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2024

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Articles 31 - 60 of 761

Full-Text Articles in Chemical Engineering

Synthesis Of Activated Carbon From Coconut Shell And Recycled Styrofoam Nanofiber For Water Filtration, Rahma Dani, Ismet Ismet, Leni Marlina, Rona Alisya, Muhamad Abel Kirana Aldi, Anggi Ludiansyah, Lintang Auliya Kurdiati, Meutia Kamilatun Nuha Ap Idjan, Agung Mataram, Muhammad Rama Almafie, Ida Sriyanti Dec 2024

Synthesis Of Activated Carbon From Coconut Shell And Recycled Styrofoam Nanofiber For Water Filtration, Rahma Dani, Ismet Ismet, Leni Marlina, Rona Alisya, Muhamad Abel Kirana Aldi, Anggi Ludiansyah, Lintang Auliya Kurdiati, Meutia Kamilatun Nuha Ap Idjan, Agung Mataram, Muhammad Rama Almafie, Ida Sriyanti

Makara Journal of Science

Water pollution affects life sustainability; hence, several efforts have been exerted to overcome this problem. For ex-ample, nanofiber membrane technology is introduced to retain solutes while allowing only water molecules to pass through the system. Therefore, this study aimed to maximize the technology for water filtration using the electrospin-ning method by combining Styrofoam waste-based polymer with activated carbon from coconut shell waste (ACCS). The nanofiber diameter produced ranged from 590 nm to 610 nm with porous characteristics and without beads. The carbon content varied from 68.04% to 69.84%, according to the energy dispersive X-ray measurement, demonstrating the composite’s effectiveness. The …


Optimization Of Tps Films Using An Adaptive Design Of Experiments Approach In A Bayesian Optimization Framework, Theresa Marks, Gracie White, Scott Lohman, Mayank Malhotra Dec 2024

Optimization Of Tps Films Using An Adaptive Design Of Experiments Approach In A Bayesian Optimization Framework, Theresa Marks, Gracie White, Scott Lohman, Mayank Malhotra

The Journal of Purdue Undergraduate Research

Plastic pollution, amounting to 12 million tons annually, necessitates sustainable alternatives to single-use plastics. Compostable thermoplastic starch (TPS) films show promise but lack strength and durability compared to traditional plastics. This study employs an adaptive design of experiments (DoE) approach to enhance TPS films by optimizing testing points. The research focuses on varying concentrations of plasticizers (acetic acid and glycerol) in a water and potato starch mixture, aiming to identify the optimal ratio maximizing tensile strength and % elongation at break. Gaussian process regression (GPR) with uncertainty estimation and Bayesian optimization (BO) utilizing an acquisition function (AF) are employed. The …


Zeolite 13x Particles With Porous Tio2 Coating And Ag2o Nanoparticles As Multi-Functional Filler Materials For Face Masks, Wei Su, Kaiying Wang, Han Yu, Fateme Fayyazbakhsh, Jeremy Watts, Yue-Wern Huang, Jee-Ching Wang, Xinhua Liang Dec 2024

Zeolite 13x Particles With Porous Tio2 Coating And Ag2o Nanoparticles As Multi-Functional Filler Materials For Face Masks, Wei Su, Kaiying Wang, Han Yu, Fateme Fayyazbakhsh, Jeremy Watts, Yue-Wern Huang, Jee-Ching Wang, Xinhua Liang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Adsorbent components in face masks are crucial for protecting individuals exposed to dangerous situations. In this study, one porous TiO2 layer was deposited on zeolite 13X particles by coating hybrid organic/inorganic titanium alkoxide film via molecular layer deposition (MLD), followed by heat treatment to remove organic components in the MLD film. Various concentrations of Ag2O nanoparticles were impregnated on the TiO2-coated 13X particles, offering a wide range of antibacterial, antifungal, and antiviral characteristics. The obtained composite particles were characterized using X-ray photoelectron spectroscopy and thermal gravimetric analysis to study the composition and mass loading of …


