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Articles 961 - 990 of 2020
Full-Text Articles in Chemical Engineering
Strong Stability Of A Class Of Difference Equations Of Continuous Time And Structured Singular Value Problem, Qian Ma, Keqin Gu, Narges Choubedar
Strong Stability Of A Class Of Difference Equations Of Continuous Time And Structured Singular Value Problem, Qian Ma, Keqin Gu, Narges Choubedar
SIUE Faculty Research, Scholarship, and Creative Activity
This article studies the strong stability of scalar difference equations of continuous time in which the delays are sums of a number of independent parameters τi, i = 1, 2, . . . , K. The characteristic quasipolynomial of such an equation is a multilinear function of e−τis. It is known that the characteristic quasipolynomial of any difference equation set in the form of one-delay-per-scalar-channel (ODPSC) model is also in such a multilinear form. However, it is shown in this article that some multilinear forms of quasipolynomials are not characteristic quasipolynomials of any ODPSC difference equation set. The equivalence between …
Conical Folds -- An Artifact Of Using Simple Geometric Shapes To Describe A Complex Geologic Structure, Avery Joseph Welker
Conical Folds -- An Artifact Of Using Simple Geometric Shapes To Describe A Complex Geologic Structure, Avery Joseph Welker
Masters Theses
"Accurate representation of the 3D shapes of natural folds is essential to characterization of the dynamic models for fold formation. Geometrical analysis of folds commonly relies upon analyzing patterns defined by the variation in the orientation of poles to planar surfaces deformed by a shortening event when plotted using graphical calculators (e.g., stereogram, polar tangent diagrams) to interpret the shape of folds. Stereograms for which orientation data define small circles are classified as non-cylindrical regular folds and are interpreted as "conical folds," where the shape of the fold is represented by a cone that terminates at a point. Utilizing similar …
Single-Site Catalyst Promoters Accelerate Metal- Catalyzed Nitroarene Hydrogenation, Liang Wang, Erjia Guan, Jian Zhang, Junhao Yang, Yihan Zhu, Yu Han, Ming Yang, Cheng Cen, Gang Fu, Bruce C. Gates, Feng-Shou Xiao
Single-Site Catalyst Promoters Accelerate Metal- Catalyzed Nitroarene Hydrogenation, Liang Wang, Erjia Guan, Jian Zhang, Junhao Yang, Yihan Zhu, Yu Han, Ming Yang, Cheng Cen, Gang Fu, Bruce C. Gates, Feng-Shou Xiao
Faculty & Staff Scholarship
Atomically dispersed supported metal catalysts are drawing wide attention because of the opportunities they offer for new catalytic properties combined with efficient use of the metals. We extend this class of materials to catalysts that incorporate atomically dispersed metal atoms as promoters. The catalysts are used for the challenging nitroarene hydro- genation and found to have both high activity and selectivity. The promoters are single-site Sn on TiO2 supports that incorporate metal nanoparticle catalysts. Represented as M/Sn- TiO2 (M = Au, Ru, Pt, Ni), these catalysts decidedly outperform the unpromoted supported metals, even for hydrogenation of nitroarenes substituted with various …
Pressure-Driven Stabilization Of Capacitive Deionization, Landon S. Caudill
Pressure-Driven Stabilization Of Capacitive Deionization, Landon S. Caudill
Theses and Dissertations--Mechanical and Aerospace Engineering
The effects of system pressure on the performance stability of flow-through capacitive deionization (CDI) cells was investigated. Initial data showed that the highly porous carbon electrodes possessed air/oxygen in the micropores, and the increased system pressure boosts the gases solubility in saline solution and carries them out of the cell in the effluent. Upon applying a potential difference to the electrodes, capacitive-based ion adsorption occurs in competition with faradaic reactions that consume oxygen. Through the addition of backpressure, the rate of degradation decreases, allowing the cell to maintain its salt adsorption capacity (SAC) longer. The removal of oxygen from the …
Characterization Of Rotary Bell Atomizers Through Image Analysis Techniques, Jacob E. Wilson
Characterization Of Rotary Bell Atomizers Through Image Analysis Techniques, Jacob E. Wilson
