, and Problem Reports (ETD)

The treatment of produced water as a fracturing fluid is becoming an increasingly important aspect of water management surrounding the booming of the unconventional oil and gas industry. Two main problems facing the oil and gas industry are the availability of water for well drilling and completion and disposal of the produced water. Unconventional well drilling and completion in the Utica shale requires large amounts of water. The wastewater that results after production—containing high levels of organic and inorganic matter— is usually disposed of through deep well injection. A new approach reuses this produced water as part of subsequent fracturing …

Application Of Artificial Intelligence For Co2 Storage In Saline Aquifer (Smart Proxy For Snap-Shot In Time), Marwan Mohammed Alnuaimi

Graduate Theses, Dissertations, and Problem Reports (ETD)

In recent years, artificial intelligence (AI) and machine learning (ML) technology have grown in popularity. Smart Proxy Models (SPM) are AI/ML based data-driven models which have proven to be quite crucial in petroleum engineering domain with abundant data, or operations in which large surface/ subsurface volume of data is generated. Climate change mitigation is one application of such technology to simulate and monitor CO2 injection into underground formations.

The goal of the SPM developed in this study is to replicate the results (in terms of pressure and saturation outputs) of the numerical reservoir simulation model (CMG) for CO2 injection into …

Hydrogen Underground Storage Efficiency In A Heterogeneous Sandstone Reservoir, Doaa Saleh Mahdi, Emad A. Al-Khdheeawi, Yujie Yuan, Yihuai Zhang, Stefan Iglauer

Research outputs 2014 to 2021

Underground hydrogen storage has been recognized as a key technology for storing enormous amounts of hydrogen, thus aiding in the industrial-scale application of a hydrogen economy. However, underground hydrogen storage is only poorly understood, which leads to high project risk. This research thus examined the effect of caprock availability and hydrogen injection rate on hydrogen recovery factor and hydrogen leakage rate to address some fundamental questions related to underground hydrogen storage. A three dimensional heterogeneous reservoir model was developed, and the impact of caprock and hydrogen injected rate on hydrogen underground storage efficiency were analysed with the model. The results …

Shale Softening Based On Pore Network And Laboratory Investigations, Di Zhang

Dissertations

This dissertation consists of two major parts: Firstly, experimental investigation of four major shale softening mechanisms and quantifications of structural parameters. Secondly, numerical simulations of nano-scale flow behaviors using the previous experiments determined parameters based on modified pore network modeling.

Hydraulic fracturing is widely applied to economical gas production from shale reservoirs. Still, the gradual swelling of the clay micro/nano-pores due to retained fluid from hydraulic fracturing causes a gradual reduction of gas production. Four different gas-bearing shale samples are investigated to quantify the expected shale swelling due to hydraulic fracturing. These shale samples are subject to heated deionized (DI) …

Effect Of Humic Acid On Co2-Wettability In Sandstone Formation, Mujahid Ali, Faisal Ur Rahman Awan, Muhammad Ali, Ahmed Al-Yaseri, Muhammad Arif, Mónica Sánchez-Román, Alireza Keshavarz, Stefan Iglauer

Research outputs 2014 to 2021

© 2020 Elsevier Inc. Hypothesis: Millions of tons of CO2 are stored in CO2 geological storage (CGS) formations (depleted oil reservoirs and deep saline aquifers) every year. These CGS formations naturally contain small concentrations of water-soluble organic components in particular humic acid (HA), which may drastically affect the rock wettability - a significant factor determining storage capacities and containment security. Hence, it is essential to characterise the effect of humic acid concentration on CO2-wettability and its associated impact on storage capacity. Experimental: To achieve this, we measured advancing and receding contact angles at reservoir conditions using the pendant drop tilted …

Influence Of Rock Wettability On Thf Hydrate Saturation And Distribution In Sandstones, Ghazanfer Raza Abbasi, Ahmed Al-Yaseri, Abubakar Isah, Alireza Keshavarz, Sefan Iglauer

Research outputs 2014 to 2021

Natural gas trapped in hydrate deposits is a potentially enormous source of energy which can in principle be extracted from the underground reservoir structures. These reserves can potentially also catastrophically release very large quantities of greenhouse gases to the atmosphere. One key parameter which is well known to strongly influence fluid distribution, saturation, and production is rock wettability. However, the effect of wettability on gas hydrate in sediments has not been investigated yet. We thus used nuclear magnetic resonance (NMR) spectrometry to measure relaxation times (T₂ and T₁) and the corresponding surface relaxivity of tetrahydrofuran hydrate …

Stress-State And Injection-Rate Dependent Damage Processes During The Hydraulic Fracturing Of Granite, Gayani Sasendrika Gunarathna

Dissertations

Hydraulic fracturing is a well-stimulation technique that is employed in field applications, such as enhanced geothermal systems (EGS) and shale oil/gas extraction. This research experimentally investigates the effect of the state of stress and injection rate on the hydraulic fracturing processes. In addition, a displacement discontinuity method (DDM) code, FROCK, is used to model the crack initiation and propagation in a granite specimen under hydraulic fracturing conditions. In order to conduct the experimental work, a test setup capable of applying a triaxial state of stress and water pressure inside pre-fabricated flaws cut in prismatic granite specimens is developed. Additionally, the …

Investigation Of Tracer-Surfactant-Foam Processes In Shallow Subsurface Environmental Remediation: History-Matching And Performance Prediction, Hazem Fleifel

LSU Master's Theses

In-situ subsurface remediation has been widely used as an efficient means of cleaning up non-aqueous phase liquid (NAPL) from contaminated soils and aquifer. The use of tracer, surfactant, and foam are often considered to keep track of the propagation of injected fluids in the medium, dissolve and mobilize contaminants trapped by capillary forces, and overcome the level of heterogeneity and improve displacement and sweep efficiencies.

