Chemical Engineering Commons^™

Drag Reduction In Newtonian Polymer Solutions, Harry C. Hershey

Doctoral Dissertations

"Prior work in the area of drag reduction has been mainly limited to aqueous solutions. Theoretical and empirical analyses of the resulting data in aqueous solutions have been hindered by the fact that some polymers cause drag reduction and others do not...This investigation was directed to the study of how the size and configuration of the polymer molecule in solution affected drag reduction and the related phenomenon of turbulence suppression. Apparatuses were designed and built to measure viscometric flow, curves, friction factors, velocity profiles, and normal stresses (by a jet thrust technique developed by Metzner and associates)"--Summary, page 1-2.

Correlation Of Chemical Structure And Distensibility Of Polyesters., Nitin Jhaverbhai Bhimani

Masters Theses

"Maleic anhydride and fumaric acid are important raw materials for the manufacture of unsaturated polyesters. Unsaturated polyesters are the esterification products of unsaturated dibasic acids and polyvalent alcohols, polymerized to a high molecular weight resin"--Introduction, p. 1

The Prediction Of The Viscosity Of Multi-Component Non-Polar Gaseous Mixtures At Atmospheric Pressure., Gary D. Fehsenfeld

Masters Theses

"The applicability of the Strunk, Custead, and Stevenson method for predicting the viscosities of multicomponent, non-polar, gaseous mixtures vas investigated. The viscosities of 24 ternary and quaternary gaseous mixtures were experimentally determined, at 3 temperature levels, and compared with the corresponding calculated viscosities resulting from the prediction method. In addition, the published viscosities of 64 multicomponent mixtures were compared with the corresponding calculated viscosities.

Altogether, the viscosities of 136 multicomponent, non-polar, gaseous mixtures were compared. The mixtures contained from 3 to 7 components including 16 different gases in the temperature range from 5• to 1014 ° c, and at a …

A Study Of Turbulent Mass Transfer In A Wetted-Wall Column, David William Bunch

Doctoral Dissertations

"The field of mass transfer is one of great interest to the chemical engineer. An understanding of this field is vital in the design of many types of chemical processing equipment, particularly in the areas of distillation, extraction, absorption, adsorption, and reactor analysis and design.

However, much of the knowledge in this area at the present time is in the form of empirical relationships, and the basic theory is still not well delineated. This lack of understanding leads to expensive and over-sized or under-sized equipment.

A particular area within this field which needs additional investigation is the theory of mass …

A Study Of The Eddy Diffusivity In Turbulent Heat Transfer, Frank Fu-Kun Tao

Doctoral Dissertations

"The purpose of this investigation was to determine the eddy thermal diffusivity values as a function of radial position at various Reynolds numbers for a fluid flowing turbulently in a pipe. The ratios of the eddy thermal diffusivity and the eddy viscosity were also investigated.

A vertical column of copper tube two inches in diameter was constructed which consisted of an entrance section for the development of the velocity profile and a heating section for the development of the temperature distribution. The heating section was jacketed and maintained at a constant wall temperature at about 103 ° F by the …

A New Method For The Evaluation Of Metal Primers., Bhalchandra Dave

Masters Theses

"Corrosion is the destructive attack of metal by chemical or electrochemical reaction with its environment. Rusting is usually the term applied to the corrosion of iron-base alloys with formation of corrosion products consisting largely of hydrous ferric oxides. Non-ferrous metals therefore, corrode but do not rust. ^(l4) More than 40 per cent of the world's production of steel and iron is destroyed by rusting which costs about six billion dollars every year. In 1954 the American Petroleum Industry, Subcommittee on Corrosion, published a preliminary estimate that corrosion was costing 2 the petroleum refining industry between eleven and nineteen cents per …

The Anodic Dissolution Of Cadmium In Aqueous Solution, Yun-Chung Sun

Masters Theses

"The increasing importance of prevention of corrosion in industry has stimulated extensive studies on the fundamental behavior of metals in corrosive media.

The basic mechanism of the anodic dissolution of metals such as cadmium, magnesium, and zinc in salt solutions is not completely known. Several mechanisms have been proposed by different investigators, but evidence is still lacking to draw unquestionable conclusions to explain the discrepancies which often arise between coulometric data and weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for anodic dissolution of cadmium in various electrolytes and …

A Study Of The Phase Behavior Of Carbon Dioxide-Methane-Normal Decane Systems, Raja Audi Mansoor

Masters Theses

“The effect of carbon dioxide concentration, on solubility has been studied for several carbon dioxide-methane-n-decane systems. Experimental results were obtained using differential vaporization tests. Computational results were obtained using equilibrium constants.

