Catalysis and Reaction Engineering Commons^™

Voltage-Related Power Quality Issues And Impacts On Distribution Networks With Sensitive Loads - A Review, Godwin Elinazi Mnkeni, Jackson Justo, Aviti Thadei Mushi, Bakari M. M. Mwinyiwiwa

Tanzania Journal of Engineering and Technology (TJET)

Voltage disturbances are the most important power quality (PQ) complications that customers and power utilities face in this smart era. The growing adoption of sophisticated electronic equipment and integration of renewable energy sources (RES) into power grids has increased the susceptibility of power distribution networks (PDNs) to voltage sags, swells, interruptions, flicker, and voltage imbalance. These disturbances, mainly caused by upstream faults, switching operations, and RES integration, compromise voltage PQ and system reliability. Consequently, they accelerate equipment degradation, increase electronic waste (e-waste), raise reactive power demand and maintenance costs, increase power losses, and impose substantial economic losses on customers and …

Nanostructured Cathode Catalysts For Aem Electrolysis: From Catalyst Design To Degradation And Hydrogen Dynamics, Yamini Kumaran

Electronic Theses & Dissertations (2024 - present)

Anion exchange membrane water electrolysis (AEMWE) presents a promising pathway toward cost-effective and sustainable hydrogen production by integrating the chemical robustness of alkaline systems with the compact, zero-gap design of proton exchange membrane electrolyzers. However, the widespread implementation of AEMWE is limited by the availability of highly active and durable platinum-group-metal (PGM)-free catalysts and by an incomplete understanding of their degradation behavior under realistic operating conditions.

This dissertation focuses on the development, characterization, and mechanistic investigation of nanostructured MoNi₄–MoO₂-based electrodes for efficient and stable hydrogen generation under alkaline and membrane-integrated environments. MoNi₄–MoO₂ nanorods …

Comprehensive Review Of Sensible Thermal Storage Systems For Cooking Applications, Anna K. Shariishoy

Tanzania Journal of Engineering and Technology (TJET)

This paper reviewed the sensible thermal storage systems specifically designed for cooking applications. The review focuses on the characteristics of storage materials, their practical applications, and the overall performance of the systems. The review consolidated an array of experimental and numerical research published across various sources such as journals, conferences, books, online resources, and professional reports. A systematic review is used to reach the conclusion of this paper. Significant findings from this study include the wide range of storage capacities attained from small-scale systems that can store ~1–5 MJ of energy for a single meal to bigger systems that can …

Predicting The Influence Of Aggregate Size And Distribution On Cementitious Concrete Properties: A Review, Innocent J. Macha

Tanzania Journal of Engineering and Technology (TJET)

Cement concrete has been in use for centuries as one of the primary construction materials. Its demand in the construction industry is expected to continue for several centuries before the full development of alternative products. However, one of the main areas of research interest is understanding how its constituents can be tailored to make its properties predictable to reduce risks associated with structural failures, reconstruction and reduced durability. These hindrances associated with cementitious concrete result from several attributes, including constituent material characteristics, mixing ratios and workmanship. Understanding the predictability of cement concrete properties requires computer modelling tools to provide reliable …

Optimizing The Processing Temperature For Synthesis Of Silver Nanoparticles Within Cellulose-Wool Keratin Supramolecular Matrix Using Butylmethylimmidazolium Chloride Ionic Liquid, Ngesa E. Mushi

Tanzania Journal of Engineering and Technology (TJET)

To date, the synthesis of silver nanoparticles on the surface of cellulose and wool keratin biopolymer, while dissolved in ionic liquid, is attractive because of its biomedical potential. However, the optimal processing temperature for the nanoparticle formation is unclear. The previously reported temperature of approximately 120°C gives unpredictable results. The current study employs a combination of 50% cellulose and 50% keratin, along with 69 mg of silver chloride, in Butylmethylimidazolium Chloride BMImCl ionic liquid, using a single-pot process to produce a supramolecular film via non-derivatized mechanochemical interactions. The primary objective is to experimentally establish the processing temperature to achieve stable …

Assessment Of Factors Contributing On Early Rotting Of Chromated Copper Arsenate Treated Utility Power Distribution Wood Poles In Tanzania, Innocent J. Macha

Tanzania Journal of Engineering and Technology (TJET)