Theses and Dissertations--Mechanical and Aerospace Engineering
Three methods were developed to better understand and characterize the near-field dynamic processes of rotary bell atomization. The methods were developed with the goal of possible integration into industry to identify equipment changes through changes in the primary atomization of the bell. The first technique utilized high-speed imaging to capture qualitative ligament breakup and, in combination with a developed image processing technique and PIV software, was able to gain statistical size and velocity information about both ligaments and droplets in the image data. A second technique, using an Nd:YAG laser with an optical filter, was used to capture size statistics …
Targeting Metastatic Breast Cancer With Statin Drugs And Coq10, Jacob Thrasher
Targeting Metastatic Breast Cancer With Statin Drugs And Coq10, Jacob Thrasher
Honors Theses
Statin drugs are commonly prescribed to lower cholesterol levels in patients, but recently statins have been under investigation as a potential anti-cancer drug. Statins are HMG-CoA reductase inhibitors and subsequently inhibit the mevalonate pathway and cholesterol synthesis. Since cholesterol trafficking is vital in the growth and metastasis of cancer, statin drugs are being studied to explore their effects on cancer cells. CoQ10, one of the products from the mevalonate pathway, also has shown some potential anti-cancer properties, but its use to combat cancer is controversial. While some studies have shown that CoQ10 supplements can be synergistic with other cancer treatment …
O-Glcnac Post Translational Modification Of Hypoxia-Inducible Factor (Hif) Proteins, Hailey Elisabeth Grisham
O-Glcnac Post Translational Modification Of Hypoxia-Inducible Factor (Hif) Proteins, Hailey Elisabeth Grisham
Honors Theses
O-linked β-N-acetylglucosamine (O-GlcNAc) post-translational modification (O- GlcNAcylation), plays a vital role in many metabolic pathways, including those of numerous diseases. New research methods and basic functional roles of O-GlcNAc post- translational modification on metabolism, human health, and cancer are quickly developing, but a vast amount of research remains on the specificity of this pathway towards specific proteins. In this study, T47D breast cancer cells were used as an in vitro model to investigate the effects of O-GlcNAc modification on hypoxia-inducible factor (HIF) proteins.
Interfacial Corrosion Of Copper And The Formation Of Copper Hydroxychloride, Mary Teague, Shengxi Li, Hongbo Cong
Interfacial Corrosion Of Copper And The Formation Of Copper Hydroxychloride, Mary Teague, Shengxi Li, Hongbo Cong
Williams Honors College, Honors Research Projects
Electrical circuitry is an industry, among many others, heavily using the element of copper. Ensuring the mechanical integrity of Cu is crucial, especially in salt environments, for the multifaceted composition of circuits. 4N NaCl solution (equilibrium concentration in ~84% RH) simulated this three-phase system. Rectangular Cu samples were partially immersed in both ambient and continuous lab air sparging atmospheres to understand waterline corrosion of the metal. Open circuit potentials (OCP) were continuously taken during the immersion testing for a maximum of 5 days. A scanning electron microscopy (SEM) equipped with an energy dispersive X-ray spectrometer (EDS), Raman spectroscopy, and 3-D …
Tandem Mass Spectrometry (Ms/Ms) For Determination Of Architecture Of Synthetic Polymers, Shoumik Saha
Tandem Mass Spectrometry (Ms/Ms) For Determination Of Architecture Of Synthetic Polymers, Shoumik Saha
Williams Honors College, Honors Research Projects
Tandem Mass Spectrometry (MS/MS) was used to determine the architecture of synthetic polymers and they are difluorene-N3, 3-difluorene-N3 and VPOSS-3-difluorene. VPOSS materials usually exhibit electrochemical properties and the research was performed to determine their accurate structure and to provide evidence of their proper synthesis. The compounds were mixed with a matrix solution, DCTB, and a silver salt to enable proper protonation. The solvent mixture was on a MALDI plate and then put into the mass spectrometer. The mass spectrum generated was analyzed and each fragment was identified to structures with the synthetic polymers via ChemDraw. Thus, trial …
