Other Chemical Engineering Commons^™

Development Of A Monitoring Framework For The Detection Of Diversion Of Intermediate Products In A Generic Natural Uranium Conversion Plant, Jennifer L. Ladd-Lively

Doctoral Dissertations

The objective of this work is the development of an on-line monitoring and data analysis framework that could detect the diversion of intermediate products such as uranium dioxide, uranium tetrafluoride, and uranium hexafluoride in a natural uranium conversion plant (NUCP) using a multivariate statistical approach. This was an initial effort to determine the feasibility of this approach for safeguards applications. This study was limited to a 100 metric ton of uranium (MTU) per year NUCP using the wet solvent extraction method for the purification of uranium ore concentrate. A key component in the multivariate statistical methodology was the Principal Component …

Studies Of Reaction Processes For Voloxidation Methods, Jared Allen Johnson

Doctoral Dissertations

Various facets of the voloxidation process and processes that have been derived from the voloxidation process have been investigated since its development over four decades ago. Despite the numerous studies performed, gaps remain in understanding of particular fundamental aspects of the reaction processes. In this work, several of these specific aspects of the oxidation processes for standard voloxidation and NO₂ [nitrogen dioxide] voloxidation are studied experimentally and modeled.

In the case of standard voloxidation, the oxidation rates of simulant UO_­2 [uranium dioxide] pressurized water reactor pellets in oxygen-rich environments were studied with an emphasis on the controlling phenomena …