Chemical Engineering Commons^™

Hydrogen Generation From Ammonia Borane And Water Through The Combustion Reactions With Mechanically Alloyed Al/Mg Powder, Daniel Rodriguez

Open Access Theses & Dissertations

Finding and developing a safe and effective method for hydrogen storage is integral to its use as an alternative source of energy. The goal of the studies described in this Thesis was to investigate the feasibility of developing combustible hydrogen-generating compositions based on ammonia borane and novel energetic materials such as nanocomposite and mechanically alloyed reactive materials, recently obtained by Prof. Edward Dreizin's team at the New Jersey Institute of Technology (NJIT). Such compositions could be stored for long time and release hydrogen on demand, upon ignition. The first phase of the research included thermodynamic calculations for combustion of ammonia …

A Circuit-Based Algorithm For Two-Phase Flow At The Pore Scale In Porous Media, Todd Dorethy

Open Access Theses & Dissertations

Models of two-phase flow in porous media are of practical interest in many fields of science and engineering such as in oil recovery and hydrology. For this class of problem, an immiscible fluid is injected into a single-phase, porous medium to evict its valuable, native fluid. Because the aim is to amass as much of the indigenous fluid as possible, models attempt to output reliable flow regime patterns depicting how well the invading fluid displaces the native fluid.

Flow regime patterns generally depend upon the geometry of the domain, stimulation at the boundaries, and properties of the invading and native …

Electrospinning Applications Air Filtration And Superhydrophobic Materials, Negar Ghochaghi, Adetoun Taiwo

Graduate Research Posters

Electrospinning is a widely applicable technique that generates non-woven fibers in the micro and nano range. In this project two of its applications are highlighted namely filtration media and enhancement of wettability. The first project demonstrates that electrospinning can be used to produce new fiber filtration media with controlled microstructure. The bimodal and unimodal orthogonal and random filters were made and characterized against their filtration efficiency and pressure drop. Figure of Merit (FOM) was also calculated and discussed. It is shown that the FOM increases when the electrospun fibers are arranged into alternating layers of aligned course and fine fibers. …

Modelling Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell System, Wayne Doherty

Doctoral

Biomass is of major interest as a renewable energy source in the context of climate change and energy security. Traditional biomass conversion technologies achieve low electrical efficiencies. Biomass gasification (BG) coupled with fuel cells offer higher efficiencies. Gasification is a process in which a carbonaceous fuel is converted to a combustible gas. It occurs when a controlled amount of oxidant is reacted at high temperatures with available carbon in a fuel within a gasifier. Two technologies (circulating fluidised bed air gasification and dual fluidised bed steam gasification) were modelled. Solid oxide fuel cells (SOFCs) are well suited to integration with …

Synthesis Of Tungsten Oxide Nanowires Onto Ito Glass Using T-Cvd, Tomy Abuzairi, Bohr-Ran Huang, Tzu-Ching Lin

Makara Journal of Technology

Tungsten oxide is an n-type semiconductor with interesting physical and chemical properties that make it suitable for various technological applications. Tungsten oxide nanowires were synthesized not only at low temperature but also without the use of any catalysts. The tungsten oxide nanowires were synthesized at 550 °C with tungsten layers onto the ITO glass using thermal chemical vapor deposition (T-CVD). The SEM image shows that the tungsten oxide nanowires are effectively grown with the 200 nm tungsten film. The Raman spectra shoulder at ~690 cm-1 proves the synthesized of tungsten oxide nanowires.

Radiation Characteristics Of A Planar Strip Dipole Antenna And A Slot Dipole Antenna For Thz Applications, Catur Apriono, Eko Tjipto Rahardjo

Makara Journal of Technology

The development of a THz system often requires a device that is used to radiate or detect THz waves. One way to fulfill this requirement is to use an antenna. Therefore, we need to consider the radiation characteristics of an antenna working in the THz region. In this paper, we present simulation study of two dipole antennas, i.e. a planar strip dipole antenna and a slot dipole antenna. The simulation results show that a planar strip dipole antenna has a better radiation efficiency (more than 95%) compared to the slot dipole. It also shows that an efficiency of more than …

The Effect Of Pressing Temperature And Time On The Quality Of Particle Board Made From Jatropha Fruit Hulls Treated In Acidic Condition, Apri Heri Iswanto, Fauzi Febrianto, Yusuf Sudo Hadi, Surdiding Ruhendi, Dede Hermawan

