Chemical Engineering Commons^™

Application Of Principal Component Proximity Transform And Geostatistics Methods For Volume Shale Distribution As Reservoir Characreristic Imaging In Seismic 3d, Nur Islami

Makara Journal of Technology

Application of Principal Component Proximity Transform and Geostatistics Methods for Volume Shale Distribution as Reservoir Characreristic Imaging in Seismic 3D. Principal component proximity transform (PCPT) technique was used to predict the content of volume shale into seismic data in reservoir modeling framework. The goal in this research is to get the volume shale imaging in three dimensions and allow for reservoir modelling. The reservoir modelling requires an integrated quantitative and qualitative data sources collected separately, such as well and seismic data. Integrating PCPT and Geostatistic methods can generate the detail information for characterization of reservoir’s properties. Finally, it shows that …

Application Of Empirical Orthogonal Function Models To Analyze Shoreline Change At Bangkalan Madura, Darius Arkwright, Suntoyo Suntoyo

Makara Journal of Technology

Bangkalan’s shoreline, especially on the opposite side of Surabaya, has been evaluated to determine the morphological changes due to wave attack, near-shore current, long-shore sediment transport and coastal configuration. This research aims to determine the dominant patterns of variation of Bangkalan’s shoreline change, expressed by Eigen-function in empirical orthogonal function (EOF) models. That was started with data collection such as oceanographic data (wave and tidal), bathymetry and topographic map and sediment data. All data was used for forecasting two-monthly shoreline. Coordinate of two-monthly shoreline was used as input of EOF model. The first Eigen mode is a profile of shoreline …

Establishment Code Hand Palm (Palm Code) 2d Gabor-Based Method, I Ketut Gede Darma Putra, Wira Bhuana, Erdiawan Erdiawan

Makara Journal of Technology

Establishment Code Hand Palm (Palm Code) 2D Gabor-Based Method. Palmprint is relatively new in physiological biometrics. Palmprint ROI segmentation and feature extraction are two important issues in palm print recognition. This paper introduces two steps in the center of mass moment method for ROI segmentation that will be applied in the Gabor 2D filter to obtain palm code as palmprint feature vector. Normalized Hamming distance was used to measure the similarity degrees of two feature vectors of palmprint. The system was tested using database 1000 palmprint images generated from 5 samples from each of the 200 persons randomly selected with …

The Effectiveness Of Anaerobic Baffled Reactor And Rotating Biological Contactor In Batik Wastewater Treatment, Augustinus Ignatius Kristijanto, Widhi Handayani, Purwanti Asih Anna Levi

Makara Journal of Technology

Batik is one of popular arts of Indonesia. The batik industries in Sragen, Central Java, are prepared to compete in global market. In order to realize that objective, batik products should fulfill some qualifications, one of which is “environmental friendliness”. As batik production is usually generating wastewater which pollutes the environment, the technology of wastewater treatment should be developed to solve the problem. This preliminary study has been done to assess the effectiveness of anaerobic baffled reactor (ABR) and rotating biological contactor (RBC) in batik wastewater treatment. In 40 days of treatment period, the ABR performance in reducing pollutants showed …

Physical Characterization And Desulfurization Of Biobriquette Using Calcium-Based Adsorbent, Mahidin Mahidin, Asri Gani, Khairil Khairil

Makara Journal of Technology

Combustion of coal and co-combustion of their co-fuel contribute to gas emissions. Among the gas emissions are SOx, NOx, CO and CO2. Introduction of calcium based adsorbent is addressed to absorb SO2 that release to the atmosphere during the combustion process. Objective of the research is at first to observe the physical characteristics of biobriquettes as a function of briquette compositions (coal to palm kernel shell ratios) and Ca/S ratios (Ca in adsorbent and S in briquette) using a natural adsorbent (shellfish waste). The second objective is to investigate desulfurization characteristics as a function of Ca/S ratios and desulfurization temperatures …

Flutter Analysis Of Rx-420 Balistic Rocket Fin Involving Rigid Body Modes Of Rocket Structures, Novi Andria

Makara Journal of Technology

Flutter Analysis of RX-420 Balistic Rocket Fin Involving Rigid Body Modes of Rocket Structures. Flutter is a phenomenon that has brought a catastrophic failure to the flight vehicle structure. In this experiment, flutter was analyzed for its symmetric and antisymmetric configuration to understand the effect of rocket rigid modes to the fin flutter characteristic. This research was also expected to find out the safety level of RX-420 structure design. The analysis was performed using half rocket model. Fin structure used in this research was a fin which has semispan 600 mm, thickness 12 mm, chord root 700 mm, chord tip …

