Chemical Engineering Commons^™

Improving Pv Module Efficiency Through Cooling, Blake Bradley

Chemical Engineering Undergraduate Honors Theses

The Solarbacks researched and designed a variety of cooling methods that could be used to improve the efficiency of photovoltaics. These cooling methods can be separated into two categories: active and passive methods. The active cooling method of hydraulic cooling and the passive cooling methods of heat sinks (fins), optical coatings, thermosyphons, phase change materials, and thermoelectric generators were all taken into consideration as potential cooling methods. Passive cooling methods were preferred because the use of electricity required for the cooling mechanism would reduce the net electricity and subsequent profit from the panels.

Two variations of hydraulic cooling were researched: …

Improving Pv Module Efficiency Through Cooling, Megan Reynolds

Chemical Engineering Undergraduate Honors Theses

The Solarbacks researched and designed a variety of cooling methods that could be used to improve the efficiency of photovoltaics. These cooling methods can be separated into two categories: active and passive methods. The active cooling method of hydraulic cooling and the passive cooling methods of heat sinks (fins), optical coatings, thermosyphons, phase change materials, and thermoelectric generators were all taken into consideration as potential cooling methods. Passive cooling methods were preferred because the use of electricity required for the cooling mechanism would reduce the net electricity and subsequent profit from the panels.

Two variations of hydraulic cooling were researched: …

Solution To Exide Technologies Inbatec Inefficiency, Shixuan Hou, Reagan Gilker, Mary Fairley, Spencer Christian, Covenson Latouche

Chemical Engineering Undergraduate Honors Theses

The inefficiency of the battery charging time in Inbatec Units 1 and 2 in the Exide Technologies Fort Smith was initially investigated by a student team in Fall 2019, and the investigation was continued into Spring 2020. The Exide Technologies facility in Fort Smith, Arkansas utilizes 13 Inbatec units to charge the lead-acid batteries. The Inbatec systems circulate the sulfuric acid solution through a cooling tower to maintain to optimal charging temperature. Previous analysis of the charging process for Inbatec Units 1 and 2 show the cooling tower have the capacity to quickly remove the excess heat in the sulfuric …

Solution To Exide Technologies Inbatec Inefficiency, Mary Fairley, Reagan Gilker, Spencer Christian, Shixuan Hou, Covenson Latouche

Chemical Engineering Undergraduate Honors Theses

The inefficiency of the battery charging time in Inbatec Units 1 and 2 in the Exide Technologies Fort Smith was initially investigated by a student team in Fall 2019, and the investigation was continued into Spring 2020. The Exide Technologies facility in Fort Smith, Arkansas utilizes 13 Inbatec units to charge the lead-acid batteries.

The Inbatec systems circulate the sulfuric acid solution through a cooling tower to maintain to optimal charging temperature. Previous analysis of the charging process for Inbatec Units 1 and 2 show the cooling tower have the capacity to quickly remove the excess heat in the sulfuric …

Improving Pv Module Efficiency Through Cooling, Harrison Dawson

Chemical Engineering Undergraduate Honors Theses

The Solarbacks researched and designed a variety of cooling methods that could be used to improve the efficiency of photovoltaics. These cooling methods can be separated into two categories: active and passive methods. The active cooling method of hydraulic cooling and the passive cooling methods of heat sinks (fins), optical coatings, thermosyphons, phase change materials, and thermoelectric generators were all taken into consideration as potential cooling methods. Passive cooling methods were preferred because the use of electricity required for the cooling mechanism would reduce the net electricity and subsequent profit from the panels.

Two variations of hydraulic cooling were researched: …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Kevin Le, Adrian Damian, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The team researched, designed, and economically analyzed a full-scale adsorption column system to be applied in mining processes that leave high amounts of fluoride in their effluent. This system was designed to remove fluoride from water saturated with calcium sulfate, as calcium sulfate is present in high amounts in certain mining processes. Currently, high density sludge (HDS) is commonly employed to reduce fluoride concentrations, but due to solubility limits the sludge treatment cannot lower fluoride below 10 mg/L (ppm). The current enforceable EPA standard for discharged water is at 4 mg/L (ppm), although mining companies anticipate that this standard will …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Michelle Dopp, Kevin Le, Ethan Phan, Mary Johnson, Jacqueline Payne, Adrian Damian, Courtney Golman