The study aimed to assess the factors contributing to the premature decay of Chromated Copper Arsenate (CCA) treated utility power distribution wooden poles in Tanzania. Deteriorated poles samples from various regions in Tanzania were analyzed using handheld X-ray spectrometry to quantify the retention of CCA preservative chemicals. The ages of these poles were estimated based on annual growth rings. The findings indicated that premature failure of CCA treated wooden poles is attributed to an imbalance in the chemical composition of the preservative solution. The study found that CuO retention in most samples ranged between 10-18 kg/m3, significant lower that the …

Investigation Of Heavy Metal Composition And Associated Health Risks From Selected Groundwater Wells In Temeke, Dar-Es-Salaam, Justin M. Jeremiah

Tanzania Journal of Engineering and Technology (TJET)

Water quality continues to be the challenge to residents in Dar es Salaam due to various anthropogenic activities in the city. This study was conducted to assess groundwater quality by determining concentrations of heavy metals. Both probability and Nonprobability sampling techniques were used to collect samples from 40 groundwater wells in 24 wards of Temeke municipal and analysed using Microwave Plasma Atomic Emission Spectrometer (Agilent 4210 MP-AES) at the Geochemistry Laboratory of the University of Dar es Salaam. Results indicated varying heavy metal concentrations ranging from 0.71 ± 0.08 to 6.64 ± 0.21 mg/l for As, 0.02 ± 0.01 to …

Production Of Biofertilizer From Fruit And Garden Waste, Neema Msuya

Tanzania Journal of Engineering and Technology (TJET)

The project focused on the production of bio-fertilizer from fruit and garden waste, with a specific emphasis on utilizing pineapple tops in the composting process. The objective was to produce and assess the properties of the bio fertilizer obtained from this process and evaluate its potential application in agriculture. In this study, the composting process was done in a 0.7 m long, 0.85 wide and 1.1 m high vessel, and 0.238 m3 pineapple top wastes, resulting in 0.35 m3 of biofertilizer. The bio fertilizer produced exhibited favorable characteristics, including a moisture content of 36%, pH of 7.1, and a total …

Modeling Of Amine-Based Co2 Capture Process, Zafar Safarovich Turakulov

Chemical Technology, Control and Management

A significant factor influencing climate change is the release of carbon dioxide (CO₂) into the atmosphere as a consequence of human activities such as the combustion of fossil fuels. Climate change can be slowed down by taking action to mitigate industrial-scale CO₂ emissions. Currently, the most advanced technology for capturing CO₂ from industrial flue gases is the post-combustion CO₂ capture based on amine absorption. However, due to the high energy penalties of existing CO₂ capture technologies and insufficient carbon markets, it is necessary to develop methods that compete with these technologies or minimize their …

Ambient Air Emission Profiles Of Polycyclic Aromatic Hydrocarbons Around A Typical University Power House In Nigeria, Oyetunji Okedere

Tanzania Journal of Engineering and Technology (TJET)

The level of electricity generation in Nigeria is presently grossly inadequate. Consequently, the productive sectors of the economy do not presently enjoy an uninterrupted supply of electrical energy from the country’s national grid and the downtime is in most cases too much. Using diesel-fueled electric power generators has become an attractive alternative to meet the shortfall in the energy supply gap. In this study, the levels of polycyclic aromatic hydrocarbons in the vicinity of the diesel-fueled electric power generators operated by Osun State University, Osogbo, Nigeria were investigated with a view to ascertain the priority levels and carcinogenic PAHs. Since …

Rheological Properties Of Aged Crude Hard Wood Pyrolysis Oil, Divina D. Kaombe

Tanzania Journal of Engineering and Technology (TJET)

Upon storage of the pyrolysis oil, aging reactions may initiate phase separation and change of the rheological properties. These changes lead to unfavourable fuel characteristics in handling, transportation and applications. Efforts have been made for alleviation including methods on how to avoid these aging effects and development of equipment capable of handling aged pyrolysis liquids with unfavourable fuel characteristics. Therefore, the aim of this study was to explore the rheological properties of phase separated pyrolysis liquid fuel. Two batches of a well – stored poplar wood pyrolysis oils were used for the investigation; one batch was diluted with water to …

Assessment Of Heavy Metal Concentration In Soils Around Geita The Gold Mine, Tanzania, Mariam G. Mgendi, Mkabwa L. K Manoko, W.J.S. Mwegoha, C. Southway C. Southway