This study shows an actual remediation process to reduce NAPL within a military base in South Korea, by injecting tracer and surfactant solutions together for a duration of 10 days. The site consists of 5 …

Modeling Of Leakage Through Fault-Zone Structures In Co2 Geological Storage, Dayna Rodriguez Zambrano

LSU Master's Theses

Faults intersecting target geological CO₂ storage zones have important implications for storage integrity. Potential leakage pathways due to fluid over-pressurization are investigated in this project to ensure long-term containment of injected CO₂. Numerical flow simulations coupled with a geomechanical module are presented in this work with the purpose of determining the extent of CO₂ up-fault migration, the driving mechanisms of leakage and the corresponding response of quantified pore pressure and stress variations.

This study uses dual-continuum models performed by using CMG (2017) to correctly account of flow through fractures in a fault damage zone. Numerical simulations …

Thermomechanical Analysis Of Rock Asperity In Fractures Of Enhanced Geothermal Systems, Chao Zeng

Doctoral Dissertations

"Enhanced Geothermal Systems (EGS) offer great potential for dramatically expanding the use of geothermal energy and become a promising supplement for fossil energy. The EGS is to extract heat by creating a subsurface system to which cold water can be added through injection wells. Injected water is heated by contact with rock and returns to the surface through production well. Fracture provides the primary conduit for fluid flow and heat transfer in natural rock. Fracture is propped by fracture roughness with varying heights which is called asperity. The stability of asperity determines fracture aperture and hence imposes substantial effect on …

Diagenesis And Formation Stress In Fracture Conductivity Of Shaly Rocks; Experimental-Modelling Approach In Co2-Rock Interactions, Abiola Olukola Olabode

LSU Doctoral Dissertations

In large scale subsurface injection of carbon dioxide (CO₂) as obtainable in carbon sequestration programs and in environmentally friendly hydraulic fracturing processes (using supercritical CO₂), long term rock-fluid interaction can affect reservoir and seal rocks properties which are essential in monitoring the progress of these operations. The mineralogical components of sedimentary rocks are geochemically active particularly under enormous earth stresses, which generate high pressure and temperature conditions in the subsurface. While geomechanical properties such as rock stiffness, Poisson’s ratio and fracture geometry largely govern fluid flow characteristics in deep fractured formations, the effect of mineralization can …

Thawing Out: The Role Of The Arctic Council Service In A Melting Arctic, Taylor J. Enos

Pell Scholars and Senior Theses

With the changing natural and political climate of the Arctic, conflicts over resource extraction and navigation will become inevitable. Empowering an intergovernmental institution like the Arctic Council Service may be the only solution. This paper analyzes the importance and history of the Arctic as a political environment, which is prone to abuse in the very near future at the hands of Russia and the United States.

Numerical Modeling Of Fluid Migration In Hydraulically Fractured Formations, Toyin Christie Aseeperi

Graduate Theses and Dissertations

Economic production from low permeability shale gas formations has been made possible by the introduction of horizontal drilling and hydraulic fracturing. To ensure that gas production from these formations is optimized and carried out in an environmentally friendly approach, knowledge about the patterns of gas flow in the shale reservoir formation is required. This work presents the development of a shale gas reservoir model for the characterization of flow behavior in hydraulically fractured shale formations. The study also seeks to develop more computationally efficient approaches towards the modeling of complex fracture geometries. The model evaluates the migration patterns of gas …

Physical Impact Of Waterjet-Based Sediment Remediation On Benthic Organisms, Grace Harper, Andrew Curtis Elmore, Christopher Redell, Gavin Risley, Joel Gerard Burken

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Adding Activated Carbon to Sediments Has Been Shown to Be an Effective Means of Reducing the Bioavailability of Certain Contaminants. the Current State of the Practice is to Mechanically Mix Activated Carbon to a Target Concentration of 3 Percent at Depths of Approximately 30 Cm using a Rotovator or Similar Construction Equipment. Waterjets Have Been Used to Cut Hard Material using a Mixture of Water and an Abrasive. If Activated Carbon is Substituted for the Abrasive, Waterjets Have the Potential to Use Surface Injection as a Replacement for Mechanical Mixing during Sediment Remediation. a Perceived Benefit of Waterjet-Based Sediment Remediation …

Development Of A Waterjet System For Direct Delivery Of Granular Iron And Activated Carbon To Remediate Contaminated Aqueous Sediments, Gavin H.R. Risley, Andrew Curtis Elmore, Joel Gerard Burken, Grzegorz (Greg) Galecki