Application Of Digital Rock Physics And Machine Learning To Improve The Understanding Of Fluid Flow Behavior Through Porous Media, Md Irfan Khan Dec 2024

Application Of Digital Rock Physics And Machine Learning To Improve The Understanding Of Fluid Flow Behavior Through Porous Media, Md Irfan Khan

Mechanical Engineering Theses

Accurately estimating reservoir rock properties and understanding capillary trapping mechanisms are crucial for fluid storage and flow modeling in porous media, particularly for applications such as carbon dioxide sequestration (CCS) and underground hydrogen storage (UHS). This thesis presents a comprehensive workflow that combines machine learning techniques and pore-network modeling approach to predict petrophysical properties and assess the impact of microscopic pore structures on capillary trapping. In the first part, a convolutional neural network (CNN) framework is used to predict rock properties—such as porosity, throat area, and pore surface area—from micro-computed tomography (micro-CT) X-ray images. It has been observed that incorporating …


Acoustofluidics-Based Intracellular Nanoparticle Delivery, Zhishang Li, Zhenhua Tian, Jason N. Belling, Joseph Rich, Haodong Zhu, Zhehan Ma, Hunter Bachman, Liang Shen, Yaosi Liang, Xiolin Qi, Liv K. Heidenreich, Yao Gong, Shujie Yang, Wenfen Zhang, Peiran Zhang, Yingchun Fu, Yibin Ying, Steven J. Jonas, Yanbin Li, Paul S. Weiss, Tony J. Huang Dec 2024

Acoustofluidics-Based Intracellular Nanoparticle Delivery, Zhishang Li, Zhenhua Tian, Jason N. Belling, Joseph Rich, Haodong Zhu, Zhehan Ma, Hunter Bachman, Liang Shen, Yaosi Liang, Xiolin Qi, Liv K. Heidenreich, Yao Gong, Shujie Yang, Wenfen Zhang, Peiran Zhang, Yingchun Fu, Yibin Ying, Steven J. Jonas, Yanbin Li, Paul S. Weiss, Tony J. Huang

Faculty Publications

Controlled intracellular delivery of biomolecular cargo is critical for developing targeted therapeutics and cell reprogramming. Conventional delivery approaches (e.g., endocytosis of nano-vectors, microinjection, and electroporation) usually require time-consuming uptake processes, labor-intensive operations, and/or costly specialized equipment. Here, we present an acoustofluidics-based intracellular delivery approach capable of effectively delivering various functional nanomaterials to multiple cell types (e.g., adherent and suspension cancer cells). By tuning the standing acoustic waves in a glass capillary, our approach can push cells in flow to the capillary wall and enhance membrane permeability by increasing membrane stress to deform cells via acoustic radiation forces. Moreover, by coating …


Rational Design Of Nanoparticles For Overcoming Barriers Of Nucleic Acid Delivery: Applications In Cancer Therapeutics, Angelea M. Maestas-Olguin Dec 2024

Rational Design Of Nanoparticles For Overcoming Barriers Of Nucleic Acid Delivery: Applications In Cancer Therapeutics, Angelea M. Maestas-Olguin

Chemical and Biological Engineering ETDs

The use of exogenous nucleic acid technologies to modulate aberrant protein expression resulting from genetic mutations is a promising therapeutic approach for the treatment of diseases such as cancer. The promise of nucleic-based therapeutics is dependent on the development of platforms that effectively protect nucleic acids from nuclease degradation and deliver the nucleic acids to specific intracellular locations (nucleus or cytosol) of target cells. The application of nanotechnology for development of nucleic acid-based nanomedicines is poised to revolutionize the clinical landscape of cancer. In this dissertation, I demonstrated the rational design, synthesis and evaluation of a lipid coated mesoporous silica …


Predictive Modeling And Sustainability Assessment Of Hydrothermal Liquefaction Of Seaweeds: A Techno-Economic And Life Cycle Analysis Approach, Micheal O. Asama Dec 2024

