Chemical Engineering Commons^™

Architecture And Trilogy Of (Law, Theory And Hypothesis), Ahmed Hashim Hameed

Al-Esraa University College Journal for Engineering Sciences

The general cognitive expositions had focused on the study of the general knowledge frameworks of the field of architecture, with both concepts that influencing and influenced by them, which used to contain them without referring to their intellectual origins in order to understand their general effect and their role in the cognitive enrichment to the architectural field. This, in return, showed the importance of direction to study the role, influence and effect of trilogy (Law, theory and hypothesis) in the field of architecture, according to their general reality knowledge and their specific theoretical and intellectual characteristics. This research deals with …

The Impact Of Spatial Location Of Functions To Identify Architectural Forms As A Landmark (Case Study - Contemporary Islamic Architecture -), Ibtisam Abdulelah Mohammed Al Khafaji, Maha Haki Ismaeil

Al-Esraa University College Journal for Engineering Sciences

This research discusses the impact of spatial location of functions inside architectural form to enhance visual legibility and how it can improve the possibilities of identifying them as a landmark. The absence of a clear conceptual frame which can be used to describe this impact forms the basic research problem. The objective aim of the research is to clarify and describe this impact. To achieve this objective aim, an analytical process was used. We supposed that spatial location of functions enhances visual legibility of forms, then improves our possibility of identifying them as a landmark. For applying the conceptual frame, …

Effect Of Loading Level Of Hybrid Reinforced Concrete Deep Beams Under Repeated Loading, Sawsan Akram Hassan, Ghsoon Ali Faroun

Al-Esraa University College Journal for Engineering Sciences

This research is devoted to investigating the experimental and theoretical behavior of hybrid deep beams under monotonic and repeated two-point loading. The dimensions and the flexural reinforcement of the deep beams were kept constant. In this work, the idea of a hybrid beam is completely different. Two types of concrete were used but not in the cross-section. The first type, which is fiberous concrete (FC), was used in casting beam sides (shear spans), while the second type was conventional concrete (CC) which was used in the middle portion of the beam (between two shear spans). This was done to strengthen …

Reverse Osmosis Method For Sulphate Re-Moval From Treated Wastewater Of Al-Doura Refinery, Rana Mohammed Rasheed

Al-Esraa University College Journal for Engineering Sciences

The treated wastewater by the industrial Wastewater Treatment Plant (WWTP) commonly named (INGECO) in Al-Doura refinery suffers from highly sulfate concentrations that exceed the EPA specified limits of 250 mg/L. Therefore, laboratory water quality historical data have been reviewed and analyzed to determine the annual rate, maximum, and peak sulfate concentrations that were found to be 360 mg/L, 425 mg/L, and 550 mg/L, respectively. Through field inspection aimed at specifying the reasons for the high sulfate concentrations in the wastewater of most refinery process units, it was found that the maximum required sulfate remaining concentration should not exceed 10 mg/L …

Comparison Between Regular And Irregular Configuration In Earthquake Resistant Design, Ali Nur-Aldeen Azeez, Ali Mohsen Jaafer Al-Khafaji

Al-Esraa University College Journal for Engineering Sciences

Earthquake-resistant design is one of the greatest challenges that must be considered by the Architect because it is a serious natural disaster that affects the stability and durability of the building. Due to the connection between the seismic behavior of buildings with its formal configuration and the differences in seismic resistance between regular and irregular buildings, the research problem presented as the confusion of seismic behavior of irregular buildings and their difference from the regular buildings when earthquakes occur. The aim of the research is to clarify the differences between regular and irregular configurations, also clarifying the design considerations in …

Pedestrian Movement Within Residential Areas, Abd Alali Hamza Mohamed

Al-Esraa University College Journal for Engineering Sciences

The network of transport within residential areas, especially within residential neighborhoods, consists mainly of roads designed to provide relative safety for road users and to prioritize solutions that enhance safety. It is believed that the pedestrian movement network should be separated from the car movement network, with a focus on road design, pedestrian paths, and the types of vehicles used in these areas to ensure safety. This research explores the solutions developed in the planning of roads and walkways in traditional housing schemes within the urban fabric of old cities. It examines the approaches and conclusions of modern models of …

