Catalysis and Reaction Engineering Commons^™

Valorization Of Biomass Derivatives To Monomers By M-Mox Catalytic Hydrogenation & Hydrodeoxygenation, William Steere, Samir Castilla-Acevedo, Ben Auer, John Styers, Alan Allgeier

UNH URC Open (2026 and after)

With increasing concern regarding global warming contributions by fossil fuels in petrochemical production, the potential use of biomass-derived molecules to serve as a more eco-friendly feedstock has grown in popularity. Specifically, sebacic acid, a versatile chemical used to produce nylons, plasticizers, and lubricants, has the potential to be obtained from bio-renewable feedstocks and alleviate environmental drawbacks from fossil fuel petrochemical production. Our research validates the catalytic conversion of the biomass-derived 2,2’-bifuran 5,5’-dicarboxylate (BFDCM) to sebacic acid (SA), through M-MO_x catalyzed hydrogenation and hydrodeoxygenation. Catalytic activity tests were conducted for four different Pd-supported catalysts (C, Al₂O₃, …

Enzyme-Catalyzed Reactions Using Enzymes Immobilized On Non-Spherical Particles, Alexander D. Redfearn

Honors Theses and Capstones

Modern and industrial chemical reactions often utilize enzyme-catalyzed reactions to increase product yields. Given the high cost of enzymes it is desirable to preserve the activity of the enzymes and reuse them several times. In this study, I explored the possibility of immobilizing enzymes on custom-made non-spherical SU-8 microparticles to conduct enzyme-catalyzed reactions in flow reactors. The decomposition of hydrogen peroxide using bovine liver catalase was studied due to its well-understood enzyme kinetics. Soft lithography techniques were used to synthesize prismatic SU-8 microparticles. I will discuss the progress that has been made in immobilizing the enzyme on the particle surface …

Synthesis Of Copper Oxide Nanoparticles In Droplet Flow Reactors, Christopher Reilly

Honors Theses and Capstones

Synthesis of metal oxide nanoparticles within droplet flow reactors is advantageous over batch synthesis due to the elimination of concentration and temperature gradients inside the reactor and prevention of reactor fouling. We present results on the synthesis of copper oxide nanoparticles using aqueous droplets of copper acetate and acetic acid inside a bulk stream of sodium hydroxide in 1-octanol. Varying the copper acetate, acetic acid, and sodium hydroxide concentration resulted in needle-like and plate-like nanoparticles of varying sizes. The rate of mass transfer from the bulk to the droplet phase was found to increase with flow rate and addition of …

Photocatalytic Decomposition Of Phenol Under Visible And Uv Light Utilizing Titanium Dioxide Based Catalysts, Marjorie G. Steiner

Honors Theses and Capstones

Pollution in wastewater effluvia from phenol and phenolic compounds is a common occurrence in many industrial manufacturing plants. Phenol is toxic to human beings as well as a contaminant to the environment, meanwhile, it is difficult to remove from wastewater due to its non-biodegradable nature. To boost the rate of decomposition, various catalytic approaches have been developed. With the interest of decreasing operation cost, titanium dioxide (TiO₂) based catalysts have emerged as good candidates for the photocatalytic process.

In this honors project, a series of TiO₂ based catalysts, including TiO₂, N-TiO₂, Cu-TiO_{2 …}

Phenol Deoxygenation Over Hydrotreating Catalysts, Madelyn R B Ball

Honors Theses and Capstones

Phenol deoxygenation has been investigated as a model reaction for the deoxygenation of fatty acid methyl esters in biodiesel. Hydrodeoxygenated biodiesel is a drop-in fuel for petroleum diesel, and is a premium diesel with a high cetane number. As the first step in this research, two molybdenum catalysts were prepared, characterized and tested in a small-scale reactor. These catalysts were found to produce small amounts of benzene and cyclohexanol in the product stream, and confirmed the activity of the catalyst. A commercial cobalt molybdenum catalyst (Harshaw HT-400) was also tested and benzene, cyclohexanol, and cyclohexane were identified as products. Future …

Comparison Of Biomass To Bio-Oils Reactor Systems: Direct Conversion Vs. Companion Coal Gasification, Alexandra Eicher

Honors Theses and Capstones

It is well known that the United States’ dependence on crude-oil negatively affects its economy, safety, and environment. To alleviate these negative consequences, a more economical and environmentally-friendly source of fuel, such as biomass, should be explored. The conversion of biomass to bio-oils involves the pyrolysis of biomass at about 500°C, thus requiring a great deal of heat. This heat source could be the excess waste heat from a coal gasifier.

As such, this report specifies the design of an industrial plant that produces bio-oils from biomass by using the waste heat from a coal gasifier. It is designed to …