Chemical Engineering Commons^™

Investigation Of The Effect Of Supercritical Carbon Dioxide Extraction On The Adsorption Capacity Of Date Pits, Haliemeh Imad Sweidan

Chemical and Petroleum Engineering Theses

This thesis aims to develop and investigate an innovative use of date pits, a common and abundant agricultural waste in the UAE. It is suggested that date pits may be used to produce date pit oil, and the powder residue from this extraction process may be used as a low cost adsorbent for removal of lead from water. This thesis aims to investigate the effects of the parameters pressure, temperature, and particle size on the extraction yield when using supercritical carbon dioxide (SC-CO₂) to extract oil from date pit powder. This oil is a valuable component which has many applications …

Evaluation Of Electrocoagulation For Chloride And Ammonium Removal From The Reject Brine Effluent Pretreated By Solvay Process, Miada Abubaker Ali

Theses

Excessive use of desalination, due to the increase in freshwater demand, results in large productions of reject brine. Therefore, the development of an efficient treatment process of the reject brine becomes vital. The Solvay process is one of the main treatment technologies, wherein NH₃ is introduced to convert soluble Na⁺ into insoluble NaHCO₃. However, in this process, Cl^- is not removed and NH₄⁺ is introduced, and therefore electrocoagulation has been proposed for their removal. The experiment was designed using Minitab with different initial concentrations of chloride (7400 – 32600 mg/l), current densities (0.033 …

Oil Recovery By Surfactant Flooding; Sensitivity Analysis To Technical Parameters And Economic Analysis, Hadel Mohsen Moustafa

Theses

Various enhanced oil recovery methods including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after the primary and secondary recovery have been exhausted. Surfactant flooding is one of the chemical methods that is capable of recovering more oil by decreasing the IFT and/or wettability alteration.This piece of work aims to asses and select the development options using surfactant process that maximize oil recovery for a synthetic reservoir model by optimizing technical and economic analysis.

Reservoir simulation study using ECLIPSE 100 was used to study the different development options of surfactant flooding applied …

Evaluation Of Smart Water Flooding In A Selected Uae Carbonate Oil Reservoir, Mohammad Jasem Khalifi

Chemical and Petroleum Engineering Theses

Water flooding is by far the most common method of improved oil recovery applied in oil reservoirs. Water is the cheapest source of external energy that has been used over decades in water flooding schemes, provided that the damage does not adversely affect its injectivity. Displacement efficiency of water flooding can be significantly affected by crude oil/water/rock interactions. Historically, some consideration was given to such interactions in the practice of reservoir engineering. In recent years, extensive research in this area has documented that higher oil recoveries can be obtained when low-salinity water is injected in a formation with high salinity …

Experimental Investigation Of Co2 Transport Through Combined Membrane Absorber And Regenerator, Nima Mohammadrasool Atbaei

Chemical and Petroleum Engineering Theses

Greenhouse gases such as carbon dioxide have been known to contribute significantly to global warming, which in turn has resulted in serious global environmental problems. Carbon dioxide is the main gaseous contaminant in the atmosphere, representing about 80% of greenhouse gases. It is reported that industry and power plants using fossil fuels such as coal-combustion power generators produce half of the CO₂ emissions. These emissions create the need for low energy-consumption, and efficient technologies for the capture and removal of CO₂ from gas mixtures produced by industrial sources.

Conventional gas absorption processes for the removal of CO_{2 …}

Carbon Dioxide Capture By Steel-Making Residues In A Fluidized Bed Reacto, Suhaib Mohammad Hameedi

Theses

Global warming is one of the most challenging problems facing societies these days, and it is known to be caused by the increasing emissions of Green House Gases (GHG's), mainly CO₂, from various human activities. To solve such a problem, or at least minimize its effects, several actions have been considered. One of these actions is carbon capture, which has many different options and techniques. This research focuses on the capture of CO₂ through reactions with steel-making residues, an alkaline solid by-product of the steel-making process. The aim is to sequester CO₂ and form carbonates, which …

Contact Angle And Ift Measurements Of Smart Water At Elevated Temperatures And Pressures For Evaluating Wettability In A Selected Carbonate Reservoir In The Uae, Jassim Abubacker Ponnambathayil

Theses

Water flooding has been regarded as a well-known secondary oil recovery method. In the recent years, extensive research on crude oil, brine, and rock systems has acknowledged that the composition of the injected water can change wetting properties of the reservoir during a water flood in a promising way to improve oil recovery. Hence, injection of “smart water” with correct salinity and composition is considered as a tertiary recovery method. The mechanism behind wettability alteration that is promoted by smart water injection has been a topic of discussion in carbonate and sandstone formations. In this work, some key properties of …

Oil Recovery By Flooding; Sensitivity Analysis To Technical Parameters, Rana Osama Fahmi Saqer

Theses

Numerous enhanced oil recovery techniques including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after both primary and secondary recovery have been exhausted. Polymer flooding is one of the chemical methods that recover more oil by decreasing the mobility of the system; by increasing the viscosity of the injected water that results in an improvement in the volumetric sweep efficiency.

