Chemical Engineering Commons^™

Principles Of Eliminating The Impact Of Disturbances On Integrated Information And Analytical Systems, Orifjon Olimovich Zaripov, Umidjon Sharabidinovich Hamrakulov, Fatima Faxritdinovna Isxakova

Chemical Technology, Control and Management

Today, production management using integrated information and analytical systems and their integration with the elements of Industry 4.0 is considered one of the most pressing problems in all areas of production. The correct formation of the structure of information systems in their development contributes to the formation of elements of Industry 4.0 and their further full and high-quality integration into other areas. When implementing these processes, one of the most important steps is to reduce the impact of disturbances on integrated information and analytical systems. Taking into account the above, the article considers mathematical models of the principles of eliminating …

Bimetallic Catalyst For Lignin Depolymerization, Qishen Lyu

McKelvey School of Engineering Graduate Student Theses & Dissertations

This thesis is motivated by concerns regarding the need to develop more sustainable and economic technologies to meet rising global manufacturing and energy demands. These concerns have renewed governmental, industrial, and societal determination to reduce the world’s dependence on conventional natural resources and has led to considerable research on producing fuels and chemicals from feedstocks other than petroleum. Lignocellulosic biomass represents an abundant and renewable resource that could displace petroleum feedstock producing biofuels and multiple valuable chemical products with reduced greenhouse gas emissions. Lignin is the second abundant biopolymer source in nature and is found almost everywhere. Since the 1950’s, …

Resolving Anodic Current And Temperature Distributions In A Polymer Electrolyte Membrane Water Electrolysis Cell Using A Pseudo-Two-Phase Computational Fluid Dynamics Model, J. Lopata, Z. Kang, J. Young, G. Bender, J. W. Weidner, H-S. Cho, Sirivatch Shimpalee

Faculty Publications

Expanding upon our prior experimental work, we constructed a three-dimensional model of a polymer electrolyte membrane water electrolyzer using computational fluid dynamics. We applied the assumption of pseudo-two-phase flow, the flow of two phases with equal velocity. Experimental data were used to obtain parameters and to determine the conditions under which this model was valid. Anodic distributions of current density, temperature, liquid saturation, and relative humidity were obtained at various flow rates. The overall current density and temperature difference from inlet to outlet at the anode agreed strongly with experimental measurements under most circumstances. This verification allowed us to further …

Pyrolysis Kinetics Of Wildland Vegetation Using Model-Fitting Methods, Ellie Amini, Mohammad-Saeed Safdari, Nathan Johnson Brigham, David R. Weise, Thomas H. Fletcher

Faculty Publications

Slow-heating pyrolysis experiments of 14 plant species native to forests in the southern United States were conducted in a TGA to find the kinetic parameters for slow pyrolysis of all live and air-dried plant samples. Kinetic coefficients were determined from the data using model-fitting methods, resulting in single kinetic parameters for the entire pyrolysis process which can be used by wildland fire modelers. The model forms explored here are a simple one-step model and single and multiple reaction distributed activation energy (DAE) models. The mass loss and derivative mass loss data were fitted simultaneously at heating rates of 10, 20, …

A Process To Produce Battery Grade Silicon From Natural Halloysite Clay, Nathan Clarke

Utah Space Grant Consortium

We demonstrate the production of silicon from a clay mineral, halloysite, as a low-cost silicon source for high-energy anodes in aviation batteries. The halloysite-derived silicon demonstrated 1800 mAh/g capacity after formation cycles, comparable to other developing silicon materials.

Feedback Control Of Particle Positions Using Electric Fields And Chemical Gradients, Mark Mcdonald

Utah Space Grant Consortium

Programmable self-assembly is a promising route to new biomaterial and metamaterial synthesis methods. An important step towards programmable self-assembly is moving component parts to desired locations. We do this by designing and simulating a controller that modifies an external field to move particles on desired paths. We first design a controller using electric fields by modifying established methods, then we apply the insights gained from the electric field controller to a chemical controller that uses model predictive control.

