Chemical Engineering Commons^™

A Review Of Field Oil-Production Response Of Injection-Well Gel Treatments, Munqith Aldhaheri, Mingzhen Wei, Na Zhang, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

As life-span extenders, bulk gels have been widely applied to rejuvenate oil production from uneconomic producers in mature oil fields by improving the sweep efficiency of improved-oil-recovery (IOR)/enhanced-oil-recovery (EOR) floods. This paper presents a comprehensive review of the responses of injection-well gel treatments implemented between 1985 and 2014. The survey includes 61 field projects compiled from SPE papers and US Department of Energy reports. Seven parameters related to the oil-production response were evaluated according to the reservoir lithology, formation type, and recovery process, using univariate analysis and stacked histograms. The interquartile-range (IQR) method was used to detect the underperforming and …

Compression Set Improvement Of Thermoplastic Vulcanizates For High Temperature Tubing, Mitchell Valaitis

Williams Honors College, Honors Research Projects

It was hypothesized that increasing the curative level of the fluorocarbon rubber (FKM) used in manufacturing of thermoplastic vulcanizate (TPV) materials would decrease the compression set values of the TPV enough for it to be suitable as a flexible, lightweight alternative to high operating temperature thermoset rubber tubing currently being used for power steering hose. First, promising TPV formulations were identified by varying the polyamide (PA) and FKM used in a Brabender mixer. Four different types of polyamide and four different types of FKM were investigated, with two of the FKM types and one polyamide type identified as being promising. …

Multidimensional Mass Spectrometry Of Chemonic™ Ccg-6 Nonionic Surfactant With Separation By Polarity And Shape, Charles Johnson

Williams Honors College, Honors Research Projects

Chemonic™ CCG-6 surfactant is a water-soluble poly(ethylene glycol) (PEG) conjugated alkyl glyceride emollient. This surfactant exists as a complex mixture of a glycerol cores conjugated with poly(ethylene glycol) branches (PEGylation) that were partially esterified with caprylic (C8) and capric (C10) acids. These may be esterified on one, two, or all three arms of the glyceride. The architecture of the structures in this mixture was studied using multidimensional mass spectrometry (MS). Mass spectrometry was interfaced with ultra-performance liquid chromatography (UPLC) and ion mobility (IM) separation. The mixture was separated by reversed-phase LC, oligomers of the star-branched polymer were separated according to …

Sorption Of Benzene, Toluene And Ethylbenzene By Plasticized Poly (Ethyl Methacrylate) Using Quartz Crystal Microbalance At 298.15k, Kiranpreet Kaur

USF Tampa Graduate Theses and Dissertations

Quartz crystal microbalances (QCM) are chemical sensors used for liquid and vapor sensing. In this thesis work, plasticized poly (ethyl methacrylate) (PEMA) coated QCM was used to study sorption behavior of benzene, ethylbenzene and toluene in respective polymer at 298.15K. Poly (ethyl methacrylate) (PEMA) is a promising polymer with solubility parameter close to BTEX compounds, but it's glassy and rigid nature at room temperature make it less sensitive. The addition of plasticizers (Diisononyl cyclohexane-1,2-dicarboxylate (DINCH) and Diisooctyl azelate (DIOA)) lowers the glass transition temperature, provides flexibility and thus increases the free volume of the polymer to enhance analyte sorption. In …

Definite Indefiniteness Of "Molecular Weight" As A Claim Term For Polymer-Related Patents, Ping-Hsun Chen

The Journal of Business, Entrepreneurship & the Law

The molecular weight of a polymer is not just a number for a single molecule. In fact, molecular weight measurement is based on a large volume of molecules of the same polymer. Due to the non-uniformity of molecular weights, there are several methods to measure an “average molecular weight” of a polymer. Unfortunately, the Federal Circuit in Teva Pharms. USA, Inc. v. Sandoz, Inc., 789 F.3d 1335 (Fed. Cir. 2015), held that the term “molecular weight” in several polymer claims was indefinite, because the term could mean either peak average molecular weight, number average molecular weight, or weight average molecular …

Molecular Dynamics Simulation Of Polymer Nanocomposites In Extreme Environments, Farzin Rahmani