Chemical Engineering Undergraduate Honors Theses

The Moo Pig Sooie’s researched, designed, and economically analyzed a full-scale adsorption column system to be applied in mining processes that leave high amounts of fluoride in their effluent. This system was designed to remove fluoride from water saturated with calcium sulfate, as calcium sulfate is present in high amounts in certain mining processes. Currently, high density sludge (HDS) is commonly employed to reduce fluoride concentrations, but due to solubility limits the sludge treatment cannot lower fluoride below 10 mg/L (ppm). The current enforceable EPA standard for discharged water is at 4 mg/L (ppm), although mining companies anticipate that this …

Solution To Exide Technologies Inbatec Inefficiency, Spencer Christian, Shixuan Hou, Mary Fairley, Reagan Gilker, Covenson Latouche

Chemical Engineering Undergraduate Honors Theses

The inefficiency of the battery charging time in Inbatec Units 1 and 2 in the Exide Technologies Fort Smith was initially investigated by a student team in Fall 2019, and the investigation was continued into Spring 2020. The Exide Technologies facility in Fort Smith, Arkansas utilizes 13 Inbatec units to charge the lead-acid batteries. The Inbatec systems circulate the sulfuric acid solution through a cooling tower to maintain to optimal charging temperature. Previous analysis of the charging process for Inbatec Units 1 and 2 show the cooling tower have the capacity to quickly remove the excess heat in the sulfuric …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Jacqueline Payne, Mary Johnson, Kevin Le, Michelle Dopp, Courtney Golman, Adrian Damian, Ethan Phan

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Ethan Phan, Adrian Damian, Kevin Le, Mary Johnson, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective high-density sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Scale-Up Of Polyaniline Cellulose Membranes, Isaac Bodemann

Chemical Engineering Undergraduate Honors Theses

Polyaniline coated cellulose membranes show impressive conductive properties that may be used to innovate traditional charged separation techniques, such as electrodeionization. However, these membranes are not sold to consumers, so they cannot be easily integrated into such systems. This research focuses on the scale-up and development of positively charged anion exchange membranes to be used in EDI cells. Novel cellulose membranes were made using lab-specific cellulose. These membranes were then coated using a polyaniline technique adopted from a paper titled, “Flexible Electrically Conductive Nanocomposite Membrane Based on Bacterial Cellulose and Polyaniline." This paper details the methods used to add the …

Solution To Exide Technologies Inbatec Inefficiency, Reagan Gilker, Mary Fairley, Spencer Christain, Shixuan Hou, Covenson Latouche

Chemical Engineering Undergraduate Honors Theses

The inefficiency of the battery charging time in Inbatec Units 1 and 2 in the Exide Technologies Fort Smith was initially investigated by a student team in Fall 2019, and the investigation was continued into Spring 2020. The Exide Technologies facility in Fort Smith, Arkansas utilizes 13 Inbatec units to charge the lead-acid batteries.

The Inbatec systems circulate the sulfuric acid solution through a cooling tower to maintain to optimal charging temperature. Previous analysis of the charging process for Inbatec Units 1 and 2 show the cooling tower have the capacity to quickly remove the excess heat in the sulfuric …

Improving Pv Module Efficiency Through Cooling, Ashley Cox

Chemical Engineering Undergraduate Honors Theses

The Solarbacks researched and designed a variety of cooling methods that could be used to improve the efficiency of photovoltaics. These cooling methods can be separated into two categories: active and passive methods. The active cooling method of hydraulic cooling and the passive cooling methods of heat sinks (fins), optical coatings, thermosyphons, phase change materials, and thermoelectric generators were all taken into consideration as potential cooling methods. Passive cooling methods were preferred because the use of electricity required for the cooling mechanism would reduce the net electricity and subsequent profit from the panels.

Two variations of hydraulic cooling were researched: …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Adrian Damian, Kevin Le, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Improving Pv Module Efficiency Through Cooling, Brandon Conrad, Blake Bradley, Ashley Cox, Donhy Mai, Harrison Dawson, Megan Reynolds, George Hill

Chemical Engineering Undergraduate Honors Theses

The Solarbacks researched and designed a variety of cooling methods that could be used to improve the efficiency of photovoltaics. These cooling methods can be separated into two categories: active and passive methods. The active cooling method of hydraulic cooling and the passive cooling methods of heat sinks (fins), optical coatings, thermosyphons, phase change materials, and thermoelectric generators were all taken into consideration as potential cooling methods. Passive cooling methods were preferred because the use of electricity required for the cooling mechanism would reduce the net electricity and subsequent profit from the panels.

