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2022

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Articles 421 - 450 of 657

Full-Text Articles in Chemical Engineering

Kinetic And Thermodynamic Analyses For Pyrolysis Of Hemp Hurds Using Discrete Distributed Activation Energy Model, Panuphong Mankeed, Thossaporn Onsree, Salman Raza Naqvi, Sirivatch Shimpalee, Nakorn Tippayawong Mar 2022

Kinetic And Thermodynamic Analyses For Pyrolysis Of Hemp Hurds Using Discrete Distributed Activation Energy Model, Panuphong Mankeed, Thossaporn Onsree, Salman Raza Naqvi, Sirivatch Shimpalee, Nakorn Tippayawong

Faculty Publications

In many counties, hemp is becoming a high-valued economic crop. Post-processing, more than 65% w/w of its starting material becomes waste. Herein, pyrolysis of hemp hurds/residues was investigated under low (10-50 degrees C/min) and intermediate (100-150 degrees C/min) heating rates using a discrete distributed activation energy model (DAEM). Thermochemical decomposition of hemp hurds occurred in three stages: drying, active pyrolysis, and char formation, accounting for 70-80% w/w overall weight loss. With the discrete DAEM, the model can be utilized for predicting pyrolysis behaviors of hemp hurds accurately with correlation coefficient of over 0.99. Different reaction mechanisms appeared between the low …

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Electro‐Driven Materials And Processes For Lithium Recovery—A Review, Anna Siekierka, Marek Bryjak, Amir Razmjou, Wojciech Kujawski, Aleksandar N. Nikoloski, Ludovic F. Dumée Mar 2022

Electro‐Driven Materials And Processes For Lithium Recovery—A Review, Anna Siekierka, Marek Bryjak, Amir Razmjou, Wojciech Kujawski, Aleksandar N. Nikoloski, Ludovic F. Dumée

Research outputs 2022 to 2026

The mass production of lithium‐ion batteries and lithium‐rich e‐products that are required for electric vehicles, energy storage devices, and cloud‐connected electronics is driving an unprecedented demand for lithium resources. Current lithium production technologies, in which extraction and purification are typically achieved by hydrometallurgical routes, possess strong environmental impact but are also energy‐intensive and require extensive operational capabilities. The emergence of selective membrane materials and associated electro‐processes offers an avenue to reduce these energy and cost penalties and create more sustainable lithium production approaches. In this review, lithium recovery technologies are discussed considering the origin of the lithium, which can be …

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Selective Penetration Behavior Of Microgels In Superpermeable Channels And Reservoir Matrices, Yang Zhao, Baojun Bai Mar 2022

Selective Penetration Behavior Of Microgels In Superpermeable Channels And Reservoir Matrices, Yang Zhao, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Gel treatment is an effective way to attack excessive water production in many mature oilfields around the world. Selective penetration is desired for successful gel treatments. That is, gel materials should easily penetrate the target zones (i.e., channeling features such as superpermeable channels) without entering/damaging the nontarget zones (i.e., reservoir matrices or oil zones). This study revealed that presence of threshold penetration pressure (ΔPth) was responsible for selective penetration behavior of tested microgels. The concept of ΔPth was utilized to figure out favorable working conditions for effective gel treatments. Microgel dispersions were injected into superpermeable (super-k) sandpacks (mimicking super-k channels …

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Recent Advances In Structural Regulation On Non-Precious Metal Catalysts For Oxygen Reduction Reaction In Alkaline Electrolytes, Xue Wang, Li Zhang, Chang-Peng Liu, Jun-Jie Ge, Jian-Bing Zhu, Wei Xing Feb 2022

Recent Advances In Structural Regulation On Non-Precious Metal Catalysts For Oxygen Reduction Reaction In Alkaline Electrolytes, Xue Wang, Li Zhang, Chang-Peng Liu, Jun-Jie Ge, Jian-Bing Zhu, Wei Xing