Journal of Humanities and Social Sciences

Health issues related to gold mining cannot be underestimated. Gold mining produce acid mine drainage (AMD), which in turn releases heavy metals into the nearby environment, hence causing environmental pollution. Heavy metals are naturally very toxic, thus pose a great health concern especially when their concentration exceeds the recommended permissible limits. In this study, concentrations of five heavy metals—including Pb, Ni, Cr, Cu and Zn—were assessed in the soil around Geita Gold Mine (GGM). A total of 17 sampling sites were established from which the soil samples were collected at 0-15cm and 15-30cm soil depth. The concentration of both total …

The Potentials Of Faecal Sludge Treatment Using Local Conditioners In Tanzania: A Review, Doglas Benjamin1

Tanzania Journal of Engineering and Technology (TJET)

Worldwide, every day human beings generate millions of tons of Faecal Sludge (FS), which is rich in water, nutrients, energy, and organic compounds. Yet FS is not being managed in a way that permits us to derive value from its reuse, while at the same time, millions of farmers struggle with depleted soils and lack of water. In most of the developing countries, energy for cooking is mainly derived from cutting of trees, either as wood or charcoal. Resource recovery and reuse from FS can create livelihoods, enhance food security, support green economies, reduce waste and contribute to cost recovery …

The Effect Of Rotation And Temperature On The Inhibition Performance Of Cashew (Anacardium Occidentale L.) Nut Shell Liquid On Co2 Corrosion Of Carbon Steel, J Mutasingwa

Tanzania Journal of Engineering and Technology (TJET)

A natural extract of cashew nut shells, Cashew Nut Shell Liquid (CNSL) was investigated as a corrosion inhibitor for carbon steel in 3% NaCl solutions saturated with CO2 gas using electrochemical techniques (i.e. potentiodynamic polarization and ac-impedance). The investigation was performed at different temperatures under static and dynamic conditions using a Rotating Disk Electrode (RDE). It was found that CNSL reduces the electrochemical processes taking place on carbon steel undergoing corrosion. The percentage inhibitor efficiency increases with increase in CNSL concentration and decreases with rise in temperature. Better performance at low CNSL concentration was registered under dynamic conditions and room …

Investigation Of The Effect Of Particle Size On Groundnut-Oil Solvent Extraction, S Manyele

Tanzania Journal of Engineering and Technology (TJET)

An investigation of the effect of particle size on the performance of vegetable oil recovery by solvent extraction is reported. Experiments were conducted using soxhlet extractor, groundnuts and n-hexane. Samples were grouped into mean particle sizes of 0.25, 0.75, 1.3, 3.3, and 7.5 mm using standard sieves. The effect of particle size was studied for extraction time intervals of 1, 2, 3, 4, 5 and 8 hours. The oil yield, oil recovered per kg solvent used, kg solvent lost per unit time, and the rate of extraction (kg oil recovered per hour) decreased with increasing particle size. Meanwhile, the percent …

Geometric Programming As A General Method For Phase And Reaction Equilibrium Calculations, Godwill Mrema

Tanzania Journal of Engineering and Technology (TJET)

Geometric programming has been used to calculate a large mtmber ofdifferent ideal and non-ideal equilibria, including, for reaction and For non-ideal Systems the primal program is solved a number Of times With the nan-ideal terms fixed each time. After each primal solution, the nan-ideal terms are "'hdated using the corresponding dun! solution. This iteration generally converges. We have included one counter-example, where the failure is caused by the equation Of state, which Cannot giu• correct roots.

Performance Of Aerobic Bioreactors During Treatment Of Tanning Industry Wastewater, Samwel V. Manyele

Tanzania Journal of Engineering and Technology (TJET)

The performance of aerobic bioreactors loaded with novel biomass support (the KMT® support particles) during the treatment of tanning industry wastewater is presented in this paper. The wastewater samples were collected from TANWAT Company in Njombe, which extracts tannins from barks of the wattle tree. The wastewater generated from T ANWAT is very acidic with high loading of organic compounds, which are very complex and difficult to biodegrade using conventional methods. The paper introduces a new technology for treatment of heavily loaded industrial wastewater, like tannins, that is the Three-Phase Fluidized Bed Bioreactor (TPFBB) which utilizes the KM'f® support particles. …

Socio-Economic Impacts Of Computer Viruses In Tanzania, M Victor

Tanzania Journal of Engineering and Technology (TJET)

