Chemical Engineering Commons^™

Modeling The Thermodynamics Of Butadiene And Carbon Dioxide Coupling Reactions, Alexis Sarantos

Williams Honors College, Honors Research Projects

This project will analyze the synthesis reaction of ethenylated 𝛿-valerolactone (EVL), specifically to determine certain thermodynamic properties of EVL and its coproducts. The thermodynamic properties of the reaction products can then be utilized to make the development of a large-scale process simpler and safer. The properties that will be determined are the heats of formations, heat capacities, and changes in enthalpy caused by each product during the reaction, and these will be used to determine whether the energy produced by the reaction is sufficient to maintain formation of the desired product. Additionally, a process model of heat flows and energy …

Effects Of Soil Properties On Cp Performance, Cecilia Segretario

Williams Honors College, Honors Research Projects

This research aims to evaluate the affect of various soil properties on the effectiveness of cathodic protection (CP) in preventing underground pipeline corrosion. Metal coupons of common pipeline materials with applied CP will be mounted in several separate controlled soil environments to manipulate real world underground corrosion scenarios. Each soil environment will have different physical properties by mixing the soil with a prepared chemical solution. The physical properties to be evaluated include pH, resistivity, and moisture content. At the end of a corrosion duration, weight loss method will be used to evaluate the corrosion rate over that period. Additionally, the …

Effects Of Polyolefin Types On Catalytic Hydrocracking, Kenneth Jackson Seeber

Williams Honors College, Honors Research Projects

Plastic waste recycling has become an important conversation in the last couple of decades with pollution on the rise. One of the few ways to recycle plastics is by breaking these long-chained polymers down via catalytic processes. Due to many plastic products being a blend, it is imperative that any chosen catalyst that could be used for recycling should be able to handle different types of polymers. This paper discusses how tungsten carbide over silica (W_xC/SiO₂) catalyzes the degradation of a few selected polymers and polymer blends. From this research it was determined that W_{x …}

Comsol Simulation Of Pipeline Corrosion With Cathodic Protection, Ethan Scalzo

Williams Honors College, Honors Research Projects

Cathodic protection (CP) is a widely used technique to mitigate corrosion in buried steel pipelines. This study uses COMSOL Multiphysics to model and analyze the performance of both sacrificial anode and impressed current systems in a simulated 3D environment. The model solves for pipeline potential, current density, and corrosion rate within a surrounding soil domain to assess protection coverage across the pipeline. Simulations were conducted to evaluate the influence of electrode and electrolyte properties on CP effectiveness. The study demonstrates that COMSOL Multiphysics is an effective tool for modeling CP systems, offering insights that align with established industry practices. While …

Polystyrene Plastic Waste As An Organic Hydrogen Carrier, Alaina Bachmann

Williams Honors College, Honors Research Projects

The proposed research develops and studies catalytic chemical processes that enables using polystyrene (PS) plastic waste as solid “organic hydrogen carriers” (OHC). Demands for OHCs are driven by desire to alleviate climate change, by replacing carbon-based energy sources with hydrogen. However, hydrogen is highly flammable and difficult to store and transport so OHCs are needed to facilitate its transportation. Common OHCs are liquid petroleum chemicals with unsaturated chemical structures. They can be hydrogenated to store hydrogen and dehydronated to release hydrogen at desired application sites. The proposed research aims to investigate the following cycle: hydrogen storage by hydrogenation of PS …

Quantifying The Effectiveness Of Rhamnolipid As A Biocide: Assessing Comparability Of A Modified Solution, Rosemary Sterling

Williams Honors College, Honors Research Projects

The CO2 induced corrosion of carbon steel in oil and gas pipelines, exacerbated by sulfate-reducing bacteria (SRB), poses a serious threat to infrastructure. This study evaluates the effectiveness of rhamnolipid (RhL), a biosurfactant, as a corrosion inhibitor and potential SRB biocide in simulated pipeline environments. Using a Postgate-C Modified Produced Water Simulant, which demonstrated electrochemical behavior comparable to industry-standard solutions while sustaining SRB, corrosion trials were conducted with and without RhL. Mass loss and electrochemical data revealed that RhL significantly reduced corrosion rates—by 85% on average and up to 99% instantaneously in a 4-day trial. Visual and analytical results from …

Optimized Pi Compound Mixing Strategy, Cecilia Mainzer

Williams Honors College, Honors Research Projects

The project focuses on developing an optimal mixing strategy for a polyisoprene (PI) compound at the Goodyear Tire & Rubber Company. The aim is to optimize performance objectives of the compound. The project involved research, design iterations, mixing analyses, and performance evaluations, while adhering to engineering codes and standards.

The design process includes analyzing differences between two mixing technologies, intermesh and tangential rotors; altering mixing conditions; and exploring additional polymer systems and coupling technology of the compound.