Journal of Electrochemistry

Oxygen reduction reaction (ORR) in alkaline electrolytes is an important electrochemical process for metal-air batteries and anion exchange membrane fuel cells (AEMFCs). However, the sluggish kinetics spurs intensive research on searching robust electrocatalysts. Non-precious metal catalysts (NPMCs) that can circumvent the cost and scarcity issues associated with platinum (Pt)-based materials have been pursued and the challenges lie in the performance improvement to rival Pt-based benchmarks. As the composition and structure of the NPMCs have a significant impact on the catalytic performance, precise regulation on the catalyst structure holds great promise to bridge the activity gap between NPMCs and Pt-based benchmarks. …

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Recent Advances In Electrochemical Kinetics Simulations And Their Applications In Pt-Based Fuel Cells, Ji-Li Li, Ye-Fei Li, Zhi-Pan Liu Feb 2022

Recent Advances In Electrochemical Kinetics Simulations And Their Applications In Pt-Based Fuel Cells, Ji-Li Li, Ye-Fei Li, Zhi-Pan Liu

Journal of Electrochemistry

Theoretical simulations of electrocatalysis are vital for understanding the mechanism of the electrochemical process at the atomic level. It can help to reveal the in-situ structures of electrode surfaces and establish the microscopic mechanism of electrocatalysis, thereby solving the problems such as electrode oxidation and corrosion. However, there are still many problems in the theoretical electrochemical simulations, including the solvation effects, the electric double layer, and the structural transformation of electrodes. Here we review recent advances of theoretical methods in electrochemical modeling, in particular, the double reference approach, the periodic continuum solvation model based on the modified Poisson-Boltzmann …

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Facet Dependent Oxygen Evolution Activity Of Spinel Cobalt Oxides, Li-Hua Zhang, Hong-Yuan Chuai, Hai Liu, Qun Fan, Si-Yu Kuang, Sheng Zhang, Xin-Bin Ma Feb 2022

Facet Dependent Oxygen Evolution Activity Of Spinel Cobalt Oxides, Li-Hua Zhang, Hong-Yuan Chuai, Hai Liu, Qun Fan, Si-Yu Kuang, Sheng Zhang, Xin-Bin Ma

Journal of Electrochemistry

Water splitting is a promising technology to produce clean hydrogen if powered by renewable energies, where oxygen evolution is the rate determining step at an anode. Here we adjust the different crystal planes of the cobalt oxides catalyst to expose more effective active sites through a hydrothermal process, so as to improve the reaction activity for oxygen evolution. The samples were well characterized by TEM, SEM and XRD. Among the three synthetic crystal planes (100), (111) and (110) of spinel cobalt oxides, the (100) crystal plane has the highest intrinsic activity. Combining in-situ infrared and DFT calculations, we …

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Selective Co2 Reduction To Formate On Heterostructured Sn/Sno2 Nanoparticles Promoted By Carbon Layer Networks, Xue Teng, Yanli Niu, Shuaiqi Gong, Xuan Liu, Zuofeng Chen Feb 2022

Selective Co2 Reduction To Formate On Heterostructured Sn/Sno2 Nanoparticles Promoted By Carbon Layer Networks, Xue Teng, Yanli Niu, Shuaiqi Gong, Xuan Liu, Zuofeng Chen

Journal of Electrochemistry

Tin (Sn)-based materials have emerged as promising electrocatalysts for selective reduction of CO2 to formate, but their overall performances are still limited by electrode structures which govern the accessibility to active sites, the electron transfer kinetics, and the catalytic stability. In this study, the heterostructured Sn/SnO2 nanoparticles dispersed by N-doped carbon layer networks (Sn/SnO2@NC) were synthesized by a melt-recrystallization method taking the low melting point of Sn (m.p. 232oC). The N-doped carbon layer networks derived from polydopamine could attract more electrons on the electrocatalyst, serve as conductive agents and protect the ultrafine nanoparticles from …

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Mass Loading Optimization For Ethylene Glycol Oxidation At Different Potential Regions, Sheng-Nan Sun, Zhi-Chuan Xu Feb 2022

