Chemical Engineering Commons^™

Determination Of Significant Parameters That Drive Fracture Optimization In The Glauconite Formation, Southern Chile, Ghassan Saleh Mahdi Alqatrani

Masters Theses

"The Glauconite Formation in the Magallanes Basin of Southern Chile is a clay- and silica-rich formation with low permeability. As with many of the unconventional resources, the Glauconite Formation requires a hydraulic fracturing operation to enhance the productivity of the wells in this area.

Data and pertinent information of fracturing, completion, and reservoir quality parameters along with post-fracture production data were collected to initiate a database of nearly 70 wells, to be used to develop a better understanding of the fracturing behavior, optimize the well stimulation, and overcome the major barriers in the hydraulic fracturing of the Glauconite Formation. The …

Dynamic Liquefied Natural Gas (Lng) Processing With Energy Storage Applications, Farhad Fazlollahi

Theses and Dissertations

The cryogenic carbon capture™ (CCC) process provides energy- and cost-efficient carbon capture and can be configured to provide an energy storage system using an open-loop natural gas (NG) refrigeration system, which is called energy storing cryogenic carbon capture (CCC-ES™). This investigation focuses on the transient operation and especially on the dynamic response of this energy storage system and explores its efficiency, effectiveness, design, and operation. This investigation included four tasks.The first task explores the steady-state design of four different natural gas liquefaction processes simulated by Aspen HYSYS. These processes differ from traditional LNG process in that the CCC process vaporizes …

Maximizing Orc Performance With Optimal Match Of Working Fluid With System Design, Kirtipal Barse, Michael Mann

Chemical Engineering Faculty Publications

This article compares constrained system design to non-constrained system design for the basic Organic Rankine Cycle (ORC). The 12 working fluids studied include eight dry-type, three isentropic, and one wet-type fluids. The ORC model was developed using Aspen HYSYS® and validated with data obtained from the literature. The constrained design compared the performance of working fluids for a fixed heat exchanger and turbine configuration. A non-constrained design was studied by altering the design specifications for the heat exchangers and turbine to match the working fluid. An energy and exergy analysis was performed using first and second law efficiency. The exergy …

Modeling And Optimization Of High-Performance Polymer Membrane Reactor Systems For Water–Gas Shift Reaction Applications, Andrew J. Radcliffe, Rajinder P. Singh, Kathryn A. Berchtold, Fernando V. Lima

Faculty & Staff Scholarship

In production of electricity from coal, integrated gasification combined cycle plants typically operate with conventional packed bed reactors for the water-gas shift reaction, and a Selexol process for carbon dioxide removal. Implementation of membrane reactors in place of these two process units provides advantages such as increased carbon monoxide conversion, facilitated CO2 removal/sequestration and process intensification. Proposed H2-selective membranes for these reactors are typically of palladium alloy or ceramic due to their outstanding gas separation properties; however, on an industrial scale, the cost of such materials may become exorbitant. High-performance polymeric membranes, such as polybenzimidazoles (PBIs), present themselves as low-cost …

Aspen Simulation Of Oil Shale And Biomass Process, Anand Alembath

Masters Theses

"This thesis focuses on design and analysis of two major chemical processes using computer simulation which performs a steady state computation. The objective is to design processes using Aspen simulation to establish optimum operating conditions by performing various simulation runs which are challenging to execute at lab scale.

Increasing energy needs and decline of global oil prices has shifted our focus on commercially developing unconventional and renewable resources. Commercialization of any process relies on developing a process model that identifies different process parameters by performing a steady state mass and heat balance. Aspen simulation is considered an effective process modeling …

Analysis Of The Fabrication Conditions In Organic Field-Effect Transistors, Rachel M. Rahn, Yan Zhao, Jianguo Mei

The Summer Undergraduate Research Fellowship (SURF) Symposium

Polymer-based organic field-effect transistors have raised substantial awareness because they enable low-cost, solution processing techniques, and have the potential to be implemented in flexible, disposable organic electronic devices. The performance of these devices is highly dependent on the processing conditions, as well as the intrinsic properties of the polymer. Processing conditions play an important role in semiconductor film formation and device performance. These factors may provide an important link between structure and performance. In this study, an empirical analysis tool, Process Scout, was applied to assess processing factors such as polymer concentration and silicon modification. This sanctioned the creation of …