Validation data confirms that the mixing technology and compound recipe meets all success metrics, including stiffness, hysteresis, adhesion, cure rate, and tear performance …

Alloy Corrosion Resistance Project, Noah Gourley

Williams Honors College, Honors Research Projects

This Honors Research Project aims to determine the material performance of two metal alloys – 316L and Alloy 20CB-3 – in terms of corrosion resistance. The project will answer the following research questions: What effect do phosphoric acid and heptanoic acid solutions have on the passive film of 316L and Alloy 20CB-3 metal alloys? How do the metal alloys resist corrosion under flow conditions of the acids? What is the viability of these alloys to be used in a chemical process involving these acids?

Effects Of Energy Drink Additives On Crayfish Metabolism, Katherine Paltz

Williams Honors College, Honors Research Projects

The effects of caffeine and additives commonly found in energy drinks were tested on crayfish to record changes, if any, in their metabolism. Three experimental groups were studied: 1. Caffeine; 2. Caffeine + Glucuronolactone; 3.) Caffeine + Glucuronolactone + Taurine. Caffeine is a common stimulant used to improve mental awareness, headaches, memory, and athletic performance. Glucuronolactone is connected with cardiovascular issues and aggressive behavior. Taurine is said to improve mood and focus. The experiment was performed at two different caffeine levels: 600mg and 1200mg for an initial 1 hour of exposure and 10 hours after exposure used as a pseudo-baseline. …

Wetting Transition Of 3d-Printed Surface Features, Delia Weitzel

Williams Honors College, Honors Research Projects

This project aims to build on the previous research of prior students in the study of the wetting transition of a textured, 3D-printed surface. The surfaces studied will be constructed by a resin printer in the lab and will be composed of an array of uniform, microscopic pillars. Features of the textured surface, such as pillar diameter, pillar spacing, and pillar height, will be varied to study the impact on the wetting transition of water, oil, and a combination of water and oil. The wetting transition is defined as a transition from a state where the surface cavities are occupied …

The Effects Of Relative Humidity And Valency On Water Absorption And Structure In Polyelectrolyte Brushes, Andrea Klima

Williams Honors College, Honors Research Projects

The purpose of this project was to understand the relationship between relative humidity, ion valency, and the structure of water on positively (PMETAC) and negatively (PSPMA) charged polyelectrolyte brushes. The polyelectrolyte brushes were synthesized using Activators Regenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP) and were soaked in concentrations containing 0.1 M of the target counterion. The brushes were then exposed to humid vapor, and spectra were collected in 5% intervals between 0% and 85% for each counterion. Two trials were completed for each counterion studied to ensure agreement between datasets. In all spectra, peaks appeared for the …

Schaeffler Icvd Coating Machine, Louis Mcgrath

Williams Honors College, Honors Research Projects

Chemical Vapor Deposition (CVD) is mutual technology used to deposit thin film through a gaseous phase by vaporizing the solid materials. This conventional process usually requires high thermal stability of the materials, which is not applicable for most of the polymeric materials. Therefore, a novel process, initiated Chemical Vapor Deposition (iCVD) is developed by introducing the gaseous monument and initiator to form the thin film in-situ. By adjusting the free-radical polymerization in the vapor phase, a variety of thin and uniform polymer films can be achieved. Depending on the chemistry, iCVD has many categories. This report explains the design …

Degradable Staples And Delivery Device, Meha Elango, Jessica Cabrera, Makayla Scarpitti, Kareemat Melaiye

Williams Honors College, Honors Research Projects

The scope of this project is to design a method to secure skin grafts to healthy tissue. The ultimate goal for the proposed method is to be dissolvable in some form. Currently, skin grafts procedures utilize staples in most cases to hold a skin graft in place, but there are disadvantages that come with it. Staples are easy to place, but time consuming during the removal procedure. They also cause a lot of pain and discomfort for the patient. The goal of this project is to determine a way a secure skin grafts to healthy skin in order to reduce …

Assessing Co2 Capture On Amine Sorbents At Low Vacuum Swing Conditions, Brock Haas, Payton Taylor

Williams Honors College, Honors Research Projects

Carbon dioxide (CO2) emissions to Earth's atmosphere have increased rapidly in recent decades largely due to growing fossil fuel use in human-led activities The research contained in this proposal assesses a way to capture CO2 concentration in the atmosphere. The project studies the effectiveness of a vacuum swing adsorption (VSA) process for capture of CO2 from air. CO2 will first be adsorbed by introducing an amine sorbent to a CO2-rich environment for a predetermined period. The amine sorbent will be placed in a VSA unit that will operate at the desorption stage. The sorbent will then be sent to a …