Mass Loading Optimization For Ethylene Glycol Oxidation At Different Potential Regions, Sheng-Nan Sun, Zhi-Chuan Xu

Journal of Electrochemistry

Designing and fabricating the electrocatalysts is attracting more and more attention in recent years due to a global interest in developing techniques for electrochemical energy conversion and storage, as well as elelectro-synthesis of valuable chemicals. The activity is one of the key performance parameters for electrocatalysts, while the observed activity can be affected by mass loading of electrocatalysts. Here, we take cobalt oxide (Co3O4)/graphite paper electrode (Co3O4/GPE) as a model electrode to demon-strate how the mass loading of Co3O4 catalyst influences ethylene glycol (EG) oxidation in alkaline (KOH) by …

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Structural Degradation Of Ni-Rich Layered Oxide Cathode For Li-Ion Batteries, Jia-Yi Wang, Sheng-Nan Guo, Xin Wang, Lin Gu, Dong Su Feb 2022

Structural Degradation Of Ni-Rich Layered Oxide Cathode For Li-Ion Batteries, Jia-Yi Wang, Sheng-Nan Guo, Xin Wang, Lin Gu, Dong Su

Journal of Electrochemistry

Nickel(Ni)-rich layered oxide has been regarded as one of the most important cathode materials for the lithium-ion batteries because of its low cost and high energy density. However, the concerns in safety and durability of this compound are still challenging for its further development. On this account, the in-depth understanding in the structural factors determining its capacity attenuation is essential. In this review, we summarize the recent advances on the degradation mechanisms of Ni-rich layered oxide cathode. Progresses in the structure evolution of Ni-rich oxide are carefully combed in terms of inner evolution, surface evolution, and the property under thermal …

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Decellularized Articular Cartilage Microgels As Microcarriers For Expansion Of Mesenchymal Stem Cells, Esmaiel Jabbari, Azadeh Sepahvandi Feb 2022

Decellularized Articular Cartilage Microgels As Microcarriers For Expansion Of Mesenchymal Stem Cells, Esmaiel Jabbari, Azadeh Sepahvandi

Faculty Publications

Conventional microcarriers used for expansion of human mesenchymal stem cells (hMSCs) require detachment and separation of the cells from the carrier prior to use in clinical applications for regeneration of articular cartilage, and the carrier can cause undesirable phenotypic changes in the expanded cells. This work describes a novel approach to expand hMSCs on biomimetic carriers based on adult or fetal decellularized bovine articular cartilage that supports tissue regeneration without the need to detach the expanded cells from the carrier. In this approach, the fetal or adult bovine articular cartilage was minced, decellularized, freeze-dried, ground, and sieved to produce articular …

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Ph-Responsive Nanocarriers In Cancer Therapy, Nour M. Alsawaftah, Nahid S. Awad, William G. Pitt, Ghaleb A. Husseini Feb 2022

Ph-Responsive Nanocarriers In Cancer Therapy, Nour M. Alsawaftah, Nahid S. Awad, William G. Pitt, Ghaleb A. Husseini

Faculty Publications

A number of promising nano-sized particles (nanoparticles) have been developed to conquer the limitations of conventional chemotherapy. One of the most promising methods is stimuli-responsive nanoparticles because they enable the safe delivery of the drugs while controlling their release at the tumor sites. Different intrinsic and extrinsic stimuli can be used to trigger drug release such as temperature, redox, ultrasound, magnetic field, and pH. The intracellular pH of solid tumors is maintained below the extracellular pH. Thus, pH-sensitive nanoparticles are highly efficient in delivering drugs to tumors compared to conventional nanoparticles. This review provides a survey of the different strategies …

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Thermosensitive Polymers And Thermo-Responsive Liposomal Drug Delivery Systems, Waad H. Abuwatfa, Nahid S. Awad, William G. Pitt, Ghaleb A. Husseini Feb 2022