The relation between solubility, bubble point pressure and solution carbon dioxide is presented. A ternary diagram showing the bubble point pressure behavior as a function of system composition is also presented”--Abstract, page ii.

Study Of Mass Transfer In Oscillating Droplets., Subhash Vishnu Gangal

Masters Theses

"The object of this investigation was to study the resistance to mass transfer inside single oscillating liquid droplets falling in a liquid medium. The following four systems were studied: (1) 3% acetic acid in nitrobenzene and water, (2) 25% acetic acid in nitrobenzene and water, (3) 3% acetic acid in nitrobenzene and glycerin in water, and (4) benzyl alcohol and water. The individual mass transfer coefficients were computed by using the Handlos and Baron relation and were compared with the experimentally determined dispersed phase mass transfer coefficients. The average absolute deviation of the observed values of dispersed phase mass transferred …

Separation Of Cationic And Colloidal Fractions Of Radioactive Fission Elements By Electrodialysis., Ronald Dean Mitchell

Masters Theses

"The rapid increase in radioisotope applicat i ons necessitates improved technology for separation and purification of the fission product elements. Electrodialysis techniques employing Permutit anion exchange membranes (3148) and cation exchange membranes (3142) were used to separate strontium from cesium and to fractionate cerium from promethium. The methods were based upon organic complex formations in basic solution.

Separations of radio strontium and radio cesium were affected with both anion and cation exchange membranes in a three-cell electro dialyzer with EDTA as a chelating agent at a pH of 11.0o Fractionation of radiocerium and radio promethium were affected with anion exchange …

The Prediction Of The Thermal Conductivity Of Various Binary Non-Polar Gaseous Mixtures., Chester Foon-Chen Feng

Masters Theses

"A simple method for predicting the thermal conductivity of binary non-polar gaseous mixtures from the force parameters of the pure components and composition was developed. The method is an extension of the application of the combining methods previously derived for viscosity predictions. Altogether, the published thermal conductivities of 683 binary non-polar mixtures at various temperature levels were compared with the corresponding calculated thermal conductivities resulting from the prediction method. The corresponding values predicted from Hirschfelder, Curtiss and Bird's expression were also compared.

Among the 683 binary mixtures, there were 138 di-di, di-poly, and poly-poly mixtures, 241 mono-

A Study Of The Separation Of A Mixture Of Carbon Dioxide And Hydrogen By Means Of An Orifice., Larry Gene Bauer

Masters Theses

"The purpose of the investigation was an attempt to verify a statement made by Partridge in an effort to discover a new method of separating gaseous mixtures. Partridge stated that when a constant pressure is applied on two gases of different specific gravity, a larger volume of the l igl1ter gas is forced through the orifice. Orifices of 1.016, 0.319, and 0.222 millimeter in diameter were used in the course of the investigation.

It was found that with the apparatus used in the research endeavor, no separation of the mixture of hydrogen and carbon dioxide could be obtained"--Abstract, p. i

The Dissolution Of Deformed Magnesium In Sulfuric Acid., William J. Daniels

Masters Theses

"The negative difference effect exhibited by magnesium while anodically dissolving in saline solutions has been attributed in part by Kokoulina and Kabanov to the expulsion of univalent magnesium ions ^{1, 2}. Recent experimenters have discounted the concept of the anodic expulsion of uncommon valency ions and have explained both the positive and negative difference effects observed for magnesium in dilute acids on the basis of anodic polarization, film disruption, and disintegration of the magnesium anode, i.e. "chunk effect"^{3, 4}.

The purpose of this present investigation was to study the difference effect for deformed magnesium in a dilute …

The Indole Acetic Acid Oxidase Of Hygrophorus Conicus., Dilip N. Patel

Masters Theses

"The purpose of this investigation was to determine an assay method for measuring the activity of the indole acetic acid oxidase present in Hygrophorus conicus. This enzyme converts tryptamine or indole acetic acid (IAA) into oxindole acetic acid (OIAA).

An assay method for measuring the activity of the enzyme was developed based on the spectrophotometric measurement of tryptamine, IAA, and OIAA. Several other assay methods were tried. The colorimetric method of Gordon and Weber ^(l4) was found to be useful for a quantitative determination of IAA and was insensitive to OIAA. Paper chromatography proved to be useful as a qualitative …

The Removal Of Residual Organic Materials From Sewage Plant Effluents Using Continuous Foam Flotation., Ajab S. Malik

Masters Theses

"This investigation was conducted to determine the feasibility of using a continuous foam flotation process for the removal of soluble organic materials from sewage treatment plant effluents. All effluents contained alkyl benzene sulfonates (ABS), derived from synthetic detergents. The studies were conducted on a laboratory scale. The reduction in the chemical oxygen demand was used as a measure of the effectiveness of the removal of the organic materials. In addition, ABS determinations were employed to study the fate of the detergent.

