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Biochemical and Biomolecular Engineering Commons

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Eastern Kentucky University

Photocatalyst

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Toward The Synthesis And Characterization Of Pb-Doped Zns Nanocrystals For Solar Energy Applications, Allison Durr Jan 2016

Toward The Synthesis And Characterization Of Pb-Doped Zns Nanocrystals For Solar Energy Applications, Allison Durr

Online Theses and Dissertations

Efficient and affordable energy conversion and energy storage technologies are required to meet society’s increasing demands. Semiconductor nanocrystals are particularly attractive materials for solar energy conversion applications, as their tunable optoelectronic properties can be manipulated to both optimize the absorbance of solar photons and to afford desirable electronic properties. Further tunability of binary semiconductor nanocrystal systems can be realized through substitutional doping. However, doping can be difficult, as the dopants can cause significant lattice strain in the host crystals. Lead-doped ZnS nanocrystals are one promising material for the conversion of solar photons into storable fuels such as hydrogen gas. The …