Makara Journal of Technology

The high of pH of jatropha fruit hulls causes the negative properties of particleboard made from this material. Adjusting the particle acidity and pressing conditions (temperature and time) is among the technical modifications available to improve this particleboard’s properties. Particle acidity has been adjusted in a previous research project, and immersing the particles in acetic acid was found to be the best treatment in this preliminary research. In order to improve the particleboard’s properties, an experiment was conducted to determine the best pressing temperature and time. The objective of the research was to evaluate the influence of pressing temperature and …

Microgrid Development Using A Grid Tie Inverter, Hartono Budi Santoso, Budiyanto Budiyanto

Makara Journal of Technology

The use of renewable energy sources (RES), especially photovoltaic (PV), to meet the demand of electrical energy has been getting a great deal of attention as an alternative solution to electrical energy deficit problems. RES are being applied in power systems in a variety of configurations including microgrid systems. One of the characteristics of a microgrid is capability to supplying power to grid when there is an excess power to supply local load. This research examines the chances of saving power consumption from grid using power converters grid tie inverter (GTI) in a microgrid configuration. The test is done by …

Surface Treatment Of Fly Ash For Improving The Tensile Strength Of Fly Ash/Unsaturated Polyester Composites, Sugiman Sugiman, Paryanto Dwi Setyawan

Makara Journal of Technology

The paper presents the surface treatment of fly ashes using acid and alkali solution on the tensile strength of the fly ash/unsaturated polyester (UP) composites. Sulfuric acid (H2SO4), hydrofluoric acid (HF) and sodium hydroxide (NaOH) solution with concentration of 0%, 5%, 10%, 15%, and 20% (by weight) were used for surface treatment of fly ashes. Generally, the tensile strength of the treated fly-ash/UP composites shows a significant increase compared to the untreated fly ash. Of all surface treatments studied, the optimum tensile strength was obtained at a concentration of 10%. At this concentration, at a fly ash content of 30% …

Recycling Roof Tile Waste Material For Wall Cover Tiles, Ambar Mulyono, Silfia Mona Aryani, Joko Lulut

Makara Journal of Technology

Prior research on roof tile waste treatment has attempted to find the appropriate technology to reuse old roof tile waste by create wall cladding materials from it. Through exploration and experimentation, a treatment method has been discovered to transform the tile fragments into artificial stone that resembles the shape of coral. This baked clay artificial stone material is then processed as a decorative element for vertical surfaces that are not load-bearing, such as on the interior and exterior walls of a building. Before applying the fragments as wall tiles, several steps must be taken: 1) Blunting, which changes the look …

Semiconductor Thermal Neutron Detector, Toru Aoki, Aki Miyake, Takayuki Nakano, Akifumi Koike, Hisashi Morii, Hidenori Mimura

Makara Journal of Technology

The CdTe and GaN detector with a Gd converter have been developed and investigated as a neutron detector for neutron imaging. The fabricated Gd/CdTe detector with the 25 mm thick Gd was designed on the basis of simulation results of thermal neutron detection efficiency and spatial resolution. The Gd/CdTe detector shows the detection of neutron capture gamma ray emission in the 155Gd(n, g)156Gd, 157Gd(n, g)158Gd and 113Cd(n, g)114Cd reactions and characteristic X-ray emissions due to conversion-electrons generated inside the Gd film. The observed efficient thermal neutron detection with the Gd/CdTe detector shows its promise in neutron radiography application. Moreover, a …

Advanced Visualization Techniques Of Hot-Jet Combustion Of Lean And Ultra-Lean Substances, Timothy I. Machin, Li Qiao

The Summer Undergraduate Research Fellowship (SURF) Symposium

Research has been conducted on ignition of natural gas as a potential replacement for fossil fuels. A reason natural gas is not widely used and adapted is because of the harmful emissions created when combusted in rich mixtures, but if the gas can be burned at a lean or ultra-lean equivalence ratio, these emissions can be reduced or even eliminated. One method of burning lean and ultra-lean substances is by use of hot-jet ignition. This method ignites the substance near its combustion temperature, reducing the harmful emissions. This method is not yet fully understood, and so research must be done …

Dna Based Carbon Nanotube Porphyrin Nanohybrids Molecular Recognization And Regeneration, Molly M. Riccitelli, Hanyu Zhang, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

