Biochemical and Biomolecular Engineering Commons^™

Dead Zones In Porous Catalysts: Concentration Profiles And Efficiency Factors, Roger L. York, Kaitlin M. Bratlie, Lloyd R. Hile, Larry K. Jang

Kaitlin M. Bratlie

This paper examines the conditions under which a dead zone, or a portion of the catalyst devoid of reactant, can form in a porous catalyst in which simultaneous reaction and diffusion are occurring. The condition that allows for the existence of a dead zone is defined by a critical Thiele modulus. When the Thiele modulus - the ratio of chemical reaction to diffusion - is greater than the critical Thiele modulus, a dead zone exists. This dead zone can be mathematically defined by a change of boundary conditions. We examine nth order reactions in isothermal infinite slabs, infinite cylinders, and …