Analytical And Computational Simulation Approaches To Design Low Energy Glass Block, Floriberta Binarti, Agustinus Djoko Istiadji, Prasasto Satwiko, Priyo Tri Iswanto

Makara Journal of Technology

Analytical and Computational Simulation Approaches to Design Low Energy Glass Block. An environmentally friendly process was developed to produce a low embodied energy glass block from waste glasses. The energy efficiency of the glass block is represented by its thermal conductance (U)

Medium Density Fibreboard Made Of Acetylated Sludge From Paper Mill, Luthfi Hakim, Evalina Herawati, I Nyoman Jaya Wistara

Makara Journal of Technology

Medium Density Fibreboard Made of Acetylated Sludge from Paper Mill. Research of using sludge as raw material for making medium density fibreboard (MDF) was useful to create additional value of sludge. The objective of the research was to evaluate physical properties, mechanical properties, and durability of MDF from acetylated sludge in 4 levels of acetate anhydride (0%, 3%, 5%, and 7%) with 3 replicates. The MDF was made using dry process. After materials were mixed with adhesives, they were pressed using hotpress under 170 oC temperature and 45 Pa pressure for 25 minutes. The size of the MDF sample was …

Optimation Of Nitrogen And Phosphorus In Azolla Growth As Biofertilizer, Hany Handajani

Makara Journal of Technology

Nitrogen is one of the most important minerals for living organisms. Azolla is known as a small water fern which can fix nitrogen through the symbiotic association with the blue green algae Anabaena. Experimental studies were carried out in the glass house, investigating the growth of Azolla using different levels of nitrogen and phosphorus in the media. The experiment used 12 treatments with 3 levels of nitrogen (0, 5, and 10 mg atom/L) and 4 levels of phosphorus (0, 10, 20, and 30 mg atom/l) in a factorial design with 3 replicates. The results show that the highest biomass for …

Antibacterial Activity Of Papaya Leaf Extracts Against Pathogenic Bacteria, Elisa Friska Romasi, Jessica Karina, Adolf Jan Nexson Parhusip

Makara Journal of Technology

It was reported that the extracts of papaya leaves could inhibit the growth of Rhizopus stolonifer. Antibacterial activity of Carica papaya leaf extracts on pathogenic bacteria was observed in this study. Papaya leaves were extracted by using maceration method and three kinds of solvents: ethanol, ethyl acetate, and hexane. Papaya leaf extracts were tested against Bacillus stearothermophilus, Listeria monocytogenes, Pseudomonas sp., and Escherichia coli by agar diffusion method. The objectives of this study were to determine extract ability against pathogenic bacteria, to observe the influence of pH, NaCl, and heat on extracts ability, and to observe extract ability against B. …

Cassava Pulp As A Biofuel Feedstock Of An Enzymatic Hydrolysis Proces, Djuma’Ali Djuma’Ali, Nonot Soewarno, Sumarno Sumarno, Dyah Primarini, Wahono Sumaryono

Makara Journal of Technology

Cassava pulp, a low cost solid byproduct of cassava starch industry, has been proposed as a high potential ethanolic fermentation substrate due to its high residual starch level, low ash content and small particle size of the lignocellulosic fibers. As the economic feasibility depends on complete degradation of the polysaccharides to fermentable glucose, the comparative hydrolytic potential of cassava pulp by six commercial enzymes were studied. Raw cassava pulp (12% w/v, particle sizeμm) hydrolyzed by both commercial pectinolytic (1) and amylolytic (2) enzymes cocktail, yielded 70.06% DE. Hydrothermal treatment of cassava pulp enhanced its susceptibility to enzymatic cleavageas compared to …

Alos/Palsar Image Processing Using Dinsar And Log Ratio For Flood Early Detection In Jakarta Based On Land Subsidences, Dodi Sudiana, Mia Rizkinia

Makara Journal of Technology

Flood that occurred in Jakarta is not only influenced by rainfall, urban planning system and drainage alone, but also may be involved land subsidence (LS). LS is possible in because Jakarta stands on top of layers of sediments and the presence of ground water consumption in very large quantities. In this research, the Advanced Land Observing Satellite (ALOS)/Phased Array type L-band Synthetic Aperture Radar (PALSAR) data was processed to determine the level of LS in Jakarta area and its relation to flood potential area. Differential interferometry method (DInSAR) was performed on two PALSAR data with different acquisition years, i.e. 2007 …