In the search to improve solar cells, scientists are exploring new materials that will provide better current transfer. One material that has emerged as a strong contender is the single walled carbon nanotube (SWNT). Current DNA-SWNT based films combined with chromophores have poor operational lifetimes compared to commercial solar cells. Once exposed to light the chromophore begins to degrade, eventually rendering the solar cell unusable. To solve this problem, we used a method involving multiple steps. First we found which DNA sequences formed structures around the SWNT that could hold the most chromophores by using a spectrophotometer to test the …

Experimental Study Of Co2 Recycling Using Metal-Oxide Enhanced Coconut Char Gasification: Catalytic Effect Of Potassium Carbonate On Gasification, Mengqi Gao, Indraneel Sircar, Jay P. Gore

The Summer Undergraduate Research Fellowship (SURF) Symposium

Biomass gasification is an important process in the production of bio-derived fuels and renewable energy. Biomass gasification with CO₂ is an endothermic process requiring high temperatures, resulting in low process-efficiency. Metals found in the ash in biomass feedstock have shown rate-promoting effects on the C-CO₂ reaction and have motivated the study of low-temperature catalytic gasification. The present study investigates the catalytic effects of potassium (K) on the biomass gasification reactivity of a coconut-derived char (>99.9% carbon) within the temperature range of 600 – 1000 ^oC. A wet-impregnation technique is used to prepare K-treated chars. Gasification of …

Low Volume Dispensing With High Speed Dispensers, Sunny Agarwal

Graduate Dissertations and Theses

With the high pace of innovation in the semiconductor manufacturing industry, there has been an increasing demand for more energy efficient and environmental friendly products. This research relates to a complex process of fluid dispensing at low volumes on a printed circuit board. Currently, a more refined non-contact dispensing terminology named “Streaming” is widely used to stream out material at low volumes for various applications. The key solution is to frame a dispensing method that lends itself most closely to the requirements of a specific production process.

This study represents a detailed approach of dispensing low volumes of materials in …

The Effect Zeolite Addition In Natural Rubber Polypropylene Composite On Mechanical, Structure, And Thermal Characteristics, Nurdin Bukit, Erna Frida

Makara Journal of Technology

This study was conducted to determine the effect of zeolite as filler on mechanical properties, and thermal structure blends of natural rubber and polypropylene (NR/PP). In this study, NR/PP/PP-g-MA blends was filled uncalcined zeolite and calcined zeolite at different weight percent of the 2, 4, and 6%. Samples were characterized to determine the tensile strength, fracture elongation and Young's modulus. Structure of the samples was investigated using XRD method and thermal characteristics were analyzed using DTA/TGA technique. The results obtained for tensile strength showed a significant influence with the addition zeolite of the NR/PP blends at 2% by weight of …

The Plasma Electrolysis Phenomenon In A Two-Compartment Reactor For Chlor-Alkali Production, Nelson Saksono, Fakhrian Abqari, Setijo Bismo

Makara Journal of Technology

Chlor-alkali is one of the most important processes in the chemical industry. It produces chlorine and caustic soda, which become the main feedstock of daily products. The aim of this study is to report the phenomenon of plasma electrolysis and how it can be used in chlor-alkali production for more efficient energy consumption. When the plasma is formed, the current fluctuates and gradually declines. Plasma electrolysis begins with the process of electrolysis itself. Due to Joule heating, gas bubbles are formed and a sheath is made on both electrodes, resulting in the plasma field. Plasma electrolysis can be identified by …

Determining The Air Gap Length Of An Axial Flux Wound Rotor Synchronous Generator, Abdul Multi, Iwa Garniwa, Uno Bintang Sudibyo

Makara Journal of Technology

The air gap length of the designed axial flux wound rotor (AFWR) synchronous generator is determined properly according to the design parameters. One of the distinct advantages of an axial flux (AF) machine is its adjustable air gap. An AF generator’s performance might be controlled by adjusting its air gap. The designed generator has a smallscale capacity that has 1 kW, 380 V, and 50 Hz. The windings are laid into slots made from laminated core. The slots are carved in the face of the stator and rotors. The generator has a single-double-sided slotted wound stator sandwiched between twin rotors. …