Design Of An Experimental Solid Rocket Motor, Johnathan Bettes, Andrew Fuller

Williams Honors College, Honors Research Projects

This project utilizes mechanical and chemical principles to characterize propellant grains and to manufacture a custom nozzle to create experimental Solid Rocket Motors (SRMs) with a propellant called Angry Listerine. For the propellant grains, one major non-chemical factor that determines its thrust performance is the grain geometry, or the core of the grains for which hot gases flow through the propellant and out of the nozzle to further react with exposed chemical surfaces. The two kinds of grain geometries analyzed and tested in this report are called MoonBurner, an offset circular core, and Finocyl, a gear-shaped core. The nozzle for …

Causational Analysis And Rectification Of Issues Concerning Scale Formation On Hot-Rolled Straight Bar Product And Its Effects On Ultrasonic Testing, Riley Mattix

Williams Honors College, Honors Research Projects

At Charter Steel's NDT Processing Plant located in Cleveland, Ohio, a concern has arisen regarding the recently implemented bar straightening and UT (Ultrasonic Testing) equipment. A substantial amount of mill scale, which is typically removed during the straightening process, is persisting on the bar’s surface throughout most of the NDT procedure. This lingering scale has been observed to flake off once inside the UT equipment, introducing unwanted noise and phantom peaks into the UT readings. Additionally, thick mill scale has been identified as a source of background interference in the received data. In contrast, bars that have been subjected to …

Construction Composites Of Recycled Pvc And Recycled Polyolefins, Natalie Prusovic

Williams Honors College, Honors Research Projects

Current construction composites are typically only composed of polyvinyl chloride (PVC) and recycled PVC (rPVC). This proposed project will investigate if recycled polyethylene (rPE) and polypropylene (rPP) can be used instead of PVC in those materials. Different compositions of rPE, rPP, and rPVC blends will be compounded and a T-peel test will be performed to test the adhesion.

Exploring Natural Raw Materials For The Development Of Hot Melt Adhesives For Linings Of Paintings, Erica Factor

Williams Honors College, Honors Research Projects

Natural raw materials will be explored for developing hot melt adhesives for the lining of paintings. The leading raw material is a natural resin called "Damar". This resin is obtained from the tree family Dipterocaupocea in India and Southeast Asia. This material has shown promising results from initial testing. Damar, with the potential for other natural raw materials, will be combined with synthetic ingredients to create sustainable formulations. The formulations will be tested on linen to replicate the application onto paintings. The sustainability, tackiness, texture, and overall performance of each formula will be considered. Once a formulation has been selected, …

Determination Of Spore Viability In Concrete Across Several Factors Using Most Probable Number, Samuel Boyer

Williams Honors College, Honors Research Projects

To determine the lowest concentration of spore added to polyurethane-cement composite (PUCCO) particles that can still germinate after curing in concrete. This research project is a small addition to the larger research project being undertaken by Mirza Mohammed Rashiduzzaman for his Masters. The larger project involves the use of fungal spores added in concrete to act as a self-healing component when cracks form in the concrete structure over time. These spores are suspended in a protective oil and loaded into small, hardened sponge-like PUCCO cubes to act as growth points when water and air can reach the PUCCO in the …

Removal Of Residual Stress In 3d Printed Polymers, Christian Jenkins

Williams Honors College, Honors Research Projects

This project aims to investigate the relationship between stress relaxation and the reduction of dimensional shrinkage and warping in 3D printed polymers produced through fused filament fabrication. The hypothesis suggests that residual stress in 3D printed structures results from factors such as temperature differences, molecular-level contributions, and rapid cooling, causing post-printing warpage and damage. To mitigate these issues, the project proposes annealing 3D printed polymers in a hot sandbath to allow stress relaxation without warping. The study will employ a Dynamic Mechanical Analysis (DMA) machine to assess mechanical properties of relaxed and unrelaxed samples, comparing their effectiveness. The project's timeline …

Aggregation-Induced Emission Probe For Alzheimer's Detection And Treatment Screening, Gemini Ramlo

Williams Honors College, Honors Research Projects

The proposed project is to research if ROF-2, an aggregation-induced emitter, can be used to screen medications for Alzheimer's Disease and to accurately detect this disease, along with its progression. This will be done through multiple incubation periods using different identifiers that have already been solidified within Alzheimer's research to prove its ability and accuracy within screening and detection regarding this disease.

Comparing Weathering Effects Of Ultraviolet And Xenon Arc Accelerated Aging On Polyvinyl Chloride, Collin Mcinnes

Williams Honors College, Honors Research Projects

As the ubiquitousness of polymers increases and begins seeing use in outdoor settings, the need to fully understand how these materials degrade is also necessary. This study aims to compare two known accelerated aging methods, namely an ultraviolet light chamber and a xenon arc light chamber, to understand what differences, if any, manifest in the mechanical, chemical, and cosmetic deterioration of polyvinyl chloride (PVC) after long-term exposure. The study utilizes Fourier-transform infrared spectroscopy, dynamic mechanical analysis, thermogravimetric analysis, and colorimetry analysis to determine the extent of degradation and potential discrepancies between the aging methods.

Distillery, Clare Nicholas, Patrick Hanlon

Williams Honors College, Honors Research Projects

The goal for this project is to make a cost effective still. We will be implementing cost saving parts to create a cheap but effective still. From initial research conducted, we will try to combine a stainless steel still and copper still together so that the cheaper material (stainless steel) and the component that removes sulfur compounds (copper) are both implemented. The ME side of the project will focus on the actual design and construction of the parts that will be implemented into the still. Included in the design process will be calculations of heat transfer for the current and …

Running Shoe Pedometer, Benjamin Kasper

Williams Honors College, Honors Research Projects

Running shoe pedometer aims to solve the issue of worn out running shoes. It can be difficult to know just how many miles you have run in your shoes and when a new pair is needed. Running in old shoes and worn out shoes is heavily linked to injury. My proposed project is a device that is powered by the compressive forces on the shoes soles that counts the number of steps the wearer takes using a microcontroller. Then, when the shoe reaches milestone that indicate it has been used 75% 90% and 100% of its expected life, it will …

Beeswax Wraps As An Alternative To Single-Use Plastics, Sarah Skiver

Williams Honors College, Honors Research Projects

The project goal was to compare the food storage efficacy of sustainable beeswax wraps verses the single-use plastic methods of resealable plastic sandwich bags and plastic cling wrap. The goal was also to test the reusability of the beeswax wraps, as it is a key advantage of beeswax wraps that is advertised. The project purpose was to explore sustainable and eco-friendly alternatives to single use plastics, which are harmful to the environment in both their production and their disposal. Food spoilage was compared in beeswax wrap, plastic sandwich bags, and plastic cling wrap, and spoilage was also observed in a …

Structural Design And Application Of Polymeric Silicon Elastomers, Jacob Wyant

Williams Honors College, Honors Research Projects

The purpose of this project was to determine how the polymeric structure and mechanical properties of this elastomer are affected by the ratio between the polydimethylsiloxane macromolecular chains and the crosslinkers. These were determined via tensile and compression testing. Then, spiropyran was added to observe how this fluorescence and crosslinking agent affected the elastomer. Also, the elastomer’s fluorescent and icephobic nature were tested. The elastomers with a higher ratio of crosslinker to macromolecular chain could withstand higher tensile and compressive strains but failed at lower stresses than their counterparts with lower concentrations of crosslinkers. The elastomers were also found to …

Teflon Replacement In Pans, Teodora Neamtu

Williams Honors College, Honors Research Projects

The purpose of the project is to determine an optimal prepping method of common cooking oils for pans that will be as effective as Teflon non-stick pans. The reason for this is to replace Teflon coating in pans, which can be very toxic for humans and the environment. Teflon has been a common coating for non-stick surfaces that is useful when cooking things such as eggs. To determine an optimal cooking method, three different oils were used: olive oil, vegetable oil, and shortening. The oils were tested on an aluminum pan by cooking egg whites at various temperatures, cooking times, …

Analysis Of Plastic Pyrolysis Oil Separation Using Chemcad, Brian Berish, Juliana Mcgaffic

Williams Honors College, Honors Research Projects

Excessive plastic waste is a massive global issue. Plastic pyrolysis is a process of melting plastic in the absence of oxygen to create an wax-oil type substance called pyrolysis oil. This project will use a ChemCAD simulation to perform a distillation of a predetermined plastic pyrolysis oil into usable products. Heat integration will be used to construct a heat exchanger network and estimate utility usage. Sizing and costing of all equipment will be calculated and an overall cost analysis of the completed simulation will be performed to determine the economic viability of plant construction. Market research for potential products will …

Level And Temperature Controlled Vessel, Cameron Macesich

Williams Honors College, Honors Research Projects

Using two Arduino microcontrollers, level and temperature Proportional-Integral control systems for a continuously stirred tank reactor were designed and configured. Open-loop step tests were performed and fitted with First Order Plus Time Delay responses so that controller tuning parameters could be analytically derived. The effectiveness of the designed systems was evaluated by monitoring the response of closed-loop setpoint changes.

Defining The Proper Operating Time For The Septa Extractor, Abigail Jones

Williams Honors College, Honors Research Projects

Anionic polymerizations are a common type of reaction used to produce synthetic rubber. During these reactions, it is necessary to charge initiators, modifiers, and other substances, through pressurized containers that are sealed with rubber septa. These septa prevent oxygen and moisture from entering the pressurized container, and the reactor, though they need to be cleaned before use to remove other impurities. Currently a glass Soxhlet Extractor is used to remove such impurities, and though effective, it has a limited capacity, so it has to run frequently. This limitation led to the commissioning of the Septa Extractor, which is an automated …