Systematic Design, Optimization, And Sustainability Assessment For Generation Of Efficient Wastewater Treatment Networks, Kirti Maheshkumar Yenkie, Emmanuel A Aboagye, Sean M. Burnham, James Dailey, Rohan Zia, Carley Tran, Maya Desai

Henry M. Rowan College of Engineering Departmental Research

Due to population growth and economic development, there has been an increase in global wastewater (WW) generation footprint. There are different technologies associated with the wastewater treatment (WWT) process. The challenge is to select technologies that minimize the cost of treatment, as well as meet purity requirements. Further, there is a need to integrate sustainability analysis to facilitate a holistic decision. With the application of systems engineering, sustainable and cost-effective solutions can be achieved. In this work, we apply systems engineering to generate a sustainable and cost-effective solution. A superstructure was generated by categorizing technologies into four treatment stages. After …

Exploration Of The Sludge Biodiesel Pathway, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Wastewater sludge is an overlooked source of fat, oil, and grease (FOG) that could be converted into biodiesel. The United States produces about 8 million tons of sludge per year. The disposal cost for this amount of sludge is about 2 billion US dollars. The widespread availability and low cost of sludge compared to other biodiesel raw materials make it an economical choice for a renewable fuel. Using sludge as a raw material can produce 25 to 30 mg per gram of fatty acid methyl ester (FAME); the main component of biodiesel. Sludge biodiesel has the potential of transforming a …

2020-21 Aiche Student Design Competition: Naphtha Processing, Brenna Kathleen Flynn, Hannah Orebaugh, Paul Deaton

Honors Capstone Projects and Theses

No abstract provided.

Valorization Of Secondary Agriculture Residues, Narendra Kumar

Master's Theses

Secondary agriculture residues have the potential to be major contributors as resources for energy and sustainably sourced materials production. Separating secondary agricultural residues, which have already been transported to processing centers, into individual biomass components could convert these wastes into bioproducts. Many types of pretreatments to achieve this separation involve chemicals that are hazardous for the environment. Several deep eutectic solvents (DES) that are biocompatible have been investigated for their ability to deconstruct rice hulls and sugarcane bagasse. Mass yield, enzymatic hydrolysis of the pretreated biomass, fiber analysis, and Fourier transform infrared spectroscopy have confirmed that the DES formic acid:choline …

Economic Feasibility Of Mixed Plastic Waste Pyrolysis Using Twin Reactor System In Northwest Arkansas, Carol Rogers, Patricia Means, Renato Gonzalez, Kaida Sheets, Hayden Townsend

Chemical Engineering Undergraduate Honors Theses

Plastic waste generation is increasing at an unsustainable rate while recycling solutions remain stagnant. As a chemical means of recycling, mixed plastic waste pyrolysis can generate synthetic oil appropriate for use as fuel in power generation from plastic waste that otherwise accumulates in landfills. With the scaling of a commercial plastic pyrolysis process in Northwest Arkansas (NWA) modeled after an operational sawdust pyrolysis unit in Huntsville, Arkansas, economic analysis resulted in 26.3% internal rate of return. Therefore, construction of a commercial mixed plastic-to-fuel pyrolysis plant is economically justified and should be pursued. To effectively implement the proposed design, NWA must …

Valorization Of Secondary Agriculture Residues, Narendra Kumar

Doctoral Dissertations

Secondary agriculture residues have the potential to be major contributors as resources for energy and sustainably sourced materials production. Separating secondary agricultural residues, which have already been transported to processing centers, into individual biomass components could convert these wastes into bioproducts. Many types of pretreatments to achieve this separation involve chemicals that are hazardous for the environment. Several deep eutectic solvents (DES) that are biocompatible have been investigated for their ability to deconstruct rice hulls and sugarcane bagasse. Mass yield, enzymatic hydrolysis of the pretreated biomass, fiber analysis, and Fourier transform infrared spectroscopy have confirmed that the DES formic acid:choline …

Ceramic Tiles Production From Cullet And Agricultural Wastes Obtained From Wheat And Sugarcane Cultivation, Mai H. Roushdy