Characterization Of The Cylinderical Split Internal-Loop Photobioreactor With Scenedesmus Microalgae: Advanced Culturing, Modeling, And Hydrodynamics, Laith S. Sabri
Doctoral Dissertations
"Microalgae are fast growing photoynthetic microorganisms and it have very wide range of industrial applications such as biofuels and wastewater treatment. These cells can be grown in a wide variety of systems ranging from open culture systems (e.g., ponds) to closed culture systems of photobioreactor (e.g., airlift). The open culture systems exist in the external environment, and hence, are not intrinsically controllable. However, the microalgae production in enclosed photobioreactors faces prohibitively high production costs with special difficulty in reactor design and scale-up. The light availability and utilization efficiency in the photobioreactor in terms of design and scale-up consider as the …
Integrated Study On The Applicability Of Co₂-Eor In Unconventional Liquids Rich Reservoirs, Dheiaa Khafief Khashan Alfarge
Integrated Study On The Applicability Of Co₂-Eor In Unconventional Liquids Rich Reservoirs, Dheiaa Khafief Khashan Alfarge
Doctoral Dissertations
"Unconventional Liquids Rich Reservoirs (ULR) such as Bakken, Niobrara, and Eagle Ford have become the main target for oil and gas investors as conventional formations started to deplete and diminish in number. These unconventional plays have a huge oil reserve; however, the predicted primary oil recovery is still low as an average of 7.5 %. Unconventional Improved Oil Recovery (UIOR) techniques are still a new concept in the oil industry because there is no commercial project for any IOR technique so far. Injecting carbon dioxide (CO₂) might be the most potential strategy to improve oil recovery in such complex plays. …
Developing A 3d In Vitro Model By Microfluidics, Hung-Ta Chien
Developing A 3d In Vitro Model By Microfluidics, Hung-Ta Chien
Dissertations and Theses
In vitro tissue models play an important role in providing a platform that mimics the realistic tissue microenvironment for stimulating and characterizing the cellular behavior. In particular, the hydrogel-based 3D in vitro models allow the cells to grow and interact with their surroundings in all directions, thus better mimicking in vivo than their 2D counterparts. The objective of this thesis is to establish a 3D in vitro model that mimics the anatomical and functional complexity of the realistic cancer microenvironment for conveniently studying the transport coupling in porous tissue structures. We pack uniform-sized PEGDA-GelMA microgels in a microfluidic chip to …
An Integrated Method For Forecasting Well Deliverability In Gas Condensate Reservoirs With Bottom Aquifer Drive, Abdulaziz Ellafi, Ralph E. Flori, Shari Dunn-Norman
An Integrated Method For Forecasting Well Deliverability In Gas Condensate Reservoirs With Bottom Aquifer Drive, Abdulaziz Ellafi, Ralph E. Flori, Shari Dunn-Norman
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Gas condensate reservoirs constitute a significant portion of global hydrocarbon reserves. In these reservoirs, liquids develop in the pore space once bottomhole pressure falls below dew point. This results in the formation of a liquid bank near the wellbore region which decreases gas mobility, which then reduces gas inflow. In such complex reservoirs, it is important to correctly describe PVT impacts, adjustments to well test analysis and inflow performance, and then combine all effects in the reservoir analysis. The literature contains many references to individual adjustments of PVT analysis, well testing, or inflow performance for gas condensate reservoirs, but few …
Learning From Experience: An Automatic Ph Neutralization System Using Hybrid Fuzzy System And Neural Network, Ethar H.K. Alkamil, Seaar Al-Dabooni, Ahmed K. Abbas, Ralph Flori, Donald C. Wunsch
Learning From Experience: An Automatic Ph Neutralization System Using Hybrid Fuzzy System And Neural Network, Ethar H.K. Alkamil, Seaar Al-Dabooni, Ahmed K. Abbas, Ralph Flori, Donald C. Wunsch
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