Thermosensitive Polymers And Thermo-Responsive Liposomal Drug Delivery Systems, Waad H. Abuwatfa, Nahid S. Awad, William G. Pitt, Ghaleb A. Husseini

Faculty Publications

Temperature excursions within a biological milieu can be effectively used to induce drug release from thermosensitive drug-encapsulating nanoparticles. Oncological hyperthermia is of particular interest, as it is proven to synergistically act to arrest tumor growth when combined with optimally-designed smart drug delivery systems (DDSs). Thermoresponsive DDSs aid in making the drugs more bioavailable, enhance the therapeutic index and pharmacokinetic trends, and provide the spatial placement and temporal delivery of the drug into localized anatomical sites. This paper reviews the fundamentals of thermosensitive polymers, with a particular focus on thermoresponsive liposomal-based drug delivery systems.

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Torrefaction Of Oil Palm Empty Fruit Bunch Biomass, Mohamad Azri Sukiran Feb 2022

Torrefaction Of Oil Palm Empty Fruit Bunch Biomass, Mohamad Azri Sukiran

Student Works (2020-2029)

Empty fruit bunches (EFB) have great potential to be used as a renewable fuel. Its current low rate of utilization due largely to high moisture content and low calorific value (CV) can be overcome via a thermal pretreatment namely torrefaction. This study investigated the effects of torrefaction temperature, residence time, particle size and moisture content on EFB’s final products distribution and their characteristics in a fixed bed reactor. The solid products (torrefied EFB) obtained were analyzed by various methods such as proximate and ultimate analyses, CV, scanning electron microscopy (SEM), Fourier transform infrared (FTIR), x-ray diffraction (XRD) and thermogravimetric analysis …

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Wettability Alteration Process At Pore-Scale During Engineered Waterflooding Using Computational Fluid Dynamics, Yongqiang Chen, Ping Chang, Guang Xu, Quan Xie Feb 2022

Wettability Alteration Process At Pore-Scale During Engineered Waterflooding Using Computational Fluid Dynamics, Yongqiang Chen, Ping Chang, Guang Xu, Quan Xie

Mining Engineering Faculty Research & Creative Works

Engineered waterflooding modifies chemistry of injected brine to efficiently and environmentally friendly enhance oil recovery. The common practice of engineered waterflooding includes low salinity waterflooding (LSW) and carbonated waterflooding. Among these oil recovery methods, wettability alteration has been perceived as a critical physicochemical process for additional oil recovery. While extensive work has been conducted to characterize the wettability alteration, the existing theory cannot explain the conflict oil recovery between secondary mode (injecting engineered water at the very beginning of flooding) and tertiary mode (injecting engineered water after conventional waterflooding), where secondary engineered waterflooding always gives a greater incremental oil recovery …

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Descriptive Statistical Analysis Of Experimental Data For Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao, Mingzhen Wei, Baojun Bai Feb 2022

Descriptive Statistical Analysis Of Experimental Data For Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactants have been the widely used agents to alter the wettability of carbonate rocks to more water-wet and enhanced oil recovery (EOR). As one of major EOR methods, an effective surfactant huff-puff application design requires comprehensive guidelines about where, how, and when this method could be applied. In order to construct such guidelines, a dataset including 338 effective surfactant imbibition tests is established by collecting information from nearly 50 publications. Based on this dataset, descriptive statistical analysis methods are used to conduct data analysis, including three main parts. The first part establishes the application guidelines for surfactant huff-puff treatments which …

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Strategy For Conjugating Oligopeptides To Mesoporous Silica Nanoparticles Using Diazirine-Based Heterobifunctional Linkers, Md Arif Khan, Ramy W. Ghanim, Maelyn R. Kiser, Mahsa Moradipour, Dennis T. Rogers, John M. Littleton, Luke H. Bradley, Bert C. Lynn, Stephen E. Rankin, Barbara L. Knutson Feb 2022