Chemical Engineering

Agricultural wastes are a big source for environmental pollution so it’s a good choice to recycle them so as to get an environmental and economic benefit. The purpose of this research is to determine the possibility of recycling two types of agriculture wastes obtained from wheat and sugarcane cultivation in addition to broken glass (cullet) as raw materials for ceramic wall tiles production. The used agriculture wastes are the agricultural residue obtained from wheat and sugarcane cultivation. The experimental work starts with performing XRF and sieve analysis for all raw materials. Ceramic wall tiles specimens were made with dimensions 110.4 …

Remote Performance Modulation Of Ultrafiltration Membranes By Magnetically And Thermally Responsive Polymer Chains, Arijit Sengupta, Anh Vu, Xianghong Qian, Sumith R. Wickramasinghe

Chemical Engineering Faculty Publications and Presentations

Ultrafiltration membranes, that respond to an external magnetic field and local temperature have been developed. Surface-initiated activator-generated electron transfer (AGET) atom transfer radical polymerization (ATRP) has been used to graft poly(N-isopropylacrylamide) (PNIPAm) from the surface of 300 kDa regenerated cellulose membranes. The polymerization initiator was selectively attached to the entire membrane surface, only the outer membrane surface or only the inner pore surface. A superparamagnetic nanoparticle was attached to the end of the polymer chain. The DI water flux as well as the flux and rejection of bovine serum albumin were investigated in the absence and presence of a 20 …

Household Income And Air Pollution At Public Schools In The United States, Katyland Facas, Kristina Wagstrom

Honors Scholar Theses

Poor air quality at schools may negatively impact students’ academic performance.1 2 3 In this study we look at the relationship between ambient, outdoor air quality and student socioeconomic status at United States public schools. We used free and reduced lunch eligibility, as part of the USDA’s National School Lunch Program, as an indicator of household income. We focus on nitrogen dioxide (NO2), ozone (O3), and particulate matter smaller than 2.5 microns (PM2.5). We used ambient pollutant concentration estimates at census block group resolution (Kim et al.) as the outdoor air pollution concentration at each school.4 We found a positive …

Biopolymeric Materials For Tissue Regeneration, Cell Manufacturing, And Drug Delivery, David Alfonso Castilla-Casadiego

Graduate Theses and Dissertations

The development of materials for tissue regeneration, cell manufacturing, and drug delivery is possible by the manipulation of polymer properties and the use of three different techniques including layer-by-layer, electrospinning, and molding technique.

By applying the layer-by-layer technique over biomaterials, it is possible to develop polymeric multilayers that promote a more favorable environment for cellular functionality, increasing the possibility of improving their acceptance in the area of implantation. IRVASE demonstrated being a powerful technique that allows for a reliable characterization of the physical-chemical and thermal properties of the fabricated surfaces. This opens the possibility to monitor the design of surfaces …

Process Design And Optimization Of A Once-Through Dimethyl Ether Process Using Aveva Process Simulation, Jerrod Scott

Honors Theses

The primary purpose of the project on which I wrote this thesis was to design an optimize a once-through dimethyl ether process utilizing a software called AVEVA Process Simulation. The process was initially modeled and optimized to minimize the EAOC of the distillation column. The result of that effort was an optimized column with six stages with the feed entering the column at stage six. It had a height of 3 m, diameter of 0.44 m, and an EAOC of $65,100. This optimized solution was submitted to a Toller. The Toller provided available equipment to model the plant. From here, …

Economic Feasibility Of A Methanol To Dimethyl Ether Production Process To Avoid Contract Failure Shortfalls From The Covid-19 Pandemic, Jacob Noll, Robert Wasson, Harrison Mckinnis

Honors Theses

Our team entered the 2021 AVEVA Academic Competition, where teams of undergraduate senior chemical engineering students competed across the country. The competition was composed of two parts: the base case design and the optimization of a chemical process. As part of the competition, our team is acting as the Engineering team for a fictional company that has given us this project. Due to COVID-19, our methanol producing company has lost a contract with a customer, leaving 23,000 tonnes/yr of unclaimed methanol. We have two choices with this methanol: either sell the methanol on the market at the spot price for …