Giant Magnetostriction In Annealed Co1-XFeX Thin-Films, Dwight Hunter, Will Osborn, Ke Wang, Nataliya Kazantseva, Jason R. Hattrick-Simpers, Richard Suchoski, Ryota Takahashi, Marcus L. Young, Apurva Mehta, Leonid A. Bendersky, Same E. Lofland, Manfred Wuttig, Ichiro Takeuchi

Faculty Publications

Chemical and structural heterogeneity and the resulting interaction of coexisting phases can lead to extraordinary behaviours in oxides, as observed in piezoelectric materials at morphotropic phase boundaries and relaxor ferroelectrics. However, such phenomena are rare in metallic alloys. Here we show that, by tuning the presence of structural heterogeneity in textured Co_1−xFe_x thin films, effective magnetostriction λeff as large as 260 p.p.m. can be achieved at low-saturation field of ~10 mT. Assuming λ100 is the dominant component, this number translates to an upper limit of magnetostriction ofλ100≈5λeff >1,000 p.p.m. Microstructural analyses …

Comparison Of Microwave And Conventionally Sintered Yttria-Doped Zirconia Ceramics, Colin J. Reidy, Thomas J. Fleming, Stuart Hampshire, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper reports on improvement of the physical and mechanical properties of Y₂O₃-ZrO₂ ceramics through compositional optimization, the use of nanograined powders and utilization of microwave sintering. ZrO₂ with 2-5 mol% Y₂O₃, prepared from nanopowders, was sintered in both conventional and microwave furnaces under exactly the same heating schedule. It was found that microwave sintering improves physical and mechanical properties of Y₂O₃-ZrO₂ ceramics compared with conventional sintering. Compositions containing 2 mol% Y₂O₃ exhibit the greatest improvement due to retention of tetragonal ZrO …

Supported Monoethanolamine For Co2 Separation, Morris D. Argyle, Zhuoyan Sun, Maohong Fan

Faculty Publications

An alternative method for using monoethanolamine (MEA) in CO2 separation is developed from the viewpoints of the MEA-CO2 reaction environment and the process of spent sorbent regeneration. The method could be used to considerably reduce energy consumption compared to conventional aqueous MEA processes. MEA-TiO2 (MT) CO2 sorbent is synthesized using pure MEA and a support material, TiO2. The performance of the MT sorbent on CO2 separation was investigated in tubular reactors under various experimental conditions. The effects of several major factors on CO2 sorption by the MT sorbent were investigated. The sorption capacity of the MT sorbent increased with MEA …

Computational Studies Of Ion Transport In Polymer Electrolytes, Hui Wu

Doctoral Dissertations

Improving ionic conductivity and lithium mobility in polymer electrolytes is important for their practical use for battery electrolytes. In this study, a combination of molecular dynamics and Monte Carlo simulations was used to bring insight into lithium ion transport in poly(ethylene oxide) (PEO) with plasticizers and also next to alumina solid surface doped with lithium salt. The simulations were performed using a moderately high molecular weight polymer (Mn = 10,000 g/mol) at an EO:Li ratio of 15. For the plasticized system, the PEO with LiN(CF3SO 2)2 (LiTFSI) was mixed with 10 wt% plasticizers that included either cyclic ethylene carbonate …

Role Of Ammonia In The Activiation Of Methanol Dehydrogenase/Cytochrome C(L) Enzyme, Ancy Kunjumon

Doctoral Dissertations

Recent advancement in enzyme catalysis has opened ways to design efficient biocatalysts, bio-sensors and bio-fuel cells. An in-depth knowledge about the mechanism of the reaction taking place within the enzymes is of great importance to achieve these goals. In this dissertation, various computation methods are applied to investigate the mechanism behind enzyme catalysis in the presence of compounds called activators.

Methanol dehydrogenase (MDH) is a well-known bio-catalyst that can oxidize excess of methanol from the environment to formaldehyde. The enzyme works well within the bacterial environment, but under in vitro, it loses activity. Ammonia is used as an activator …

Polymorphic Structures Of Alzheimer's Beta-Amyloid Globulomers, Jie Zheng

Chemical, Biomolecular, and Corrosion Engineering Faculty Research

Misfolding and self-assembly of Amyloid-β (Aβ) peptides into amyloid fibrils is pathologically linked to the development of Alzheimer's disease. Polymorphic Aβ structures derived from monomers to intermediate oligomers, protofilaments, and mature fibrils have been often observed in solution. Some aggregates are on-pathway species to amyloid fibrils, while the others are off-pathway species that do not evolve into amyloid fibrils. Both on-pathway and off-pathway species could be biologically relevant species. But, the lack of atomic-level structural information for these Aβ species leads to the difficulty in the understanding of their biological roles in amyloid toxicity and amyloid formation.