Electronic Theses and Dissertations

In this dissertation, lower length scale phenomena associated with the responses of hybrid materials to harsh and extreme environments were studied. The goal of this research was to reveal the underlying mechanisms of damage mitigation in these materials and the role that interface, and relevant material component interactions play in the overall material response. First, the thermal decomposition behavior of a technologically important material system, i.e., pristine graphene (PG) and graphene oxide (GO) reinforced poly(ethylene oxide) (PEO), was investigated using a reactive molecular dynamics simulation methodology. The simulations were performed in both non-isothermal (dynamic gravimetric) and isothermal modes of decomposition. …

Surface Tension, Interfacial Tension And Phase Behavior: Interactions Of Surfactant/Polymer Solutions With Crude Oil, Michael A. Steinerd, Jaeyub Chung, Bryan W. Boudouris, Nathan C. Schultheiss, Elias I. Franses

The Summer Undergraduate Research Fellowship (SURF) Symposium

Advanced oil recovery techniques, beyond primary and secondary recovery, are required in order to produce additional oil in existing reservoir rock. Here, we evaluated a combination of polymer and surfactant aqueous solutions, in order to generate a working fluid capable of achieving high-performance enhanced oil recovery (EOR). In this recovery process, surfactant is added to the water flooding mixture in order to lower the interfacial tension between the oil and the water. If the interfacial tension can be decreased by ~1,000-fold, then the aqueous solution can mobilize and displace the oil. Moreover, a polymer is added to the aqueous solution …

Effect Of High Cationic Flocculant On Anaerobic Digestion Of Municipal Wastewater., Prathap D. John

Electronic Theses and Dissertations

Anaerobic digestion (AD) of municipal sludge is a widely used stabilization process at municipal wastewater treatment plants. It is highly effective in reducing sludge volume and produces methane gas which is used as fuel in the wastewater plant. Following digestion sludge is sent to a centrifuge to separate the solids from the liquids. Louisville MSD adds flocculent to material in the centrifuge to better coagulate the solids, thereby aiding in separation of the solids from the liquids. The potential for further AD, COD reduction, and methane generation of the liquid effluent from the centrifuge was unknown, particularly in regards to …

Green Synthesis Nanocomposite Membranes, Dibakar Bhattacharyya, Vasile Smuleac, Rajender S. Varma, Subhas K. Sikdar

Chemical and Materials Engineering Faculty Patents

A nanocomposite membrane includes a macroporous polymer membrane having a plurality of pores. A plurality of metal nanoparticles are synthesized and immobilized within those plurality of pores. The nanoparticles are reduced and capped with a green reducing and capping agent such as green tea extract.

Formation Of Polymer Micro-Tubes, Daniel Peters

Williams Honors College, Honors Research Projects

Abstract

Current demand for organs is greater than the supply of donated organs, which means that a new method of obtaining replacement organs needs to be found. The objective of the research is to evaluate the use of thermo-triggered self-rolling polymer tubes that can be used for scaffolds in tissue engineering. Additionally, the research also includes a method for forming polymer tubes through the removal of a sugar fiber, coated with a thin film of polymer, by dissolving it in deionized water. For the first approach, the effect of the aqueous environment and temperature on a polymer bilayer was observed …

Evaporation-Induced Formation Of Well-Ordered Surface Patterns On Polymer Films, Wei Sun

Theses and Dissertations--Chemical and Materials Engineering

Various techniques of fabricating surface patterns of small scales have been widely studied due to the potential applications of surface patterns in a variety of areas. It is a challenge to fabricate well-ordered surface area efficiently and economically. Evaporation-induced surface patterning is a promising approach to fabricate well-ordered surface patterns over a large area at low cost. In this study, the evaporation-induced surface patterns with controllable geometrical characteristics have been constructed. The dewetting kinetics on deformable substrate is also investigated.

Using simple templates to control the geometry and the evaporation behavior of a droplet of volatile solvent, various gradient surface …

Synthesis And Characterization Of Chemically Functionalized Shape Memory Nanofoams For Unattended Sensing Applications, Anna Paola Soliani

All Dissertations

The work in this dissertation is devoted to the synthesis and characterization of novel materials for off-line unattended sensing: shape-memory grafted nanofoams. The fabrication process and characterization of highly efficient, polymeric nanosensor element with the ability to selectively detect analytes and retain memory of specific exposure events is reported. These shape memory nanofoams could potentially act as efficient and highly sensitive coatings for evanescent waveguide-based optical monitoring systems. On exposure to specific analytes, the polymeric coatings locally change their internal structure irreversibly at the nanolevel, affecting the local optical properties such as refractive index. Currently, enrichment polymer layers (EPLs) are …