A flotation cell, equipped with the means of controlling the air and liquid flow rates, was used. Air flow …

Mass Transfer To Droplets: Effect Of Non-Newtonian Continuous Phase., Hsin Chih Wu

Masters Theses

"Since non-Newtonian fluids are frequently encountered in the chemical and process industries, it is important that the transport processes which are commonly encountered be thoroughly investigated. Although studies of fluid mechanics and heat transfer with these fluids have been reported, virtually no work has been reported in the study of mass transfer. This is particularly true of mass transfer in turbulent flow.

The purpose of this investigation is to study the liquid-liquid mass transfer phenomenon in turbulent flow associated with single droplets in non-Newtonian continuous phases. The results are compared with those obtained in Newtonian systems. The data obtained will …

Design, Construction And Characterization Of A 10-Liter Batch Pilot Plant Fermentor., Sylvester Ogden

Masters Theses

"A 10-liter batch type pilot plant fermentor has been designed and constructed. The design incorporated most of the desirable features of previous designs reported in the literature.

The stainless steel fermentor has a multi-speed agitator and aeration rates as high as 15 cubic feet per hour. Temperature indicating, temperature controlling, pH measuring, and automatic foam controlling systems are included in the design.

Sulfite oxidation rates have been determined for the unit at 15 operating conditions. A maximum sulfite oxidation rate of 1060 millimoles of oxygen per liter per hour has been obtained.

Fermentation using a Torulopsis utilis yeast culture has …

The Submerged Culture Of Thiobacillus Thio-Oxidans In A Pilot Scale Fermentor, Edward Hibbert Crum

Masters Theses

"A strain of Thiobaci.llus thiooxidans was isolated from a West Virginia coal mine drainage. This strain was characterized by its production of sulfuric acid in shake flasks. The strain was also compared with a pure culture of h thiooxidans obtained from the American Type Culture Collection (ATCC number 8085).

The strain was grown in submerged culture in a 16-liter pilot scale fermenter. Two aeration systems, air and air enriched with carbon dioxide, were examined. The air enriched with carbon dioxide gave a much more rapid growth rate. The culture reached the mid-log phase of growth after 80 hours of incubation …

The Anodic Dissolution Of Zinc In Nitrate Solution., Jo Lisle Reed

Masters Theses

"The increasing demand for protective metals as coatings and non-corrosive alloys has stimulated extensive research on the fundamental behavior of metals in corrosive media.

One of the problems still unsolved is the nature of the mechanism of the anodic dissolution of metals like zinc, magnesium, beryllium, cadmium, and aluminum in aqueous salt solutions. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometric data and the weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for the anodic dissolution of zinc …

The Removal Of Abs From Tap Water Solutions And Sewage Plant Effluents At Various Air Rates Using Continuous Foam Flotation., Ratan F. Daboo

Masters Theses

"This investigation was performed to study the removal of Alkyl Benzene Sulfonate (ABS) from tap water solutions and sewage treatment plant effluents by continuous foam flotation and to determine the effect of the air flow rate on the removal.

A flotation cell provided with controlled air and liquid flow rates was used for the continuous process. Air flow rates between zero and 29.4 cubic feet per hour were investigated. A liquid feed flow rate of 120 milliliters per minute was used for most of the experiments with one run made at 60 milliliters per minute. The liquid samples were analyzed …

The Performance Of A Mechanically-Aided Countercurrent Extraction Column., Jerry James Carr

Masters Theses

"In recent years liquid extraction has become a major industrial method for the separation of liquid solutions. Liquid extraction has proven successful in some separations performed only with great difficulty by other, more common mass-transfer operations. Th e industrial utilization of liquid extraction has resulted in considerable interest in the design and performance correlations of high-capacity, high-efficiency extraction equipment.

Continuous countercurrent columns, filled with various packings, baffles, and plates, have been found to be relatively ineffective in liquid extract on service. The density difference of the contacted phases is generally insufficient to, by itself, cause the intimate contact necessary for …

Permeability Of Organic Protective Coatings And Relation To Film Thickness, Bipin N. Doshi

Masters Theses

“Special types of coating systems are used to protect industrial products and structures against corrosion. Many millions of dollars are spent each year for these coatings. The ability of protective coatings to reduce or inhibit corrosion depends on a variety of factors such as dry film thickness, resistance to permeation of ions and vapors, temperature, pressure, structure of binder, nature of pigment, electrolytic resistance, and many others.