In oil and gas industry, the pH level is one of the most important indicators of mud contamination while drilling. Although the process has simple components, the pH neutralization process is complicated in the mud circulation system. This difficulty is due to the high nonlinearity of the process. In this paper, the fuzzy neural network (FNN) is integrated to the fuzzy logic controller (FLC) to create a system which identifies pH fluctuation into a drilling mud system, assesses and signals its severity. And then, it automatically actuates a chemical treating fluids valve (CTFV), such as Caustic Soda (CS), for neutralizing …
Solvent And Concentration Effects Governing The Hierarchical Organization Of Asphaltenes: A Small-Angle X-Ray Scattering Study, Hasan Rejoanur Rahman
Solvent And Concentration Effects Governing The Hierarchical Organization Of Asphaltenes: A Small-Angle X-Ray Scattering Study, Hasan Rejoanur Rahman
Open Access Theses & Dissertations
Asphaltenes are a group of planar molecules found in crude oil and are prone to aggregation which often causes blockage of pipes along the oil production stream resulting a huge economic downside. In an effort to understand the hierarchical organization of asphaltene in different solvents and concentrations, the solution structure of various asphaltene solutions were studied using small-angle x-ray scattering (SAXS). Solvents were chosen based on miscibility maps. Such maps are generated on the critical value of the solubility parameter difference between asphaltenes or asphaltene components, and a range of solvents. The critical factors that affect asphaltene and asphaltene component …
Analyzing The Spectral Energy Cascade In Turbulent Channel Flow, João Rodrigo Andrade, Ramon Silva Martins, Gilmar Mompean, Laurent Thais, Thomas B. Gatski
Analyzing The Spectral Energy Cascade In Turbulent Channel Flow, João Rodrigo Andrade, Ramon Silva Martins, Gilmar Mompean, Laurent Thais, Thomas B. Gatski
CCPO Publications
An analysis of the spectral turbulent kinetic energy budget in a fully developed turbulent plane channel flow is performed. Direct numerical simulation data are evaluated at friction Reynolds numbers Reτ of 180 and 1000. The analysis is focused on the influence of the Reynolds number on the spectral cascade of energy and the corresponding energy cascade in physical space in the presence of inhomogeneity and anisotropy. The turbulent kinetic energy distribution is compared for both Reynolds numbers, and the relevant characteristics of the energy transfer process in a wall-bounded turbulent flow are described. Differences in energy cascade are noted …
Miscible Gases Based Eor In Unconventional Liquids Rich Reservoirs: What We Can Learn, Dheiaa Alfarge, Mortadha Alsaba, Mingzhen Wei, Baojun Bai
Miscible Gases Based Eor In Unconventional Liquids Rich Reservoirs: What We Can Learn, Dheiaa Alfarge, Mortadha Alsaba, Mingzhen Wei, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Over the last decade, Unconventional Liquids Rich Reservoirs (ULR) have become the main target for oil and gas investors as conventional formations started to deplete and diminish in numbers. These unconventional plays have a huge oil reserve; however, the primary oil recovery factor is predicted to be less than 10%. Unconventional Improved Oil Recovery (UIOR) techniques are still a new concept in the oil industry since there is no commercial project reported for any IOR technique yet. Miscible gas based EOR technique might be the most potential strategy to improve oil recovery in such complex plays. In this study, a …
Advanced Ion Management To Improve Oil Recovery In Oil-Wet Carbonate-Sandstone Composite Reservoirs, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Waleed H. Al-Bazzaz
Advanced Ion Management To Improve Oil Recovery In Oil-Wet Carbonate-Sandstone Composite Reservoirs, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Waleed H. Al-Bazzaz