Characteristics Of Vacuum Freeze Drying With Utilization Of Internal Cooling And Condenser Waste Heat For Sublimation, Muhammad Idrus Alhamid, Nasruddin Yusuf, Indra Teuku Meurah Mahlia, Engkos Ahmad Kosasih, Muhamad Yulianto, Rio Ricardi

Makara Journal of Technology

Vacuum freeze drying is an excellent drying method, but it is very energy-intensive because a relatively long drying time is required. This research investigates the utilization of condenser waste heat for sublimation as a way of accelerating the drying rate. In addition, it also investigates the effect of internal cooling combined with vacuum cooling in the pressure reduction process. Jelly fish tentacles were used as the specimen, with different configurations for condenser heat waste and internal cooling valve opening. The results show that heating with condenser heat waste can accelerate the drying rate up to 0.0035 kg/m2.s. In addition, pre-freezing …

A New Experimental Approach To Evaluate Plasma-Induced Damage In Microcantilever, Yuki Nishimori, Shinji Ueki, Masakazu Sugiyama, Seiji Samukawa, Gen Hashiguchi

Makara Journal of Technology

Plasma etching, during micro-fabrication processing is indispensable for fabricating MEMS structures. During the plasma processes, two major matters, charged ions and vacuum–ultraviolet (VUV) irradiation damage, take charge of reliability degradation. The charged ions induce unwanted sidewall etching, generally called as “notching”, which causes degradation in brittle strength. Furthermore, the VUV irradiation gives rise to crystal defects on the etching surface. To overcome the problem, neutral beam etching (NBE), which use neutral particles without the VUV irradiation, has been developed. In order to evaluate the effect of the NBE quantitatively, we measured the resonance property of a micro-cantilever before and after …

Observation Of Photovoltaic Effect And Single-Photon Detection In Nanowire Silicon Pn-Junction, Arief Udhiarto, Sri Purwiyanti, Daniel Moraru, Takeshi Mizuno, Michiharu Tabe

Makara Journal of Technology

We study nanowire silicon pin and pn-junctions at room and low temperature. Photovoltaic effects are observed for both devices at room temperature. At low temperature, nanowire pn-junction devices show their ability to detect single photon. This ability was not been observed for pin devices. Phosphorus-boron dopant cluster in the depletion region is considered to have the main role for single-photon detection capability. Fundamental mechanism of dopant-based single-photon detection in nanowire pn-junction is described in details.

Improvement In Performance Of Zno Based Dsc Prepared By Spraying Method, Rangga Winantyo, Devinda Liyanage, Kenji Murakami

Makara Journal of Technology

This paper reports the effect of TiCl4 on the performance of ZnO based DSC. ZnO was used due to its stability against photo-corrosion and photochemical properties similar to TiO2. Thin films of nanocrystalline ZnO were deposited on transparent conducting oxide glass using spray method. The ZnO films were treated using TiCl4. The cell’s efficiency was found to be 2.5% with TiCl4 post-treatment and 1.9% without TiCl4 post-treatment.

Influences Of Surface Morphology Of Nanostructured Rutile Tio2 Nanorods/Nanoflowers As Photoelectrode On The Performance Of Dye-Sensitized Solar Cell, Mohd Khairul Bin Ahmad, Kenji Murakami

Makara Journal of Technology

Aligned Rutile TiO2 nanorods (r-TNRs) and TiO2 nanoflowers (r-TNFs) were successfully prepared by hydrothermal method. Using hydrochloric acid (HCl) as chelating agent and titanium butoxide (TBOT) as precursor, aligned r-TNRs with r-TNFs were successfully growth onto fluorine-doped tin oxide (FTO) with different morphologies. The influences of surface morphologies to the rutile based Dye-sensitized solar cell (DSC) efficiency are discussed. The highest lightto- electric energy conversion efficiency, 1.80% is achieved using different concentration under simulated solar light illumination of 100 mWcm-2 (1.5 AM).