The initial work done by Larry Inglis on the permeability of coatings and it's relation to thickness of coating films showed that the permeability, as determined by under film corrosion, was independent of …

Permeability And Adsorbed Flow Of Carbon Dioxide And Propene Through Porous Silica., Jorgen Lovland

Masters Theses

"It has been known for over a century that gases diffuse through some porous barriers at a rate inversely proportional to the square root of the molecular weight. The difference in diffusion rate can obviously be used to separate gases with different molecular weight. Since other methods for separation like distillation and adsorption usually are simpler and cheaper, separation by gaseous diffusion has found few practical applications. One notable exception is the separation of the gaseous hexafluorides of u²³⁸ and u²³⁵.

Later investigations on the permeation of gases through porous materials have shown that when gases diffuse …

Viscosities Of Various Binary Non-Polar Gaseous Mixtures., Gerald Lee Stevenson

Masters Theses

"Viscosity is an important physical property involving the transport of momentum in a fluid. Momentum is transferred within a fluid under an existing velocity gradient as the driving force. Since momentum transfer is actually attained by the dynamic interaction between particles of mass, a description of molecular interaction is essential in order to accurately predict the viscosity of a fluid. Temperature affects fluid viscosity by increasing the kinetic energy of the fluid system and thus the frequency by which molecules are involved in interaction. There have been many theoretical studies made concerning the intermolecular potential energy statements which serve as …

Development Of A Technique For The Determination Of Capillary Pressure Curves Using A Constantly Accelerated Centrifuge, Robert N. Hoffman

Masters Theses

"A new technique for determining capillary pressure curves with a centrifuge has been developed and tested. Capillary pressure curves were determined for six cores by this technique and were compared to the curves for the same cores determined by the semi-permeable barrier technique. The technique differs from previously reported centrifuge techniques in that the centrifuge was slowly accelerated from zero to the maximum desired speed, rather than being held constant at particular, progressively higher speeds. An important advantage of this technique over other methods for determining capillary pressure curves is the short time required to obtain the desired amount of …

The Separation Of Strontium-90 From Cesium-137 And Fractionation Of Rare Earth Elements By Liquid-Liquid Extraction., Surendra D. Khanna

Masters Theses

No abstract provided.

A Study Of The Dissolution Of Titanium-Oxygen-Nitrogen Alloys In Hydrofluoric Acid, Arliss V. Martin

Doctoral Dissertations

"The purpose of this investigation was to study the effect of oxygen and nitrogen (in the alpha solid solution range) on the kinetics and electrochemistry of titanium dissolution in hydrofluoric acid. Dissolution rates, activation energies, difference effects, and potential measurements were determined with TiO_XN_Y sintered alloys and sheet metal. Values of x ranged from 0.01 to 0.126 and values of x. from 0.001 to 0.230.

Dissolution rates were determined using a gas evolution technique. Temperatures were varied from 5 to 45°C. The hydrogen evolution rates were converted to TiO_XN_Y dissolution rates by means of …

Separation Of Radioactive Fission Products By Electrodialysis Using Aminopolycarboxylic Acids., Harry C. Hershey

Masters Theses

"The development of nuclear fission reactors to convert nuclear energy into electrical energy for use in industry, public utilities, military applications, and space exploration has resulted in ever increasing quantities of radioactive waste solutions. Significant reductions in nuclear fuel costs will be obtained when economical processes have been developed for recovery and purification of valuable fission products which are contained in radioactive waste solutions and are in demand for many research applications.

The United States Atomic Energy Commission has supported exhaustive studies to recover fission products by processes involving the more common unit operations such as extraction, distillation, crystallization, and …

The Construction And Evaluation Of A Small Scale Laboratory Fermentor For Batch And Continuous Studies., Robert Murray Logan

Masters Theses

"The purpose or this investigation was to design and construct a suitable apparatus for the aerobic culture or microorganisms to be used for preliminary batch studies and eventually, continuous fermentations.

The general design of the apparatus was patterned after small scale equipment described in the literature. Construction or the apparatus was carried out in the shop of the Department of Chemical Engineering and Chemistry. All of the necessary machining was done by the author.

The aeration-agitation system was evaluated by the use or the sulfite oxidation rate determination. The oxygen transfer rate provided by the apparatus was round to be …

Effects Of Gamma Radiation On Ion Exchange Membranes., John R. C. Roop

Masters Theses

No abstract provided.