Low-Grade Kaolin Clay Natural Resource For Use As A Supplementary Cementitious Material In Structural Concrete Elements, Brandon X. Lorentz

USF Tampa Graduate Theses and Dissertations

At the turn of the century, low-grade kaolin clay (LGK) was presented as a widely available and potential natural resource of supplementary cementitious materials (SCM) for producing high performance concretes. In using LGK as an SCM, clinker production is reduced, aiding environmental concerns with associated CO2 emissions. These types of clays have very heterogeneous mineralogy and microstructural characteristics, causing unique influences on concrete structural and flow performance, although these influences are not well understood. This research studies LGK natural to the state of Florida and assesses their potential use as high performance SCM.

Ten kaolin clays were obtained through a …

Analysis Of Identification Method For Bacterial Species And Antibiotic Resistance Genes Using Optical Data From Dna Oligomers, Ryan L. Wood, Tanner Jensen, Cindi Wadsworth, Mark Clement, Prashant Nagpal, William G. Pitt

Faculty Publications

Bacterial antibiotic resistance is becoming a significant health threat, and rapid identification of antibiotic-resistant bacteria is essential to save lives and reduce the spread of antibiotic resistance. This paper analyzes the ability of machine learning algorithms (MLAs) to process data from a novel spectroscopic diagnostic device to identify antibiotic-resistant genes and bacterial species by comparison to available bacterial DNA sequences. Simulation results show that the algorithms attain from 92% accuracy (for genes) up to 99% accuracy (for species). This novel approach identifies genes and species by optically reading the percentage of A, C, G, T bases in 1000s of short …

Analysis Of Identification Method For Bacterial Species And Antibiotic Resistance Genes Using Optical Data From Dna Oligomers, Ryan L. Wood, Tanner Jensen, Cindi Wadsworth, Mark Clement, Prashant Nagpal, William G. Pitt

Faculty Publications

Bacterial antibiotic resistance is becoming a significant health threat, and rapid identification of antibiotic-resistant bacteria is essential to save lives and reduce the spread of antibiotic resistance. This paper analyzes the ability of machine learning algorithms (MLAs) to process data from a novel spectroscopic diagnostic device to identify antibiotic-resistant genes and bacterial species by comparison to available bacterial DNA sequences. Simulation results show that the algorithms attain from 92% accuracy (for genes) up to 99% accuracy (for species). This novel approach identifies genes and species by optically reading the percentage of A, C, G, T bases in 1000s of short …

Synthesis And Characterization Of Chitosan Based Catalyst For Catalysis Applications, Hany A. Elazab, Yousab G. Remiz, M. A. Radwan, M. A. Radwan, M. A. Sadek

Chemical Engineering

In this research, chitosan based catalyst synthesis and characterization was investigated for different application in catalysis as chitosan based catalyst was combined with metal oxides in order to be used in dye removal of methyl orange (MO). Diluted acetic acid was used to dissolve chitosan then different percentages for metallic ions were mixed with diluted chitosan and then, 500 μL were added to the sample to reduce the metal salts then, microwave was used to heat the mixture for 5 minutes and then dried at 80-100 °C. Finally, X- ray diffraction was used to confirm the catalyst prepared. The aim …

Responsive Economic Model Predictive Control For Next-Generation Manufacturing, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

There is an increasing push to make automated systems capable of carrying out tasks which humans perform, such as driving, speech recognition, and anomaly detection. Automated systems, therefore, are increasingly required to respond to unexpected conditions. Two types of unexpected conditions of relevance in the chemical process industries are anomalous conditions and the responses of operators and engineers to controller behavior. Enhancing responsiveness of an advanced control design known as economic model predictive control (EMPC) (which uses predictions of future process behavior to determine an economically optimal manner in which to operate a process) to unexpected conditions of these types …