Design Of An Undergraduate Laboratory Experiment Utilizing A Stirred-Tank, Jacketed Bioreactor, Brennen Middleton

Honors Theses

Bioreactors are utilized in many industries, such as the food, alternative fuel, and pharmaceutical industries, to design and manufacture products. Unlike the similar chemical batch reactors utilized in many chemical processing facilities, bioreactor utilization requires engineers to consider a wider range of operating conditions and parameters. This results in a more complex reaction system and controls network. Due to this, it is imperative for chemical and biomedical engineering students to not only understand the theory surrounding these reactor systems, but also understand how to properly design and perform operating procedures with these systems. Thus, it was determined to create an …

Ethylbenzene Production Case Study And Optimization, Brandon Borek

Honors Theses

The objective of this project was to investigate the process of producing ethylbenzene from the liquid-phase reaction of ethylene and benzene and perform parametric and topological optimizations to increase the net present value of the production facility. To do so, the base case conditions of the process were modeled and quantified economically followed by an investigation into the existing process to determine conditions that could be altered to improve the economic viability of the project. After optimizing the parametric conditions and topology of the process, the net present value of the project was increased by 305 million dollars to 191 …

Dynamics In Drops As Confined Systems Containing Nanoparticles: Reformation Of Nanoparticles And Evaporation Of Water, Vijitha Mohan, Xianjie Qiu, Partho Neogi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Brine is used to displace crude oil in a reservoir and its performance improves when brine contains nanoparticles. It is the presence of nanoparticles in confinements, such as at dynamic contact lines and in thin films, which is of importance. The investigators here have determined a fast way to obtain confined systems by evaporating a small drop of water containing nanoparticles. Water droplets containing nanoparticles of alumina or silica were evaporated on surfaces of polyethylene terephthalate sheets, which are partially wet by water, and glass which is fully wet. After the liquid in the drops evaporated, the residues were examined …

Comparison Of Tensile Properties Of Triaxial Braided Carbon Fiber Composites Made From Vacuum Assisted Resin Transfer Molding (Vartm) And Autoclave Molding, Donald A. Klosterman, Charles Browning

Chemical and Materials Engineering Faculty Publications

Triaxially braided fiber composites are increasingly being used in aerospace, ballistic, and sporting good applications due to their inherent damage tolerance, torsional stability, and cost compared to woven fabrics and unidirectional preforms. There have been numerous publications over the past 15-20 years on the mechanical properties and failure mechanisms of triaxial braided composites. However, most of these have involved panels made with autoclave curing. In the present study, braided carbon fiber composites were made using autoclave curing and vacuum assisted resin transfer molding (VARTM). The goal of the study was to compare the physical and tensile properties of quasi-isotropic panels …

Mapping Three Dimensional Interactions Between Biomolecules And Electric Fields., Joseph Patrick Brian P.E.

Electronic Theses and Dissertations

Electroporation is a technique that induces the formation of open pores in cell membranes by the application of an electric field. Electroporation is widely practiced in research and clinical work for transfection of genetic sequences and drug molecule transport through the membrane barrier. However, a full theoretical explanation of the molecular mechanisms and thermodynamics responsible for pore formation, structure, and longevity does not yet exist. Advances in molecular dynamics simulations have enabled theoretical studies of electroporation with previously unobtainable fidelity spanning biologically relevant timescales. All-atom simulations utilizing the recently developed method of computational electrophysiology demonstrate that pore size correlates to …

Detecting The Leakage In The Pipeline System Through Flow Parameter Analysis, Hao Fu

Theses and Dissertations

The pipeline is an efficient way to transport oil and gas over long distances. However, leakage can occur when the pipes have been running for a long time. The leak of energy resources will cause economic loss in millions of dollars, pollute the local environment, and result in safety problems. Therefore, the technology of pipeline leak detection is very crucial during the energy transport process.