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Waterflooding with different ionic composition called advanced ion management which play a role with ionic composition of injected water to enhance the oil production. In the last decade, many studies pointed out that the composition of injected water could changes rock wettability during waterflooding. The main purpose of this study is to evaluate the effects of SO4 and low salinity water on improving oil recovery in oil-wet carbonate reservoirs. Sulfate ion concentration, low salinity water, rock composition, porosity, and permeability were examined using a designed model. Typical seawater, increase SO4, two and three times in the seawater, and …
New Insights Of Low Salinity Water Flooding In Low Permeability-Low Porosity Clay Rich Sandstone Reservoir, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Waleed H. Al-Bazzaz
New Insights Of Low Salinity Water Flooding In Low Permeability-Low Porosity Clay Rich Sandstone Reservoir, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Waleed H. Al-Bazzaz
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
One of the EOR technologies is low-salinity water flooding (LSWF) is an EOR method that operates at a lower cost than other EOR methods, which makes it a preferred area of interest for oil industry economists, who continue to call for EOR costs to come down. The aim is to minimize the possible cost to recover as much oil as possible. The performance of low salinity waterflooding in decreasing residual oil saturation in low permeability-porosity clay-rich sandstone reservoir. Porosity test, core flooding test, XRD and scanning electron microscopy (SEM) tests were achieved in this study. Salinity effect on the porosity, …
Application Of Integrated Reservoir Geomechanics For Well Planning Of High-Angled Wells In A Mature Oil Field, Ahmed K. Abbas, Ralph E. Flori, Yousif M.B. Al-Asadi, Mortadha Alsaba, Nasser A. Al-Hamad
Application Of Integrated Reservoir Geomechanics For Well Planning Of High-Angled Wells In A Mature Oil Field, Ahmed K. Abbas, Ralph E. Flori, Yousif M.B. Al-Asadi, Mortadha Alsaba, Nasser A. Al-Hamad
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Zubair oil reservoir has a significant potential to contribute to the petroleum supply in Iraq. Drilling highly deviated wells is a commonly used approach to enhance the production in mature fields. Drilling these wells in the Zubair Formation has been a challenge due to severe wellbore instability issues. This study presents how integrated reservoir geomechanics was used for efficient well planning and safe drilling of nearly horizontal wells (75° Inclination) through Zubair depleted sandstone oil reservoir. In this study, an integrated workflow was implemented mainly to build a geomechanical model using offset well data. The in-situ principal stresses and their …
Using Managed Pressure Drilling To Reduce Stuck Pipe Problem, Ethar H.K. Alkamil, Husam R. Abbood, Ralph E. Flori, George Medley, Sagar Nauduri, Mortadha Alsaba
Using Managed Pressure Drilling To Reduce Stuck Pipe Problem, Ethar H.K. Alkamil, Husam R. Abbood, Ralph E. Flori, George Medley, Sagar Nauduri, Mortadha Alsaba
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Differences between mud pressure in a wellbore and pore pressure in high permeability rocks can lead to differential sticking, particularly when drilling deviated wells and encountering mud losses. Several solutions, all challenging, can be used to address this problem, where the conventional mitigation method of managing the mud weight (MW) is often used. However, managed pressure drilling (MPD) offers a promising solution with a positive risk-adjusted cost and other benefits. Wells in the E oilfield in southern Iraq are typically drilled overbalanced and therefore often experience a high percentage of non-productive time (NPT) due to differential sticking. This study evaluates …
A Novel Ultra-Low Interfacial Tension Nanofluid For Enhanced Oil Recovery In Super-Low Permeability Reservoirs, Derong Xu, Baojun Bai, Ziyu Meng, Qiong Zhou, Zhe Li, Yao Lu, Hairong Wu, Jirui Hou, Wanli Kang
A Novel Ultra-Low Interfacial Tension Nanofluid For Enhanced Oil Recovery In Super-Low Permeability Reservoirs, Derong Xu, Baojun Bai, Ziyu Meng, Qiong Zhou, Zhe Li, Yao Lu, Hairong Wu, Jirui Hou, Wanli Kang
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