Evaluation Of Capacitive Deionization Desalination Technology For Irrigation, Ziad Khalifa, Moustafa Elshafei Prof, Abdalrahman Amer, Eng, Ashraf Seleym Dr, Tamer Samir Eng

Chemical Engineering

Desalination of brackish groundwater has great potential to alleviate the problem of the limited water resources in Egypt. In this paper, we studied the desalination of brackish water for irrigation purposes using capacitive deionization (CDI) technology. We investigated a modular unit for use in greenhouses (GH). A GH for the production of tomato requires about 3.2 m3/d of water. The target CDI unit has a production capacity of 32 m3/d for irrigation of 10 greenhouses from brackish water. The paper provides an extensive simulation study to illustrate the influence of various design parameters and to unveil the CDI technology pros …

Preparation, Characterization And Biological Activity Of Novel Schiff Base Complexes Based On La, Er And Yb Metal Ions, Hoda Ahmed, Walaa H. Mahmoud, Islam M. Al-Akraa Dr, Gehad G. Mohamed

Chemical Engineering

The tridentate [HL, (4-[(2-(2-quinolinoimino)-3, 5-dibromobenzyl) amino] cyclohexanol)]Schiff base ligand was prepared from the condensation reaction of 2-quinoline carbaldehyde with the drug ambroxol. The prepared HL ligand was further used in the preparation of some new complexes via the reaction with La(III), Er(III) and Yb(III) metal ions. The geometry of the prepared complexes was proposed from elemental analysis, FT-IR, 1H NMR, thermal and magnetic susceptibility. 1H NMR showed that the three nitrogen atoms of the ligand were responsible for the complex formation. The thermal analysis technique provided a clear prospect about the decomposition steps of the Schiff base ligand and its …

Synthesis And Characterization Of Chitosan Based Catalyst For Catalysis Applications, Hany A. Elazab, Yousab G. Remiz, Mostafa A. Radwan, M. A. Sadek

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research, chitosan-based catalyst synthesis and characterization was investigated for different application in catalysis as chitosan-based catalyst was combined with metal oxides in order to be used in dye removal of methyl orange (MO). Diluted acetic acid was used to dissolve chitosan then different percentages for metallic ions were mixed with diluted chitosan and then, 500 µL were added to the sample to reduce the metal salts then, microwave was used to heat the mixture for 5 minutes and then dried at 80-100 °C. Finally, X- ray diffraction was used to confirm the catalyst prepared. The aim of this …

Development Of Novel Adsorbent For Industrial Wastewater Treatment, Hassaan M. Shehata, Dalia A. Ali, Islam M. Al-Akraa, Hoda A. Elsawy, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

The main objective of this research project is to perform some experimental procedures to inform the ability of the novel adsorbent used in this project. The chemical modification of the adsorbent is the chemical oxidation of pure powder chitosan using some specific redox pairs which are potassium dichromate and sodium bisulphite. After preparing the modified chitosan, there are some parameters that must be discussed during the adsorption process. The first parameter is the time parameter, showing experimentally the optimum time for adsorption under certain conditions by collecting values of absorbance and concentration of thymol blue adsorbed after the process from …

Mathematica As An Efficient Tool To Optimize The Kinetic Study Of Ethyl Acetate Hydrolysis, M. H. El Dewaik, Mamdouh Gadalla, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Mathematica is a powerful program for computing both numeric and algebraic calculations as well as graphing two- and three-dimensional curves and surfaces. It is used increasingly in many fields of science now such as physics, engineering, chemistry and even biology because of the fast interaction of mathematics with almost the fields of science nowadays. We report here, optimizing the kinetic data for the hydrolysis of ethyl acetate through caustic soda via using Mathematica.