The goals of the research are to develop mathematical models based on experimental data and CFD simulation to detect single and multiple leaks in a pipeline and/or pipeline system. The new methods use daily recorded …

Settling Of Spherical Particles In High Viscosity Friction Reducer Fracture Fluids, Ghith Biheri, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Investigating the key factors that impact fluid rheology and proppant static settling velocity in high viscosity friction reducers (HVFRs) is a critical aspect for successful proppant transport in hydraulic fracture treatment. In this study, the rheological properties of HVFRs were tested at various temperature ranges (i.e., 25, 50, 75, and 100◦C) and different HVFR concentrations (i.e., 1, 2, 4, and 8 gpt). Three sizes of spherical particle diameters (i.e., 2, 4, and 6 mm) were selected to measure the static settling velocity. The fracture fluid was tested in two fracture models: an unconfined glass model and a confined rectangular model …

Aveva Competition 2021: Dimethyl Ether Production Process, Nicholas Gaouette

Honors Theses

The following study was conducted to assess the economic and process feasibility of a dimethyl ether (DME) production process. A portion of the methanol produced by an existing facility would be used to produce DME through a dehydration reaction. DME production is being considered as a means to compensate for lost methanol revenue, as methanol prices have recently decreased and an excess supply is present on the open market.

The first milestone in the study was the construction of a working process model within AVEVA Process Simulation. This steady-state process model would provide information essential to further design and optimization …

Design And Analysis Of A Process To Convert Methanol Into Dimethyl Ether, Elisa M. White

Honors Theses

A recent economic downturn led to the loss of a contract for a company that sells methanol. The company has two options to recover some of the profit lost from the contract termination. One option is to sell the excess methanol at the spot market price, and the second option is to implement a process to convert the excess methanol into dimethyl ether. This project investigated the implementation of a process to convert the methanol from the lost contract into dimethyl ether. The process was simulated in AVEVA Process Simulation to estimate the size of equipment needed. A toller provided …

Machine Learning Representations For Optimization Of Process Systems, Logan Watts

Chemical Engineering Undergraduate Honors Theses

The optimal operation of chemical processes provides the foundation for optimization problems to determine the most effective way to operate or design a given process. Chemical processes can be represented as nonlinear systems of equations with decision variables, resulting in a problem that can be solved through nonlinear solvers. The downfalls of nonlinear solvers create the need for improved methods of finding globally optimal solutions to the design or operation of a chemical process. The project will seek to evaluate the use of artificial neural networks to approximate nonlinear systems of equations for the purpose of optimizing chemical processes. The …

Peptoid-Functionalized Gold Nanoparticles For Zika Virus Envelope Protein Detection, Meagan Olsen

Chemical Engineering Undergraduate Honors Theses

Detection and identification of viral pathogens is essential in providing effective and rapid medical treatment. Well-established detection methods can be expensive, slow, and sometimes unable to provide the needed sensitivity and specificity. The Zika virus is one clinically relevant pathogen that cannot be easily identified due to cross-reactivity with other viruses from the same family. Electrochemical sensors enhanced with peptoid-functionalized gold nanoparticles (AuNPs) are an alternative to traditional techniques that offers rapid, accurate, label-free pathogen detection for point-of-care diagnostics. To this end, a peptoid capable of binding to the Zika virus envelope protein was developed and its binding affinity for …

Promotion Of Human Schwann Cell Proliferation Using Heparin/Collagen Coated Nerve Conduits, John Magness

Chemical Engineering Undergraduate Honors Theses

Often in the aftermath of an injury or surgery, the sense of touch and muscle control is lost in the affected area as nerves are damaged or severed and fail to grow back completely. The regeneration of the nerve cells can be promoted by treating the nerves with nerve conduits. Nerve conduits are hollow cylinders of bio-compatible materials that can be surgically implanted to the disconnected nerve to promote and direct the growth of nerves. The objectives of this research are to investigate the ability of nerve conduits treated with layer-by-layer coatings to promote the growth of Schwann cells, to …