The exploration and development of super-low permeability reservoirs have become a global focus in recent years. However, conventional flooding systems commonly face problems of high injection pressure and poor displacement efficiency in super-low permeability reservoirs. Thus, it is imperative to find new flooding agents that tackle such problems. In this study, a novel ultra-low interfacial tension (IFT) nanofluid was formulated, consisting of surfactants to achieve ultra-low IFT and silica nanoparticles to reduce injection pressure. The compatibility test between the surfactants and silica nanoparticles in 10,000 mg/L NaCl solution at 90 °C was conducted to ensure their adaption to harsh reservoir …
Testing And Evaluation Of Shale Stability For Zubair Shale Formation, Ahmed K. Abbas, Ralph E. Flori, Ahmed Al-Anssari, Mortadha Alsaba
Testing And Evaluation Of Shale Stability For Zubair Shale Formation, Ahmed K. Abbas, Ralph E. Flori, Ahmed Al-Anssari, Mortadha Alsaba
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Zubair Formation consists of approximately 55% shale, which causes almost 70% of wellbore problems due to incompatibilities of drilling fluids and shale formations. The most common and effective solution to shale instability is through the design and selection of drilling fluids. Understanding the interaction between drilling fluids and shale has been a challenge due to the complexity of both physical and chemical variations in shale formations. This paper presents some of the important laboratory and well-site testing techniques that are often used by mud engineers for characterizing and remediating drilling fluids and shale interaction. Well-preserved shale samples were analyzed to …
Electroactivities Of Pd/Fe3O4-C Catalysts For Electro-Oxidation Of Methanol, Ethanol And Propanol, Tao Zou, Qing-Feng Yi, Yuan-Yuan Zhang, Xiao-Ping Liu, Guo-Rong Xu, Hui-Dong Nie, Xiu-Lin Zhou
Electroactivities Of Pd/Fe3O4-C Catalysts For Electro-Oxidation Of Methanol, Ethanol And Propanol, Tao Zou, Qing-Feng Yi, Yuan-Yuan Zhang, Xiao-Ping Liu, Guo-Rong Xu, Hui-Dong Nie, Xiu-Lin Zhou
Journal of Electrochemistry
Development of palladium (Pd) catalysts with high electroactivity for alcohol oxidation is significant for alcohol fuel cells. In this work, Pd nanoparticles were formed by sodium borohydride (NaBH4) reduction method and subsequently deposited on the surface of carbon supported ferriferrous oxide (Fe3O4/C) composites to obtain the Pd/Fe3O4-C catalysts with different Fe3O4 loadings. Their transmission electron microscopic (TEM) images show that the Pd nanoparticles were uniformly dispersed on the Fe3O4/C. Electroactivities of the prepared Pd/Fe3O4-C catalysts toward oxidations of C1-C3 …
Cobalt-Based Nitrogen-Doped Carbon Non-Noble Metal Catalysts For Oxygen Reduction Reaction, Meng-Xiu Jiang, Jing Zhang, Yue-Hua Li, Rong Zhang
Cobalt-Based Nitrogen-Doped Carbon Non-Noble Metal Catalysts For Oxygen Reduction Reaction, Meng-Xiu Jiang, Jing Zhang, Yue-Hua Li, Rong Zhang
Journal of Electrochemistry
Transition metal-nitrogen co-doped carbon catalysts have attracted significant attention because of their reasonable activity and remarkable selectivity toward oxygen reduction reaction (ORR) as cathodic reaction in fuel cells. However, the role of transition metal in the active sites of the catalysts still is uncertain. In this work, the Cox-Ny/C-T catalysts were prepared with BP2000 as a carbon source, urea (Ur) as a nitrogen source and Co(OAc)2•4H2O as a metal precursor by a simple chemical method. Meanwhile, in order to optimize the ORR activity, the catalysts were synthesized with different amounts of Co …
Core-Shell Pd@Pt Ultrathin Nanowires As Durable Oxygen Reduction Electrocatalysts, Xin Wang, Yun-Jie Xiong, Liang-Liang Zou, Qing-Hong Huang, Zhi-Qing Zou, Hui Yang
Core-Shell Pd@Pt Ultrathin Nanowires As Durable Oxygen Reduction Electrocatalysts, Xin Wang, Yun-Jie Xiong, Liang-Liang Zou, Qing-Hong Huang, Zhi-Qing Zou, Hui Yang
Journal of Electrochemistry
This paper describes a simple CO-assisted reduction approach for the controllable synthesis of ultrathin Pd nanowires along the one-dimensional (1D) direction. Ultrathin Pt films from one to several atomic layers were successfully decorated onto ultrathin Pd nanowires by utilizing Cu UPD deposition, and followed by in-situ redox replacement reaction of UPD Cu by Pt. The core–shell structure and composition of the Pd@Pt ultrathin nanowires have been verified using transmission electron microscopy and energy dispersive X-ray spectrometry. The core–shell Pd@Pt ultrathin nanowires exhibited comparative electrocatalytic activity and improved durability for the oxygen reduction reaction in comparison with commercial Pt black. The …