Effect Of Tio2 Doping On Degradation Rate, Microstructure And Strength Of Borate Bioactive Glass Scaffolds, Romina Shafaghi, Omar Rodriguez, Sunjeev Phull, Emil H. Schemitsch, Paul Zalzal, Stephen D. Waldman, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

A titanium-containing borate glass series based on the system (52-X) B₂O₃–12CaO–6P₂O₅–14Na₂O–16ZnO-XTiO₂ with X varying from 0, 5 and 15 mol% of TiO2 incorporated, identified as BRT0, BRT1 and BRT3, respectively, were used in this study. Scaffolds (pore sizes, 165–230 μm and porosity, 53.51–69.51%) were prepared using a polymer foam replication technique. BRT3 scaffolds exhibited higher compressive strength (7.16 ± 0.22 MPa) when compared to BRT0 (6.02 ± 0.47 MPa) and BRT1 (5.65 ± 0.28 MPa) scaffolds with lower, or no, TiO₂ content. The solubility of the scaffolds decreased …

Impact Of Team Formation Approach On Teamwork Effectiveness And Performance In An Upper-Level Undergraduate Chemical Engineering Laboratory Course, Erick S. Vasquez, Matthew J. Dewitt, Zachary J. West, Michael J. Elsass

Chemical and Materials Engineering Faculty Publications

This study focuses on the impact of team formation approach on teamwork effectiveness and performance spanning three years of instruction of the chemical engineering unit operations laboratory, which is an upper-level undergraduate laboratory course. Team formation approaches changed each year, and assessment tools, including peer-assessment, academic performance, and course evaluations, were employed to evaluate team performance. Approaches included three cases: instructor-selected teams based on GPA with the objective of a similar cumulative average GPA for each team, student self-selected teams, and a combination of self-selected teams with instructor-selected teams for a final experiment. For the third case, new teams were …

Full-Set Measurements Dataset For A Water-Based Drilling Fluid Utilizing Biodegradable Environmentally Friendly Drilling Fluid Additives Generated From Waste, Abo Taleb Al-Hameedi, Husam Hasan Alkinani, Shari Dunn-Norman, Mohammed M. Alkhamis, Justin D. Feliz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The oil and gas industry is moving towards more environmentally friendly practices. The environmental regulations regarding drilling waste management and disposal are motivating the industry to be more efficient with drilling operations. Environmentally friendly drilling fluid additives used in drilling operations reduces not only the negative implications on the environment but also reduces costs. This paper provides an experimental dataset of utilizing biodegradable waste materials as environmentally friendly drilling fluid additives. The data were collected through experimental evaluations of several waste materials including Potato Peels Powder (PPP), Mandarin Peels Powder (MPP), Fibrous Food Waste Material (FFWM), Palm Tree Leaves Powder …

Experimental Investigation Of Bio-Enhancer Drilling Fluid Additive: Can Palm Tree Leaves Be Utilized As A Supportive Eco-Friendly Additive In Water-Based Drilling Fluid System?, Abo Taleb T. Al-Hameedi, Husam H. Alkinani, Shari Dunn-Norman, Mustafa A. Al-Alwani, Waleed H. Al-Bazzaz, Abdullah F. Alshammari, Hussien W. Albazzaz, Rusul A. Mutar

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Serious problems will be presented due to using conventional chemical additives to regulate the drilling mud properties, as they have health, safety, and environmental side effects. Thus, there is a considerable necessity for alternative multifunctional bio-enhancer drilling mud additives, which can assist in optimizing the drilling fluid specifications and enhance its effectiveness with the least effects on the environment and the drilling personnel safety. The effects of adding two concentrations of palm tree leaves powder (PTLP) to water-based mud were conducted under fresh and aged conditions using standard API drilling fluids testing methods such as rheometer/viscometer, pH meter and temperature, …