Evaluation Of Dye And Pigment Based Ink Jet Ink Sets, Veronika Chovancova

The Hilltop Review

The development of high performance inkjet printers and inks is advancing rapidly. Manufacturers seem to introduce their new technology inks to the market on an almost daily basis. Chemists in ink laboratories are still fighting with the issue of combining a wide gamut of dye-based inks with the lightfast and weather resistance qualities of pigment-based inks into new-age ink formulations.

Three different inkjet printers and inks were investigated in this work: the Epson Stylus® Pro 5000, using a dye-based ink set, the Epson Stylus® Pro 5500, employing Archival ink technology, and the Epson Stylus® Photo 2200, with 7-color UltraChrome™ inks. …

Effects Of Pressure On The Properties Of Coal Char Under Gasification Conditions At High Initial Heating Rates, Randy C. Shurtz

Theses and Dissertations

The effects of elevated pressure and high heating rates on coal pyrolysis and gasification were investigated. A high-pressure flat-flame burner (HPFFB) was designed and built to conduct these studies. The HPFFB was designed to provide an environment with laminar, dispersed entrained flow, with particle heating rates of ~10^5 K/s, pressures of up to 15 atm, and gas temperatures of up to 2000 K. Residence times were varied from 30 to 700 ms in this study. Pyrolysis experiments were conducted at particle heating rates of ~10^5 K/s and maximum gas temperatures of ~1700 K at pressures of 1 to 15 atm. …

The Study Of Ink Pigment Dispersion Parameters, Lokendra Pal, Paul D. Fleming Iii

The Hilltop Review

The purpose of this study was to investigate the influence of rotation speed and milling time on the pigment dispersion quality. The information can be used to obtain a standard laboratory condition at which a wide range of pigments may be dispersed to formulate water-based rotogravure inks. The influence of pigment concentration and shear forces on the pigment dispersion were also studied.

The procedure consisted of dispersing the pigment using a laboratory Dispermat® SL bead mill at various milling times with two different rotation speeds and measuring the particle size and particle size distribution of the milled samples. The pigment …

Phospholipid Transport In Silicon Hydrogel Contact Lenses, Yibei Zhao

Theses and Dissertations

Dry eye syndrome has been associated with the lack of phospholipids in the tear film, leading to disruption of the tear film and subsequent irritation. Characterization of the transport and release of phospholipids from a silicone hydrogel contact lens is required to assess the possible use of these lenses for phospholipid delivery to increase patient comfort. This thesis examines the use of silicone hydrogel contact lenses as phospholipid delivery devices. Contact lenses of silicone hydrogel composition were loaded with varying amounts of radiolabeled 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) from a solution of n-propanol. These lenses were eluted at 35°C into artificial …

A Modified Surface On Titanium Deposited By A Blasting Process, Caroline O' Sullivan, Peter O'Hare, Greg Byrne, Liam O'Neill, Katie B. Ryan, Abina M. Crean

Publications

Abstract

: Hydroxyapatite (HA) coating of hard tissue implants is widely employed for its biocompatible and osteoconductive properties as well as its improved mechanical properties. Plasma technology is the principal deposition process for coating HA on bioactive metals for this application. However, thermal decomposition of HA can occur during the plasma deposition process, resulting in coating variability in terms of purity, uniformity and crystallinity, which can lead to implant failure caused by aseptic loosening. In this study, CoBlast™, a novel blasting process has been used to successfully modify a titanium (V) substrate with a HA treatment using a dopant/abrasive regime. …

Evaluation Of Cathode Materials For Low Temperature (500-700c) Solid Oxide Fuel Cells, Alexander M. Lassman

Master's Theses

Solid oxide fuel cells (SOFC) have gained a great deal of interest, due to their potential for high efficiency power generation and ability to utilize hydrogen fuel, as well as various hydrocarbon-based fuels. A recent trend in SOFC development has been towards lower operating temperatures (500-700°C), which can substantially reduce the cost and complexity of the system. This thesis presents an investigation into state of the art Ba- and La- based cathode materials for use in low temperature (500-700°C) solid oxide fuel cells.