A Soft Condensed Matter Approach Towards Mathematical Modelling Of Mass Transport And Swelling In Food Grains, Michael Chapwanya, N. Misra

Articles

Soft condensed matter (SCM) physics has recently gained importance for a large class of engineering materials. The treatment of food materials from a soft matter perspective, however, is only at the surface and is gaining importance for understanding the complex phenomena and structure of foods. In this work, we present a theoretical treatment of navy beans from a SCM perspective to describe the hydration kinetics. We solve the transport equations within a porous matrix and employ the Flory–Huggin’s equation for polymer–solvent mixture to balance the osmotic pressure. The swelling of the legume seed is modelled as a moving boundary with …

Optimizing Polymer Fluorescence For Explosives Detection, Rose K. Cersonsky

Honors Scholar Theses

Pyrene is commonly used for explosives detection, as when mixed with polystyrene, the fluorescence intensity of the resulting film can be used as an indicator of the presence of nitro-aromatic, nitro-ether, or nitro-amine explosives. Previous studieshave tested a three-component system including pyrene, polystyrene, and a salt, tetrabutylammonium hexafluorophosphate (TBAHP). From these previous studies, it has been seen that vapor pressure of the preparation area is a governing factor in the formation of excimers, which are instrumental in achieving and maintaining fluorescence intensity. In this study, three parameters – solution concentration, film thickness, and molecular weight of polystyrene are examined to …

High Temperature Polymer Dielectrics For Electric Vehicle Capacitor Applications, Kylen Johns

Chemical and Biological Engineering ETDs

Currently there is a push for low cost, high energy materials with high operating temperatures that can simultaneously reduce cost, weight, and volume in the automotive industry. Economically feasible high performance capacitors are critical to the Department of Energys goal to advance technologies that will ensure energy security and reduce the use of petroleum while reducing cost and environmental impacts. [1] Recent studies have been done to improve the inverter systems in hybrid electric vehicles (HEVs). HEVs require inverters to convert direct current to alternating current which prevents damage to the battery and powers the electric motor. Current thin film …

Toward Polymer Coating With Easy Ice Release, Chenyu Wang

Theses and Dissertations

Minimizing adhesion of ice has been the subject of extensive studies for applications such aircraft wings, wind turbine blades spacecraft, power transmission wires, while a growing interest concerns coatings for aerospace applications. The work described here describes progress for coatings and ice release test method development over the last few years. Major achievements include: (1) New Rigid Adherent-Resistant Elastomers (RARE), (2) A new Epoxied Cylinder (EC) adhesion test, (3) Validation of an ice release test, and (4) Study of ice adhesion strength on coating thickness for a PDMS elastomer. Rigid Adhesion-Resistance Elastomers (RARE) are comprised of 3F 1 terminated with …

Data Analysis And Summary For Surfactant-Polymer Flooding Based On Oil Field Projects And Laboratory Data, Pratap D. Chauhan

Masters Theses

"Enhanced oil recovery screening is considered as an important first step towards evaluating a potential EOR technique for a candidate reservoir. A vast amount of research is continuously been conducted in EOR. Therefore, it is imperative to update the screening criteria regularly.

This study involves updating the screening criteria for surfactant polymer flooding for field projects dataset and laboratory dataset. Many of the screening criteria for surfactant-polymer flooding in the literature were achieved on the basis of data collected from the EOR surveys published biennially in Oil & Gas Journals. However, these datasets contain problems like missing data and inconsistent …

Semantic Model And Updated Screening Criteria For Polymer Flooding, Laila Dao Saleh

Doctoral Dissertations

"Enhanced oil recovery (EOR) processes produce oil that conventional methods leave behind, where interfacial forces, heavy oil viscosity, and reservoir heterogeneity make it difficult to produce. Many EOR methods are available but usually cannot be used at the same time for a candidate reservoir. Therefore, it is important to select the most appropriate EOR process from among the possible techniques. EOR screening criteria have been created using EOR datasets and serve as the first step to compare the suitability of each technique for a specific reservoir. Most of these datasets are based on field data collected from EOR surveys published …

Optimization Of Polymer Separation By Gradient Polymer Elution Chromatography, Gideon R. Liem, Linda Nien-Hwa Wang