This paper reports on a research project conducted with an objective of identifying and assessing various approaches used by different computer users (Management, System Administrators and end users) in Tanzania to combat computer viruses (CVs), and to assess users' awareness level on CVs. Specifically, the study aimed at assessing the awareness level on CVs to the Tanzanian business community; analyze the socio -economic impact caused by CVs in Tanzania and; assess existing methods, capacity and limitations on controlling CVs in Tanzania. Data was collected using both questionnaires and interview from financial institutions such as NBC and BOT, and telecommunications sector …

Effectiveness Of Hot Isostatic Pressing On Healing Oxide Film Defects In Cast Aluminium Alloys, C Nyahumwa

Tanzania Journal of Engineering and Technology (TJET)

Hot isostatic pressing (hipping) of cast aluminium alloys is recognized as a means of providing improved internal soundness and mechanical properties of the castings. However, little is known about the limitations and potential benefit of the hipping process to produce reliable aluminium alloy castings containing oxide film defects due to turbulently filling of moulds. In this study, oxide film defects and fatigue lives of turbule''Zt filled unfiltered AI-7Si-Mg alloy castings have been characterised in as-cast and hipped. conditions to quantify the effectiveness of hot isostatic pressing on healing oxide film defects in the castings. The average fatigue life and fatigue …

Gasification Kinetics Of Ultrafine Coal Char Oxidation In Flame Reactions, G John

Tanzania Journal of Engineering and Technology (TJET)

Pulverized coal combustion is exceedingly complex with a  vast number of variables. In order to avoid the complications associated with the burning of coal char, a controlled study has been made of the oxidation of fine graphite in laminar methane-air flame as a contribution to the understanding of the more complex phenomena of the gasification kinetics of the char. The burning of methane is equivalent to the burning of volatiles and graphite oxidation is similar to that of coal char. Aspects of this have been simulated in experimental and computational studies of 4pm diameter graphite particle burning in methane -air …

The Decomposition Kinetics Of Solids Thermodynamic Evidence For The Enthalpy Driven Cooling Of Reaction Environment Part 2, Akwilapo D

Tanzania Journal of Engineering and Technology (TJET)

The analysis of non-isothermal kinetic data for the decomposition of calcium carbonate, CaC03 (s) ~ CaO (s) + C02 (g) in flowing nitrogen, shows that the decomposition of solids is accompanied by self-cooling/heating of the reaction environment depending on the sample mass and heating rate. The correctness of the kinetic model is established by the calculation of the enthalpy change of the reaction. This is the thermodynamic evidence of endothermic enthalpy driven cooling of the reaction environment. The enthalpy change LJH = 179.33 kJmol-1 estimated from this work for the dissociation of CaC03 is in agreement with LJH = 179.17 …

Ceramic Properties Of Chimala Kaolin Clay, Leonard Akwilapo

Tanzania Journal of Engineering and Technology (TJET)

The physico-chemical properties of kaolinite clays occurring in abundance near Chimala were studied with a view of finding out their suitability in sanitary ware production. The viscosity of the clay was found to be within the range acceptable in industrial application (≤ 500 cp for 70% solids), enhancing its prospects for the manufacture of slip cast shapes with satisfactory properties. The chemical composition of the clay reveals a high content of Fe₂O₃, 1.48%, which is expected to affect the translucency and colour of the finished ware. However, such quantity would not have detrimental effects in the production of sanitary ware. …

Aeration Efficiency Of A Three-Phase Fluidized Bed Bioreactor During Food Industry Wastewater Treatment, S Manyele

Tanzania Journal of Engineering and Technology (TJET)

The implementation Of a three-phase fluidized bed bioreaclor (TPFBB) in food- processing wastewater (FPW'W) treatment is reported. This study includes the modification Of the air distributor (plate design and gas-liquid mixing) for the bioreactor and resting of its aeration efficiency under different liquids. The aeration efficiency for wastewater samples collected from a soft drink processing industry and tannin processing industry (TANWA T) and tap water were compared. The aeration efficiency parameters studied include bed expansion, air holdup. volumetric oxygen mass transfer coefficient, and alpha factors. The variation of these parameters With air flow rates were studied at different liquid heights, …

Comparative Study Of The Dynamics Of Circulating Fluidized Bed Riser And Downer Of Equal Diameters, Samwel V. Manyele