Two variations of hydraulic cooling were researched: …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Courtney Golman, Kevin Le, Michelle Dopp, Adrian Damian, Mary Johnson, Jacqueline Payne, Ethan Phan

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Silver-Based Microbial Check Valve For Spacecraft Potable Water Systems, Tanner Burns

Chemical Engineering Undergraduate Honors Theses

As human space exploration increases, the development of a more efficient potable water treatment system suited for spacecraft becomes crucial. This Waste-management Education Research Consortium (WERC) challenge was designed to explore the viability of microbial control through the utilization of silver ions as a biocide for possible integration into the Tranquility Node 3 water purification system aboard the International Space Station (ISS). Current systems using iodine risk causing hyperthyroidism from overexposure; however, silver can be safely ingested without this side effect. After researching silver delivery methods including electrochemical ion production, controlled release, or a combination of the two, our team …

Silver-Based Microbial Check Valve For Spacecraft Potable Water Systems, Jennifer Gaines

Chemical Engineering Undergraduate Honors Theses

As human space exploration increases, the development of a more efficient potable water treatment system suited for spacecraft becomes crucial. This Waste-management Education Research Consortium (WERC) challenge was designed to explore the viability of microbial control through the utilization of silver ions as a biocide for possible integration into the Tranquility Node 3 water purification system aboard the International Space Station (ISS). Current systems using iodine risk causing hyperthyroidism from overexposure; however, silver can be safely ingested without this side effect. After researching silver delivery methods including electrochemical ion production, controlled release, or a combination of the two, our team …

Design And Cost Analysis Of Acrylic Acid Plant, Adam Ferrier

Chemical Engineering Undergraduate Honors Theses

The purpose of this project was to model and design a plant to produce 75,000 tons per year of acrylic acid. Using the design in section B.9 of Richard Turton’s Analysis, Synthesis, and Design of Chemical Processes as a starting point, a plant was designed based around the partial oxidation of propylene to acrylic acid. The final plant design produces about 86,000 tons per year of acrylic acid. Using an interest rate of 10%, the plant has a discounted cash flow rate of return of 32% over 2 years of startup and 10 years of operation. Attached is an executive …

Modeling Of Electrochemical Processes At The Magnesium Anode During Struvite Formation, Tobias Dwyer

Chemical Engineering Undergraduate Honors Theses

This study analyzes the current transients observed during the electrochemical formation of struvite from a solution of ammonium phosphate using a pure magnesium and magnesium alloy electrode. Through converting the chronoamperometric data to chronocoulometric data and fitting the data to various models, the driving mechanisms for struvite nucleation were elucidated. While the pure magnesium anode is controlled by only instantaneous nucleation at the electrode, the AZ31 alloy is nucleation controlled at short times and Cottrell diffusion controlled at long times.

Recovery Of Water And Salt From Hyper-Saline Mine Water Using Freeze Crystallization, Gabrielle Casey

Chemical Engineering Undergraduate Honors Theses

The Freezerbacks researched, designed, and economically evaluated a full-scale freeze crystallization process as well as two alternative full-scale processes: 5 stage multiple effect evaporation and reverse osmosis. All three processes were designed to treat hyper-saline mine water that was sent into evaporation pond systems. These systems were designed for Freeport-McMoRan’s mines that need to treat impacted water.

The Freeport-McMoRan copper mine in Miami, Arizona was visited in order to gain insight about the problem. The mine is no longer actively mining copper and is in the process of reclaiming land used. An essential part of restoring the land is treating …

Development Of A Ws2 Catalyst For Hydrogen Evolution And Improvement Via Platinum Nanoparticle Decoration, Alexander O'Brien

Chemical Engineering Undergraduate Honors Theses

In response to a growing global need to improve utilization of green energy, the concept of renewable energy storage via electrolytic hydrogen production has gained popularity in recent years. However, the prohibitive expense of the bulk platinum catalysts currently used for the hydrogen evolution reaction prevents such a concept from being widely adoptable. This research focuses on a possible alternative catalyst, nanolayer WS₂, which is capable of promoting the hydrogen evolution reaction while maintaining economic viability. Bulk WS₂ was prepared in semiconducting, nanolayer form through liquid phase exfoliation. Prepared catalyst inks consisting of this material demonstrated successful …

Desalination: Freeze Crystallization, Ibrahim Guiga

Chemical Engineering Undergraduate Honors Theses

The Freezerbacks researched, designed, and economically evaluated a full-scale freeze crystallization process as well as two alternative full-scale processes: 5 stage multiple effect evaporation and reverse osmosis. All three processes were designed to treat hyper-saline mine water that was sent into evaporation pond systems. These systems were designed for Freeport-McMoRan’s mines that need to treat impacted water.