The objective of this work is to asses and select the development options using polymer process that maximize oil recovery for a synthetic reservoir model where technical parameters are optimized thoroughly.

Reservoir …

Oil Recovery By Polymer Flooding; Sensitivity Analysis To Technical Parameters, Rana Osama Fahmi Saqer

Theses

Numerous enhanced oil recovery techniques including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after both primary and secondary recovery have been exhausted. Polymer flooding is one of the chemical methods that recover more oil by decreasing the mobility of the system; by increasing the viscosity of the injected water that results in an improvement in the volumetric sweep efficiency.

The objective of this work is to asses and select the development options using polymer process that maximize oil recovery for a synthetic reservoir model where technical parameters are optimized thoroughly.

Reservoir …

Optimization Of A Combined Approach For The Treatment Of Desalination Reject Brine And Capture Of Co₂, Ameera Fares Mohammad

Theses

Carbon dioxide (CO₂) is the most widespread greenhouse gas that traps heat and raises the global temperature, contributing to climate change. Existing techniques to sequester carbon dioxide have numerous environmental concerns and usually require an extensive amount of energy. New technologies and methods, such as reactions with desalination reject brine according to the Solvay process, offer new hope for the reduction of carbon dioxide concentration in the atmosphere. Brine management is another environmental concern, as many desalination plants need to find suitable approaches for the treatment or disposal of the large amounts of concentrated brine, resulting from the desalination processes. …

Evaluation Of Electrocoagulation For The Removal Of Chromium (Vi) From Brackish Groundwater, Shaima S Hamdan

Theses

Electrocoagulation (EC) has been evaluated for the removal of Cr (VI) from brackish groundwater using three different bench-scale EC reactors, namely batch stirred tank reactor (BSTR), continuous stirred tank reactor (CSTR) and a continuous electrocoagulation column (ECC). Batch EC process was experimentally examined at room temperature and the results indicated that Fe-Fe electrode pair was the most efficient arrangement and was able to achieve 100 % Cr removal at an electrocoagulation time of 5 minutes, a current density of 7.94 mA/cm², and pH of 8. A kinetic study of batch EC was then performed using both pseudo-first-order and …

Biodegradation Of Cresols Using Pseudomonas Putida Immobilized In Poly Vinyl Alcohol (Pva) Gel, Riham Mohamed Sorkatti Abu Bakr

Theses

The characteristics and viability of polyvinyl alcohol (PVA) as a support material for biomass immobilization and utilization for the biodegradation of cresols have been evaluated. PVA gel pellets were prepared by repeated freezing-thawing method using different PVA compositions. The porous structures of the PVA pellets were examined using a Compound Microscope and SEM and revealed that the matrix structure and pore size distribution were affected by PVA composition. Mechanical properties of the PVA gel were also characterized to evaluate the PVA integrity as a matrix for immobilizing microbial cells and found to be dependent on the PVA mass composition. The …

Physicochemical Characterization Of Safranal-Β-Cyclodextrin Inclusion Complexes Prepared By Supercritical Carbon Dioxide And Conventional Methods., Sanaz Abbaszadegan

Theses

Saffron (Crocus sativus. Linn) has attracted much attention over the last decade because it has a large number of potent and biologically active compounds such as crocin, crocetin, picrocrocin and safranal. Researchers have shown that safranal has high antioxidant and cytotoxicity activities against several types of tumour cells (e.g., hepatocellular carcinoma) both in-vitro and in-vivo. However, the low aqueous solubility of safranal prevents using it as a therapeutic or preventive agent.

β-cyclodextrin (β-CD) inclusion complexes are being used in pharmaceutical applications to alter physicochemical properties (e.g., solubility, volatility, stability, chemical reactivity, and bio-availability) of poorly water soluble drugs. Thus the …

Enzymatic Production Of Biodiesel From Fats Extracted From Lamb Meat Using Supercritical Co2, Hanifa Easa Taher

Theses

Due to the reduction in fossil fuel reserves and associated environmental impacts from using petroleum fuels, biodiesel has been presented as a feasible alternative because it is sustainable and environmentally friendly. In this study, it is proposed to investigate the feasibility of enzymatic production of biodiesel from waste animal fats using supercritical fluid technology for the extraction and reaction. The operating conditions that resulted in the optimum extraction and biodiesel production yield were identified. To the best of my knowledge of the investigators, the waste animal fat extracted by supercritical CO₂ (SC-CO₂) for the production of biodiesel …

Pvt Study Of Selected Uae Reservoir Fluids, Rashid Sher Mohammad

Theses

Phase behavior modeling in crude oil includes prediction of thermodynamic properties (such as saturation pressure, density, viscosity, thermal conductivity, etc.) for the vapor and liquid phases. The aim of phase behavior modeling is to establish the accuracy and reliability of the developed equation of state model to predict various other fluid phase behavior properties at high pressure and temperature conditions.