The Summer Undergraduate Research Fellowship (SURF) Symposium

High Performance Liquid Chromatography (HPLC) has been a versatile separation method for polymers for many years. Analysis of different polymers by HPLC is typically done by utilizing the differential solubility of the polymers by mixing a good solvent and an anti-solvent in various compositions. This method is called Gradient Polymer Elution Chromatography (GPEC). While GPEC has been used extensively, it commonly uses a linear gradient to separate components. Linear solvent gradients consume a lot of solvent and take a relatively long time (> 30 minutes) to complete. The goal of this study is to develop a step gradient from a …

Development Of Quantitative Ft- Ir Methods For Analyzing The Cure Kinetics Of Epoxy Resins, Sang Ha Son

Open Access Dissertations

Epoxy thermosets are important engineering materials with applications in coating, adhesives, packaging and as structural components in a variety of advanced engineering products. The ultimate performance of polymer critically depends upon the details of the cure chemistry used to produce the thermoset. In order to better understand and monitor the cure chemistry, quantitative analysis of the FT-IR response has been developed for describing the epoxy-amine curing reaction as well as monitoring the hydrogen bonding that occurs in these systems The FT-IR analysis includes (i) quantitative deconvolution of complex peaks into individual spectral contributions, (ii) peak identification via DFT analysis and …

In Vitro Cytotoxicity And Skin Irritation Testing Of Antimicrobial Conjugated Electrolytes : Interactions With Mammalian Cells, Kristin N. Wilde

Chemical and Biological Engineering ETDs

An estimated 19,000 deaths and $3-4 billion in health care costs per year in the U.S. are attributed to methicillin-resistant Staphylococcus aureus (MRSA) infections. Certain cationic phenylene ethynylene (CPE)-based polymers (PPEs) and oligomers (OPEs) have been demonstrated to exhibit dark and light-activated antimicrobial activity. Envisioned applications of these CPEs include the fabrication of antimicrobial surfaces to reduce or prevent the spread of potentially untreatable strains of bacteria. Until recently, it was unknown if the polymers or oligomers would exhibit similar biocidal activity toward mammalian cells. This work examines the toxicity of CPEs to mammalian cells at three levels: cytoxicity testing …

Investigation Of The Fracture Phenomena During The Milling Process Of Inorganic Particulates And Brittle Fracture Of Polymer Composites Using Fractal Theory, Zheng Qian

Dissertations

This dissertation investigates the applicability and usefulness of applying Fractal mathematics and to the fracture of brittle particulates in Fluid Energy Mill devices, and in particular quantifying the resulting power law particle size distributions, examining the Surface Fractal Dimension of milled particulates, and relating the Izod Impact Strength values of composites of polypropylene and Calcium carbonate particulates which are large un-milled, small milled, as well as small and produced by the simultaneous milling and coating with nano-silica to the Surface Fractal Dimension of the impact fracture surfaces.

First, the dissertation examines the behavior of un-coated and micron-sized wax pre-coated particulates …

Quantitative Analysis And Structural Characterization Of Carbonaceous Pitches, Sourabh Kulkarni

All Dissertations

Both petroleum pitches and pitches derived from pure polycyclic aromatic hydrocarbons (PAHs) are oligomeric materials that can serve as precursors for a wide variety of advanced carbon materials. The goal of this study was the structural characterization and quantitative analysis of the dominant constituent oligomers and species present in these pitches.
A key requirement for such work is the ability to fractionate these complex mixtures into samples of narrow molecular weight distribution (mol wt; MWD) that can be used as standards. To this end, semicontinuous (or semibatch) dense-gas/supercritical extraction (DGE/SCE) was used to produce monomer, dimer, and trimer fractions of …

Kinetics Of Preferential Adsorption And Equilibrium Properties Of Interfacial Layers Formed From Polymer Chains That Tether By Multiple Ends, Jose Alonzo Calderon

All Dissertations

Due to their ability to straddle phase boundaries, polymer brushes represent a model system for studies of polymer-modified surfaces. The research presented in this dissertation focuses on understanding a special type of polymer brushes formed at the solid-fluid interface by self-assembly of block copolymer chains that have the ability to tether by multiple ends, thus creating loops on the surface. Specifically, I study the self-assembly of a series of poly(2-vinylpyridine)-polystyrene-poly(2-vinylpyridine) (PVP-b-PS-b-PVP) triblock copolymers and PVP-b-PS star block copolymers adsorbed from the selective solvent toluene onto silicon and mica surfaces. The triblock and star copolymers have different molecular weights and PS/PVP …

Real-Time Raman Spectroscopy And Wide-Angle X-Ray Diffraction During Single-Layer And Multi-Layer Blown Film Extrusion, Giriprasath Gururajan