The Freeport-McMoRan copper mine in Miami, Arizona was visited in order to gain insight about the problem. The mine is no longer actively mining copper and is in the process of reclaiming land used. An essential part of restoring the land is treating …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Hannah Young

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Effect Of Thiols For Nitrogen Reduction To Ammonia, Zakary R. Ford

Chemical Engineering Undergraduate Honors Theses

Ammonia is an important chemical used for fertilizers and also a potential carbon-free hydrogen storage medium. The Haber-Bosch process is the main production process, which requires large energy- and capital-input. Therefore, it is crucial to develop an alternate scalable synthesis that provides a less energy intensive and more economical route for synthetic ammonia production. In this paper, a 1Fe1Ni film was functionalized with C₃OH and C₆OH for the electrochemical synthesis of ammonia. This work will provide some insight into how thiol ligands can increase the selectivity of the catalyst for nitrogen reduction reaction and can be …

Effects Of Ambient And Laser Light On Water Evaporation From The Surface Of Polyurethane Swabs Doped With Surfactant, Collin Campbell

Chemical Engineering Undergraduate Honors Theses

Polyurethane swabs are a common instrument for environmental sampling in the food, medical, and forensic fields due to their high recovery of organisms like viruses, spores, and bacteria. For sampling microbes in food and medical facilities, storage of the collected samples occurs under the absence of light to promote growth for more accurate testing. In the forensic fields, microbial growth results in sample contamination so the inhibition of this growth requires the drying of the swabs. This work studies the evaporation rates of water from polyurethane swabs under zero watt incident light, 30 W fluorescent bulb, 50 mW 532 nm …

The Synthesis, Purification, And Characterization Of The P3 Peptoid, Myles Joyce

Chemical Engineering Undergraduate Honors Theses

The relatively young field of nano-systems has vast applications over various different fields. Peptoids (peptide analogues) and their uses are consistently investigated components of these nano-studies. A particularly interesting group of peptoids are able to self-assemble into secondary structures under the right conditions. The P3 peptoid is able to form microspheres if properly synthesized and purified. Microspheres are frequently studied due to their low surface area to volume ratios. This unique aspect of microspheres makes them an excellent candidate for drug delivery systems; however, these systems must also be robust so that the desired compound can be encapsulated within the …

Task 1: Silver-Based Microbial Check Valve For Spacecraft Potable Water Systems, Eric Beitle

Chemical Engineering Undergraduate Honors Theses

As human space exploration increases, the development of a more efficient potable water treatment system suited for spacecraft becomes crucial. This Waste-management Education Research Consortium (WERC) challenge was designed to explore the viability of microbial control through the utilization of silver ions as a biocide for possible integration into the Tranquility Node 3 water purification system aboard the International Space Station (ISS). Current systems using iodine risk causing hyperthyroidism from overexposure; however, silver can be safely ingested without this side effect. After researching silver delivery methods including electrochemical ion production, controlled release, or a combination of the two, our team …

Recovery Of Water And Salt From Hyper-Saline Mine Water Using Freeze Crystallization, Clara Somerville

Chemical Engineering Undergraduate Honors Theses

The Freezerbacks researched, designed, and economically evaluated a full-scale freeze crystallization process as well as two alternative full-scale processes: 5 stage multiple effect evaporation and reverse osmosis. All three processes were designed to treat hyper-saline mine water that was sent into evaporation pond systems. These systems were designed for Freeport-McMoRan’s mines that need to treat impacted water.

The Freeport-McMoRan copper mine in Miami, Arizona was visited in order to gain insight about the problem. The mine is no longer actively mining copper and is in the process of reclaiming land used. An essential part of restoring the land is treating …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Kristin Moore

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …