Chemical Engineering Commons^™

Electrodeposition Of Copper-Nickel Alloys From Citrate Solutions On A Rotating Disk Electrode, Ramona Y. Ying, Patrick K. Ng, Z. Mao, Ralph E. White

Faculty Publications

A mathematical model is developed to simulate the electrodeposition of Cu-Ni alloy from citrate solutions onto a rotating disk electrode under potentiostatic control. The model includes the influence of diffusion, ionic migration, forced convection, and homogeneous equilibria. The three major electrochemical reactions treated in the model are copper deposition, nickel deposition, and hydrogen evolution. Using experimental parameters when available, the model was fitted and tested against experimentally-obtained results for different bath compositions and operating conditions. The model agreed reasonably well with the experimental results particularly in the codeposition region, –1.0 to –1.2V vs. SCE, where hydrogen evolution is not the …

Reactions Of Atomic Hydrogen With Dichloromethane In A Flow System, Shun-Hsien Huang

Theses

The reaction kinetics of atomic hydrogen with dichloromethane were studied in a tubular flow reactor with 2.6 cm I.D. Pyrex tube at pressure of 2.1 to 2.7 torr absolute and room temperature . Hydrogen atoms were generated by a microwave discharge plasma. Atomic hydrogen concentration were measured by chemiluminescence titration with nitrogen dioxide. The concentrations of hydrogen atom ranged from 2.0 * 10¹⁴ to 5.0 * 10¹⁵ atoms per cm³. Chlorocarbon reagent and products were monitored by online gas chromatography (FID).

Major products observed were hydrogen chloride and methane. The conversion of dichloromethane increases first to …

Reaction Of Hydrogen With Methylene Chloride And Carbon Tetrachloride At High Temperature, Hun Tsao

Theses

The reactions of methylene chloride and carbon tetrachloride in hydrogen in the temperature range 500 - 1000° C were studied using tubular flow reactors of three diameters. (ID: 0.40, 1.05, 1.60 cm). Residence time range was from 0.3 to 3.5 seconds. Temperature profiles of the reactors was kept within +/- 5° C of central 85% for the 18 inch long reactor, at a total pressure of 1 atmosphere. No chlorinated hydrocarbon products were observed at or above 950° C. The major products in this temperature range were CH4, C2H₂, C2H₄, C2H₆ and HCl.

The pseudo …

Thermal Decomposition Of Chlorobenzene In An Atmosphere Of Hydrogen, Edward Robert Ritter

Theses

The thermal decomposition of chlozobenzene was investigated in a tubular flow reactor at 1 atmosphere total pressure and average residence times of 0.02 - 2.5 seconds. The temperature range from 800 - 1010°C was studied in both a reductive atmosphere of hydrogen and an inert atmosphere of heIium. Complete destruction of chlorobenzene occurs at about 1000°C for an average residence time of 1 second in hydrogen gas. In the inert gas, the complete destruction of the reagent was not observed in the range of conditions which were studied. The major products observed for pyrolysis in hydrogen were benzene, HCl, and …

Reactions Of Hydrogen With Chloroform And Trichloroethylene At High Temperatures, Burhan Mahmood

Theses

The reactions of chloroform and trichloroethylene with hydrogen in the temperature range 550 to 1000°C were studied using tubular flow reactors of varying diameters. The residence time range was from 0.05 to 3.0 seconds.Two different concentrations of the chlorinated species were used, each with hydrogen in large excess. Flat temperature profiles (+/- 5°C) were achieved over 80 to 85 per cent of the 45 cm long reaction zone, with inlet gases preheated to about 400°C.

No chlorinated hydrocarbons, products or reactants were observed at /above 850°C. The major products at these temperatures were C₂H₂, C_{2 …}

Reactions Of Atomic Hydrogen With Selected Halomethane, Sriram Chari

Theses

The kinetics of the reactions of atomic hydrogen with methylene chloride and carbon tetrachloride were studied spectroscopically and chromatographically using a 4 cm i.d. discharge flow reactor at pressures of 1 to 8 mm Hg absolute and room temperature. Hydrogen atom concentrations were measured by chemiluminescence titration with nitrogen dioxide. Evidence was found for the formation of atomic carbon intermediate in the reaction with carbon tetrachloride, but methane and HCl were the chief products in both reactions for reaction times of 150 ms and higher, showing that secondary reactions were so fast that almost all halomethane consumed went toward the …