Strategy For Conjugating Oligopeptides To Mesoporous Silica Nanoparticles Using Diazirine-Based Heterobifunctional Linkers, Md Arif Khan, Ramy W. Ghanim, Maelyn R. Kiser, Mahsa Moradipour, Dennis T. Rogers, John M. Littleton, Luke H. Bradley, Bert C. Lynn, Stephen E. Rankin, Barbara L. Knutson

Chemical and Materials Engineering Faculty Publications

Successful strategies for the attachment of oligopeptides to mesoporous silica with pores large enough to load biomolecules should utilize the high surface area of pores to provide an accessible, protective environment. A two-step oligopeptide functionalization strategy is examined here using diazirine-based heterobifunctional linkers. Mesoporous silica nanoparticles (MSNPs) with average pore diameter of ~8 nm and surface area of ~730 m2/g were synthesized and amine-functionalized. Tetrapeptides Gly-Gly-Gly-Gly (GGGG) and Arg-Ser-Ser-Val (RSSV), and a peptide comprised of four copies of RSSV (4RSSV), were covalently attached via their N-terminus to the amine groups on the particle surface by a heterobifunctional linker, …

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A Detailed Hydrodynamic Study Of The Split-Plate Airlift Reactor By Using Non-Invasive Gamma-Ray Techniques, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Shadha K. Jebur, Muthanna H. Al-Dahhan Feb 2022

A Detailed Hydrodynamic Study Of The Split-Plate Airlift Reactor By Using Non-Invasive Gamma-Ray Techniques, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Shadha K. Jebur, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study focused on detailed investigations of selected local hydrodynamics in split airlift reactor by using an unconventional measurements facility: computed tomography (CT) and radioactive particle tracking (RPT). The local distribution in a cross-sectional manner with its radial's profiles for gas holdup, liquid velocity flow field, shear stresses, and turbulent kinetic energy were studied under various gas velocity 1, 2 and 3 cm/s with various six axial level z = 12, 20, 40, 60, 90 and 112 cm. The distribution in gas-liquid phases in the whole split reactor column, the riser and downcomer sides, including their behavior at the top …

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Advancing The Development Of Additively Manufactured Sequentially Cured Interpenetrating Polymer Networks, Rachael J. Ross Feb 2022

Advancing The Development Of Additively Manufactured Sequentially Cured Interpenetrating Polymer Networks, Rachael J. Ross

Theses and Dissertations

Recently vat photopolymerization (VPP), a type of additive manufacturing (AM), has the potential to be used for a variety of commercial and military applications due to the ability to make custom parts rapidly and with complex geometries. Many commercially available photopolymerizable resins consist of (meth)acrylate and epoxy functionality to ensure rapid cure time and minimal shrinkage. Today, researchers continue to find the optimal balance of (meth)acrylate/epoxy functionality in unique formulations and network configurations, such as interpenetrating polymer networks (IPN)s, to enhance processibility and the quality of the final printed part. This work explores the structure-property relationships of a set of …

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Impurity Incorporation In Solution Crystallization: Diagnosis, Prevention, And Control, Gerard Capellades, Jacob O. Bonsu, Allan S. Myerson Feb 2022

Impurity Incorporation In Solution Crystallization: Diagnosis, Prevention, And Control, Gerard Capellades, Jacob O. Bonsu, Allan S. Myerson

Henry M. Rowan College of Engineering Departmental Research

Despite their widespread use for purification, our current methods for the development of solution crystallization processes lack a sufficient understanding on how impurities incorporate in growing crystals. This is, in part, due to the large number of mechanisms often encountered for impurity incorporation, and due to limitations in our methods for diagnosis of those mechanisms. These limitations propagate into largely empirical process development strategies, which are still based on trial and error and centered on solvent selection. This manuscript highlights recent developments in the diagnosis, prevention, and control of impurity incorporation during batch and continuous crystallization. The goal is to …

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Geant4 Simulation For Radioactive Particle Tracking (Rpt) Technique, Ahmed A. Alghamdi, Thaar M. Aljuwaya, Abdullah S. Alomari, Muthanna H. Al-Dahhan Feb 2022

