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Reversible Addition - Fragmentation Chain Transfer In Microemulsions: Effect Of Chain Transfer Agent Aqueous Solubility, Jennifer M. O'Donnell, Eric W. Kaler
Reversible Addition - Fragmentation Chain Transfer In Microemulsions: Effect Of Chain Transfer Agent Aqueous Solubility, Jennifer M. O'Donnell, Eric W. Kaler
Jennifer M. Heinen
Microemulsion polymerizations are attractive for investigating compartmentalization effects in heterogeneous reversible addition - fragmentation chain transfer (RAFT) polymerizations because the propagating radicals are segregated into surfactant stabilized polymer particles, which drastically reduces the effects of biradical termination, Also, microemulsion polymerizations do not involve the large monomer droplets that are present in emulsion and miniemulsion polymerizations. RAFT microemulsion polymerizations of butyl aery late with a high water solubility chain transfer agent, methyl-2-(O-ethylxanthyl)propionate (MOEP), and a low water solubility chain transfer agent, methyl-2-(O-dodecylxanthyl)propionate (MODP), were investigated to determine the effect of chain transfer agent compartmentalization on the control of the polymerization. The …
Microstructure Evolution And Monomer Partitioning In Reversible Addition - Fragmentation Chain Transfer Microemulsion Polymerization, Jennifer M. O'Donnell, Eric W. Kaler
Microstructure Evolution And Monomer Partitioning In Reversible Addition - Fragmentation Chain Transfer Microemulsion Polymerization, Jennifer M. O'Donnell, Eric W. Kaler
Jennifer M. Heinen
Small-angle neutron scattering (SANS) studies of reversible addition - fragmentation chain transfer (RAFT) microemulsion polymerizations of butyl acrylate and 2-ethylhexyl acrylate with the RAFT agent methyl-2-(O-ethylxanthyl) propionate (MOEP) allow the observed rate retardation to be attributed to slow fragmentation of the macro-RAFT radical. Microemulsion polymerization allows the RAFT mechanism to be investigated in the absence of termination reactions so that the cause of the rate retardation frequently observed in both homogeneous and heterogeneous polymerizations may be isolated. However, the concentration of monomer at the locus of polymerization (Cmon(part)) must be known as a function of conversion before a mechanistic study …