Energy And Exergy Analysis Of Kalina Cycle For The Utilization Of Waste Heat In Brine Water For Indonesian Geothermal Field, Nasruddin Nasruddin, Agus Noor Sidiq, Abdulmajeed Mohamad, Rama Usvika

Makara Journal of Technology

The utilization of waste heat in a power plant system—which would otherwise be released back to the environment—in order to produce additional power increases the efficiency of the system itself. The purpose of this study is to present an energy and exergy analysis of Kalina Cycle System (KCS) 11, which is proposed to be utilized to generate additional electric power from the waste heat contained in geothermal brine water available in the Lahendong Geothermal power plant site in North Sulawesi, Indonesia. A modeling application on energy and exergy system is used to study the design of thermal system which uses …

Numerical And Field Data Analysis Of Drill Stem Vibration, Mohammed Fayez Al Dushaishi

Doctoral Dissertations

"Drill stem vibration is a major cause of premature failure of drill stem components and drilling inefficiency. In severe cases, drill stem vibration may lead to wellbore instability that could lead to increased operational cost. Drill stem vibrations are affected by design decisions and the drilling environment. Examples are; bottom hole assembly configurations, selection of operational parameters, and frequent changes in lithology. Vibration modeling, analysis of vibration data, and specialized vibration reduction tools are methods in use to prevent and mitigate severe vibrations.

A drill stem vibration model was created using nonlinear strain formulation which couples the axial, lateral and …

Optimized Photogrammetric Network Design With Flight Path Planner For Uav-Based Terrain Surveillance, Ivan Yair Rojas

Theses and Dissertations

This work demonstrates the use of genetic algorithms as a stochastic optimization technique for developing a camera network design and the flight path for photogrammetricapplications using Small Unmanned Aerial Vehicles. This study develops a Virtual Optimizer for Aerial Routes (VOAR) as a new photogrammetric mapping tool for acquisition of images to be used in 3D reconstruction. 3D point cloud models provide detailed information on infrastructure from places where human access may be difficult. This algorithm allows optimized flight paths to monitor infrastructure using GPS coordinates and optimized camera poses ensuring that the set of images captured is improved for 3D …

Analysis Of Advanced Supercritical Carbon Dioxide Power Cycles For Concentrated Solar Power Applications, Saeb Mostaghim Besarati

USF Tampa Graduate Theses and Dissertations

Solar power tower technology can achieve higher temperatures than the most common commercial technology using parabolic troughs. In order to take advantage of higher temperatures, new power cycles are needed for generating power at higher efficiencies. Supercritical carbon dioxide (S-CO₂) power cycle is one of the alternatives that have been proposed for the future concentrated solar power (CSP) plants due to its high efficiency. On the other hand, carbon dioxide can also be a replacement for current heat transfer fluids (HTFs), i.e. oil, molten salt, and steam. The main disadvantages of the current HTFs are maximum operating temperature …

Investigation Of Enhanced Titanium And Zinc Oxide Semiconductors For The Photodegradation Of Aqueous Organic Compounds, Innocent Udom

USF Tampa Graduate Theses and Dissertations

Growing demand and shortages of potable water sources due to industrialization have become a great concern worldwide. Various approaches and solutions have been adopted to provide cleaner and quality water. In a preliminary study, a method of treating wastewater was investigated in which algae were used to remove nutrients (nitrogen and phosphorous) from wastewater and then the algae were harvested for use as a biofuel. The results from this investigation are included in the Appendix B. Employing traditional oxidants, such as hydrogen peroxide, chlorine, and ozone, for treatment of recalcitrant organic compounds have achieved less promising results. However, photocatalysis, an …

Make Or Buy Analysis Model Based On Tolerance Design To Minimize Manufacturing Cost And Quality Loss, Cucuk Nur Rosyidi, Reza Rizkichani Akbar, Wakhid Ahmad Jauhari

Makara Journal of Technology

In a manufacturing company, manufacturing costs, or component prices, and tolerance will affect the price and the quality of a product. Companies must produce high-quality products with low manufacturing costs in order to keep their products competitive in the market; however, it is difficult to produce a high-quality product with a low manufacturing cost. Companies have difficulties in determining the components to be produced using their own manufacturing facilities (make) or outsourced to their suppliers (buy). Hence, a make or buy analysis is needed to minimize the manufacturing costs and quality loss and to determine the optimum alternative regarding make …

Optimal Trajectory Generation Using Model Predictive Control For Aerially Towed Cable Systems, Liang Sun, John Hedengren, Randal W. Beard

Faculty Publications

This paper studies trajectory generation for a mothership that tows a drogue using a flexible cable. The contributions of this paper include model validation for the towed cable system described by a lumped mass extensible cable using flight data, and optimal trajectory generation for the towed cable system with tension constraints using model predictive control. The optimization problem is formulated using a combination of the squared error and l1-norm objective functions. Different desired circular trajectories of the towed body are used to calculate optimal trajectories for the towing vehicle subject to performance limits and wind disturbances. Trajectory generation for transitions …

Energy Systems Analysis For A Solar Economy, Dharik Sanchan Mallapragada

Open Access Dissertations

The use of solar energy for human needs faces challenges owing to its relatively low energy intensity and intermittent availability, coupled with the constrained availability of renewable carbon and land resources. This study uses systems analysis tools to identify carbon and energy efficient transformations of solar energy for different purposes, including transportation fuels and grid-scale energy storage. These efforts have been complemented with a feasibility analysis of existing fossil-energy and other hybrid pathways.

In an era of limited fossil resources, liquid fuels from sustainably available (SA) biomass could meet the energy needs of the transportation sector. We present a method …

Constrained Control And Optimization Of Tubular Solid Oxide Fuel Cells For Extending Cell Lifetime, Ben Spivey, John Hedengren, Thomas F. Edgar

Faculty Publications

Extending fuel cell lifetime is a necessary objective for reducing fuel cell power generation cost of electricity. Capital costs comprise the most significant fraction of the cost of electricity. Reducing the frequency of fuel cell replacement can be achieved by implementing a control strategy that prevents excursions into operating regions causing failure. In this paper we implement a constrained MIMO model predictive controller (MPC) to avoid the failure modes relevant for a high-temperature tubular solid oxide fuel cell (SOFC) system while performing load-following. The primary causes of failure are catalyst poisoning, fuel or air starvation, carbon deposition, and microcracking. Prior …

Optimizing Fermentation Medium To Produce Cyclosporin A Using Response Surface Methodology, Rofiq Sunaryanto

Makara Journal of Technology

Response surface methodology (RSM) is a three factorial model which illustrates the relationship between one or more independent variables. RSM can be used to optimize the fermentation medium for the production of Cyclosporin A from the isolate Tolypocladium inflatum. The optimal point of the response surface area is predicted by using a seconddegree polynomial model and applying the statistic model obtained from the central composite design (CCD). The results of optimizing the fermentation medium for Cyclopsorin using the three independent variables of glucose, casein, and KH2PO4 show that all three of the independent variables affect the production of Cyclosporin A. …

A Thermodynamic Framework For The Modeling And Optimization Of Crystallization Processes, David John Widenski

LSU Doctoral Dissertations

Crystallization is a widely used chemical engineering separation unit operation process. Since this technique can produce high purity products it is used for the industrial production of many chemical compounds, such as pharmaceuticals, agrochemicals, and fine chemicals. The production of these products is a multi-million dollar industry. Any methods to improve the production of these products would be highly valued. Thus, the main objective of this work is to target model-based optimal strategies for crystallization operations specifically targeting crystal size and crystal size distribution (CSD). In particular, take the knowledge gained and translate it into an economically and practically feasible …

Natural Gas As Petroleum Fuel Substitution: Analysis Of Supply-Demand Projections, Infrastructures, Investments And End-User Prices, Abdul Qoyum Tjandranegara, Arsegianto Arsegianto, Widodo Wahyu Purwanto

Makara Journal of Technology

The petroleum fuels (PF) subsidy has long burdens the government spending, and discourages less expensive energy usage such as natural gas (NG). Exporting NG and importing the more expensive PF products cause financial losses to Indonesia. The lack of NG infrastructure is the main hurdle in maximizing domestic NG usage and so does the perception of its high investment costs burdening government spending and pushing the NG transportation cost up. This study calculates the required NG infrastructure and its investments for several levels of PF substitutions up to 2030. To balance the NG demands, the supply from each field and …

The Conversion Of Low-Grade Heat Into Power Using Supercritical Rankine Cycles, Huijuan Chen

USF Tampa Graduate Theses and Dissertations

Low-grade heat sources, here defined as below 300 ºC, are abundantly available as industrial waste heat, solar thermal, and geothermal, to name a few. However, they are under-exploited for conversion to power because of the low efficiency of conversion. The utilization of low-grade heat is advantageous for many reasons. Technologies that allow the efficient conversion of low-grade heat into mechanical or electrical power are very important to develop.