Effect Of Fe2+/Fe3+Interconvertion On Reduction Behavior Of Fe3+ In Acidic Electrolytes, Jian-Xin Qin, Feng Lin, Wen-Ping Liu, Chao Chen, Meng-De Ren
Effect Of Fe2+/Fe3+Interconvertion On Reduction Behavior Of Fe3+ In Acidic Electrolytes, Jian-Xin Qin, Feng Lin, Wen-Ping Liu, Chao Chen, Meng-De Ren
Journal of Electrochemistry
The influences of ferrous/ferric (Fe2+/Fe3+) interconvertion on electrochemical reduction and electrode reaction of Fe3+ were investigated by using linear sweep voltammetry, potentiostatic method and cyclic voltammetry (CV) in acidic electrolytes containing chloride ion (Cl-) and sulfate ion (SO42-). It was shown that the reduction process of Fe3+/Fe2+ would take place in two independent stages: (1) the reduction of Fe3+ to Fe2+ at E=0.35V and (2) the co-precipitation of Fe2+ by forming Fe(OH)2 (E≤-0.3 V) instead of Fe. The major effect of Fe2+ …
Kinetics And Mechanism Toward Electrochemical Reductions Of Sodium Bromide And Methanol Over Iron Electrodes, Qun Liao, Shu-Feng Zhang, Wen-Hua Leng
Kinetics And Mechanism Toward Electrochemical Reductions Of Sodium Bromide And Methanol Over Iron Electrodes, Qun Liao, Shu-Feng Zhang, Wen-Hua Leng
Journal of Electrochemistry
It is of technological value and scientific interest to the electro-synthesis of ferrocene, conversion of carbon dioxide (CO2) and organic electro-synthesis in non-aqueous solutions by investigating the kinetics and mechanism toward electrochemical reductions of sodium bromide (NaBr) and methanol over iron electrodes. However, few reports in the related researches are available. In this article, the kinetics and mechanism toward electrochemical reductions of NaBr and methanol over iron electrodes were examined in detail by carrying out the polarization curve and electrochemical impedance spectroscopic measurements. The results showed that methanol was the reactant, while Na+ ions were functioned only …
An Application Of M-Matrices To Preserve Bounded Positive Solutions To The Evolution Equations Of Biofilm Models, Richard S. Landry Jr.
An Application Of M-Matrices To Preserve Bounded Positive Solutions To The Evolution Equations Of Biofilm Models, Richard S. Landry Jr.
LSU New Orleans Theses and Dissertations
In this work, we design a linear, two step implicit finite difference method to approximate the solutions of a biological system that describes the interaction between a microbial colony and a surrounding substrate. Three separate models are analyzed, all of which can be described as systems of partial differential equations (PDE)s with nonlinear diffusion and reaction, where the biological colony grows and decays based on the substrate bioavailability. The systems under investigation are all complex models describing the dynamics of biological films. In view of the difficulties to calculate analytical solutions of the models, we design here a numerical technique …
The Role Of Catalytic Residue PKA On The Hydrolysis/Transglycosylation Partition In Family 3 Β-Glucosidases, Inacrist Geronimo, Christina M. Payne, Mats Sandgren
The Role Of Catalytic Residue PKA On The Hydrolysis/Transglycosylation Partition In Family 3 Β-Glucosidases, Inacrist Geronimo, Christina M. Payne, Mats Sandgren
Chemical and Materials Engineering Faculty Publications
β-Glucosidases (βgls) primarily catalyze the hydrolysis of the terminal glycosidic bond at the non-reducing end of β-glucosides, although glycosidic bond synthesis (called transglycosylation) can also occur in the presence of another acceptor. In the final reaction step, the glucose product or another substrate competes with water for transfer to the glycosyl-enzyme intermediate. The factors governing the balance between the two pathways are not fully known; however, the involvement of ionizable residues in binding and catalysis suggests that their pKa may play a role. Through constant pH molecular dynamics simulations of a glycoside hydrolase Family 3 (GH3) βgl, we …