Synthesis of A-site deficient [A=0.97] Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃ (BSCF) was …

Robust Cns Regeneration After Complete Spinal Cord Transection Using Aligned Poly-L-Lactic Acid Microfibers, Andres Hurtado, Jared M. Cregg, Han B. Wang, Dane F. Wendell, Martin Oudega, Ryan J. Gilbert, John W. Mcdonald

Chemical and Biochemical Engineering Faculty Research & Creative Works

Following spinal cord injury, axons fail to regenerate without exogenous intervention. In this study we report that aligned microfiber-based grafts foster robust regeneration of vascularized CNS tissue. Film, random, and aligned microfiber-based conduits were grafted into a 3 mm thoracic rat spinal cord gap created by complete transection. Over the course of 4 weeks, microtopography presented by aligned or random poly- l-lactic acid microfibers facilitated infiltration of host tissue, and the initial 3 mm gap was closed by endogenous cell populations. This bulk tissue response was composed of regenerating axons accompanied by morphologically aligned astrocytes. Aligned fibers promoted long distance …

Γ-Ct Measurement And Cfd Simulation Of Cross Section Gas Holdup Distribution In A Gas-Liquid Stirred Standard Rushton Tank, Yue Jin Liu, Wei Li, Lu Chang Han, Yang Cao, He An Luo, Muthanna H. Al-Dahhan, M. P. Dudukovic

Chemical and Biochemical Engineering Faculty Research & Creative Works

Cross Section Gas Holdup Distributions at 3/4 Dimensionless Static Liquid Height in a Gas-Liquid Stirred Standard Rushton Tank Were Measured using 137Cs Γ-CT Scan Measuring Technology at Larger Gas Flow Rates and Higher Impeller Rotating Speeds. the Obtained CT Scan Images and Digital Distribution Curves of Gas Holdup with Dimensionless Radius based on the CT Images Could Explain the Fluctuation Changes of Gas Holdup Distribution. the Dense Area of Gas Holdup Distribution Appeared in the Upper Space of Impeller Blades. Gas Holdup Increased Both with Gas Flow Rate and Impeller Rotating Speed, But Gas Flow Rate Had More Influence on …

Optimizing The Use Of Ultrasound To Deliver Chemotherapeutic Agents To Cancer Cells From Polymeric Micelles, Ghaleb A. Husseini, Nabil M. Abdel-Jabbar, Farouq S. Mjalli, William G. Pitt, Ala'a Al-Mousa

Faculty Publications

In this study, we present an artificial neural network (ANN) model that attempts to predict the dynamic release of doxorubicin (Dox) from P105 micelles under different ultrasonic power densities at 20 kHz. The goal is to utilize the developed ANN model in optimizing the ultrasound application to achieve a target drug release at the tumor site by controlling power density and ultrasound duration via an ANN-based model predictive control. The parameters of the controller are then tuned to achieve good reference signal tracking.

Theoretical Prediction Of Drug Release In Gi Tract From Spherical Matrix Systems, Naga Lakshmi Ramana Susarla

Dissertations

The significance of controlled release drug delivery systems (CRDDS) lies in their ability to deliver the drug at a steady rate thus reducing the dosage interval and providing a prolonged pharmacodynamic effect. But despite the steadily increasing practical importance of these devices, little is known regarding their underlying drug release mechanisms. Mathematical modeling of these drug delivery systems could help us understand the underlying mass transport mechanisms involved in the control of drug release. Mathematical modeling also plays an important role in providing us with valuable information such as the amount of drug released during a certain period of time …

Effects Of Operating And Geometric Variables On Hydrodynamics And Tablet Dissolution In Standard And Modified Dissolution Testing Apparatuses 2, Yimin Wang

Dissertations

Dissolution testing is routinely conducted in the pharmaceutical industry to provide critical in vitro drug release information for quality control purposes, and especially to assess batch-to-batch consistency of solid oral dosage forms such as tablets. Among the different types of apparatuses listed in the United States Pharmacopoeia (USP), the most commonly used dissolution system for solid dosage forms is the USP Dissolution Testing Apparatus 2, consisting of an unbaffled, hemispherical-bottomed vessel equipped with a 2-blade radial impeller.

Despite its extensive use in industry and a large body of work, some key aspects of the hydrodynamics of Apparatus 2 have received …

Multifunctional Reactive Nanocomposite Materials, Demitrios Stamatis

Dissertations

Many multifunctional nanocomposite materials have been developed for use in propellants, explosives, pyrotechnics, and reactive structures. These materials exhibit high reaction rates due to their developed reaction interfacial area. Two applications addressed in this work include nanocomposite powders prepared by arrested reactive milling (ARM) for burn rate modifiers and reactive structures. In burn rate modifiers, addition of reactive nanocomposite powders to aluminized propellants increases the burn rate of aluminum and thus the overall reaction rate of an energetic formulation. Replacing only a small fraction of aluminum by 8Al•MoO₃ and 2B•Ti nanocomposite powders enhances the reaction rate with little change …