Experimental Investigation Of Environmentally Friendly Drilling Fluid Additives (Mandarin Peels Powder) To Substitute The Conventional Chemicals Used In Water-Based Drilling Fluid, Abo Taleb T. Al-Hameedi, Husam H. Alkinani, Shari Dunn-Norman, Mustafa A. Al-Alwani, Abdullah F. Alshammari, Mohammed M. Alkhamis, Rusul A. Mutar, Waleed H. Al-Bazzaz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The non-biodegradable additives used in controlling drilling fluid properties cause harm to the environment and personal safety. Thus, there is a need for alternative drilling fluid additives to reduce the amount of non-biodegradable waste disposed to the environment. This work investigates the potential of using mandarin peels powder (MPP), a food waste product, as a new environmentally friendly drilling fluid additive. A complete set of tests were conducted to recognize the impact of MPP on the drilling fluid properties. The results of MPP were compared to low viscosity polyanionic cellulose (PAC-LV), commonly used chemical additive for the drilling fluid. The …

Efficient Catalytic Production Of Biodiesel Using Nano-Sized Sugar Beet Agro-Industrial Waste, Hosam H. Abdelhady, Hany A. Elazab, Emad M. Ewais, Mohamed Saber, Mohamed S. El-Deab

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper addresses the use of agro-industrial residue as a promising heterogeneous catalyst for the efficient production of biodiesel. That is, CaO-rich Sugarbeet agro-industrial waste (smashed down to nano-size) shows superb catalytic activity for biodiesel production via transesterification process employing sunflower oil and methanol. Physicochemical properties of the proposed catalyst are probed by TGA–DTG, XRF, XRD, FT-IR, SEM, BET, and CO2-TPD techniques. Biodiesel conversion (%) of Ca. 93% is achieved under the optimal conditions (catalyst loading of 1 wt%, methanol/oil molar ratio of 4.5:1, refluxed at 75 °C for 60 min). The relatively short reaction time indicates the enhanced kinetics …

Dry And Wet Torrefaction Of Microalgal Biomass For Biochar Production As Bioenergy Sources, Yong Yang Gan

Student Works (2020-2029)

Increasing population in global and living standards have risen the consumption of global energy. Thermochemical conversion approaches hold great potential for the biomass conversion into energy applications. Among these approaches, torrefaction is a promising technique to enhance the biomass properties, making it more practical and suitable in biofuel applications. In this study, two different species of microalgae (third generation biofuel feedstock) including Chlorella vulgaris ESP-31 and FSP-E were used as feedstocks for dry and wet torrefaction. Dry torrefaction of microalgae was performed at temperatures of 200, 250 and 300 ºC, and holding times of 15, 30, 45 and 60 min, …

Noble-Transition Alloy Absorbers For Near-Infrared Hot-Carrier Optoelectronics, Sara Karoline Figueiredo Stofela

LSU Doctoral Dissertations

Optoelectronics is the field of technology concerned with the study and application of electronic devices that source, detect and control light. Here we focus on the optical communications field which relies on optical fiber systems to carry signals to their destinations operating in the near-infrared range. To improve the performance of current optical fiber systems, one of the paths is to develop better near-infrared photodetectors.

The current group of materials used for near-infrared photodetection relies in the III-V semiconductor family. Although their spectral photosensitivity correlates well with the near-infrared, response time performance and electronic circuit integration remain limited for this …

Experimental And Computational Tools For Single Cell Analysis In Cancer Diagnostics, Manibarathi Vaithiyanathan

LSU Doctoral Dissertations

Substantial evidence shows that cellular heterogeneity commonly exists within an isogenic or clonal population. Whether in isolation or caused through a combination of the above events, cellular heterogeneity can dramatically influence cellular decision making and cell fate, however, this can be masked by the average response from a population. One approach to solve this issue is to analyze a population at the individual cell level. The goal of this work is to develop high-throughput experimental and computational platforms to screen and quantify single cancer cells for specific intracellular enzyme activities. An interdisciplinary approach was taken to 1) better understand the …

Experimental Evaluation Of How Mineralogy And Microstructure Impact Micro-Geomechanics Of Shale Rocks, Hui Du