Predictive Modeling And Sustainability Assessment Of Hydrothermal Liquefaction Of Seaweeds: A Techno-Economic And Life Cycle Analysis Approach, Micheal O. Asama

Mechanical Engineering Theses

This study presents comprehensive predictive models and an economic and environmental assessment of HTL for converting macroalgae into biofuels and valuable co-products. Predictive models were developed based on experimental kinetic data to simulate batch HTL of brown seaweed, capturing the yields of biocrude, gas, biochar, and water-soluble compounds as functions of key process variables, including temperature, time, pressure, and water-to-biomass ratio. Analysis of Variance (ANOVA) confirmed that temperature and residence time significantly affect biocrude yield, with an optimal yield of 23% achieved at 283°C, 200 bar, 54 minutes, and a 10:1 water-to-biomass ratio. The model’s predictive accuracy was validated with …


Bilayer Asymmetric-Based Metal-Organic Frameworks Membrane For Blue Energy Conversion, Rockson Kwesi Tonnah, Milton Chai, Mohammad Khedri, Milad Razbin, Reza Maleki, Amir Razmjou, Mohsen Asadnia Dec 2024

Bilayer Asymmetric-Based Metal-Organic Frameworks Membrane For Blue Energy Conversion, Rockson Kwesi Tonnah, Milton Chai, Mohammad Khedri, Milad Razbin, Reza Maleki, Amir Razmjou, Mohsen Asadnia

Research outputs 2022 to 2026

The conversion of Gibbs free energy at the interface of solutions with salinity gradients into electrical energy is essentially a means of mitigating environmental pollution and bolstering the availability of new energy sources to enhance the renewable energy portfolio. However, a three-dimensional (3D) sub-nanofluidic membrane with high ion conductivity and selectivity for a reverse electrodialysis (RED) based osmotic energy conversion in both aqueous and organic solutions remains largely unexplored. Herein, we engineered a bilayer metal organic frameworks (MOFs) membrane with polystyrene sulfonated angstrom-size channels in UiO-66-NH2 base layer and isoreticular MIL-88B membrane as the top layer to enhance permselectivity and …


Development Of A Stable And Buffered Reference Electrode For Binary Molten Chlorides Salts, Carlos Mejia, Nicholas Christensen, Ricardo Rodriguez Ceron, Devin Rappleye Dec 2024

Development Of A Stable And Buffered Reference Electrode For Binary Molten Chlorides Salts, Carlos Mejia, Nicholas Christensen, Ricardo Rodriguez Ceron, Devin Rappleye

Faculty Publications

The development of stable and buffered reference electrodes (REs) is crucial for molten salt electrochemistry, particularly in pyrochemical processing, such as electrorefining. These REs must maintain a stable potential to ensure precise control over electrorefining processes by preventing unwanted shifts in the potential that could lead to impurity deposition. This study evaluated metal chlorides and metal oxides as potential candidates for REs, with their stability assessed via electrochemical methods over extended durations. While metal chloride-based REs exhibited stable potential behavior over time, their response followed the Nernst equation, leading to potential shifts with varying concentrations of oxidized species. Metal oxide-based …


Developing A New Method For Brine Purification And Reducing Salinity Using Recycled Carbon Fiber, Fatemeh Bahaeddin Dec 2024

Developing A New Method For Brine Purification And Reducing Salinity Using Recycled Carbon Fiber, Fatemeh Bahaeddin

Thesis/ Dissertation Defenses

Brine water, defined as hot and high salt content water, can be produced in large amounts from water desalination. The potential environmental impacts of brine disposal were evaluated in several studies. Minor variations in water salinity and temperature can significantly influence marine ecosystems. Elevated salinity levels disrupt the osmotic equilibrium between aquatic organisms and their surroundings, which leads to cell dehydration. Various disposal techniques have been implemented recently, including surface water discharge, sewage discharge, deep-well injection, evaporation ponds, and land application. However, these brine disposal techniques are unviable due to their high capital costs and limited applicability. In recent years, …


Deciphering Mechanochemical Influences Of Emergent Actomyosin Crosstalk Using Qcm‑D, Emily M. Kerivan, Victoria N. Amari, William B. Weeks, Leigh H. Hardin, Lyle Tobin, Omayma Y. Al Azzam, Dana N. Reinemann Dec 2024

Deciphering Mechanochemical Influences Of Emergent Actomyosin Crosstalk Using Qcm‑D, Emily M. Kerivan, Victoria N. Amari, William B. Weeks, Leigh H. Hardin, Lyle Tobin, Omayma Y. Al Azzam, Dana N. Reinemann

Faculty and Student Publications

Purpose: Cytoskeletal protein ensembles exhibit emergent mechanics where behavior in teams is not necessarily the sum of the components’ single molecule properties. In addition, filaments may act as force sensors that distribute feedback and influence motor protein behavior. To understand the design principles of such emergent mechanics, we developed an approach utilizing QCM-D to measure how actomyosin bundles respond mechanically to environmental variables that alter constituent myosin II motor behavior.

Methods: QCM-D is used for the first time to probe alterations in actin-myosin bundle viscoelasticity due to changes in skeletal myosin II concentration and motor nucleotide state. Actomyosin bundles were …


(R2090) Analysis Of Heat And Mass Transfer In Mhd Boundary Layer Flow Of Chemically Reacting Fluid, Dharati Sheth, Manisha Patel, Dilip Joshi Dec 2024

(R2090) Analysis Of Heat And Mass Transfer In Mhd Boundary Layer Flow Of Chemically Reacting Fluid, Dharati Sheth, Manisha Patel, Dilip Joshi

Applications and Applied Mathematics: An International Journal (AAM)

Analysis of the effects of heat and mass transfer on the chemically responding boundary layer flow of a Casson fluid across a porous stretched sheet in the existence of a crosswise magnetic field is the aim of the existing work. The partial differential equations that control the current flow problems can be converted into similarity equations by applying the right similarity technique. Our goal is to use the DTM-Pade approximation to analytically solve the derived similarity equations. The transformed similarity equations are a group of nonlinear ordinary differential equations for the present flow problem. The analytical approach of the differential …


Geochemical Evidence Of Drying During The 4.2 Ka Event In Sediment Cores From The Yucatán Peninsula, Mexico, Derek K. Gibson, Jonathan Obrist-Farner, Alex Correa-Metrio, Alejandra Rodriguez-Abaunza, Carlos Castañeda-Posadas Dec 2024

Geochemical Evidence Of Drying During The 4.2 Ka Event In Sediment Cores From The Yucatán Peninsula, Mexico, Derek K. Gibson, Jonathan Obrist-Farner, Alex Correa-Metrio, Alejandra Rodriguez-Abaunza, Carlos Castañeda-Posadas

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Tropical hydroclimate variability during the Middle and Late Holocene was investigated using geochemical indicators of local-scale precipitation and evaporation preserved in sediment cores from two sites in the Mexican Yucatán Peninsula. Scanning X-Ray fluorescence spectroscopy data show generally decreasing precipitation trends during the Early and Middle Holocene. During the transition between the Middle and Late Holocene, geochemical evidence of reduced watershed erosion and increased evaporation indicate that a centennial-scale drying event impacted the region between 4.3 and 4.0 ka (kilo-anum; thousand years before present). These findings suggest that the 4.2 ka drying event, which has been previously recorded in Europe, …


Co2 Capture Utilizing Novel Deep Eutectic Solvents: Modeling, Process Simulation, And Cost Analysis, Nazneen Aspi Kolah Dec 2024

Co2 Capture Utilizing Novel Deep Eutectic Solvents: Modeling, Process Simulation, And Cost Analysis, Nazneen Aspi Kolah

Masters Theses

One of the most pressing global issues that humans face is climate change caused by anthropogenic greenhouse gas emissions, especially carbon dioxide (CO2). Conventional solvents utilized for CO₂ capture, such as amines, are widely used in industrial applications due to their high CO2 absorption capacity. However, deep eutectic solvents (DES) have attracted a lot of academic attention recently due to their biodegradability and low energy for regeneration.

This research serves as a foundational proof-of-concept for using DESs in industrial gas separation processes. Five DES are evaluated for CO2 removal from flue gases. Aspen Plus is utilized to simulate the performance …


Integrating Sustainability And Food Safety Through Quantitative Microbial Risk Assessment And Life Cycle Assessment Of Low-Moisture Foods, Jessica Bain Dec 2024

Integrating Sustainability And Food Safety Through Quantitative Microbial Risk Assessment And Life Cycle Assessment Of Low-Moisture Foods, Jessica Bain

Graduate Theses and Dissertations

Food safety and sustainability are critical concerns in the food industry. However, these areas are often evaluated separately, leading to an incomplete understanding of the overall impact of food production on human health. This dissertation aims to integrate food safety with sustainability to provide a comprehensive assessment of the impact of low-moisture foods on human health, using the almond processing supply chain as a case study.

In addition to conducting life cycle assessments (LCA) of almond processing, wheat flour production, and dried apple processing, this dissertation aims to create a framework to bridge the gap between sustainability and food safety. …


Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo Dec 2024

Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper presents the results of thermal conductivity characterization of six high oleic soybean oil (HOSO) and four high oleic canola oil (HOCO)-based hybrid nanofluids formulated with four types of nanoparticles (Graphene nanoplatelet (xGnP), TiO2, MoS2, and Al2O3) at nanoparticles wt.% concentration from 1 % to 7 % in 1 % increment using the two-step method for use in MQL machining of difficult-to-cut metals. Thermal conductivity of the formulated hybrid nanofluids were measured using Thermtest Transient Hot Wire Liquid Thermal Conductivity Meter at temperatures from 25 °C to 75 °C in increment of 10 °C. Obtained results showed that thermal …


Magnetic Resonance Imaging Trackable Pathology-Triggered Polymersomes Toward Enzyme Replacement Theranostics For Gm1 Gangliosidosis, Dorian Foster Dec 2024

Magnetic Resonance Imaging Trackable Pathology-Triggered Polymersomes Toward Enzyme Replacement Theranostics For Gm1 Gangliosidosis, Dorian Foster

All Dissertations

This dissertation investigates the development and optimization of pathology-responsive polymersomes for simultaneous enhanced magnetic resonance imaging (MRI) and enzyme replacement therapy (ERT) in the treatment of GM1 gangliosidosis (GM1). While therapeutic strategies exist for similar, non-neuropathic lysosomal storage disorders, implementation towards GM1 faces significant challenges due to the blood-brain barrier.

Herein, we developed and characterized a range of low molecular weight hyaluronic acid-b-polylactic acid (HA-PLA) polymersomes (PSs) capable of encapsulating therapeutic enzymes in their hydrophilic core. These polymersomes exhibit pathophysiology-triggered responsiveness, degrading in the presence of acidic conditions, which is characteristic of lysosomes, and enzymes such as hexosaminidase A, which …


Experimental Evaluation Of A Recrosslinkable Co2-Resistant Micro-Sized Preformed Particle Gel For Co2 Sweep Efficiency Improvement In Reservoirs With Super-K Channels, Adel Alotibi, Tao Song, Ali Al Brahim, Baojun Bai, Thomas P. Schuman Dec 2024

Experimental Evaluation Of A Recrosslinkable Co2-Resistant Micro-Sized Preformed Particle Gel For Co2 Sweep Efficiency Improvement In Reservoirs With Super-K Channels, Adel Alotibi, Tao Song, Ali Al Brahim, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A recross linkable CO2-resistant branched preformed particle gel (CO2-BRPPG) was developed for controlling CO2 injection conformance, particularly in reservoirs with super-permeable channels. Previous work focused on a millimeter-sized CO2-BRPPG in open fractures, but its performance in high-permeability channels with pore throat networks remained unexplored. This study used a sand pack model to evaluate a micro-sized CO2-BRPPG under varying conditions of salinity, gel concentration, and pH. at ambient conditions, the equilibrium swelling ratio (ESR) of the gel reached 76 times its original size. This ratio decreased with increasing salinity but remained stable …


Regulating Cox Conversion Through Catalyst Design And Reaction Energy Input, Ewa Chukwu Dec 2024

Regulating Cox Conversion Through Catalyst Design And Reaction Energy Input, Ewa Chukwu

All Dissertations

Carbon dioxide (CO₂) emissions, primarily from fossil fuel use in energy and chemical production, are the leading driver of global warming. The chemical industry is the third-largest source of these emissions, so reducing its carbon footprint—and ultimately achieving “CO₂ emissions-free” chemical manufacturing—is critical to combating global warming. Thermal catalysis is the workhorse of industrial chemical manufacturing, generating CO₂ emissions from two main sources: the actual chemical transformations of fossil feedstocks and burning of fossil fuels to provide the process heat. Therefore, developing and implementing technologies to mitigate the carbon emissions associated with these emissions sources is essential for decarbonizing the …


Mechanical Properties And Microstructural Investigation Of Aa2024-T6 Reinforced With Al2o3 And Sic Metal Matrix Composites, Hassan Raza Channar, Barkat Ullah, Muhammad Shoaib Naseem, Javed Akhter, Arshad Mehmood, Muhammad Aamir Dec 2024

Mechanical Properties And Microstructural Investigation Of Aa2024-T6 Reinforced With Al2o3 And Sic Metal Matrix Composites, Hassan Raza Channar, Barkat Ullah, Muhammad Shoaib Naseem, Javed Akhter, Arshad Mehmood, Muhammad Aamir

Research outputs 2022 to 2026

Aluminium metal matrix composites (AMMCs) using alumina (Al2O3) and silicon carbide (SiC) as reinforcement elements are gaining significant interest in various applications because of their excellent properties. In this study, Al2O3/SiC with compositions (0.5 wt.%, 1.5 wt.%, and 2.5 wt.% for each) were used as reinforcement elements in an aluminium alloy (AA2024-T6). The samples prepared were AA2024-T6 + (0.5Al2O3/0.5SiC), AA2024-T6 + (1.5Al2O3/1.5SiC), and AA2024-T6 + (2.5Al2O3/2.5SiC) using a stir-casting technique. The experimental study included density calculation mechanical properties, such as tensile strength, compressive strength and hardness. The study also included a microstructure examination of the fracture surface of the tensile …


Surface Interaction Changes In Minerals For Underground Hydrogen Storage: Effects Of Co2 Cushion Gas, Hamid Esfandyari, Alireza Safari, Ali Hashemi, Aliakbar Hassanpouryouzband, Manouchehr Haghighi, Alireza Keshavarz, Abbas Zeinijahromi Dec 2024

Surface Interaction Changes In Minerals For Underground Hydrogen Storage: Effects Of Co2 Cushion Gas, Hamid Esfandyari, Alireza Safari, Ali Hashemi, Aliakbar Hassanpouryouzband, Manouchehr Haghighi, Alireza Keshavarz, Abbas Zeinijahromi

Research outputs 2022 to 2026

Hydrogen (H2) offers a promising solution for the energy transition but storing it on a large scale at the surface poses significant technical and environmental challenges. Underground formations provide a practical alternative for large-scale H2 storage, yet understanding H2 behavior under various subsurface conditions is crucial for optimizing storage capacity and efficiency, which are influenced by rock properties such as wettability. This study addresses the gap in literature regarding the wettability of different minerals when CO2 was injected with H2 as a cushion gas. We examined the wettability of various mineral rocks in realistic subsurface circumstances. A series of wettability …


Anti-Solvent Materials Enhanced Structural And Optical Properties On Ambiently Fabricated Perovskite Thin Films, Mohammad Nur-E-Alam, Mohammad Aminul Islam, Yap Boon Kar, Tiong Sieh Kiong, Halina Misran, Mayeen Uddin Khandaker, Yasser Fouad, Manzoore Elahi M. Soudagar, Erdem Cuce Dec 2024

Anti-Solvent Materials Enhanced Structural And Optical Properties On Ambiently Fabricated Perovskite Thin Films, Mohammad Nur-E-Alam, Mohammad Aminul Islam, Yap Boon Kar, Tiong Sieh Kiong, Halina Misran, Mayeen Uddin Khandaker, Yasser Fouad, Manzoore Elahi M. Soudagar, Erdem Cuce

Research outputs 2022 to 2026

Perovskite solar cells (PSCs) hold potential for low-cost, high-efficiency solar energy, but their sensitivity to moisture limits practical application. Current fabrication requires controlled environments, limiting mass production. Researchers aim to develop stable PSCs with longer lifetimes under ambient conditions. In this research work, we investigated the stability of perovskite films and solar cells fabricated and annealed in natural air using four different anti-solvents: toluene, ethyl acetate, diethyl ether, and chlorobenzene. Films (about 300 nm thick) were deposited via single-step spin-coating and subjected to ambient air-atmosphere for up to 30 days. We monitored changes in crystallinity, electrical properties, and optics over …


Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo Dec 2024

Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper presents the results of thermal conductivity characterization of six high oleic soybean oil (HOSO) and four high oleic canola oil (HOCO)-Based hybrid nanofluids formulated with four types of nanoparticles (Graphene nanoplatelet (xGnP), TiO2, MoS2, and Al2O3) at nanoparticles wt.% concentration from 1 % to 7 % in 1 % increment using the two-step method for use in MQL machining of difficult-to-cut metals. Thermal conductivity of the formulated hybrid nanofluids were measured using Thermtest Transient Hot Wire Liquid Thermal Conductivity Meter at temperatures from 25 °C to 75 °C in increment …


Monitoring Of Laser Soldering Process In Hybrid Additive Manufacturing, Alexander P. Pustinger Dec 2024

Monitoring Of Laser Soldering Process In Hybrid Additive Manufacturing, Alexander P. Pustinger

Open Access Theses & Dissertations

Additive manufacturing (AM) has been a maturing technology that has expanded over the course of the last decade in major advancements especially in accessibility, process monitoring, modeling, and stock material design. As its industry use is growing, the demand for added improvements such as multi-functionality increases, such as with a hybrid system that allows for modification of printed parts with different electrical components like the Foundry Multi-3D system. The system's purpose is to create AM parts with multifunctional electrical components with the vision to expand to other areas of interest in manufacturing such as ISAM. This work explores the use …


Microwave-Assisted Pyrolysis Of Hydrocarbons Using Iron-Based Alumina Catalysts Obtained Via Solution Combustion Synthesis, Zachary Aidan Chanoi Dec 2024

Microwave-Assisted Pyrolysis Of Hydrocarbons Using Iron-Based Alumina Catalysts Obtained Via Solution Combustion Synthesis, Zachary Aidan Chanoi

Open Access Theses & Dissertations

The demand for hydrogen is growing which makes the development of clean and efficient H2 synthesis technologies imperative. Microwave-assisted, thermocatalytic, dehydrogenation of hydrocarbons has demonstrated the ability to generate H2 with high yield/selectivity and leaving behind valuable solid carbon byproducts. However, this microwave-assisted process is unoptimized which prevents it from being utilized in industry. A critical component of optimization is the development of a catalyst that is catalytically active, a good microwave absorber, and can be regenerated for repeated dehydrogenation cycles. Previous studies that focused on plastic waste decomposition have used iron-based alumina (FeAlxOy) made via solution combustion synthesis (SCS). …


Fabrication And Performance Of Scalable Bio-Engineered Porous Layers For Efficient Co2 Capture, Mary Sharon Rose Bondugula Dec 2024