Geant4 Simulation For Radioactive Particle Tracking (Rpt) Technique, Ahmed A. Alghamdi, Thaar M. Aljuwaya, Abdullah S. Alomari, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In the past two decades, the radioactive particle tracking (RPT) measurement technique has been proven to visualize flow fields of most multiphase flow systems of industrial interest. The accuracy of RPT, and hence the data obtained, depend largely on the calibration process, which stands here as a basis for two subsequent processes: tracking and reconstruction. However, limitations in the RPT calibration process can be found in different experimental constrains and in assumptions made in the classical Monte Carlo approach used to simulate number of counts received by the detectors. Therefore, in this work, we applied a GEANT4-based Monte Carlo code …

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Understanding The Photodegradation Mechanism Of Gaseous Acetaldehyde Over Bi2wo6 – Modified Znwo4 Photocatalyst Under Uv Light Irradiation, Mirabbos Hojamberdiev, Ronald Vargas, Shahlo Daminova, Zuhra Kadirova Feb 2022

Understanding The Photodegradation Mechanism Of Gaseous Acetaldehyde Over Bi2wo6 – Modified Znwo4 Photocatalyst Under Uv Light Irradiation, Mirabbos Hojamberdiev, Ronald Vargas, Shahlo Daminova, Zuhra Kadirova

CHEMISTRY AND CHEMICAL ENGINEERING

Indoor air quality has a significant impact on human health as people spend more time indoors. As a common indoor air pollutant, acetaldehyde is considered toxic when exposed to it for a prolonged period. The aim of this study is the enhancement of the photocatalytic activity of ZnWO4 with a monoclinic wolframite structure for degradation of gaseous acetaldehyde by modifying its surface with Bi2WO6 layered structure. The mechanisms behind the enhanced photocatalytic activity and the pathways for acetaldehyde photodegradation over the Bi2WO6-modified ZnWO4 photocatalyst are discussed.

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Modelling Of Reаctive Distillаtion Process For Etherificаtion Reаction, Adham Norkobilov, Olimjon Mаksudov, Abdulaziz Bаkhtiyorov, Orifjon Zаripov, Abbos Elmаnov Feb 2022

Modelling Of Reаctive Distillаtion Process For Etherificаtion Reаction, Adham Norkobilov, Olimjon Mаksudov, Abdulaziz Bаkhtiyorov, Orifjon Zаripov, Abbos Elmаnov

CHEMISTRY AND CHEMICAL ENGINEERING

А reаctive distillаtion system is exаmined to produce for the production of Ethyl tert butyl ether (ETBE) viа etherificаtion of isobutene with ethаnol. Optimizаtion methods using heаt integrаtion аre аlso conducted. The molаr reflux rаtio аnd reboiler duty аre cаlculаted using sensitivity аnаlysis. The bottom streаm with the sаtisfied purity of ETBE is integrаted for heаting the feed streаm to the column. Heаt integrаtion from reаctor heаt to the initiаl feed streаm аnd from bottom streаm of the column to the column inlet streаm with the purpose of аchieving tаrget feed temperаture leаds to high conversion in the reаctive distillаtion …

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Laboratory Evaluation Of Placement Behavior Of Microgels For Conformance Control In Reservoirs Containing Superpermeable Channels, Yang Zhao, Baojun Bai Feb 2022

Laboratory Evaluation Of Placement Behavior Of Microgels For Conformance Control In Reservoirs Containing Superpermeable Channels, Yang Zhao, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Gel treatment has been proven an effective method to attack excessive water production in many mature oilfields. However, not all of the application projects have successful stories. The effectiveness of a gel treatment largely depends on the transport and placement behavior of gel materials in reservoirs to be treated. In this work, we carried out systematic studies to investigate the transport, placement, water-blocking ability, fluid diversion and sweep improvement, and matrix damage effect of micrometer-sized preformed particle gels (microgels) in reservoirs containing superpermeable (super-K) channels. The impact of the channel/matrix permeability contrast and the particle/pore size ratio in the channels …

