Catalysis and Reaction Engineering Commons^™

Effect Of Household Oil Contamination And Agricultural Soil Contamination On Phyllosilicate Nanocatalyst Performance During Pyrolysis Of Polyolefins, Joey Velasquez

Master's Theses

The effect of household oil and agricultural soil contamination on catalyst performance during polyolefin pyrolysis was simulated on mixed virgin plastic pellets by evaluating contamination influence on mixed plastic degradation temperatures. Three phyllosilicate nanocatalysts including Fulcat435, Fulcat22F and Y-Zeolite were evaluated in this work based on a literature review of catalyzed plastic pyrolysis and these catalysts’ ability to lower plastic decomposition temperature by 50 °C – 100 °C. These findings were confirmed in this research through thermogravimetric analysis of a polyolefin mixture and further developed in furnace experiments containing household oil and agricultural contamination. Household oil contamination deactivated each of …

Analysis And Optimization Of Colorimetric Nanosensors For Rapid Detection Of Microbes In Water, Ruby A. Lang

Master's Theses

Access to safe water is a basic human right recognized by the United Nations General Assembly in 2010 (WHO, 2020). However, a least 2.2 billion people globally still are without safely managed water services meaning they use a drinking water source that can be contaminated with faeces (WHO, 2020). With such a pressing global health issue, it is clear that improvement to water systems is important and required in the Agenda 2030 Sustainable Development Goals (SDGs). However, to improve water systems and prove they are safe water sources, water quality testing must occur. A solution to this issue is the …

Microkinetic Modeling And Analysis Of Ethanol Partial Oxidation And Reforming Reaction Pathways On Platinum At Short Contact Times, Maura A. Koehle

Master's Theses

No abstract provided.

Evaluation Of Cathode Materials For Low Temperature (500-700c) Solid Oxide Fuel Cells, Alexander M. Lassman

Master's Theses

Solid oxide fuel cells (SOFC) have gained a great deal of interest, due to their potential for high efficiency power generation and ability to utilize hydrogen fuel, as well as various hydrocarbon-based fuels. A recent trend in SOFC development has been towards lower operating temperatures (500-700°C), which can substantially reduce the cost and complexity of the system. This thesis presents an investigation into state of the art Ba- and La- based cathode materials for use in low temperature (500-700°C) solid oxide fuel cells.

Synthesis of A-site deficient [A=0.97] Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃ (BSCF) was …

Applied Control Strategies At A Cogeneration Plant, Joseph William Burns

Master's Theses

The purpose of this paper is to demonstrate the effectiveness of “classical strategies for dynamic control” on authentic cogeneration processes. These strategies are applied to several processes at the University of Connecticut’s cogeneration plant. Case studies of their applications are presented in this paper. Strategies that are applied include the following:

1) The classical SISO feedback structure

2) The First Order Plus Dead Time (FOPDT) process model

3) The Internal Model Control (IMC) correlations for PI controller tuning

4) Static feed forward with feedback trim

5) Cascade Control