Tanzania Journal of Engineering and Technology (TJET)

The microscopic flow dynamics of the 100-mm internal diameter riser/downer circulating fluidized bed (CFB) unit were monitored using a solids concentration fiber optic probe. The comparison was conducted by comparing radial profiles Of the dynamic parameters derived from time-series analysis techniques (statistical and chaos analyses). The solids concentration signals used were recorded under similar operating conditions (gas velocity of 8.0 m/s and solids flux of 100 kg/m2s). Similar axial elevations were compared (entrance and fully developed sections of die reactors). A1 each loca!ion, the signals were sampled a! afrequency of 970 Hz for duration of 30 seconds. It was observed …

Review Of The Product Development Process And Information Flow In The Manufacturing Industry: Problems And A Possible Wav Forward, E Opiyo

Tanzania Journal of Engineering and Technology (TJET)

No abstract provided.

Production Of Biogas From Water Hyacinth: Effect Of Substrate Loading In Semi-Batch & Batch Operations, J Katima

Tanzania Journal of Engineering and Technology (TJET)

A study was carried out to establish the effect of substrate loading rate on the production of biogas from water hyacinth. The experiments revealed that the maximum methane yield in a batch process was 0.166 normal litre (NLVg Of volatile solids (VS) added at substrate concentration of 25 g dry mass'litre after five days of incubation. The maximum methane yield in a semi-batch process was 0.153 NWg VS added at 1.30 g VS'litre day and retention time Of 15 days.

Recyclability Of Modified Ps-Aq Pulps At Around Kappa 30, Rwaichi Minja

Tanzania Journal of Engineering and Technology (TJET)

Bleachable grade pulps prepared from Nonvegian softwood spruce chips while simulating possible alternatives of improving pulp yield by application Of polysulphide (PS) and anthraquinone (AQ) have been used in this study. The tests for recyclability were performed on hydrogen form pulps. The pulps considered were Iso- Thermal cooking (ITC) kraft pulp which was used as a reference pulp, conventional PS-AQ pulp, soda PS-AQ pulp and kraft PS-AQ pulp. The loss Of swelling ability (homification) Of the pulps, was determined by measurement of water retention value (W R V). The results showed that, PS-AQ pulps had similar or slightly better swelling …

Application Of Vibrational Techniques In Determination Of Dynamic Properties Of Agricultural Products-State Of The Arton Of Vibrational Techniques In Determination Of Dynamic Properties Of Agricultural Products-State Of The Art, Silas Kajuna

Tanzania Journal of Engineering and Technology (TJET)

Vibration is one of the techniques employed in the determination of dynamic properties of fruits and vegetables. It entails generation of a mechanical or acoustic vibrational signal which is propagated through the flesh of the agricultural material. A transducer is either attached or held close to the specimen to monitor the propagation of the signal through the specimen. The manner in which the signal is transmitted through the material is analyzed, and the dynamic properties of the specimen which relate to its firmness or its internal being are derived. The technique has been around for the past 30 years or …

Oxygen Transfer In A Three-Phase Fluidised Bed Bioreactor With Novel Biomass Support When Used In Industrial Wastewater Treatment, S Manyele,

Tanzania Journal of Engineering and Technology (TJET)

The effect of support mass and liquid height on the oxygen transfer in the three- phase fluidised bed were experi/nenta/ly investigated. Novel biomass support, rhe KMT*, with density of 850 kg/n/ and an equivalent size, dp 8.3 mm, has been used in this work. The oxygen transfer rate was expressed in terms of rhe volumetric oxygen transfer coefficient, kca. It has been found out that the* a values increased with increasing support mass up to a critical solids load of 4.0 kg, above which the kca decreased and that kca decreased with increasing liquid height. It has been recommended that …

New Technologies For Thermal Disposal Of Sewage Sludge, T Ogada

Tanzania Journal of Engineering and Technology (TJET)

The traditional methods for the disposal of sewage sludge are landfilling, recycling as fertilisers in agricultural lands, dumping into sea and incineration. In thc recent past, Sludge incineration has been rapidly gaining ground duc to environmental constraints facing the Other methods. However, the cost of pollution control during sewage sludge incineration is currently very high due to the expensive flue gas treatment facility required. Futhermore, large quantity Of ash is produced which is highly contaminated with heavy metals and must be disposed off in special landfilling sites in order to avoid ground water pollution. To reduce the cost Of pollution …