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Synergistic Enhancement Of Formic Acid Electro-Oxidation On Ptxcuy Co-Electrodeposited Binary Catalysts, Yaser M. Asal, Ahmad M. Mohammad, Sayed S. Abd El Rehim, Islam M. Al-Akraa Feb 2022

Synergistic Enhancement Of Formic Acid Electro-Oxidation On Ptxcuy Co-Electrodeposited Binary Catalysts, Yaser M. Asal, Ahmad M. Mohammad, Sayed S. Abd El Rehim, Islam M. Al-Akraa

Chemical Engineering

A propitious binary catalyst composed of Pt and Cu which were electrodeposited simultaneously onto a glassy carbon (GC) substrate was recommended for the formic acid (FA) electro-oxidation reaction (FAOR); the principal anodic reaction in the direct FA fuel cells (DFAFCs). The simultaneous co-electrodeposition of Pt and Cu in the catalyst provided an opportunity to tune the geometric functionality of the catalyst to resist the adsorption of poisoning CO at the Pt surface that represented the major impediment for DFAFCs marketing. The catalytic activity of the catalyst toward FAOR was significantly influenced by the (Pt4+/Cu2+) molar ratio of the electrolyte during …

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Mass Advection–Diffusion In Creeping Flow Through An Orifice Plate: A Model For Nanoporous Atomically Thin Membranes, Harpreet Atwal, Anika Wong, Michael Boutilier Feb 2022

Mass Advection–Diffusion In Creeping Flow Through An Orifice Plate: A Model For Nanoporous Atomically Thin Membranes, Harpreet Atwal, Anika Wong, Michael Boutilier

Chemical and Biochemical Engineering Publications

Continuum transport equations are commonly applied to nanopores in atomically thin membranes for simple modeling. Although these equations do not apply for nanopores approaching the fluid or solute molecule size, they can be reasonably accurate for larger nanopores. Relatively large graphene nanopores have applications in small particle filtration and appear as unwanted defects in large-area membranes. Solute transport rates through these nanopores determine the rejection performance of the membrane. Atomically thin membranes commonly operate in a regime where advection and diffusion both contribute appreciably to transport. Solute mass transfer rates through larger nanopores have previously been modeled by adding continuum …

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Synthesis And Evaluation Of A Novel Polyacrylamide Functionalized Nano-Silica As A Calcium Carbonate Inhibitor In Upstream Applications, Nadhem Ismail, Ali Alshami, Ibnelwaleed A. Hussein Feb 2022

Synthesis And Evaluation Of A Novel Polyacrylamide Functionalized Nano-Silica As A Calcium Carbonate Inhibitor In Upstream Applications, Nadhem Ismail, Ali Alshami, Ibnelwaleed A. Hussein

Chemical Engineering Faculty Publications

Calcium carbonate scale forms in production and injection wells, precipitating upon pressure and temperature changes, incompatible water mixing, and dehydration. Production shutdown is one of the most dramatic consequences caused by calcium carbonate scale formation. We synthesized, characterized, and tested a polyacrylamide functionalized nano-silica (PAM-SiO2NPs) inhibitor that prevents calcium carbonate formation at high temperatures and high brine. Positive compatibility results were confirmed before the inhibition efficiency test, whereby the efficiency was calculated by quantifying the calcium ions left in solution using ICP-OES. The inhibitor was effective at temperatures of 40, 60, and 80 °C, with pH values of …

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Small-Pore Zeolite Membranes: A Review Of Gas Separation Applications And Membrane Preparation, Zishu Cao, Ninad Anjikar, Shaowei Yang Feb 2022

Small-Pore Zeolite Membranes: A Review Of Gas Separation Applications And Membrane Preparation, Zishu Cao, Ninad Anjikar, Shaowei Yang