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

While the Techniques and Technologies Associated with Contaminated Sediment Remediation Are Relatively Mature, There Are Several Issues Associated with These Practices that Make Them Unattractive. the Inability of Currently Used Mechanical Mixing Implements to Place Amendments in Aqueous Environments and their Intrusive Behavior toward Benthic Communities Are Just Two Examples of a Necessity for an Improved Delivery Method. Waterjets May Be a Viable Option for Placement of Particulate Remediation Amendments, Such as Activated Carbon and Granular Iron, at Depth. a Custom Waterjet Nozzle and Injection System Has Been Fabricated by the Authors to Examine This Delivery Concept. the Developed Injection …

Transition Metal Catalysts For Hydrodesulfurization Reactions Applied To Petroleum Industry, Brenda Torres

Open Access Theses & Dissertations

Catalysis plays a fundamental role in petroleum refining and basic petrochemical industries creating new routes in the development of industrial processes. Moreover, catalysis has become indispensable to the solution of environmental pollution problems and therefore on public health. World wide concerns for preservation of the environment has motivated the development of "Green" catalyst based technologies, to achieve a better utilization of petroleum resources and demands for cleaner transportation fuels. These environmental concerns have led to increasingly drastic regulations on sulfur, nitrogen and aromatics content in fuels. Sulfur content in the motor and diesel fuels is continuously reduced by regulations to …

Fatigue Of Drill Pipes Used In Horizontal Directional Drilling, Feibai Ma

Doctoral Dissertations

Fatigue is the most common cause of mini-HDD drill rod failure. It can occur at stress levels far below the normal operating stress in most drill stem components. Fatigue failures occur because the drill rod, after it has been forced into a curved path, undergoes a cyclic bending stress oscillating from tension to compression in concert with the other stress components caused by torque, thrust, or pullback.

When a rod breaks underground, there is considerable extra cost caused by the delay in “fishing” out the broken rod as well as the cost of replacing the rod. On the other hand, …

Simulation Of Temperature And Stress Fields During Rcc Dam Construction, Ronaldo Luna, Yongfu Wu

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The worldwide experience in the construction of roller-compacted concrete (RCC) dams together with the use of numerical solutions, allows the simulation of different scenarios in a computer. It is well documented that thermal control is one of the most important problems for RCC dam construction. The dam temperature changes due to the heat produced by the internal hydration of concrete and the environmental boundary conditions influencing the elastic modulus and creep properties of concrete. The construction process was simulated to study how the temperature and stress change during dam construction. The numerical methodology considers the effect of temperature on the …

Assessment Of Environmental Implications Of Abandoned Oil And Gas Wells, Donald L. Warner, Cary L. Mcconnell

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A detailed study was made of the potential for abandoned oil and gas wells in the Lower Tuscaloosa sand of Mississippi and Louisiana to act as conduits for movement of saline water from the Lower Tuscaloosa into underground sources of drinking water (USDW's). Finite-difference numerical modeling determined the extent that water might be forced from the Lower Tuscaloosa sand into a USDW as a result of injection into the Lower Tuscaloosa. Within the range of conditions modeled, water from the Lower Tuscaloosa never traveled into a USDW. On the basis of the modeling, we concluded that it is unlikely that …

Geotechnical Evaluation Of The Support Of Coal Pillars In Underground Coal Mines., John D. Rockaway, Richard W. Stephenson

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The Study Described Was Accomplished through an Investigation of Both the Intact and Insitu Geotechnical Properties of the Sub coal Strata and through the Installation of Floor Movement Monitoring Instrumentation. the Method of Bearing Capacity Analysis Developed by A. S. Vesic Was Used to Define Pillar Stability. This Method Includes Provisions for Taking into Consideration a Two-Layer System Such as Assumed for Mine Conditions Where a Weak Underclay overlies Firmer Strata.

The Operator’S Guide For Minimizing Energy Costs, Charles Dare, Frank A. Gerig

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The consumption of petroleum by transportation activities is increasing despite the finite limits on its supply. This paper concentrates on the motor vehicle driver, his driving habits, and guides to reduced fuel consumption which would enable the individual to curtail wasteful practices with respect to vehicle operation.

New Genera And Species Of Myripristid Fishes, In The Gulf Coast Cenozoic, Known From Otoliths (Pisces, Beryciformes)

School of Mines and Metallurgy Bulletins

Studies of fossil and Recent otoliths (sagittae) supply an important line of evidence, bearing on classification of teleost fishes, supplementary to that of anatomy, osteology, and "phylogenetic" paleoichthyology.

Squirrelfishes ( " Holocentridae" of authors) are generalized forms in which evolutionary divergence of some mag nitude is reflected in unpreservable details of anatomy, inconspicuous skeletal structures, and striking differentiation of the sagittae. Otoliths show the holocentroid complex to consist of one homogeneous unit (l\fyripristidae, elevated) and another more heterogeneous group (Holocentridae, restricted). These lineages have been separate. at least since the middle Eocene.

A revised classification, based on available lines of …