In the first part of this work, a new and reliable phase behavior apparatus designed in Brazil was used for the two-stage recombination process and phase behavior measurements. The recombination of the surface sample fluids (first-stage separator gas and stock-tank …

Optimization Of Co2 Wag Processes In A Selected Carbonate Reservoir: Laboratory Study, Mohamed Elwy Abdalla Amin

Theses

Miscible gas flooding using carbon dioxide is currently investigated as a possible EOR process for a number of United Arab Emirates (UAE) reservoirs. The major factors affecting the implementation of CO₂ floods are the availability of CO₂ at economic prices and the net utilization ratio of CO₂ per barrel of additional oil recovered.Minimizing net utilization requires controlling the high mobility ratio which causes lower sweep. To control the mobility ratio, the Water-Alternating CO₂-gas (WAG) technique is proposed.

The objective of this work is to experimentally assess the recovery of oil with CO₂ injection in …

Supercritical Co2 Extraction Of Oil From Henna Flower: Experimental, Mathematical Modeling, And Antioxidant Activity, Bushra Saeed Mohammed Dohai

Theses

Henna is a plant that has been used traditionally for coloring nail, skin, and hair, and as medicinal plant. The supercritical fluid technology offers a considerable promise as extraction media due to its advantages over other conventional extraction techniques. The extraction of volatile components from flowers of henna was studied using supercritical carbon dioxide at temperatures and pressures ranging from 35 to 55°C and 80 to 120 bar, respectively. A maximum extraction yield of 31 % from 2g of henna flowers was obtained at 45 °C and 120 bar. The composition of the extracts was investigated by gas chromatography technique. …

Recovery Of Carbon Dioxide From Flue Gases, Fahad Husain Al-Masabi

Theses

In this thesis, the modeling and simulation of the absorption of dilute CO₂ into falling film of aqueous solutions of a sterically hindered amine, 2-anino-2-methyl-1-propanol (AMP), was carried out using COMSOL Multiphysics Version 3.3. The operating cases were divided in two groups: (1) gas turbine operating cases (CO₂ 3 mol %) and (II) boiler operating cases (CO₂ 8.5 mol %). The key operating parameters for the studied cases are CO₂ partial pressure, operating temperature and amine concentration in the aqueous solution. The simulation focused on the following: (1) CO₂ Loading in aqueous AMP solution; (2) …

Carbon Dioxide Capture From Flue Gases, Mohamed Rashid Al Rashid

Theses

Global warming and climate change are believed to be caused by the greenhouse effect. CO₂ has been regarded as the main contributor to global climate change which directly results in serious environmental problems. Half of the anthropogenic CO₂ emission sources are emitted from the combustion of fossil fuels in industries and power plants worldwide. The absorption behavior of Carbon dioxide from flue gases can be studied using conventional absorber and polymeric hollow fiber membrane contractors. An industrial absorber data was compared with simulated data using hollow fiber membrane contractor using the gPROMs software package. In this analysis, with …

Optimum Non Hydrocarbon Gas Injection Development Process And Ultimate Recovery Maximization., Abdulla A.F. Abed

Theses

A multi layered heterogeneous reservoir was selected for this study. The integrated reservoir characterization model and the pertinent transformed reservoir simulation history matched model were quality assured and quality checked.

The development scheme was identified and selected where the pattern and completion of the wells were defined to fit the heterogeneity of the reservoir characterization model. Lateral and maximum block contact holes were investigated.

The development processes studied were mainly hydrogen sulphide, carbon dioxide, nitrogen and rich hydrocarbon gas. The Water Alternating Gas/ Simultaneous Water Alternating Gas (WAG/SWAG) processes were also assured. In addition to the main gas and WAG/SWAG …

Low Salinity Flooding In A Selected Carbonate Reservoir: Experimental Approach, Mohamed Yehia Mohamed Mahmoud

Theses

Low-salinity water flooding LoSal^TM has been used to improve oil recovery for many decades. Historically, the mechanisms behind this improvement in oil recovery were attributed to the pressure maintenance and displacement of oil by injected water, i.e. physical mechanism. Recently, evidence from laboratory and field tests indicated that water flooding also involves chemical processes and that modifying of the injection brine salinity and its ionic composition can significantly impact the oil recovery. Several theories regarding the mechanism of LoSal^TM flooding have been discussed in the literature. These include interfacial tension reduction, wettability alteration (cation exchange), change in pH …