Fatigue Life Prediction Of The Keel Structure Of A Tsunami Buoy Using Spectral Fatigue Analysis Method, Angga Yustiawan, Ketut Suastika, Wibowo Harso Nugroho

Makara Journal of Technology

One of the components of the Indonesia Tsunami Early Warning System (InaTEWS) is a surface buoy. The surface buoy is exposed to dynamic and random loadings while operating at sea, particularly due to waves. Because of the cyclic nature of the wave load, this may result in a fatigue damage of the keel structure, which connects the mooring line with the buoy hull. The operating location of the buoy is off the Java South Coast at the coordinate (10.3998 S, 108.3417 E). To determine the stress transfer function, model tests were performed, measuring the buoy motions and the stress at …

Production Optimization For Plan Of Gas Field Development Using Marginal Cost Analysis, Suprapto Soemardan, Widodo Wahyu Purwanto, Arsegianto Arsegianto

Makara Journal of Technology

Gas production rate is one of the most important variables affecting the feasibility plan of gas field development. It take into account reservoir characteristics, gas reserves, number of wells, production facilities, government take and market conditions. In this research, a mathematical model of gas production optimization has been developed using marginal cost analysis in determining the optimum gas production rate for economic profit, by employing the case study of Matindok Field. The results show that the optimum gas production rate is mainly affected by gas price duration and time of gas delivery. When the price of gas increases, the optimum …

Aspen Plus Simulation Of Biomass Gasification In A Steam Blown Dual Fluidised Bed, Wayne Doherty, Anthony Reynolds, David Kennedy

Book/Book Chapters

The efficient utilisation of biomass resources is of utmost importance. Biomass gasification offers much higher efficiencies than combustion. Gasification is a process in which a fuel is converted to a combustible gas (syngas). A dual fluidised bed gasifier known as the fast internally circulating fluidised bed (FICFB) was selected. It has been demonstrated at industrial scale and data is readily available for model validation. An Aspen Plus model was developed to simulate the FICFB gasifier. The model is based on Gibbs free energy minimisation and the restricted equilibrium method was used to calibrate it. The model has been validated and …

Ramjet Combustion Chamber, Paul Cameron Stone

Aerospace Engineering

A ramjet combustion chamber is designed and some initial assembly fabrication and test completed as a component of a ramjet graduate project for California Polytechnic State University, San Luis Obispo Supersonic Wind Tunnel. The combustor design is driven by a theoretical model created by a Cal Poly graduate student, Harrison Sykes. Temperature, pressure, and fuel flow will be measured.

Analysis Of Hole Lifetime In Soi Mosfet Single-Photon Detector, Dedy Septono Catur Putranto, Wei Du, Hiroaki Satoh, Atsushi Ono, Purnomo Sidi Priambodo, Djoko Hartanto, Hiroshi Inokawa

Makara Journal of Technology

Hole lifetime in the silicon-on-insulator (SOI) metal-oxide-semiconductor field-effect transistor (MOSFET) singlephoton detector was evaluated by the analysis of drain current histograms for different light intensities and substrate voltages. It was found that the peaks in the histogram corresponding to the larger number of stored holes grew as the gate bias decreased. This was attributed not to the increased light absorption efficiency or collection efficiency of the photo-generated holes, but to the prolonged hole lifetime presumably caused by the higher transverse electric field inside the body of SOI MOSFET.

Biodiesel Reactor Design With Glycerol Separation To Increase Biodiesel Production Yield, Budy Rahmat, Imas Siti Setiasih, Roni Kastaman

Makara Journal of Technology

The study consisted of reactor design used for transesterification process, effect of glycerol separation on transesterification reaction, determination of biodiesel quality, and mass balance analysis. The reactor was designed by integrating circulated pump/stirrer, static mixer, and sprayer that intensify the reaction in the outer tank reactor. The objective was to reduce the use of methanol in excess and to shorten the processing time. The results showed that the reactor that applied the glycerol separation was able to compensate for the decreased use of the reactant methanol from 6:1 to 5:1 molar ratio, and changed the mass balance in the product, …

Development Of Seebeck-Coefficient Measurement Systems Using Kelvin-Probe Force Microscopy, Kazutoshi Miwa, Faiz Salleh, Hiroya Ikeda

Makara Journal of Technology

Thermoelectric device is investigated by a number of researchers in order to enhance the thermoelectric efficiency. It is known that the efficiency can be improved by quantum effect. However, it is difficult to measure the thermoelectric characteristics of nanometer-scale structures. Thus a new measurement method is expected to be developed. We propose to apply Kelvin-probe force microscopy (KFM) to characterization of thermoelectric materials. KFM can locally observe surface potential of Fermi energy of a sample without touching the sample surface. In the present paper, we estimate the Seebeck coefficient of thin Si-on-insulator layers using KFM.