Fabrication And Performance Of Scalable Bio-Engineered Porous Layers For Efficient Co2 Capture, Mary Sharon Rose Bondugula

Theses and Dissertations

This dissertation addresses the critical challenge of mitigating climate change by advancing CO2 capture technologies. As global CO2 emissions continue to rise, effective methods for capturing and separating CO2 from industrial processes are essential to combat climate change. Existing CO2 capture systems, such as Pressure Swing Adsorption (PSA) and Temperature Swing Adsorption (TSA), often rely on packed bed designs that face limitations, including poor heat and mass transfer, slow gas diffusion, and low thermal conductivity, reducing their efficiency. To overcome these challenges, this dissertation explores innovative solutions by developing advanced adsorbent coatings and scalable bed configurations.

This research begins by …


Nickel Electrocatalysts On Carbon Supports For The Hydrogen Evolution Reaction., Mohan Paudel Dec 2024

Nickel Electrocatalysts On Carbon Supports For The Hydrogen Evolution Reaction., Mohan Paudel

Electronic Theses and Dissertations

Hydrogen is an important energy storage alternative to fossil fuels due to its high energy density. Currently, most hydrogen is produced through petroleum feedstocks, which produce large amounts of carbon dioxide. However, a more eco-friendly method is the electrocatalytic splitting of water into hydrogen and oxygen. Efficient catalysts for the hydrogen evolution reaction (HER) are typically platinum group metals, which are rare and expensive. There is growing interest in developing HER electrocatalysts with earth-abundant metals for water electrolysis. Nickel, which lies in the same group in the periodic table as Pt and has similar chemical properties, is explored extensively for …


High Energy Density Lithium-Ion Battery Materials., Rachel Dewees Dec 2024

High Energy Density Lithium-Ion Battery Materials., Rachel Dewees

Electronic Theses and Dissertations

Growth of the EV industry has created an increased demand for Li-ion battery electrode materials, and support of a robust lithium-ion battery supply chain is a national imperative. For mainstream acceptance in the American market, the range of EVs must be improved, i.e., the energy density of the battery must be increased. Increasing the specific capacity of the electrode materials is the most direct strategy for increasing the energy density of the battery. Silicon anode materials have a theoretical capacity of over 3700 mAh·g-1 - an order of magnitude beyond that of the graphitic materials which are currently implemented. …


Using Nano-Ities For Detection Of Metal Ions In Complex Aqueous Solutions, Mohammed Muzammil Nishar Ahmed Dec 2024

Using Nano-Ities For Detection Of Metal Ions In Complex Aqueous Solutions, Mohammed Muzammil Nishar Ahmed

Theses and Dissertations

Recent urbanization has induced a rapid increase in heavy metal exposure to humans. The exploitation of heavy metals for economic gains coupled with poor and economically infeasible recycling methods have led to poor management of heavy metal wastes, which has opened up several pathways for heavy metals to enter the human body. Such heavy metals target many vital organs, but the early symptoms are common and difficult to diagnose. Severe symptoms appear in later stages and are very expensive to treat and the damage caused to the health are not typically reversable in such later stages. To counter this issue, …


Adsorption Of Harmful Algal Bloom Toxins Using Biochar, Cadianne Chambers Dec 2024

Adsorption Of Harmful Algal Bloom Toxins Using Biochar, Cadianne Chambers

Theses and Dissertations

Harmful Algal Bloom (HAB) events involve the proliferation of microalgae which discharge lethal toxins into fresh and brackish water bodies due to anthropogenic and climatic activities. Common examples of HABs include causative organisms such as Cyanobacteria, Pyrodinium bahamense and more. These genera are known to release potent toxins including Microcystins, and Saxitoxins, respectively, which can seriously endanger human and marine health. Ingestion of these toxins can result in several health problems, such as nausea, vomiting, gastroenteritis, skin irritation, liver damage, paralysis, and respiratory arrest. The Great Lakes, Gulf of Maine, Florida’s coasts, Lake Erie, and Lake Okeechobee have all been …