All Dissertations

Properties exhibited by blown films are controlled by the microstructure developed during their processing. Therefore, real-time measurement of microstructure during the blown film extrusion can help in better control and optimization of the process needed to obtain desired properties. The objectives of this research were (i) to conduct real-time microstructural measurements during single-layer and multi-layer blown film extrusion of polypropylene (PP) and low-density polyethylene (LDPE) using real-time Raman spectroscopy; (ii) to conduct real-time wide-angle X-ray diffraction (WAXD) during single-layer blown film extrusion of LDPE to obtain crystallinity and orientation values during the process; and (iii) to investigate the effect of …

Effect Of Carbon Nanofibers On Microstructure And Properties Of Polymer Nanocomposites, Sungho Lee

All Dissertations

Nano-modifiers are typically three orders of magnitude smaller in size than their micro-counterparts. At this scale, interactions between matrix molecules and the nano-modifiers can lead to novel physical and chemical properties of the resulting nanocomposites. Carbon nanofibers (CNFs) are a class of nano-modifiers that has received significant attention recently because they have superior electrical conductivity and mechanical properties with a high aspect ratio (length over diameter). Several recent research studies have focused on enhancing electrical and mechanical performance of composites in the presence of CNFs. However, the influence of CNFs on the structure of the polymer matrix is important in …

Fabrication And Characterization Of Poly(Propylene Fumarate) Scaffolds With Controlled Pore Structures Using 3-Dimensional Printing And Injection Molding, Kee-Won Lee, Shanfeng Wang, Lichun Lu, Esmaiel Jabbari, Bradford L. Currier, Michael J. Yaszemski

Faculty Publications

Poly(propylene fumarate) (PPF) is an injectable, biodegradable polymer that has been used for fabricating preformed scaffolds in tissue engineering applications because of in situ crosslinking characteristics. Aiming for understanding the effects of pore structure parameters on bone tissue ingrowth, 3-dimensional (3D) PPF scaffolds with controlled pore architecture have been produced in this study from computer-aided design (CAD) models. We have created original scaffold models with 3 pore sizes (300, 600, and 900 µm) and randomly closed 0%, 10%, 20%, or 30% of total pores from the original models in 3 planes. PPF scaffolds were fabricated by a series steps involving …

Method Of Preparing A Composite Polymer And Silica-Based Membrane, Dibakar Bhattacharyya, Stephen M. Ritchie, Leonidas G. Bachas, Jamie A. Hestekin, Subhas K. Sikdar

Chemical and Materials Engineering Faculty Patents

A method for preparing a chemically activated or polyamino acid functionalized membrane includes the steps of permeating a silica-based membrane with a solution of silane and a solvent so as to react methoxy groups of the silane with silanol groups of the membrane to incorporate epoxide groups and attaching a polyamino acid to the membrane by reacting a terminal amine group of the polyamino acid with one of the epoxide groups on the membrane.

Preparing And Regenerating A Composite Polymer And Silica-Based Membrane, Dibakar Bhattacharyya, Stephen M. Ritchie, Leonidas G. Bachas, Jamie A. Hestekin, Subhas K. Sikdar

Chemical and Materials Engineering Faculty Patents

A method for preparing and regenerating a chemically activated or polyamino acid functionalized membrane includes the steps of permeating the silica-based membrane with a solution of silane and a solvent so as to react methoxy groups of the silane with silanol groups of the membrane to incorporate epoxide groups and attaching a polyamino acid to the membrane by reacting a terminal amine group of the polyamino acid with one of the epoxide groups on the membrane. The membrane is regenerated after metal entrapment by utilizing helix-coil properties of polyamino acids.

High Efficiency Separation Of Microbial Aggregates Using Capillary Electrophoresis, J. M. Schneiderheinze, Daniel W. Armstrong, G. Schulte, David J. Westenberg

Chemistry Faculty Research & Creative Works

Recent advances in the technique of capillary electrophoresis have demonstrated fast, highly efficient separation of mixtures of intact microbes. This paper describes the application of this technique for the separation of microbial aggregates of Micrococcus luteus, Saccharomyces cerevisiae, or Alcaligenes faecalis. The aggregates of these microbes were resolved into several highly efficient peaks with analysis times under 10 min and efficiencies approaching 1 000 000 plates m-1 in some cases. A reproducible relationship was found between the electrophoretic mobility and the aggregation number or size of the cluster under a given set of experimental conditions. Often, cellular aggregation was reversible …