This work investigates the potential of supercritical Rankine cycles in the conversion of low-grade heat into power. The performance of supercritical Rankine cycles is studied using ChemCAD linked with customized excel macros …

Biohydrogen Production By The Hyperthermophilic Bacterium Thermotoga Neapolitana, Xiaohui Yu

All Dissertations

ABSTRACT Thermotoga neapolitana can use different sources of carbon and nitrogen for growth and produces biological hydrogen. Sources of carbon (glucose, sucrose, xylose, xylan, cellulose, cellobiose, starch, corn starch, beet bulp pellet, and rice flour) and nitrogen (yeast extract, fish meal, cottonseed meal, canola meal, linseed meal, and soybean meal) were compared. In the carbon studies, glucose, sucrose, rice flour, and xylan produced similar levels of hydrogen. In the nitrogen studies, Trypticase combined with alternative nitrogen sources can efficiently increases the yield of hydrogen produced by Thermotoga neapolitana. Yeast extract with trypticase as the dual nitrogen sources produced significantly increased …

Optimal Operating Strategy For Wells With Downhole Water Sink Completions To Control Water Production And Improve Performance, Ozan Arslan

LSU Doctoral Dissertations

Downhole water sink (DWS) technology is an alternative to conventional limited-entry completions to control water production in wells with bottom water drive. DWS wells comprise two completions: the bottom completion produces water and keeps the top completion open to oil inflow. The system performance depends on careful manipulation of the top and bottom rates to maximize oil productivity and produce oil-free water from the bottom completion. Conventional nodal analysis cannot provide a solution for DWS wells because the critical rates for water coning change with water drainage rate. A reservoir simulator is used to model two-phase flow to the dual …

Optimization Of Cell Density And Dilution Rate In Pichia Pastoris Continuous Fermentations For Production Of Recombinant Proteins, Wenhui Zhang, Chih-Ping Liu, Mehmet Inan, Michael M. Meagher

Papers in Biomolecular Engineering

This paper provides an approach for optimizing the cell density (X_c) and dilution rate (D) in a chemostat for a Pichia pastoris continuous fermentation for the extracellular production of a recombinant protein, interferon τ (INF-τ). The objective was to maximize the volumetric productivity (Q, mg INF-τ I^-1 h^-1), which was accomplished using response surface methodology (RSM) to model the response of Q as a function of X_c and D within the ranges 150 ≤ X_c ≤ 450 g cells (wet weight) l^-1 and 0.1 μm ≤ D …

The Significance And Effects Of Oil Injection On The Performance Of Sliding Vane Compressors., M Mkumbwa

Tanzania Journal of Engineering and Technology (TJET)

A computer model of a sliding vane air compressor was used to predict the behaviour of machines having different geometries operating at different conditions. The performance parameters which were calculated by the model were the free air delivery, power input and specific capacity which is defined as the free air delivery per unit of power input.The model also included the study of the effects of Oil injection on these mentioned compressor performance parameters. The paper describes the simulation model developed incorporating an analysis Of the effects of the oil injected into the compressor on lhe thermodynamic processes taking place in …

Design Approach For Small Scale Continuous, Steady State Plants, O Kaunde

Tanzania Journal of Engineering and Technology (TJET)

One of the major steps in the design of a process plant is development of an appiopriate flowsheet. At this step, the technical solutions may be con- sidered in relation to the social and economic factors. In this paper, guide- lines for developing a flowsheet for continuous, steady State process in a developing country environment have been proposed. To illustrate the pro- posed guidelines, a case study involving design of an ethanol distillation plant has been used.

Process Control Of Activated Sludge Treatment, Phase Ii, Richard I. Kermode, Robert W. J. Brett, Joseph D. Pault Jr.

KWRRI Research Reports

Material balances on substrate and microorganisms were derived in conjunction with various mixing configurations thought to accurately describe the activated sludge process. These models include the completely mixed with bypass, plug flow, and plug flow with bypass. Two sets of kinetic mechanisms for substrate utilization and bacterial growth were employed.

A feed forward controller was designed from linear approximations of the material balances derived in the completely mixed with bypass mixing model. Utilizing frequency response methods, the controller was found essentially identical to a completely mixed modeled controller developed in a prior investigation.

Through computer simulation the controller's effectiveness was …