Chemical & Biomedical Engineering Faculty Publications

There have been significant advancements in small-pore zeolite membranes in recent years. With pore size closely related to many energy- or environment-related gas molecules, small-pore zeolite membranes have demonstrated great potential for the separation of some interested gas pairs, such as CO2/CH4, CO2/N-2 and N-2/CH4. Small-pore zeolite membranes share some characteristics but also have distinctive differences depending on their framework, structure and zeolite chemistry. Through this mini review, the separation performance of different types of zeolite membranes with respect to interested gas pairs will be compared. We aim to give readers an idea of membrane separation status. A few representative …

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A Detailed Hydrodynamic Study Of The Split-Plate Airlift Reactor By Using Non-Invasive Gamma-Ray Techniques, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Shadha K. Jebur, Muthanna H. Al-Dahhan Feb 2022

A Detailed Hydrodynamic Study Of The Split-Plate Airlift Reactor By Using Non-Invasive Gamma-Ray Techniques, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Shadha K. Jebur, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study focused on detailed investigations of selected local hydrodynamics in split airlift reactor by using an unconventional measurements facility: computed tomography (CT) and radioactive particle tracking (RPT). The local distribution in a cross-sectional manner with its radial's profiles for gas holdup, liquid velocity flow field, shear stresses, and turbulent kinetic energy were studied under various gas velocity 1, 2 and 3 cm/s with various six axial level z = 12, 20, 40, 60, 90 and 112 cm. The distribution in gas–liquid phases in the whole split reactor column, the riser and downcomer sides, including their behavior at the top …

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Tracking The Heavy Metal Contaminants Entrained With The Flow Into A Trickle Bed Hydrotreating Reactor Packed With Different Catalyst Shapes Using Newly Developed Noninvasive Dynamic Radioactive Particle Tracking, Binbin Qi, Omar Farid, Alexandre França Velo, Jihane Mendil, Sebastián Uribe, Yasunobu Kaneko, Kei Sakakura, Yasuhito Kagota, Muthanna H. Al-Dahhan Feb 2022

Tracking The Heavy Metal Contaminants Entrained With The Flow Into A Trickle Bed Hydrotreating Reactor Packed With Different Catalyst Shapes Using Newly Developed Noninvasive Dynamic Radioactive Particle Tracking, Binbin Qi, Omar Farid, Alexandre França Velo, Jihane Mendil, Sebastián Uribe, Yasunobu Kaneko, Kei Sakakura, Yasuhito Kagota, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

A newly developed modified Dynamic Radioactive Particle Tracking system (DRPT) was used to investigate the heavy metal contaminants deposition locations in different catalyst beds, sphere, cylinder, trilobe, and quadrilobed in Trickle Bed Reactors. In the present paper, Kernel Density Estimator (KDE) was used to estimate the probability density distributions of heavy metal contaminants depositions in terms of bed radius height. The result shows that the four cases have similar probability density distribution in terms of radius, while the spherical catalyst has the larger distribution range in terms of bed height. The heavy metal deposition is directly related to the pressure …

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Geant4 Simulation For Radioactive Particle Tracking (Rpt) Technique, Ahmed A. Alghamdi, Thaar M. Aljuwaya, Abdullah S. Alomari, Muthanna H. Al-Dahhan Feb 2022

Geant4 Simulation For Radioactive Particle Tracking (Rpt) Technique, Ahmed A. Alghamdi, Thaar M. Aljuwaya, Abdullah S. Alomari, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In the past two decades, the radioactive particle tracking (RPT) measurement technique has been proven to visualize flow fields of most multiphase flow systems of industrial interest. The accuracy of RPT, and hence the data obtained, depend largely on the calibration process, which stands here as a basis for two subsequent processes: tracking and reconstruction. However, limitations in the RPT calibration process can be found in different experimental constrains and in assumptions made in the classical Monte Carlo approach used to simulate number of counts received by the detectors. Therefore, in this work, we applied a GEANT4-based Monte Carlo code …

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