LSU Doctoral Dissertations

Shales play an essential role in petroleum exploration and production because they can occur either as unconventional reservoir rocks for hydrocarbon extraction via hydraulic fracturing or as caprocks for conventional reservoirs and subsurface gas/ waste storage. For both extraction and storage applications, the success rate is directly depending on the rigorous candidate selection. Conventional rock characterization techniques normally measure rock properties by seismic/logging at the reservoir scale, and on drilled/outcrop cores at the core scale. However, shales are highly heterogeneous in composition, containing a large number of reactive minerals in micro/nanoscale with significantly different properties. The structural features and properties …

The Desorption Kinetics Of Methane From Nonaqueous Fluids For Enhanced Well Control, James Lee Nielsen Jr.

LSU Master's Theses

The mass transfer of a dissolved gas evolving to return to the gaseous phase from a liquid is governed by many parameters. This process affects the development of an oil and gas well due to the possibility of gas contamination occurring from either an influx entering the wellbore, or drilling through gas-bearing formations. Once this dissolved hydrocarbon gas circulates up the wellbore, it will begin to evolve from solution and poses a potential risk to drilling equipment, the environment, and personnel at a drilling rig. Being able to predict the behavior of gas desorption based on a known set of …

First-Principle Study On The Interaction Of Ligands With Gold And Effects On Catalytic Activities, Xun Cheng

LSU Doctoral Dissertations

The extensive use of fossil fuels has increased the atmospheric concentration of CO₂, resulting in global climate change. One way to mitigate the CO₂ challenge is to convert it into useful chemicals electrocatalytically using renewable energies. Recent studies suggest that ligand-modified gold electrodes can enhance the Faradaic efficiency (FE) and selectivity of the electrochemical CO₂ reduction reaction (CO₂RR). This theoretical research, primarily based on density functional theory (DFT), has been carried out to understand the interactions of ligands with Au and possible effects on electrocatalytic activities. We systematically modeled and studied the adsorption of …

A Study Of Particle-Laden Flows From Meso And Micro-Scale Perspectives, Daniel Guedes De Oliveira

LSU Doctoral Dissertations

Particle-laden flows are investigated numerically from a meso-scale perspective using Computational Fluid Dynamics coupled with Discrete Element Method (CFD-DEM) and from a micro-scale perspective using Particle Resolved Direct Numerical Simulation (PR-DNS). For the former, the dynamics of a pseudo-2D pulsed fluidized bed (PFB) consisting of 400,000 to 800,000 particles was investigated (Chapters 2 and 3). The focus is on the capabilities of CFD-DEM to (1) reproduce pattern formation in these systems and (2) further the understanding of the dynamics of PFB's as a function of pulsation parameters. In Chapter 4, a two-spheres system is investigated with a recently implemented PR-DNS …

Nanoscale Colocalization Of Fluorogenic Probes Reveals The Role Of Oxygen Vacancies In The Photocatalytic Activity Of Tungsten Oxide Nanowires, Meikun Shen, Tianben Ding, Steven T. Hartman, Fudong Wang, Christina Krucylak, Zheyu Wang, Che Tan, Bo Yin, Rohan Mishra, Matthew D. Lew, Bryce Sadtler

Electrical & Systems Engineering Publications and Presentations

Defect engineering is a strategy that has been widely used to design active semiconductor photocatalysts. However, understanding the role of defects, such as oxygen vacancies, in controlling photocatalytic activity remains a challenge. Here, we report the use of chemically triggered fluorogenic probes to study the spatial distribution of active regions in individual tungsten oxide nanowires using super-resolution fluorescence microscopy. The nanowires show significant heterogeneity along their lengths for the photocatalytic generation of hydroxyl radicals. Through quantitative, coordinate-based colocalization of multiple probe molecules activated by the same nanowires, we demonstrate that the nanoscale regions most active for the photocatalytic generation of …